Dissociation of H2S in non-equilibrium gliding arc “tornado” discharge

The process of hydrogen sulfide, H₂S, dissociation was studied in a non-equilibrium gliding arc “tornado” (GAT) plasma discharge. Utilizing GAT ensured uniform H₂S gas treatment in the reactor. In addition, it created a low temperature zone near the cylindrical wall of the reactor, while maintaining a high temperature zone near the reactor axis. An energy cost of 1.2 eV per H₂ molecule was achieved in this plasma system at atmospheric pressure. These results are particularly important for the oil industry, which consumes large amounts of hydrogen in oil hydro-treatment, and for gas industry because of the high H₂S content in “sour” gas.     

Relationship between “clearness index” and “cloudiness index” at a tropical station (Ilorin, Nigeria)

Total (global) solar radiation, H, and diffuse solar radiation, H_d were measured at Ilorin (8° 30′N 4° 42′E) Nigeria. From these, the daily values of H/H₀ and H_d/H were computed, where H₀ is the extraterrestrial radiation. The relationship between the two ratios and their variation with the prevailing atmospheric conditions were examined.The ratios were found to be opposite in characteristics. H/H₀ has high values in clear atmospheres and low values in cloudy or turbid atmospheres; and vice-versa for H_d/H. The two ratios are negatively linearly related and with this fact, two simple mathematical models were obtained for estimating H_d/H in terms of H/H₀.     

Environmental assessment and extended exergy analysis of a “zero CO2 emission”, high-efficiency steam power plant

Aim of this paper is to analyze the performance of an innovative high-efficiency steam power plant by means of two “life cycle approach” methodologies, the life cycle assessment (LCA) and the “extended exergy analysis” (EEA).

The plant object of the analysis is a hydrogen-fed steam power plant in which the H₂ is produced by a “zero CO₂ emission” coal gasification process (the ZECOTECH^© cycle). The CO₂ capture system is a standard humid-CaO absorbing process and produces CaCO₃ as a by-product, which is then regenerated to CaO releasing the CO₂ for a downstream mineral sequestration process.

The steam power plant is based on an innovative combined-cycle process: the hydrogen is used as a fuel to produce high-temperature, medium-pressure steam that powers the steam turbine in the topping section, whose exhaust is used in a heat recovery boiler to feed a traditional steam power plant.

The environmental performance of the ZECOTECH^© cycle is assessed by comparison with four different processes: power plant fed by H₂ from natural gas steam reforming, two conventional coal- and natural gas power plants and a wind power plant.     

Rebuttal to “The Marginal Cost of CO2 Emissions”: C. Azar, Energy19, p. 1255 (1994)

In “The Marginal Cost of CO₂ Emissions”, Azar criticizes my early works on the shadow price of CO₂ emissions. In this note, I refute those criticisms.     

Hydrogen permeation through a Pd-based membrane and RWGS conversion in H2/CO2, H2/N2/CO2 and H2/H2O/CO2 mixtures

This study investigated the effect of gases such as CO₂, N₂, H₂O on hydrogen permeation through a Pd-based membrane −0.012 m² – in a bench-scale reactor. Different mixtures were chosen of H₂/CO₂, H₂/N₂/CO₂ and H₂/H₂O/CO₂ at temperatures of 593–723 K and a hydrogen partial pressure of 150 kPa. Operating conditions were determined to minimize H₂ loss due to the reverse water gas shift (RWGS) reaction. It was found that the feed flow rate had an important effect on hydrogen recovery (HR). Furthermore, an identification of the inhibition factors to permeability was determined. Additionally, under the selected conditions, the maximum hydrogen permeation was determined in pure H₂ and the H₂/CO₂ mixtures. The best operating conditions to separate hydrogen from the mixtures were identified.     

A note on the formation of “salt-finger” and “diffusive” interfaces in three-component systems

Thin density interfaces determine the fluxes of heat or solute through doubly-diffusive convection. Vertical transports are achieved by either “salt finger” convection or molecular diffusion. The influence of a third diffusing property upon the type of interface formed at an initial density discontinuity is explored here. There may be a strong dependence upon molecular diffusivities, and some interfaces are observed to have a complicated structure.     

Combustion characteristics of H2/N2 and H2/CO syngas nonpremixed flames

Turbulent nonpremixed H₂/N₂ and H₂/CO syngas flames were simulated using 3D large eddy simulations coupled with a laminar flamelet combustion model. Four different syngas fuel mixtures varying from H₂-rich to CO-rich including N₂ have been modelled. The computations solved the Large Eddy Simulation governing equations on a structured non-uniform Cartesian grid using the finite volume method, where the Smagorinsky eddy viscosity model with the localised dynamic procedure is used to model the sub-grid scale turbulence. Non-premixed combustion has been incorporated using the steady laminar flamelet model. Both instantaneous and time-averaged quantities are analysed and data were also compared to experimental data for one of the four H₂-rich flames. Results show significant differences in both unsteady and steady flame temperature and major combustion products depending on the ratio of H₂/N₂ and H₂/CO in syngas fuel mixture.     

Photoreduction of N2 to NH3 and H2O to H2 on metal doped TiO2 catalysts (M = Ce, V)

The photosynthesis of NH₃ from N₂ and the photogeneration of H₂ from H₂O under non-sacrificial conditions on M/TiO₂ (M = Ce, V) are reported. The yields are superior to those earlier reported for similar metal doped TiO₂ catalysts. The flat band potentials of these catalysts have been determined and correlated to their catalytic activity.     

Comparative studies of “all sol–gel” electrochromic devices with optically passive counter-electrode films, ormolyte Li ion-conductor and WO3 or Nb2O5 electrochromic films

Laminated electrochromic (EC) devices are becoming increasingly important for making “smart” windows and switchable displays. Mostly, polymeric Li⁺ ionic conductors in combination with vacuum deposited active electrochromic and counter-electrode films are used. In this paper we report on the development of all sol–gel EC devices, that is, those where all three internal layers are prepared via the sol–gel route, including the ionically conductive inorganic–organic hybrid (ormolyte). The electrochemical and optical properties of EC devices are presented and the cycling stability and reversibility of their optical modulation assessed. The results show that WO₃/ormolyte/SnO₂ : Mo, WO₃/ormolyte/SnO₂ : Sb, WO₃/ormolyte/SnO₂ : Sb : Mo, Nb₂O₅/ormolyte/SnO₂ : Sb : Mo and WO₃/ormolyte/LiCo-oxide exhibit a transmission modulation dependent on the thickness of the active electrochromic and counter-electrode films and the thickness of the ormolyte layer. Electrochemical and optical properties of individual films are described and correlated with the stability of the all sol–gel EC devices.     

Electrochemical supercapacitor behavior of Ni3(Fe(CN)6)2(H2O) nanoparticles

Nanosized Ni₃(Fe(CN)₆)₂(H₂O) was prepared by a simple co-precipitation method. The electrochemical properties of the sample as the electrode material for supercapacitor were studied by cyclic voltammetry (CV), constant charge/discharge tests and electrochemical impedance spectroscopy (EIS). A specific capacitance of 574.7 F g⁻¹ was obtained at the current density of 0.2 A g⁻¹ in the potential range from 0.3 V to 0.6 V in 1 M KNO₃ electrolyte. Approximately 87.46% of specific discharge capacitance was remained at the current density of 1.4 A g⁻¹ after 1000 cycles.     

Production of H2 via thermal decomposition of H2S and separation of H2 and H2S by pressure swing adsorption

Preferable conditions for the thermal decomposition of hydrogen sulfide, one step in thermochemical water splitting cycles of metal-sulfur families, are described. To separate hydrogen from hydrogen sulfide after condensation of sulfur a pressure swing adsorption on zeolite or carbon molecular sieves is proposed which may also be suitable for separating hydrogen sulfide from other gas mixtures such as natural gas and noble gas.     

The solubility of Ni in molten Li2CO3–Na2CO3 (52/48) in H2/H2O/CO2 atmosphere

In this work the solubility of a Ni–Al anode for MCFC has been studied at atmospheric pressure and two different temperatures using various gas compositions containing H₂/H₂O/CO₂. It is well known that nickel is dissolved at cathode conditions in an MCFC. However, the results in this study show that nickel can be dissolved also at the anode, indicating that the solubility increases with increasing CO₂ partial pressure of the inlet gas and decreasing with increasing temperature. This agrees with the results found by other authors concerning the solubility of NiO at cathode conditions. The dissolution of Ni into the melt can proceed in two ways, either by the reduction of water or by the reduction of carbon dioxide.     

Convenient storage of concentrated hydrogen peroxide as a CaO2·2H2O2(s)/H2O2(aq) slurry for energy storage applications

Prior investigations have proposed, and successfully implemented, a stand-alone supply of aqueous hydrogen peroxide for use in fuel cells. An apparent obstacle for considering the use of aqueous hydrogen peroxide as an energy storage compound is the corrosive nature of the nominally required 50 wt.% maximum concentration. Here we propose storage of concentrated hydrogen peroxide in a high weight percent solid slurry, namely the equilibrium system of CaO₂·2H₂O₂(s)/H₂O₂(aq), that mitigates much of the risk associated with the storage of such high concentrations. We have prepared and studied surrogate slurries of calcium hydroxide/water that are assumed to resemble the peroxo compound slurries. These slurries have the consistency of a paste rather than a distinct two-phase (liquid plus solid) system. This paste-like property of the prepared surrogates enable them to be contained within a 200 lines-per-inch. (LPI) nickel mesh screen (33.6% open area) with no solids leakage, and only liquid transport driven by an adsorbent material is placed in physical contact on the exterior of the screen. This hydrogen peroxide slurry approach suggests a convenient and safe mechanism of storing hydrogen peroxide for use in, say, vehicle applications. This is because fuel cell design requires only aqueous hydrogen peroxide use, that can be achieved using the separation approach utilizing the screen material here. This proposed method of storage should mitigate hazards associated with unintentional spills and leakage issues arising from aqueous solution use.     

Photogalvanic behaviour of [Cr2O2S2(1-Pipdtc)2(H2O)2] in aqueous DMF

The photogalvanic behaviour of [Cr₂O₂S₂(1-Pipdtc)₂(H₂O)₂] was performed in a Honda Cell using 100% DMF and different percentages of water-DMF systems. The maximum potential of 200 mV with 18 μA of current was generated in DMF. The experiments were performed at different pH conditions and added dyes. The system was found to generate a maximum potential of 86, 67 and 36 mV at pH∼4, 7 and 8, respectively, at 65 °C. Malachite green and methylene blue (10⁻⁴ M) produced maximum potential of 100 and 82 mV, respectively. The system was reversible when the irradiated solution was aerated immediately. When the solution was kept in dark for a long time (12 h) and then aerated, the solution was found to be irreversible. The Cr(V) is photoreduced to Cr(IV) with the light irradiation and the unstable Cr(IV) reverts to Cr(V) by aerial oxidation.     

Quantification of “delivered” H2 by a volumetric method to test H2 storage materials

We set up and validated a volumetric method to quantify the amount of hydrogen “delivered” after saturation of a solid material as adsorber at different pressures (up to 100 kg_f/cm²) and temperatures (down to 77 K). This is the practically most relevant datum to quantify the effectiveness of an adsorbent for the present application. A complementary dynamic method has been also developed to take into account the reversibility of adsorption and to assess in at least a semi-quantitative way the strength of interaction between H₂ and the adsorbent. The method has been applied to compare the hydrogen storage capacity of some significant different carbon-based materials (two active carbons and one graphite), as supplied or after thermal treatments under oxidising or reducing conditions. The best results, ca. 7 wt% H₂ “delivered”, were achieved after saturation at 77 K, 20 kg_f/cm² with an active carbon with ca. 3000 m²/g of apparent specific surface area. The thermal treatments, almost always inducing a drop in surface area, showed effective only for saturation at 273 K, in particular the oxidising procedure. This was correlated to the formation of surface oxidised species, likely carboxylic groups, which improved the interaction strength between H₂ and the adsorbent.     

Modelling and experimentation of the “Shell” dryer

The “Shell” dryer is an African solar food dryer using natural convection. Its design has been defined by users, in function of local working conditions and of its easy using. But it is necessary for the best behaviour of this dryer to optimize its air flow section design. We present here a theoretical study of a “rustic” process, through mathematical modelisation tools.     

Catalytic transformation of H2S for H2 production

Hydrogen sulfide (H₂S) gas is a by-product from natural gas refining, hydrodesulfurization of various fossil fuels, and syngas cleaning from pyrolysis and gasification. Catalytic pyrolysis of H₂S provides an alternative and effective pathway to recover both H₂ and sulfur. Catalysts from hydrotalcite of ZnAl, ZnNiAl, and ZnFeAl were employed for H₂S pyrolysis and compared with TiO₂ and MoS₂ at atmospheric pressure and temperatures in the range of 923–1123 K. Kinetic analysis was carried out in a packed bed reactor which revealed the effect of H₂S partial pressures to be of the order of 0.8–1 with respect to H₂S. The developed novel catalysts showed improved performance with significantly reduced activation energy compared to TiO₂ by 30 kJ/mol as well as higher H₂S conversion during pyrolysis (17% at 1173 K) than with MoS₂ catalyst, even at high H₂S partial pressure which is necessary for viable hydrogen production. The new approach showed an alternate economical and efficient pathway of catalyst design to obtain high activity and stability for simultaneous H₂ energy and pure sulfur recovery from unwanted H₂S resources.     

Mesoscale modeling of a “Dunkelflaute” event

In the near future, wind and solar generation are projected to play an increasingly important role in Europe's energy sector. With such fast‐growing renewable energy development, the presence of simultaneous calm wind and overcast conditions could cause significant shortfalls in production with potentially serious consequences for system operators. Such events are sometimes dubbed “Dunkelflaute” events and have occurred several times in recent history. The capabilities of contemporary mesoscale models to reliably simulate and/or forecast a Dunkelflaute event are not known in the literature. In this paper, a Dunkelflaute event near the coast of Belgium is simulated utilizing the Weather Research and Forecasting (WRF) model. Comprehensive validation using measured power production data and diverse sets of meteorological data (e.g., floating lidars, radiosondes, and weather stations) indicates the potential of WRF to reproduce and forecast the boundary layer evolution during the event. Extensive sensitivity experiments with respect to grid‐size, wind farm parameterization, and forcing datasets provide further insights on the reliability of the WRF model in capturing the Dunkelflaute event.     

Thermal evaluation of a “Winter House”

In this paper, the transient thermal model of a “Winter House” has been presented for a cold climatic region of Srinagar in India. In order to reduce the fluctuations in living room temperature, the effect of an isothermal mass has been incorporated in the thermal model. An analytical expression for room temperature has been derived to evaluate the performance of the “Winter House” by incorporating the effect of movable insulation during the night. Numerical calculations were done in terms of system as well as climatical parameters. Some isothermal mass, like water, has been considered to stabilize the room temperature throughout the day and right. For further heating, the effect of the roof as an air collector has also been taken into account.