耐剥离特厚Cr—Mo轧制复合钢板

1 绪言 石油精炼设备的高温高压氢反应容器,过去采用把奥氏体不锈钢堆焊在板厚80～200mmCr—Mo钢上的堆焊复合钢。由于操作条件缘故,在母材与复合材界面有时产生因氢聚积引起的剥离裂纹。近年来随着轧制复合钢技术的发展及轧机大型化,就能用轧制复合钢来取代堆焊复合钢,这从经济上说是很有价值的。     

铁素体晶界结构对管线钢HIC敏感性的影响

摘要：铁素体作为酸性环境用管线钢的主要组织类型之一,探究其晶界结构与管线钢氢致开裂（HIC）敏感性之间关系,可为进一步优化管线钢的抗HIC性能提供指导。对热轧态管线钢进行不同工艺热处理,采用扫描电子显微镜（SEM）、电子背散射衍射（EBSD）、透射电子显微镜（TEM）观察了试样的晶界、位错结构及氢鼓泡、氢致裂纹形貌,用电化学充氢及动态充氢方法对试样的HIC敏感性及氢致塑性损失进行了测试,用电化学氢渗透及氢微印实验对试样的氢捕获效率及氢原子分布进行了观察与分析,探索了铁素体晶界结构与HIC敏感性之间内在关联。其结果表明：当材料中以小角度晶界占主导或大小角度晶界比例约为1∶1时,对氢原子的捕获效率较高,HIC敏感性也相对较大;大小角度晶界均能捕获氢原子,但与氢的作用机制不同,大角度晶界主要促进氢致裂纹萌生,而小角度晶界主要促进氢致裂纹扩展。     

308L和347L焊缝金属的氢致滞后断裂行为

奥氏体不锈钢 30 8L和 347L的焊缝金属能发生氢致滞后断裂 ,而且比 30 4L母材更敏感。用单边缺口试样动态充氢法测出的氢致滞后断裂门槛应力强度因子 KIH随可扩散氢浓度 C0 的对数而线性下降。 3种材料氢致滞后断口的形貌与 KI 以及 C0 有关 ,当 KI 较高或 C0 较小时是韧窝断口 ;当 KI 较低或 C0 较高时是脆性断口     

氢对不锈钢电渣堆焊层塑韧性的影响

模拟加氢反应器的工作条件（ｐ＝ １７．５ ＭＰａ，ｔ＝ ４５０ ℃）对００Ｃｒ２０Ｎｉ１０Ｎｂ 电渣堆焊层充氢。结果表明，充氢导致堆焊层断裂韧性值减小、塑韧性显著降低。在面弯试验中，堆焊层由于充氢后脆化而发生小角度开裂，其面弯断口呈脆性准解理形态，并有较多的二次裂纹；面弯产生的显微裂纹沿δ／γ相界分布。据此认为充氢首先使δ／γ相界面脆化。充氢后的堆焊层经６３０ ℃×４ ｈ 去氢处理可消除氢脆现象，使塑韧性恢复。     

308L和347L焊缝金属的氢致滞后断裂行为

奥氏体不锈钢３０８Ｌ和３４７Ｌ的焊缝金属能发生氢致滞后断裂,而且比３０４Ｌ母材更敏感。用单边缺口试样动态充氢法测出的氢致滞后断裂门槛应力强度因子ＫＩＨ随可扩散氢浓度ＣＯ的对数而线性下降。３种材料氢致滞后断口的形貌与ＫＩ以及ＣＯ有关,当ＫＩ较高或ＣＯ较小时是韧窝断口;当ＫＩ较低或ＣＯ较高时是脆性断口。     

探究热处理工艺对SUS301不锈钢硬度的影响

研究了热处理工艺保温的温度和时间对奥氏体不锈钢SUS301试样硬度的影响。探究试样在不同保温温度、相同保温时间下和在相同保温温度、不同的保温时间两种条件下,热处理后水冷试样硬度的变化,发现热处理温度在500℃之前,SUS301不锈钢由于在冷却过程中产生残余应力硬度会略微增加;500℃之后奥氏体不锈钢由于固溶作用,应力得以释放,硬度显著下降;热处理温度相同,增加热处理时间,SUS301不锈钢的硬度略微下降。     

非金属夹杂物对焊接氢致裂纹敏感性的影响及机理研究

本文详细研究了硫化物、氧化物等非金属夹杂物对10Ni5CrMoV低碳中合金高强度钢焊接氢致裂纹敏感性的影响及其机理。插销实验结果表明:细小弥散的非金属夹杂物明显提高焊接氢致裂纹抗力。对充氢试样的扩散氢及残余氢的测量结果得出:非金属夹杂物能作为氢的有效陷井而降低氢的表观扩散系数,提高残余氢含量。对HAZ相变行为的研究发现:细小弥散的非金属夹杂物能明显阻碍HAZ奥氏体晶粒长大,使M_s点提高,促进马氏体充分自回火,降低HAZ最高硬度。对实验结果的综合分析认为:细小弥散非金属夹杂物对低碳中合金高强度钢焊接氢致裂纹抗力的改善主要是由于这些夹杂物对HAZ相变行为产生影响的结果,而对HAZ中氢扩敌行为的影响则是次要因素。     

动态充氢电流密度对BG110S油井管力学性能的影响

利用 MTS-810材料试验机测量了BG110S油井管在动态拉伸(边充氢边拉伸)实验中的力学性能,并利用扫描电镜观察分析了拉伸断口形貌,研究了动态充氢电流密度对油井管力学性能的作用,讨论了氢原子浓度对油井管氢脆敏感性的影响。实验结果表明：随着充氢电流密度的增加,BG110S试样的屈服强度和抗拉强度先增大后减小;试样的伸长率、断面收缩率及拉伸韧性连续降低;试样的拉伸断口形貌由韧性断裂特征向脆性断裂特征转变;试样的氢脆敏感性连续增加。当动态充氢电流密度i＜30 mA/cm2时,氢原子在 BG110S试样中呈现固溶强化作用,而当i≥30 mA/cm2后,氢原子在BG110S试样中则呈现氢致脆化作用。     

不同处理状态下0.1C-5Mn中锰钢的氢脆敏感性

摘要：对热轧0.1C-5Mn中锰钢进行了3种不同的处理制度：在两相区分别进行5min(TG7样)和30min退火(TG8样),随后将一部分TG8样再500℃回火60min(TG8-500样),其余TG8样则拉伸预变形5%(TG8-5%样),然后利用电化学充氢和慢应变速率拉伸实验研究了3种试样的氢脆敏感性。结果表明,3种试样的奥氏体体积分数均约为12%,然而其氢含量和氢脆敏感性却不同,其中TG8-500样几乎不呈现氢脆敏感性,而TG7和TG8-5%样的氢脆敏感性指数分别为56%和67%。扫描电镜断口分析表明,充氢的TG7和TG8-5%样的拉伸断口呈现穿晶+沿晶的混合断裂机制,而充氢的TG8-500样则呈现韧窝韧性断裂,且存在较多的二次裂纹。3种实验钢氢脆敏感性的这种差异主要与其微观组织特征特别是原奥氏体晶界的逆转变奥氏体有关。     

数据清洗对热轧微合金钢性能预报模型的改进

摘要：对热轧0.1C-5Mn中锰钢进行了3种不同的处理制度：在两相区分别进行5min(TG7样)和30min退火(TG8样),随后将一部分TG8样再500℃回火60min(TG8-500样),其余TG8样则拉伸预变形5%(TG8-5%样),然后利用电化学充氢和慢应变速率拉伸实验研究了3种试样的氢脆敏感性。结果表明,3种试样的奥氏体体积分数均约为12%,然而其氢含量和氢脆敏感性却不同,其中TG8-500样几乎不呈现氢脆敏感性,而TG7和TG8-5%样的氢脆敏感性指数分别为56%和67%。扫描电镜断口分析表明,充氢的TG7和TG8-5%样的拉伸断口呈现穿晶+沿晶的混合断裂机制,而充氢的TG8-500样则呈现韧窝韧性断裂,且存在较多的二次裂纹。3种实验钢氢脆敏感性的这种差异主要与其微观组织特征特别是原奥氏体晶界的逆转变奥氏体有关。     

China's Major Non-ferrous Metals Imports & Exports

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Zinc Production by Province in 2014

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80% of Chinese Firms Purchasing Overseas Mines Ended up in the Red

<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic     

Copper Processing Profit Dropped Sharply,Copper Consumption Will Face Impact in the Second Half of the Year

正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field,     

Central Geological Prospecting Fund Newly Added 16.47 Million Tonnes of Bauxite in 2013

正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF     

Manufacturers of Copper Tube for Central Air Conditioner Use Face Mounting Pressure in the Final Quarter of the Year

正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure     

Xinjiang Ranks No.1 in Production of Primary Aluminum in China

正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year,     

Shenhuo Coal Industry and Electricity Power Completed800,000 t/a Aluminum Project in Xinjiang

正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform.     

Guangdong Metal Transaction Center has Become the Second Largest Precious Metal Transaction Platform Nationwide

正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness.     

Seven Rare Earth Projects Involving Close to 3 Billion Yuan Investment Landed In the HighTech Zone

正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully.