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水性聚氨酯纳米复合涂料的制备 总被引:11,自引:1,他引:11
通过接枝法制备了丙烯酸改性聚氨酯(PUA)乳液,重点研究引发剂用量对PUA黏度和转化率的影响。结果表明,0.3%用量的引发剂取得了较高的转化率,制得了稳定性好、性能优异的PUA乳液。以合成的PUA为基础,分别以纳米级的Al2O3、ITO和SiO2等为填料,配制成具有良好耐磨性、隔热性和UV屏蔽性等特殊功能的水性聚氨酯纳米复合涂料,并进行性能测试。 相似文献
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水性聚氨酯树脂的合成和性质研究 总被引:2,自引:0,他引:2
通过对不同体系、不同配方下水性聚氨酯乳液及其涂膜的研究,发现了不同种类的二异氰酸酯、二元醇,不同含量的亲水单体、亲水基团以及改性单体、扩链剂、溶剂等对水性聚氨酯性能均有影响,得到适用于木器漆、皮革织物类涂层、防水涂料等的水性聚氨酯树脂。 相似文献
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水性聚氨酯弹性树脂及其建筑防水涂料的制备与研究 总被引:2,自引:0,他引:2
研究水性聚氨酯(PU)弹性树脂、水性聚氨酯/丙烯酸酯(PU/PA)复合弹性树脂及其建筑防水涂料的合成与制备。考察不同聚醚、-NCO/-OH比值、亲水单体用量、扩链交联及PA/PU比值等因素对水性树脂力学性能,固含量和耐水性等的影响。探讨填料/乳液配比、增塑剂用量对防水涂料力学性能、同含量和低温柔性的影响。研究表明,所制得的水性聚氨酯弹性树脂及其防水涂料强度高、弹性好,属于新型的高性能环保型建筑材料。 相似文献
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聚氨酯——丙烯酸酯乳液的结构与性能 总被引:5,自引:0,他引:5
以蓖麻油与聚醚(N210,Mn=1000)、甲苯二异氰酸酯(TDI)为主要原料,乙二醇和二乙烯三胺进行两次扩链,引入环氧氯丙烷、马来酸酐等亲水单体,通过丙酮法制得了稳定的水性聚氨酯乳液。将乳液与外加乳化剂、水混合后加入含有偶氮二异丁腈(AIBN)的丙烯酸丁酯溶液,在80℃反应3h,再升温反应1h,可得到稳定的聚氨酯 丙烯酸酯乳液,使聚丙烯酸酯的耐溶剂性能有较大的提高,并对其进行了红外光谱、透射电镜以及DSC分析。结果表明,聚氨酯乳液和聚丙烯酸酯乳液并不是简单的机械共混,而是部分PU所含的CC双键和BA发生接枝共聚反应,构成了网络(I)PU富集在壳层,网络(Ⅱ)PA富集在核的近似核壳结构,并且二者分子链相互贯穿与缠结,形成了互穿网络结构。 相似文献
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丙烯酸改性水性聚氨酯乳液的合成及表征 总被引:8,自引:1,他引:8
采用接枝法制备丙烯酸改性水性聚氨酯(PUA)乳液,研究了二羟甲基丙酸(DMPA)、甲基丙烯酸甲酯(MMA)对PUA乳液吸水率、黏度及涂膜硬度的影响,并用红外分析法表征了水性PUA与水性PU和共混型PU/PA在分子结构上的差异。 相似文献
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ATO/WPU复合隔热涂料的制备与性能研究 总被引:1,自引:0,他引:1
将异佛尔酮二异氰酸酯(IPDI)、聚醚220和二羟甲基丙酸(DMPA)等原料通过丙酮法合成水性聚氨酯(WPU),与纳米氧化锡锑(ATO)分散液复合后制得ATO/WPU复合隔热涂料.研究了DMPA用量和NCO/OH摩尔比对涂膜吸水率和硬度的影响,分析了ATO用量对涂膜隔热效果和透射光谱的影响.结果表明,DMPA用量5%,NCO/OH摩尔比为1.2,ATO的质量百分数为6%时,制得的涂膜硬度为2H,吸水率为15%,可见光区平均透过率达65%以上,红外区平均透过率仅33.51%,其隔热效果比空白玻璃可降温达9℃. 相似文献
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《Construction and Building Materials》2010,24(7):1286-1295
In this study, the effects of aggregate type on the physical and mechanical properties of hardened self-consolidating concrete produced with lightweight aggregate (SCLC) were investigated. In experiments, three coarse lightweight aggregate (LWA) types, pumice, volcanic tuff and diatomite, and normal limestone aggregate were used. Different combinations of water to binder ratio and superplasticizer dosage levels were prepared for the SCLC mixtures. The total powder content (cement and mineral additives) was constant in the experiments. Physical properties such as thermal conductivity, dry unit weight, porosity and capillarity; mechanical properties such as compressive and splitting tensile strength, modulus of elasticity and abrasion resistance were determined in hardened condition. The results, in general, showed that SCLC with LWA in lower unit weight has lower mechanical and physical properties except for thermal properties when compared to properties of SCC. 相似文献
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D.J. de Ridder L. Villacorte J.Q.J.C. Verberk G.L. Amy J.C. van Dijk 《Water research》2010,44(10):3077-3086
Solute hydrophobicity, polarizability, aromaticity and the presence of H-bond donor/acceptor groups have been identified as important solute properties that affect the adsorption on activated carbon. However, the adsorption mechanisms related to these properties occur in parallel, and their respective dominance depends on the solute properties as well as carbon characteristics. In this paper, a model based on multivariate linear regression is described that was developed to predict equilibrium carbon loading on a specific activated carbon (F400) for solutes reflecting a wide range of solute properties. In order to improve prediction accuracy, groups (bins) of solutes with similar solute properties were defined and solute removals were predicted for each bin separately. With these individual linear models, coefficients of determination (R2) values ranging from 0.61 to 0.84 were obtained. With the mechanistic approach used in developing this predictive model, a strong relation with adsorption mechanisms is established, improving the interpretation and, ultimately, acceptance of the model. 相似文献
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Utilizing rock mass properties for predicting TBM performance in hard rock condition 总被引:9,自引:1,他引:8
Saffet Yagiz 《Tunnelling and Underground Space Technology incorporating Trenchless Technology Research》2008,23(3):326-339
The key parameters on the estimation of tunnel-boring machine (TBM) performance are rock strength, toughness, discontinuity in rock mass, type of TBM and its specifications. The aim of this study is to both assess the influence of rock mass properties on TBM performance and construct a new empirical equation for estimation of the TBM performance. To achieve this aim, the database composed of actual measured TBM penetration rate and rock properties (i.e., uniaxial compressive strength, Brazilian tensile strength, rock brittleness/toughness, distance between planes of weakness, and orientation of discontinuities in rock mass) were established using the data collected from one hard rock TBM tunnel (the Queens Water Tunnel # 3, Stage 2) about 7.5 km long, New York City, USA. Intact rock properties were obtained from laboratory studies conducted at the Earth Mechanics Institute (EMI) in the Colorado School of Mines, CO, USA. Based on generated database, the statistical analyses were performed between available rock properties and measured TBM data in the field. The result revealed that rock mass properties have strong affect on TBM performance. It is concluded that TBM performance could be estimated as a function of rock properties utilizing new equation (r = 0.82). 相似文献
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Low-temperature properties of the modified bitumens containing styrene–butadiene–styrene (SBS) polymers were investigated using conventional methods, dynamic mechanical analysis (DMA) and bending beam rheometer (BBR). Effects of the characteristics of base bitumens and polymers and the proportion of the components on these properties were studied. The results indicated that SBS polymers improved low-temperature properties of bitumens. The degree of improvement generally increased with SBS content and were influenced slightly by SBS structure. The study also showed a statistically linear relationships between different low-temperature parameters. 相似文献