Current reconstruction from magnetic field using spherical harmonic expansion to reduce impact of disturbance fields

A current reconstruction method, for determining currents in a set of parallel infinitely long conductors located above the ground from measured magnetic field, is developed. The method is designed to work even if three-dimensional external disturbance fields from external sources are present. The external field is written as an expansion in spherical harmonics. Therefore, the field in the different measurement points is regarded as a linear combination of the expansion coefficients and the currents to be determined. A linear equation system is formed with the currents and the expansion coefficients as the unknowns. The currents are reconstructed by solving the equation system using least squares method and Tikhonov regularization. If the characteristics of the ground below the conductors are known with sufficient precision, the ground effect can also be included into the model. Results of various simulations show that the method works well and noise in the measured magnetic field can be handled.     

Change in reaction pathway of nickel(II) complex induced by magnetic fields

Three identical hydrothermal self-assembly reactions in a mixture of nickel nitrate hexahydrate, nicotinic acid, sodium azide were carried out with the applied magnetic fields of 0, 0.15, 0.3 T, respectively. It was found that [Ni_1.5(N₃)(nic)₂(Hnic)]_n can be obtained at 160 °C for 48 h without an applied magnetic field, while the final product totally changed into [Ni₂(nic)₄(H₂O)] as a 0.3 T weak magnetic field was employed in the reaction. Both of the two products show three-dimensional frameworks, however, they display two different coordination geometries with different ligands. We consider the mechanism base on changes of magnetic susceptibilities and structures of [Ni₂(nic)₄(H₂O)], and propose a view that the magnetic field can reduce the activation energy of reaction pathways according to transition state theory. The possible reason of the decrease of activation energy is that a magnetic field can mediate coupling among the Ni²⁺ ions during the formation of [Ni₂(nic)₄(H₂O)], which is indicated by the slight changes of microstructure of crystal, such as bond angle and length.     

Assessment of occupational exposure to magnetic fields in high-voltage substations (154/34.5 kV)

This work proposes the survey of magnetic field measurements taken in 154/31.5 kV substations in the city of Antalya for occupational exposure assessment. For measurements, three substations have been taken into account, where four occupants are present for each 8 h of shift, which means 12 occupants are present during the day. Operator desks at three different substations read a lowest magnetic field of 0.3 microT at minimum loaded season and reached up to 1 microT at maximum loaded season, which means operators exposed to a magnetic field of > or = 0.3 microT 8 h d(-1). In switch gear regions, maximum magnetic field reading is 23 microT at minimum loaded season and reached up to 70 microT. Outdoor magnetic field measurement at circuit breaker region goes up to 62 microT with respect to operator heights.     

Apparatus for calorimetric measurements of losses in MgB2 superconductors exposed to alternating currents and external magnetic fields

Inexpensive superconducting wires with low AC losses would open up for a large superconductor market in AC electrical power applications. One candidate for this market is the MgB₂ conductor. In the development of an AC optimized superconductor, high-quality measurements of the AC losses under application-like conditions must be available. This article describes an apparatus built for this purpose. The measurement method is calorimetric. The temperature increase of the superconductor sample is measured and compared to the temperature increase due to a heater with known heat input. The system is designed for measurements of losses due to magnetic fields combined with transport currents. Results from tests verifying the capabilities of the system are given, as well as from initial AC loss measurements on a tape-shaped MgB₂ superconductor.     

Use of ultra-thin aluminum oxide layer to reduce photoluminescence decay in poly(p-phenylene vinylene) films

The degradation of conjugated polymer poly(p-phenylene vinylene) (PPV) in the atmosphere upon exposure to ultraviolet light limits its applications as the emitting layer in organic light emitting diodes. In this paper we show that a thin layer of aluminum oxide around 10 nm in thickness prevents photoluminescence degradation of PPV during exposure to blue light in the atmosphere but not at lower excitation wavelengths. This oxide film is free of cracks and pinholes from transmission electron microscopy analysis.     

Construction of monoenergetic neutron calibration fields using 45Sc(p, n)45Ti reaction at JAEA

The 8 and 27 keV monoenergetic neutron calibration fields have been developed by using (45)Sc(p, n)(45)Ti reaction. Protons from a 4-MV Pelletron accelerator are used to bombard a thin scandium target evaporated onto a platinum disc. The proton energies are finely adjusted to the resonance to generate the 8 and 27 keV neutrons by applying a high voltage to the target assemblies. The neutron energies were measured using the time-of-flight method with a lithium glass scintillation detector. The neutron fluences at a calibration point located at 50 cm from the target were evaluated using Bonner spheres. A long counter was placed at 2.2 m from the target and at 60 degrees to the direction of the proton beam in order to monitor the fluence at the calibration point. Fluence and dose equivalent rates at the calibration point are sufficient to calibrate many types of the neutron survey metres.     

Electrogenerated chemiluminescence. 83. Immunoassay of human C-reactive protein by using Ru(bpy)3(2+)-encapsulated liposomes as labels

Liposomes ( approximately 100-nm diameter) containing Ru(bpy)32+ (bpy = 2,2'-bipyridine) were prepared as an electrogenerated chemiluminescent (ECL) tag for a sandwich-type immunoassay of human C-reactive protein (CRP). Polyclonal human CRP antibodies were introduced onto liposomes and magnetic beads through biotin-streptavidin interaction. The antigen-antibody conjugates formed on addition of a CRP-containing sample were separated from unreacted species magnetically. Addition of 0.1 M tri-n-propylamine and 0.1 M phosphate buffer (pH 7.6) containing 0.1 M NaCl and 1% (v/v) Triton X-100 caused liberation of the Ru(bpy)32+ from the liposome. ECL obtained in this medium showed a detection limit of 100 ng/mL for human CRP with good linearity of ECL intensity versus antigen concentration over the range 100 ng/mL-10 microg/mL.     

Use of a laser as light source for an interference study of temperature and concentration fields in liquids

The advantages of using a laser as a light source in an IAB-451 shadow instrument, used as a two-beam diffraction interferometer for studying temperature and studying temperature and concentration fields in liquids, are reported.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 16, No. 1.pp. 136–139, January, 1969.     

Use of a clustering reaction to detect low levels of moisture in bulk oxygen using an atmospheric pressure ionization mass spectrometer

Atmospheric pressure ionization mass spectrometry (APIMS) is being routinely used to quantify trace impurities in bulk gases used in the manufacture of semiconductor devices. APIMS has been successfully applied for the quantification of ppt levels of O(2), H(2)O, CO(2), and CH(4) in Ar, N(2), and He. However, it has not been successfully used to quantify trace impurities in bulk O(2) due to the low ionization potential of O(2). APIMS relies on charge-transfer reaction between the ions of the bulk gas molecules and impurity molecules. Since all the relevant impurity molecules have ionization potentials higher than that of O(2), APIMS has not been used to analyze for impurities in O(2). We report here the detection of sub-ppb levels of H(2)O in O(2) by making use of the clustering reaction between O(2)(+) and H(2)O. The declustering region in an APIMS, which is normally used to break apart unwanted and interfering clusters, has to be carefully adjusted to keep intact the weakly bound cluster O(2)(+)·H(2)O. Our results indicate a statistical detection limit of less than 300 ppt for the detection of H(2)O in O(2).     

Catalytic effect of nanogold on Cu(II)-N2H4 reaction and its application to resonance scattering immunoassay

In the medium of EDTA-NaOH, nanogold strongly catalyzed the slow reaction between hydrazine (N2H4) and Cu(II) to form Cu particles, which exhibited a strong resonance scattering (RS) peak at 602 nm. The increased RS intensity at 602 nm (DeltaI(RS)) was linear to the nanogold concentration in the range of 0.008-2.64 nM, with a detection limit of 1.0 pM Au. The rate equation obtained by the initial rate procedure was V(Cu) = K(Cu)[C(Cu(II))](2)C(OH)(1)C(Au)(1)C(N2)H4(1), with an apparent activation energy of 38 kJ x mol(-1), and the catalytic reaction mechanism was also discussed. An immunonanogold-catalytic resonance scattering spectral (RSS) assay was established for detection of microalbumin (Malb), using 10 nm nanogold to label goat antihuman Malb to obtain an immunonanogold probe (AuMalb) for Malb. In pH 5.0 citric acid-Na2HPO4 buffer solution, the AuMalb aggregated nonspecifically. Upon addition of Malb, it reacted with the probe to form dispersive AuMalb-Malb immunocomplex in the solution. After centrifugation, the supernatant containing AuMalb-Malb was obtained, and exhibited a catalytic effect on the reaction of N2H4-Cu(II) to produce large Cu particles that resulted in the I(602 nm) increasing. The increased RS intensity at 602 nm (DeltaI(602 nm)) was linear to Malb concentration (C(Malb)) in the range of 0.4 to 460 pg x mL(-1), with the regression equation of DeltaI(602 nm) = 0.3713 C(Malb) + 7.2, correlation coefficient of 0.9981 and detection limit of 0.1 pg x mL(-1) Malb. The proposed method was applied to detect Malb in healthy human urine samples, with satisfactory results.     

Design of an energy storage flywheel system using permanent magnet bearing (PMB) and superconducting magnetic bearing (SMB)

We propose a new energy storage flywheel system using a superconducting magnetic bearing (SMB) and a permanent magnet bearing (PMB). The superconducting magnetic bearing (SMB) suppresses the vibrations of the flywheel rotor. And the permanent magnet bearing (PMB) passively controls the rotor position. The energy storage flywheel system is characterized by using the two different type magnetic bearings of permanent magnet bearing (PMB) and superconducting magnetic bearing (SMB). This paper, discusses the design of the permanent magnet bearing (PMB) and the dynamics of the new energy storage flywheel system.     

A theory of material requirements planning (MRP): an empirical methodology to reduce uncertainty in MRP systems

This paper presents a theoretical MRP? model which includes both demand and supply uncertainties from quantity and timing variations. The model suggests empirical methodologies to estimate the variances of final outputs and components for estimates of safety stock requirements to reduce uncertainty. The paper suggests methodology for safety stock estimates to alleviate demand uncertainty for trade-to-stock organizations and made-to-order organizations. The paper also suggests methodologies to estimate safety stock for the production systems to alleviate supply uncertainty.     

Chemiluminescent reaction of fluorescent organic compounds with KHSO5 using cobalt(II) as catalyst and its first application to molecular imprinting

The decomposition of peroxomonosulfate (HSO5-) has been investigated by chemiluminescence (CL). A weak CL was observed during mixing the HSO5- solution with the Co2+ solution in unbuffered conditions. An appropriate amount of fluorescent organic compounds (FOCs), such as dansyl amino acids and pyrene, was added to the KHSO5/Co2+ solution, a strong CL was recorded. A possible CL mechanism, based on studies of the fluorescence, CL, and UV-visible spectra and comparison of Co3+ oxidation ability with the SO4.- radical ion, was discussed. The CL from HSO5-/Co2+ is the emission of singlet oxygen produced from the catalytic decomposition of HSO5-. It was suggested that the decomposition of HSO5- in aqueous solution with Co2+ proceeds via one-electron transfer to yield SO4.- radical ion. The FOC was attacked by SO4.- radical ion and oxidized to decompose into small molecules. During this proceeding, CL emission was given out. The present CL system has been developed as a flow injection analysis for FOCs. The detection limits (S/N = 3) were in the concentration range 10(-9)-10(-7) M for FOCs. Oxidation decomposition and CL emission of the analytes have been used in the molecular imprinting recognition. As an initial attempt, dansyl-L-phenylalanine was used as a template molecule and methacrylic acid and 2-vinylpyridine were used as functional monomers. The network copolymer imprinted with dansyl-L-phenylalanine exhibits an affinity for the template molecule. When the flowing streams of HSO5- and Co2+ solutions mixing through the molecularly imprinted polymer particles filled the flow cell, the template molecule, dansyl-L-phenylalanine reacted with the HSO5-/Co2+ solution and CL was emitted. The dansyl-L-phenylalanine was decomposed during the CL process, and the cavities of a defined shape and an arrangement of functional groups complementary to the template in the polymer were left for the next sample analysis.     

The experimental observation and investigation of defects in glass forming substances with selenium as an example by viscosimetry in magnetic and electric fields

The effect of magnetic and electric fields influence on selenium viscosity is got. The effect dependence on temperature, field strenght and direction are investigated. Using quasidefects notion the qualitative explanation of the effect is given.     

Measurement of the magnetic fields of high-voltage substations (230 kV) in Tehran (Iran) and comparison with the ACGIH threshold limit values

Measurements were made according to IEEE standard 644-1994 at a height of 1 m above floor level. It is concluded that none of the measurements exceeded the ACGIH threshold limit value. Among all control rooms the highest measured density amount is 0.69 μT in the control room of Ozgol substation and the lowest is 0.2 μT in the post of Shahid Firouzi. The control room of Ozgol substation is located in the second floor and bus-bars are located at a short distance from the window on the east, and so the highest recorded magnetic field is measured in this control room. Among all switchgear parts the highest amount 9.15 μT is measured in Kan substation. None of the measurements exceeded the ACGIH threshold limit value.     

Remanent magnetization measurements of polymeric materials containing fullerol C60(OH)24 before and after exposure to external magnetic field

The problem of low solubility of fullerene is surpassed by its functionalization with –OH groups making a new molecule called fullerol C₆₀(OH)₂₄. Materials used in this study are synthesized by incorporating fullerol into commercial soft contact lens material Definitive74 made by Contamac, UK. Three different mass concentrations of fullerol are used: 0.003%, 0.01% and 0.015%. Hence, three materials are produced and the fourth material, the standard one, was used as a reference sample. The purpose of incorporating fullerol into polymer was to develop new materials for soft contact lenses with improved optical and mechanical characteristics. The magnetic properties of polymers change due to fullerol presence therefore the aim was to show the differences in magnetic properties of the materials before and after the exposure to four different external influences. The measurements of a remanent magnetization of these materials are done by spinner magnetometer, JR-6A.     

Pd embedded in porous carbon （Pd@CMK-3） as an active catalyst for Suzuki reactions： Accelerating mass transfer to enhance the reaction rate

Heterogeneous catalysts are promising candidates for use in organic reactions due to their advantages in separation, recovery, and environment compatibility. In this work, an active porous catalyst denoted as Pd embedded in porous carbon （Pd@CMK-3） has been prepared by a strategy involving immersion, ammonia- hydrolysis, and heating procedures. Detailed characterization of the catalyst revealed that Pd（0） and Pd（I1） species co-exist and were embedded in the matrix of the porous carbon （CMK-3）. The as-prepared catalyst has shown high activity toward Suzuki reactions. Importantly, if the reaction mixture was homogenized by two minutes of ultrasonication rather than magnetic stirring before heating, the resistance to mass transfer in the pore channels was significantly reduced. As a result, the reactions proceeded more rapidly and a four-fold increase in the turnover frequency （TOF） could be obtained. When the ultrasonication was employed throughout the entire reaction process, the conversion could also exceed 90% even without the protection of inert gas, and although the reaction temperature was lowered to 30 ℃. This work provides a method for fabricating highly active porous carbon encapsulated Pd catalysts for Suzuki reactions and proves that the problem of mass transfer in porous catalysts can be conveniently resolved by ultrasonication without any chemical modification being necessary.     

A novel pilot-scale production of fuel gas by allothermal biomass gasification using biomass micron fuel (BMF) as external heat source

A novel pilot-scale allothermal biomass gasification system integrating steam gasification, thermal cracking, and catalytic reforming aiming at fuel gas production was developed. Biomass micron fuel (BMF) was used as external heat source by combusting with air in the combustor. Biomass feedstock was gasified with steam, and then, tar in the produced gas was decomposed by thermal cracking and catalytic reforming. The waste heat of high-temperature flue gas and fuel gas was recovered and used for biomass feedstock pre-heating and steam generation, respectively. The fuel gas yield is 1.36 Nm³/kg with lower heating value of 11.61 MJ/Nm³. An overall energy analysis of the system was also investigated. The results showed that the cold gas efficiency and energy conversion efficiency in this system are 88.11 and 63.59 %, respectively. Meanwhile, combustion of BMF accounts for 25.66 % of the total energy input.