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在pH值为3的NH3.H2O-NH4Cl介质中,镧,铈,镨与偶氮胂Ⅲ(ASAⅢ)形成配合物,并于-0.71V(vs.SCE)处产生灵敏的配合物吸附波峰电流与镧,铈,镨浓度分别为3.6×10^-8~1.4×10^-6mol/L,1.8×10^-8~8.6×10^-7mol/L,3.5×10^-8~7.0×10^-7mol/L范围内呈线性关系,测得镧与偶氮胂Ⅲ的配合比为1:1。稳定常数为4.5×10^ 相似文献
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研究测定磷矿石中微量砷的新方法,以硝酸银—乙酸—聚乙烯醇(PVA)—乙醇作为砷化氢吸收液,Zn-KI-SnCl2为还原体系的新银盐光度法测定砷。As3+质量浓度在0~7.5μg/5ml范围内服从Beer定律。方法回收率为96%~100.5%,分析含砷1.60×10-3%,RSD为1.23%,方法检出限为1.9×10-6g/L。 相似文献
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分光光度法测定盐酸环丙沙星 总被引:1,自引:0,他引:1
研究了0.1mol·L-1的硫酸介质中,盐酸环丙沙星与三氯化铁的显色反应。盐酸环丙沙星浓度在3.3×10-5~7.3×10-4mol·L-1(0.012~0.27mg·L-1)范围内符合比尔定律,ε=1.85×103L·(mol·cm)-1。测得络合物组成比为1∶1。本方法简便准确,可用于片剂和胶囊中盐酸环丙沙星的测定。 相似文献
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利用霉变玉米胚组织研制了对二甲基亚硝胺(DMNA)、二乙基亚硝胺(DE-NA)和甲基苄基亚硝胺(MBNA)等选择性响应的新型组织传感器。该传感器灵敏度高,重现性好,选择性好,其线性范围2.0×10-6~2.0×10-3mol·L-1,检测下限1.3×10-7mol·L-1,斜率为59.2(30°C,pH7.5)。 相似文献
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串联式压电传感器测定水中阴离子表面活性剂 总被引:4,自引:0,他引:4
基于阴离子表面活性剂与季铵盐反应前后电导的改变和压电传感器能响应溶液电导率的性质,建立了串联式压电传感器测定水中阴离子表面活性剂的新方法。在500μg氯化十六烷基吡啶存在下,十二烷基磺酸钠的浓度在3.6×10-7~5.7×10-5mol·L-1范围内与压电传感器的频移值呈线性关系,相关系数为0.9989,检测下限为1.7×10-7mol·L-1。用此法测定了环境水样中的阴离子表面活性剂,其加标回收率为94.4%~100.2%,相对标准偏差小于4.9% 相似文献
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本文提出了在乙酸-乙酸钠介质中,铋(三价)-皮素配合物1.5次微分吸附伏安法测定铋的方法。试验了各种影响因素,建立了一个测定范围为3.0×10-9~1.0×10-7mol/L、检出下限为1.0×10-9mol/L的测定铋的新方法。该法可用于人发及锰盐等样品中微量铋的分析,结果令人满意。 相似文献
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分光光度法测定盐酸环丙沙星 总被引:2,自引:0,他引:2
研究了0.1mol·L^-1的硫酸介质中,盐酸环丙沙星与三氯化铁的显色反应。盐酸环丙沙星浓度在3.3×10^-5 ̄7.3×10^-4mol·L^-1(0.012 ̄0.27mg·L^-1)范围内符合比尔定律,ε=1.85×10^3L·(mol·cm)^-1。测得络合物组成比为1:1。本方法简便准确,可用于片剂和胶囊中盐酸环丙沙星的测定。 相似文献
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对水质中钙、镁和硬度的在线监测方法进行了研究。利用稳定性好、灵敏度高的偶氮氯膦Ⅲ作显色剂,在pH70时,加入EGTA掩蔽钙,测定镁;在pH为25,掩蔽镁的干扰,测定钙,在线分析时,采用混合分析流程,加三通分流消除气泡干扰,测定数据稳定可靠,镁的测试范围1×10-3~48×10-3mmol/L,钙的测试范围1×10-3~50×10-3mmol/L,钙镁的检测限05×10-3mmol/L,该方法开发成在线仪器,可单独测定钙、镁,又可根据水样得到水质硬度,具有较好的实用性。 相似文献
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本文研制出以芦竹碱-四苯硼钠为电活性物的PVC膜电极。在pH2.0~7.0水浴液中,电极的残性响应范围、平均斜率和检出下限分别为6.3×10 ̄5~1.0×10 ̄(-2)mol/L、57mV/△PC和2.2×10 ̄(-5)mol/L.电极响应速度快,稳定性好,可用于快速测定植物中芦竹碱的含量,方法准确可靠。 相似文献
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毛细管气相色谱法测定多种有机磷农药在柑桔上的残留 总被引:7,自引:0,他引:7
本文采用HP1701毛细管柱为分离柱,测定了柑桔中7种有机磷农药残留量;比较了常用的七种有机磷农药在柑桔生长不同时期的残留情况。本法对7种有机磷农药的回收率范围为83.5~106.4%,变异系数为3.0~7.8%,检测限为0.1~20×10-9g。 相似文献
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Humberto Hinojosa‐Gómez Jorge Solares‐Ramírez Enrique R. Bazúa‐Rueda 《American Institute of Chemical Engineers》2015,61(9):3081-3093
The VLLE flash is important in water and hydrocarbons mixtures, hydrocarbon and CO2 rich mixtures, and hydrocarbon methane rich mixtures that are encountered in reservoir performance and recovery studies. A robust VLLE flash algorithm is proposed. The equilibrium and mass balance equations are solved as a constrained minimization problem. An inverse barrier function is used to handle the inequality constrains to solve for the phase fractions. It warrants always arriving to the solution. The challenging cases analyzed showed that the initialization procedure proposed, together with successive substitution iteration in the outer loop, is a good method for a stable VLLE flash algorithm, even near critical points. Whenever the result is in the region outside the three‐phase physical domain, the solution suggests that the system has fewer phases. In one of the cases analyzed, a region with three liquid phases was encountered and the algorithm found two different solutions with positive phase fractions. © 2015 American Institute of Chemical Engineers AIChE J, 61: 3081–3093, 2015 相似文献
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Phase equilibria and structural properties of thiophene/[Bmim][BF4]: A molecular insight from monte carlo simulations
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Yongping Zeng Chunfeng Wang Junmei Hu WenLin Xu Yueyang Xu Shengui Ju 《American Institute of Chemical Engineers》2014,60(11):3916-3924
The phase equilibria of thiophene in 1‐butyl‐3‐methylimidazolium tetrafluoroborate ([Bmim][BF4]) is calculated by Monte Carlo simulation in Gibbs ensemble using a united atom force field. The liquid density of studied ionic liquid and the vapor pressure of thiophene in [Bmim][BF4] were compared with corresponding experimental data reported in the literature, and a good agreement was obtained. In order to describe the solubility of thiophene in this ionic liquid, we have calculated the radial distribution functions and spatial distribution functions of thiophene/IL mixtures to study the interaction of thiophene with cations and anions of [Bmim][BF4] in the liquid phase. The local composition concept in fluid was also examined to give further insight into the liquid structure. The results show that thiophene is well organized around the terminal carbon atom of the butyl or methyl chain attached to the imidazolium ring of cations and tends to adopt a symmetrically distribution on the anions. © 2014 American Institute of Chemical Engineers AIChE J, 60: 3916–3924, 2014 相似文献
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本文可视为是新编《尿素工学》一书的第二篇补充文章[1]。尿素物系是一个挥发性弱电解质物系,汽液平衡热力学计算方法甚为复杂。本文提供一个在相图上计算汽液平衡的新方法,简易实用。 相似文献
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In this work a Flory‐Huggins model modified to account for some unique features of Aqueous Two‐Phase Systems is presented. The model takes into account observed solvation between water and polymer molecules through the incorporation of a hydration shell to express the number of water molecules bonded to each polymer molecule. The parameters of the modified equation were determined using experimental data of ATPS containing poly (ethylene glycol) and dextran. The results revealed remarkable improvement in the correlation ability of the model. A general expression that defines the number of water molecules in the hydration shell was also obtained. 相似文献