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Droplet microfluidics is likely to play a central role in the development of lab-on-a-chip technologies and as a result, significant research is directed toward this field. Understanding the spatiotemporal dynamics of discrete droplets inside microfluidic devices and the design of microfluidic devices for specific tasks are some of the dominant research topics. These works have since resulted in the development of microfluidic devices with functionalities, such as sorting, merging, synchronization, storing etc. However, the anticipated application of microfluidic devices to more complex problems will require more integrated devices that can incorporate the above functionalities on a single chip. In the current work, we present a genetic algorithm optimization-based design tool for discovering very large-scale integration of discrete microfluidic networks for a given objective function. The application of the algorithm is demonstrated through a combinatorial sequencing problem, where the objective is to achieve three different droplet combinatorial sequences for three different droplet types. Multiple fascinating, but nonobvious designs were discovered for this application. It is difficult to imagine such devices being designed using trial and error experimental procedure, which has been the main route for obtaining microfluidic device designs. With advances in technologies for fabrication of microfluidic devices, the current tool can be a significant step toward drastically cutting down on the laborious trial-and-error design process and help in developing droplet microfluidics-based lab-on-a-chip platforms cheaper and faster. 相似文献
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ABSTRACT The extraction of Ni(II) from 1.0 mol-dm-3aqueous NaNO3medium by di-(2-ethylhexyl) phosphoric acid (HDEHP) dissolved in toluene has been studieo as a function of the total extractant concentration, the equilibrium pH and the total raetal concentration in the aqueous phase. Nickel distribution data have been interpreted in terms of the formation of NiR2(HR)2, and NiR2species in the organic phase in the low pH range anc by the formation of Na-HUEHP micelles, due to the neutralization of the reagent in the organic phase, and the further exchange of Na+by Ni2+in these micelles in the high pH range for each of the total extractant concentrations used. 相似文献
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(6)协调运转的控制--在固定的机器支承筒体上安置着为实现下列控制程序的诸凸轮扇形件:初型模气缸向上,压制气缸往下,压制气缸向上,初型模气缸往下[得凸轮片装在一公用的可活动的托架上,它们当机器运转(即"头"公转)时会通过相应的杠杆去驱去并调整各运动,压制时间便得到变更],预吹制,终吹制,颈环离合器,供水阀,吹气头往下,成型模打开. 相似文献
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《分离科学与技术》2012,47(2):297-303
Abstract Molecular weight distribution curves obtained by GPC are broadened if concentration and flow rate are fixed in the usual range. Therefore, the apparent nonuniformity U app of the samples is larger than the real non-uniformity U = (Mw/Mn) ?1. For a number of fractionated and unfractionated samples of polymethyl methacrylate we determined M n and M w by osmotic, light-scattering, and viscosity measurements. Thus, the real value of U can be compared to U app obtained by GPC at different concentrations and flow rates, υ. The excess nonuniformity U exc is evaluated as function of concentration c, polydispersity, molecular weight, and flow rate. For c = 0 and υ = 0, U exc is not far from zero. For standard conditions one certain value of the excess standard deviation of the elution volume allow calculation of U exc for narrow and broader distributions and the obtaining of nearly correct values for the real nonuniformity U. 相似文献
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本实验主要研究了回收PET瓶片在催化剂和二元醇存在下,进行醇解和酯交换转化为各种不同组成具有端羟基低分子链段和二醇,进而醇解产物与反丁烯二酸酯化缩聚为用于墨粉树脂的聚酯。探索了从原料配比到反应工艺条件等多方面因素合成聚酯树脂的条件。利用聚酯回收料为原料醇解后直接合成墨粉用聚酯树脂的工艺简单、产品质量稳定、具有良好的经济效益和环保效应。 相似文献
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稀土在搪瓷与玻璃中的应用(三) 总被引:5,自引:0,他引:5
4 玻璃的稀土澄清脱色4.1 氧化铈澄清剂在玻璃的熔制过程中,为了排除玻璃液中残留的微小气泡,在配合料中需要添加澄清剂。其作用是在玻璃熔化的澄清阶段分解放出氧气,将玻璃液中的小气泡扩大,逸出液面。氧化剂本身则由高价的氧化物变成低价态。氧化铈为变价氧化物。二氧... 相似文献
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V. Spitzer F. Marx J. G. S. Maia K. Pfeilsticker 《European Journal of Lipid Science and Technology》1990,92(4):165-168
The fatty acid composition of the seed oil of Curupira tefeensis was analysed by capillary GC of their methyl esters. The gaschromatographic assignments were ensured by corresponding mass spectra. The oil is composed to more than 62% of very long chain fatty acids (>C18). Erucic acid is found to be the main component (35%). The position of the double bonds of the monounsaturated fatty acids (MUFAME) was verified after derivatization with dimethyl disulfide and subsequent GC/MS analysis. All identified MUFAME belong to the (n-9-)type. The UV-spectroscopical data show that approx. 1.2% conjugated acetylenic fatty acids occur in the oil. Furthermore IR- and NMR-spectroscopical investigations and the basic analyses of the seed were carried out. 相似文献
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Two new thiophene-substituted porphyrins and their zinc complexes were synthesized and electropolymerized via thiophene units on different electrode surfaces. Electrochemical characterizations show that the resultant polythiophenemetalloporphyrin hybrid materials are highly electroactive and exhibit remarkable higher electrochemical stability. Interestingly, they exhibit a charge-trapping effect. A mechanism for the observed charge-trapping phenomenon was proposed and supported by using model compounds. The deposited polymer films on different electrode surfaces exhibit a homogeneous morphology and possess good processability (soluble in polar solvents such as DMSO or DMF). Besides electrochemical method, UV/vis, NMR, FTIR, TEM and SEM were employed to characterize the new hybrid material. 相似文献
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The authors describe an experimental set-up, using transfer function analysers, which allows for the impedance of a hanging mercury drop electrode to be measured at frequencies as low as 3 × 10−3 Hz, and for the low frequency limit of that impedance to be compared with the slope of the current-voltage curve. The device is applied to the reduction of the persulfate anion in a 1 M LiCl solution, in a region of potential where the current-voltage curve has a negative slope. 相似文献