共查询到19条相似文献,搜索用时 250 毫秒
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二氧化氯杀灭水中铜绿微囊藻的影响因素 总被引:1,自引:0,他引:1
试验研究了二氧化氯与铜绿微囊藻的接触时间、二氧化氯投加量、藻初始浓度、pH值、有机物和氨氮含量对二氧化氯杀灭铜绿微囊藻效果的影响,考察了二氧化氯与混凝工艺的协同除藻效果。结果表明,二氧化氯与铜绿微囊藻最佳接触时间为10min。铜绿微囊藻杀灭率随二氧化氯投加量增大而提高,随pH值升高及有机物含量的增大而下降。由氯化铵形成的氨氮的存在对溶液的pH值有影响而使铜绿微囊藻杀灭率稍有提高。当叶绿素d初始浓度低于27.12μg/L时,二氧化氯杀藻率随藻初始浓度的升高而提高,但当叶绿素a初始浓度高于27.12μg/L时,杀藻率随藻初始浓度的升高而逐渐下降。二氧化氯与混凝具有协同除藻作用,当二氧化氯的投加量为0.5mg/L,聚合氯化铝10mg/L时,铜绿微囊藻杀灭率达到96.17%。 相似文献
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稳定性二氧化氯溶液在使用中 ,先要加活化剂 ,目前一般用固体柠檬酸 ,经过活化才能激发出杀菌、消毒的有效浓度。而有效浓度激发多少 ,存放中衰减快慢与加入活化剂的量、加活化剂的操作程序、环境温度等因素有关。本文就上述各种因素对稳定性二氧化氯有效浓度和杀菌效果的影响进行试验观察 相似文献
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近年来二氧化氯生产方法和应用方面的研究已成为化工和环保的热点。本文从开拓二氧化氯的应用市场着眼, 并结合环境友好的理念, 以蔗渣浆羧甲基纤维素接枝丙烯酸制备的高吸水树脂为缓释基材, 琼脂为交联剂, 制成一种新型长效缓释型固体二氧化氯, 并考察了它的影响因素。实验结果表明:酸性活化剂的种类和用量、蔗渣浆纤维基质高吸水树脂的用量、温度、稳定性二氧化氯溶液的浓度是影响固体二氧化氯释放通量的因素, 且柠檬酸是最佳的缓释活化剂, 固体ClO2及含固体ClO2的产品应在低温下保存, 制备长效缓释型的产品, 稳定性二氧化氯溶液的浓度不宜超过l%。研究结果表明:新型缓释型固体二氧化氯制备工艺简单, 价格低廉, 使用安全有效;设计不同平均释放通量, 不同有效释放时间的固体二氧化氯产品可以根据使用环境, 添加不同浓度的稳定性二氧化氯溶液、不同数量的缓释基材、控制酸性活化剂的种类和加入量来实现, 对二氧化氯的广泛应用具有一定的理论和实践指导作用。 相似文献
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稳定性二氧化氯的制备与其稳定性的研究 总被引:8,自引:0,他引:8
稳定性二氧化氯是国际上公认的高效安全低毒消毒剂,有广泛的发展前景。本文主要研究了以亚氯酸钠为原料制备稳定性二氧化氯,探讨了加水量与稳定性二氧化氯浓度之间的关系,同时对稳定性二氧化氯的稳定性也进行了初步探讨,这对推广应用稳定性二氧化氯很有实用价值 相似文献
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固载二氧化氯的杀菌特性及其应用研究 总被引:1,自引:0,他引:1
以自行设计的C lO2释放量测定装置,测定了固载C lO2在不同空间中的释放量,以自然落菌法、稀释平板倾注法确定C lO2气体杀菌率,考察了固载二氧化氯释放时间、气体浓度与杀菌率间的关系和固载C lO2对多个菌种的杀菌效果。研究表明:对大肠杆菌,C lO2气体浓度仅需0.31~0.36 mg/m3,杀菌1 h,杀菌率可达到99.55%;当C lO2气体浓度在1.64~1.78 mg/m3内,欲达到100%的杀菌率,霉菌所需有效作用时间小于2 h;而枯草芽孢杆菌要达到4.5 h以上。在有效空间内,C lO2气体杀菌的浓度控制在100~1500μg/m3之间有较好杀菌效果。 相似文献
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Maarten Schalekamp Dr. 《臭氧:科学与工程》1986,8(2):151-186
With the application of chlorine gas in drinking water treatment processing after the turn of this Century, great success was achieved. With the advance of analytical techniques in the field of trace matter, Rook (1)as well as Bellar, Lichtenberg and Kroner (2) succeeded in 1974 to establish the presence of chloroform and other chlorinated compounds in treated drinking water, namely as the result of chlorination. During tests to minimize the problems of chloroform, of chlorite and chlorate by the simultaneous addition of chlorine andchlorine dioxide, it was discovered that already a small dosage of chlorine dioxide was sufficient to reduce drastically the formation of chloroform andother trihalomethanes. The aimof future treatment techniques in Zurich is the preoxidation with ozone in place of chlorine and chlorine dioxide. Considering the mode of effect of the various oxidizing agents and the longer flow time through the biological activated carbon filters (asa result of the ozonation), ozone is – according to studies made by Grob and the Zurich Water Supply with ozonized Lake Zurich water – the most economical oxidation process with the best effect, i.e., without formation of toxic or carcinogenic substances. The pre– and/or intermediate oxidation with ozone surely will be the right way in the foreseeable future. 相似文献
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The reaction of chlorine dioxide with hydrogen peroxide was studied in a well stirred batch reactor in a pH range of 3.60 to 5.07, which is of interest for commercial chlorine dioxide bleaching of chemical pulp. The reaction rate was determined by following the consumption of chlorine dioxide and hydrogen peroxide and the formation of chlorite. The rate equation was established. It was found that the concentration dependencies of chlorine dioxide, hydrogen peroxide and hydroxide ion were all first-order. A reaction mechanism compatible with the rate equation was proposed. Since it was found in previous work that chlorite in chlorine dioxide solution by the addition of small amount of hydrogen peroxide potentially led to a decrease in the formation of organically bound chlorine during chlorine dioxide bleaching, two methods were suggested to implement this technique in a bleach plant. 相似文献
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This study was designed to elucidate the behavior of chlorine dioxide in drinking water systems. Furthermore, the factors
that influence the formation of chlorite, chlorate in terms of reaction time, concentration of chlorine dioxide, pH, temperature
and UV irradiation were experimentally reviewed. At 20 ‡C, pH 7, 70–80% of chlorine dioxide injected was converted to chlorite
and 0–10% of that was transformed into chlorate within 120 min with 2.91 mg/L of DOC. The amount of chlorite formed also increased
when pH and temperature increased. As DOC content increased, the residual chlorine dioxide decreased but the amount of chlorite
and chlorate were increased. These experiments revealed that chlorate was a dominant by-product under UV irradiation. The
models that were obtained by the regression analysis for the formation of chlorite and chlorate from chlorine dioxide with
Han River water are as follows: Chlorite (mg/L)=10-2.20[ClO2]0.45[pH]0.90[temp]0.27[TOC]1.04[time]0.20, Chlorate (mg/L)=10-2.61[ClO2]1.27[pH]-0.50[temp]1.28 [TOC]0.31[time]0.12 相似文献