The experimental study on the performance,combustion and emission characteristics of a diesel engine using diesel – biodiesel – diethyl ether blends

ABSTRACT

In the present research work, the experimental analysis has been executed to investigate the influence of diethyl ether as an oxygenated additive to the diesel-biodiesel blend on the performance, combustion and emission characteristics of a diesel engine. The biodiesel (Frying oil methyl ester) was prepared by the transesterification process, and the biodiesel was added (40% by volume) to the diesel fuel to prepare the diesel-biodiesel blend (D60FME40). The diethyl ether was added to the diesel-biodiesel blends D60FM35 (diesel 60% + biodiesel 35% by volume) and D60FM30 (diesel 60% + biodiesel 30% by volume) with suitable volume proportions of 5% and 10% respectively to form diesel-biodiesel-diethyl ether blends ((D60FM35DEE5) & (D60FM30DEE10)). Initially, the test was conducted with diesel fuel to obtain the baseline reference reading. Then, the reading was compared with results taken from the engine using a diesel-biodiesel blend (D60FME40) and diethyl ether blends (D60FM35DEE5) & (D60FM30DEE10). The results reveal that the maximum brake thermal efficiency was obtained with diesel fuel and it was higher than the diesel-biodiesel blend and diethyl ether blends. The peak in-cylinder gas pressure and heat release rate in the premixed stage was less for the diesel-biodiesel blend, but it was increased with the addition of diethyl ether to the blend. The diesel-biodiesel-diethyl ether blends show less carbon monoxide and hydrocarbon emissions except for NO_X emission as compared to the diesel and diesel-biodiesel blend, especially at the engine rated power.     

共轨柴油机燃用不同配比生物柴油的性能与排放特性

对某共轨柴油机燃用石化柴油、生物柴油及其混合燃料的动力性、经济性和排放特性进行了研究.在未对原机做任何改动的情况下,分别燃用了0%、5%、10%、20%和100%的5种不同体积配比的餐饮废油制生物柴油与石化柴油的混合燃料,分析比较了不同生物柴油配比对发动机功率、燃油消耗率,以及CO、HC、NO_x和烟度排放的影响.研究表明:共轨柴油机燃用生物柴油与石化柴油混合燃料后,功率略有下降,燃油消耗率有所上升;烟度、CO和HC排放减少,且随着生物柴油掺混比例的升高而降低;NO_x排放上升,且随着生物柴油掺混比例的升高而增加.     

Impact of Carbon Nanotubes and Di-Ethyl Ether as additives with biodiesel emulsion fuels in a diesel engine – An experimental investigation

In the current global energy scenario, fossil fuels face challenges with regards to exorbitant demand, environmental hazards and escalating costs. In this regard, the technical community is in quest for alternative resources. In this context, biodiesel fuel is potentially considered as alternative fuels for compression ignition engines. Hence, in this current investigation, biodiesel and biodiesel emulsions are prepared from a vegetable oil and further subjected for the blending with potential additives such as CNT (Carbon Nanotubes) and DEE (Di-Ethyl Ether) to improve the working attributes of the diesel engine. The entire investigation was carried out in five stages. In the first stage, both pure diesel and biodiesel (derived from jatropha oil) fuels were tested in the diesel engine to obtain baseline readings. In the second stage, water–biodiesel emulsion fuel was prepared in the proportion of 91% of biodiesel, 5% of water and 4% of emulsifiers (by volume). In the third stage, 50 ppm of CNT, 50 ml of DEE and combined mixture of CNT+DEE (50 ppm CNT+50 ml DEE) were mixed with the water–biodiesel emulsion fuel separately to prepare the CNT and DEE blended water–biodiesel emulsion fuels respectively. In fourth stage, the prepared emulsion fuels were subjected to stability investigations. In the fifth stage, all the prepared stable emulsion fuels were subjected for experimental testing in a diesel engine. It was observed that the CNT and DEE blended biodiesel emulsion fuels reflected better performance, emission and combustion attributes than that of pure diesel and biodiesel. At the full load, the brake thermal efficiency, NO and smoke emission of CNT+DEE fuels was 28.8%, 895 ppm and 36%, whereas it was 25.2%, 1340 ppm and 71% for pure diesel respectively. It was also observed that on adding CNT and DEE with the biodiesel emulsion fuels, the ignition delay was shortened and henceforth, the additive blended biodiesel emulsion fuels exhibited higher brake thermal efficiency and reduced emissions (NO, smoke) than that of pure diesel and biodiesel.     

Combustion characteristics of CI engine fueled with WCO biodiesel/diesel blends at different compression ratios and EGR

The present study investigated the effect of compression ratio (CR) with the use of exhaust gas recirculation (EGR) technology on the performance of combustion characteristics at different CRs and engine loads; the brake thermal efficiency (BTE), specific fuel consumption (SFC), volumetric efficiency (VOL.EFF), exhaust gas temperature, carbon dioxide emission (CO₂), hydrocarbons (HC), nitrogen oxides (NOx), and oxygen content (O₂). The single-cylinder, four-stroke compression ignition engine was run on a mixture of diesel and biodiesel prepared from Iraqi waste cooking oil at (B0, B10, B20, and B30). A comparison has been achieved for these combustion characteristics at different blends, load, and CRs (14.5, 15.5, and 16.5) at 1500 rpm constant engine speed. The transesterification process is used to produce biodiesel and ASTM standards have been used to determine the physical and chemical properties of biodiesel and compare them to net diesel fuel. The preliminary conducting tests indicated that engine performance and emissions improved with the B20 mixture. Experimental test results showed an increase in BTE when CR increased by 17% and SFC increased by 23%. It also found a higher VOL.EFF by 6% at higher pressure ratios. A continuous decrease in BTE values and an increase in SFC were sustained when the percentage of biodiesel in the mixture was increased. Emissions of carbon dioxide, HC, and NOx increased by 12%, 50%, and 40%, respectively, as CR reached high values. NOx increased with the addition of biodiesel to 35%, which necessitated the use of EGR technology at rates of 5% and 10%. The results indicated that the best results were obtained in the case of running the engine with a mixing ratio of B20 with the addition of 10% EGR, NOx decreased by 47% against a slight increase in other emissions.     

Assessing idling effects on a compression ignition engine fueled with Jatropha and Palm biodiesel blends

In this study, performance of a diesel engine operated with Jatropha and Palm biodiesel blends at high idling conditions has been evaluated. The result obtained from experiment elucidate that, at all idling modes HC and CO emissions of both blends decreases, however, NO_x emissions increases compared to pure diesel fuel. Jatropha biodiesel has higher viscosity compared to Palm biodiesel, which might have degraded the spray characteristics and caused slightly improper mixing which might have led to slightly incomplete combustion, thus at both idling conditions, Jatropha blends emitted higher CO and HC compared to Palm biodiesels. Compared to diesel fuel, CO emissions were 5.9–9.7%, 17.6–22.6%, 23.5–29%, 2.9–6.4%, 5.9–14.5% and 11.8–17.74% less, HC emissions were 10.3–11.5%, 24.13–30.76%, 34.5–39%, 6.9–7.7%, 26–27% and 31–35% less and NO_x emissions were 8.3–9.5%, 14–15%, 22–25%, 5–7.14%, 10–11.3% and 17–18% more respectively for 5, 10 and 20% blends of Palm and Jatropha biodiesel. Compared to diesel fuel, at high idling conditions brake specific fuel consumption all Palm and Jatropha biodiesel–diesel blends increased. Compared to diesel fuel, BSFC were 1.14–1.35%, 2.28–2.96%, 7.1–8.35%, 2.28–2.69%, 3.98–5.39% and 8.83–9.29% more respectively for 5, 10 and 20% blends of Palm and Jatropha biodiesel.     

Exhaust emission study on neat biodiesel and alcohol blends fueled diesel engine

In this study, neat biodiesel with octanol additive was employed in a diesel engine and its effects on engine emission were studied. The five fuels evaluated were neat palm kernal oil biodiesel, octanol blended with biodiesel by 10%, 20%, and 30% volume, and diesel. All the emissions are reduced by the addition of octanol in biodiesel in all loads owing to the higher oxygen concentration of air/fuel mixtures and improved atomization. Hence, it is concluded that the neat biodiesel and octanol blends can be employed as an alternative fuel for existing unmodified diesel engines owing to its lesser emission characteristics.     

基于不同原料生物柴油混合燃料的发动机性能研究

对一台TDI柴油机燃用花椒籽、棉籽、棕榈和餐饮废油脂4种不同原料制成的生物柴油(以10%体积比分别与柴油混合制成)的动力性、经济性和排放特性进行了试验研究,探讨了4种生物柴油对发动机性能的影响。研究结果表明:在燃用4种生物柴油时,棕榈油制生物柴油的功率和纯柴油基本一致,其余混合燃料的功率都比纯柴油略有下降;4种混合燃料的油耗与纯柴油基本一致;与纯柴油相比,生物柴油混合燃料的碳烟、CO、HC排放均较低,而NOx排放略高。     

A study on the performance and emission of a diesel engine fueled with Jatropha biodiesel oil and its blends

Biodiesel either in neat form or as a mixture with diesel fuel is widely investigated to solve the twin problem of depletion of fossil fuels and environmental degradation. The main objective of the present study is to compare performance, emission and combustion characteristics of biodiesel derived from non edible Jatropha oil in a dual fuel diesel engine with base line results of diesel fuel. The performance parameters evaluated were: brake thermal efficiency, brake specific fuel consumption, power output. As a part of combustion study, in-cylinder pressure, rate of pressure rise and heat release rates were evaluated. The emission parameters such as carbon monoxide, carbon dioxide, un-burnt hydrocarbon, oxides of nitrogen and smoke opacity with the different fuels were also measured and compared with base line results. The different properties of Jatropha oil after transestrification were within acceptable limits of standards as set by many countries. The brake thermal efficiency of Jatropha methyl ester and its blends with diesel were lower than diesel and brake specific energy consumption was found to be higher. However, HC, CO and CO₂ and smoke were found to be lower with Jatropha biodiesel fuel. NO_x emissions on Jatropha biodiesel and its blend were higher than Diesel. The results from the experiments suggest that biodiesel derived from non edible oil like Jatropha could be a good substitute to diesel fuel in diesel engine in the near future as far as decentralized energy production is concerned. In view of comparable engine performance and reduction in most of the engine emissions, it can be concluded and biodiesel derived from Jatropha and its blends could be used in a conventional diesel engine without any modification.     

柴油机燃用乙醇-生物柴油的性能试验研究

对乙醇和生物柴油的互溶性和抗水性进行了研究,在ZS195型柴油机上进行了燃用生物柴油、乙醇-生物柴油、含水乙醇-生物柴油与纯柴油的经济性与排放特性对比试验研究。试验结果表明:B90E10和B90A10混合燃料能在20℃环境温度下保持良好的物理稳定性;B90E10,B90A10和生物柴油有效燃油消耗率高于纯柴油;CO排放量,在小负荷时趋于纯柴油的排放水平,大负荷时下降;生物柴油NOx排放量在小负荷时高于纯柴油水平,而B90E10和B90A10较生物柴油依次下降,其中B90A10的NOx排放量低于纯柴油水平,大负荷时3种燃料的NOx排放量接近,均高于纯柴油水平;THC排放量均低于纯柴油水平,其中生物柴油下降幅度最大,B90E10下降幅度最小;碳烟排放较纯柴油大幅度下降,且随着燃料中含氧量的增加依次下降。     

Performance,emission and combustion characteristic of a multicylinder DI diesel engine running on diesel–ethanol–biodiesel blends of high ethanol content

Feasibility of using high percentage of ethanol in diesel–ethanol blends, with biodiesel as a co-solvent and properties enhancer has been investigated. The blends tested are D70/E20/B10 (blend A), D50/E30/B20 (blend B) D50/E40/B10 (blend C), and Diesel (D100). The blends are prepared to get maximum percentage of oxygen content but keeping important properties such as density, viscosity and Cetane index within acceptable limits. Experiments are conducted on a multicylinder, DI diesel engine, whose original injection timing was 13° CA BTDC. The engine did not run on blends B and C at this injection timing and it was required to advance timing to 18° and 21° CA BTDC to enable the use of blends B and C respectively. However advancing injection timing almost doubled the NO emissions and increased peak firing pressure. The P–θ and net heat release diagrams shows that the combustion process of these blends delayed at low loads but approaches to the diesel fuel at high loads. The comparison of blend results with baseline diesel showed that brake specific fuel consumption increased considerably, thermal efficiency improved slightly, smoke opacity reduced remarkably at high loads. NO variation depends on operating conditions while CO emissions drastically increased at low loads. Blend B which replaced 50% diesel and having oxygen content up to 12.21% by weight has given satisfactory performance for steady state running mode up to 1600 RPM however, it does not showed any benefit on peak smoke emission during free acceleration test.     

Properties and use of jatropha curcas oil and diesel fuel blends in compression ignition engine

In the present investigation the high viscosity of the jatropha curcas oil which has been considered as a potential alternative fuel for the compression ignition (C.I.) engine was decreased by blending with diesel. The blends of varying proportions of jatropha curcas oil and diesel were prepared, analyzed and compared with diesel fuel. The effect of temperature on the viscosity of biodiesel and jatropha oil was also studied. The performance of the engine using blends and jatropha oil was evaluated in a single cylinder C.I. engine and compared with the performance obtained with diesel. Significant improvement in engine performance was observed compared to vegetable oil alone. The specific fuel consumption and the exhaust gas temperature were reduced due to decrease in viscosity of the vegetable oil. Acceptable thermal efficiencies of the engine were obtained with blends containing up to 50% volume of jatropha oil. From the properties and engine test results it has been established that 40–50% of jatropha oil can be substituted for diesel without any engine modification and preheating of the blends.     

非直喷式增压柴油机燃用生物柴油的性能与排放特性

研究了非直喷式增压柴油机燃用柴油一生物柴油混合燃料的性能和排放特性。未对原机作任何调整和改动,研究了不同生物柴油掺混比例的混合燃料对功率、油耗、烟度和NOx排放的影响。结果表明：非直喷式柴油机燃用生物柴油后柴油机功率略有下降,油耗有所上升,烟度大幅下降,NOx排放增加明显。油耗、烟度和NOx的变化均与生物柴油掺混比例呈线性关系,合适的生物柴油掺混比例即可以保持柴油机的性能,又可有效地降低碳烟排放,且不引起NOx排放的显著变化。对于该增压柴油机,掺混生物柴油对外特性下的排放影响最大,影响最小的为标定转速下的负荷特性。不论是全负荷还是部分负荷,燃用生物柴油时低速下的烟度降低和NOx上升幅度均比高速时大,而同转速下高负荷时烟度降低和NOx上升更为明显。     

Emission analysis on compression ignition engine fueled with lower concentrations of Pithecellobium dulce biodiesel‐diesel blends

The present study investigates the effect of Pithecellobium dulce biodiesel (PDBD) blends with diesel fuel on compression ignition (CI) engine emissions. Initially, PDBD was prepared by using a base transesteri?cation process. The GC‐MS, ¹H NMR, and Fourier transform infrared characterization of PDBD was carried out, and fuel properties were determined. The experiments were conducted on a single cylinder, CI engine using three blended fuels: PDBD5 (5% biodiesel and 95% diesel), PDBD10 (10% biodiesel and 90% diesel), and PDBD20 (20% biodiesel and 80% diesel). The experimental outcomes revealed that 20% of PDBD reduces 19.64% carbon monoxide, 17.64% hydrocarbon, and 6.73% oxides of nitrogen emissions. Furthermore, from this study, it was inferred that the PDBD20 blend could be used as an alternative fuel for CI engines with no modi?cations in engine design.     

Biodiesel fuel in diesel micro-turbine engines: Modelling and experimental evaluation

Many performance and emission tests have been carried out in reciprocating diesel engines that use biodiesel fuel over the past years and very few in gas turbine engines. This work aims at assessing the thermal performance and emissions at full and partial loads of a 30 kW diesel micro-turbine engine fed with diesel, biodiesel and their blends as fuel. A cycle simulation was performed using the Gate Cycle GE Enter software to evaluate the thermal performance of the 30 kW micro-turbine engine. Performance and emission tests were carried out on a 30 kW diesel micro-turbine engine installed in the NEST laboratories of the Federal University of Itajubá, and the performance results were compared with those of the simulation. There was a good agreement between the simulations and the experimental results from the full load down to about 50% of the load for diesel, biodiesel and their blends. The biodiesel and its blends used as fuel in micro-turbines led to no significant changes in the engine performance and behaviour compared to diesel fuel. The exhaust emissions were evaluated for pure biodiesel and its blends and conventional diesel. The results revealed that the use of biodiesel resulted in a slightly higher CO, lower NO_x and no SO₂ emissions.     

Effect of an emission-reducing soluble hybrid nanocatalyst in diesel/biodiesel blends on exergetic performance of a DI diesel engine

The present study was set to explore the effect of a novel soluble hybrid nanocatalyst in diesel/biodiesel fuel blends on exergetic performance parameters of a DI diesel engine. Experiments were carried out using two types of diesel/biodiesel blends (i.e., B5 and B20) at four concentrations (0, 30, 60 and 90 ppm) of the hybrid nanocatalyst, i.e., cerium oxide immobilized on amide-functionalized multiwall carbon nanotubes (MWCNT). Furthermore, the exergy analysis was performed at five different loads and two engine speeds. The results obtained revealed that the exergetic parameters were profoundly influenced by engine speed and load. In general, increasing engine speed and load increased the magnitude of the destructed exergy. Moreover, the exergy efficiency increased by increasing engine load, while it decreased by elevating engine speed. However, the applied fuel blends had approximately similar exergetic efficiency and sustainability index. Interestingly, a remarkable reduction in emissions was obtained by incorporating the soluble catalyst nanoparticles to the diesel/biodiesel blends. Thus, it could be concluded that the diesel/biodiesel blends containing amide-functionalized MWCNTs-CeO₂ catalyst might substitute the use of pure diesel fuel without any unfavorable change in the exergetic performance parameters of the DI engines.     

Theoretical modeling and experimental studies on biodiesel-fueled engine

In recent years, much research has been carried out to find suitable alternative fuel to petroleum products. The use of renewable fuels like ethanol, biogas and biodiesel in diesel engines is significant in this context. The properties of biodiesel depend on the type of the vegetable oil used for the trans-esterification process. Experimental analysis of the engine with various biodiesel and its blends requires much effort and time. Hence, a theoretical model is developed to analyze the performance characteristics of the compression ignition engine fueled by biodiesel and its blends. In the present investigation, biodiesel is produced using unrefined rubber seed oil. A two-step trans-esterification process (i.e. acid–alkaline trans-esterification) is developed for the production of methyl-esters of rubber seed oil. The properties of this biodiesel are closely matched with those of diesel fuel. The performance tests are carried out on a C.I. engine using biodiesel and its blends with diesel (B20 and B100) as fuel. The effects of relative air-fuel ratio and compression ratio on the engine performance for different fuels are also analyzed using this model. The comparison of theoretical and experimental results are presented.     

Performance, emission and combustion characteristics of biodiesel fuelled variable compression ratio engine

Experiments has been carried out to estimate the performance, emission and combustion characteristics of a single cylinder; four stroke variable compression ratio multi fuel engine fuelled with waste cooking oil methyl ester and its blends with standard diesel. Tests has been conducted using the fuel blends of 20%, 40%, 60% and 80% biodiesel with standard diesel, with an engine speed of 1500 rpm, fixed compression ratio 21 and at different loading conditions. The performance parameters elucidated includes brake thermal efficiency, specific fuel consumption, brake power, indicated mean effective pressure, mechanical efficiency and exhaust gas temperature. The exhaust gas emission is found to contain carbon monoxide, hydrocarbon, nitrogen oxides and carbon dioxide. The results of the experiment has been compared and analyzed with standard diesel and it confirms considerable improvement in the performance parameters as well as exhaust emissions. The blends when used as fuel results in the reduction of carbon monoxide, hydrocarbon, carbon dioxide at the expense of nitrogen oxides emissions. It has found that the combustion characteristics of waste cooking oil methyl ester and its diesel blends closely followed those of standard diesel.     

Performance and emission study on the effect of oxygenated additive in neat biodiesel fueled diesel engine

This work presents the effect of the Di-tetra-butyl-peroxide (DTBP) as an oxygenated additive on neat used mustard oil biodiesel (B100) to evaluate the emission and performance engine characteristics. Four fuels, namely, diesel, biodiesel (Mustard biodiesel), a blend of B100-10percentage, and 20% by volume of DTBP (BD90DTBP10 and BD80DTBP20) are prepared and tested on a single cylinder, constant speed diesel engine. Experimental outcomes revealed that 20% of DTBP reduces 7.3% CO, 5.1% HC, and 4.6% NOx and 3.2% smoke emissions of B100. From this study, further, it is inferred that BD80DTBP20 blend could be utilized as an alternative fuel for a CI engine with no modifications in engine design.     

Biodiesel production from inedible animal tallow and an experimental investigation of its use as alternative fuel in a direct injection diesel engine

In this study, a substitute fuel for diesel engines was produced from inedible animal tallow and its usability was investigated as pure biodiesel and its blends with petroleum diesel fuel in a diesel engine. Tallow methyl ester as biodiesel fuel was prepared by base-catalyzed transesterification of the fat with methanol in the presence of NaOH as catalyst. Fuel properties of methyl ester, diesel fuel and blends of them (5%, 20% and 50% by volume) were determined. Viscosity and density of fatty acid methyl ester have been found to meet ASTM D6751 and EN 14214 specifications. Viscosity and density of tallow methyl esters are found to be very close to that of diesel. The calorific value of biodiesel is found to be slightly lower than that of diesel. An experimental study was carried out in order to investigate of its usability as alternative fuel of tallow methyl ester in a direct injection diesel engine. It was observed that the addition of biodiesel to the diesel fuel decreases the effective efficiency of engine and increases the specific fuel consumption. This is due to the lower heating value of biodiesel compared to diesel fuel. However, the effective engine power was comparable by biodiesel compared with diesel fuel. Emissions of carbon monoxide (CO), oxides of nitrogen (NO_x), sulphur dioxide (SO₂) and smoke opacity were reduced around 15%, 38.5%, 72.7% and 56.8%, respectively, in case of tallow methyl esters (B100) compared to diesel fuel. Besides, the lowest CO, NO_x emissions and the highest exhaust temperature were obtained for B20 among all other fuels. The reductions in exhaust emissions made tallow methyl esters and its blends, especially B20 a suitable alternative fuel for diesel and thus could help in controlling air pollution. Based on this study, animal tallow methyl esters and its blends with petroleum diesel fuel can be used a substitute for diesel in direct injection diesel engines without any engine modification.     

Effects of oxyhydrogen on the CI engine fueled with the biodiesel blends: A performance,combustion and emission characteristics study

The main purpose of this study is to analyse the effects of oxy hydrogen (HHO) along with the Moringa oleifera biodiesel blend on engine performance, combustion and emission characteristics. HHO gases were generated using the typical electrolysis process using the potassium hydroxide solution. The experiments were performed under various engine loads of 25%, 50%, 75%, and 100% in a constant speed engine. Biodiesel from the M. oleifera was prepared by the transesterification process. Further, the procured biodiesel blends mixed with neat diesel at the concentration of 20% (B20) and 40% (B40). In addition to above, the HHO gas flow rate to the engine chamber maintained at the flow rate of 0.5 L^-1. The use of the 20% and 40% blends with HHO reported less BTE compared to the neat diesel. However, B20 reported marginal rise in the BTE due to the addition of the HHO gas. On the other hand, addition of HHO gas to the blends significantly dropped the brake specific fuel consumption. With regard to the emissions, addition of the biodiesel blends reduced the concentration of the CO, HC, and CO₂. Nevertheless, no reduction reported in the formation of the NO. However, adding the HHO to the biodiesel reduced the average NOx by 6%, which is a substantial effect. Overall, HHO enriching biodiesel blends are the potential replacement for the existing fossil fuels for its superior fuel properties compared to the conventional diesel.