Investigation of the structural and reactants properties on the thermal characteristics of a premixed porous burner

Porous burners offer attractive features such as competitive combustion efficiency, high power ranges, and lower pollutant emissions. In the present study, the thermal characteristics of a porous burner are numerically investigated for a range of operating conditions and design specifications within a practical range. The premixed flame propagation of a methane/air mixture in a ceramic porous medium is simulated through an unsteady, one-dimensional model. The combustion process is modeled using a suitable single-step chemical kinetics. The reaction location is not predetermined, thus the flame is allowed to float within the solid matrix or to run off from either side of the porous medium. The numerical results indicate that flame stability and thermal characteristics of the burner are strongly dependent on the inlet mixture specifications and the solid matrix structural properties. For a fixed value of the inlet firing rate, the combustion products temperature will increase by an increase in the inlet gas temperature, an increase in the matrix porosity, or by a decrease of the matrix pore density. Among the geometrical properties, the burner length has virtually no effect on the burner performance. An increase in the solid matrix porosity or burner firing rate will increase the efficiency of the preheating zone, while increasing the inlet gas temperature or matrix pore density will cause a reduction in this efficiency. Simulation results also suggest that in order to prevent flame blow-out or flash-back, critical values of the burner settings and design parameters must be avoided.     

Lean flammability limits for stable performance with a porous burner

Applications of porous burners are of high interest due to many advantages such as extended lean flammability limit in comparison with free flame structures. In this work, laminar premixed flame propagation of methane/air mixture in a porous medium is numerically investigated. An unsteady one-dimensional physical model of a porous burner is considered, in which the flame location is not predetermined. The computational domain is extended beyond either side of the porous medium to accurately model reactions close to the edges of the solid matrix. After validation of the model and performing a baseline simulation, a parametric study is carried out to investigate the lean flammability limits of the burner and the unstable flash-back/blow-out phenomena. Stable performance diagrams are given for two controlling parameters of turn–down ratio and porous medium porosity. The simulation results indicate that the stable performance range of the burner is extended when the equivalence ratio increases; however, the blow-out region expands with an increase in the firing rate. For constant values of porosity and firing rate, increasing the equivalence ratio can change the operating regime of the burner from blow-out to a stable condition. It is observed that by the variation of porosity in the range of 0.6–0.9, and for the equivalence ratios of more than 0.6, the flame flash-back cannot occur. An equivalence ratio of 0.43 is found to be the lower limit at which the flame stabilizes in the matrix.     

A simplified numerical approach to hydrogen and hydrocarbon combustion in single and double-layer porous burners

Motivated by the fuel hydrogen applications in porous combustors, as well as hydrogen production in syngas porous devices, this work shows a simplified one-dimensional, steady state heat and mass transfer model for stabilized premixed flames in porous inert media. Single-layer and double-layer porous burner are studied. The model has three conservation equations, describing the heat transfer in the solid and fluid phases and the mass transfer in the reacting flow. The model considers a plug flow and is solved numerically by using the finite volume method. The results are compared with benchmark data, depicting the superadiabatic flames and the heat recirculation process. A parametric analysis of the model reveals the effects of the porous media properties and the Lewis and Peclet numbers on the heat and mass transfer processes. Furthermore, the effects of the flame stand-off parameter in double layer porous burner are also analyzed. The results have considered the values of the dimensionless parameters based on reference data for hydrogen/air and methane/air combustion in porous burners built with SiC and Al₂O₃.     

A numerical evaluation of combustion in porous media by EGM (Entropy Generation Minimization)

Combustion in Porous Media provides interesting advantages compared with the free flame combustion due to the higher burning rates, increased power dynamic range, the extension of lean flammability limits, and the low emissions of pollutants. A numerical code is developed in order to evaluate the effects of different parameters of combustion in porous media. The governing equations including Navier–Stokes, the solid and gas energy and the chemical species transport equations are solved using a multi-step reduced kinetic mechanism. Flame stabilization and the burner optimization are studied by EGM (Entropy Generation Minimization) method considering the effects of chemical affinities and reaction. It is found that the flames occurring at the upstream half of the porous layer are more stable and more efficient, producing less emissions than those occur at the downstream half of porous layer. Also at a specified equivalence ratio both the heat recirculation efficiency and the Merit number have similar trend by changing the flame location. For a FFL (Fixed Flame Location), there is an optimum value of equivalence ratio at which the burner efficiency is a maximum.     

惰性多孔介质内天然气预混燃烧的数学模拟评述

天然气在惰性多孔介质内的预混燃烧是一个包含燃烧、辐射、对流及导热的复杂过程，从数学模拟的角度，比较了几种不同的甲烷-空气化学反应模型，研究了多孔介质内辐射传递方程的不同求解方法，并且分析了多孔介质的导热系数、对流换热系数等对燃烧器性能的影响。     

Experimental investigation of combustion in porous heating burners

The combustion characteristics of liquefied petroleum gas inside porous heating burners have been investigated experimentally under steady-state and transient conditions. Cooling tubes were embedded in the postflame region of the packed bed of a porous heating burner. The flame speed, temperature profile, and [NO_x] and [CO] in the product gases were monitored during an experiment. Due to the heat removal by the cooling tubes, a phenomenon termed metastable combustion was observed; this is that only one flame speed exists at a particular equivalence ratio for maintaining stable combustion within the porous bed of the porous heating burner. This behavior is quite different from that of porous burners without cooling tubes, in which an extended range of flame speeds usually is found for maintaining stable combustion. After metastable combustion has been established in a porous heating burner, a change in the equivalence ratio will stop the metastable combustion and drive the flame out of the packed bed. From the steady-state results, the porous heating burner was shown to maintain stable combustion under fuel-lean conditions with an equivalence ratio lower than the flammability limit of a normal free-burning system. The flame speed in a porous heating burner was found to decrease with an increase in the length of the porous bed. Combustion within a porous heating burner has the features of low flame temperature, extended reaction zone, high preheating temperature and low emissions of NO_x and CO. The flame temperature ranged from 1050 to 1250 °C, which is ∼200 °C lower than the adiabatic flame temperature at the corresponding equivalence ratio. The length of the reaction zone could be more than 70 mm and the preheating temperature ranged from 950 to 1000 °C. Both [NO_x] and [CO] were low, typically below 10 ppm.     

Increasing the efficiency of radiant burners by using polymer membranes

Gas-fired radiant burners are used to convert fuel chemical energy into radiation energy for various applications. The radiation output of a radiant burner largely depends on the temperature of the combustion flame. In fact, the radiation output and, thus, the radiant efficiency increase to a great extent with flame temperature. Oxygen-enriched combustion can increase the flame temperature without increasing fuel cost. However, it has not been widely applied because of the high cost of oxygen production. In the present work, oxygen-enriched combustion of natural gas in porous radiant burners was studied. The oxygen-enriched air was produced passively, using polymer membranes. The membranes were shown to be an effective means of obtaining an oxygen-enriched environment for gas combustion in the radiant burners. Two different porous radiant burners were used in this study. One is a reticulated ceramic burner and the other is a ceramic fibre burner. The experimental results showed that the radiation output and the radiant efficiency of these burners increased markedly with rising oxygen concentrations in the combustion air. Also investigated were the effects of oxygen enrichment on combustion mode, and flame stability on the porous media.     

Trends in modeling of porous media combustion

Porous media combustion (PMC) has interesting advantages compared with free flame combustion due to higher burning rates, increased power dynamic range, extension of the lean flammability limits, and low emissions of pollutants. Extensive experimental and numerical works were carried out and are still underway, to explore the feasibility of this interesting technology for practical applications. For this purpose, numerical modeling plays a crucial role in the design and development of promising PMC systems. This article provides an exhaustive review of the fundamental aspects and emerging trends in numerical modeling of gas combustion in porous media. The modeling works published to date are reviewed, classified according to their objectives and presented with general conclusions. Numerical modeling of liquid fuel combustion in porous media is excluded.     

Experimental investigation of the performance of a liquid fuel-fired porous burner operating on kerosene-vegetable cooking oil (VCO) blends for micro-cogeneration of thermoelectric power

Studies related to porous burner for thermoelectric (TE) power generation have mainly focused toward achieving a specific range of power output for various applications. However, detailed analyses on the performance and emission aspects of the porous burner are lacking. In addition, physical integration between the burner and TE modules has added further complexity in this research area. Thus, this work aims to comprehend the effects of fuel–air equivalence ratio on the performance and emission characteristics of a liquid fuel-fired porous burner for micro-cogeneration of TE power. A catalytically inert Al₂O₃ porous medium was incorporated into a liquid fuel-fired porous burner operating on four mixtures of kerosene-vegetable cooking oil (VCO) blends: 100 kerosene, 90/10 KVCO, 75/25 KVCO, and 50/50 KVCO. Ten bismuth-telluride TE cells were arranged in a ten-sided polygon that, together with finned dissipators, formed a TE module electrically connected in series but thermally connected in parallel. The performance aspects at various fuel–air equivalence ratios were thoroughly evaluated with the corresponding temperature profiles, voltage, current, power output, and electrical efficiency. Results indicated that the surface temperature of the porous media was generally higher than the developed and exit flame temperature of the burner. Varying the fuel-air equivalence ratio significantly affected the electrical efficiency, with a maximum and minimum value of 1.94% and 1.10%, respectively. The power output steadily increased in the lean region, but stabilized as the fuel–air equivalence ratio slowly increased beyond the stoichiometric ratio. The CO emission was relatively lower at the lean region; however, significant amount was recorded in the rich combustion region. Moreover, NOx fluctuated between 1 ppm and 4 ppm over the entire range of fuel–air equivalence ratio.     

A Numerical and Experimental Investigation of Performance of a Nonsprayed Porous Burner

The performance of a nonsprayed porous burner (NSPB) is investigated through both numerical and experimental studies. The major requirement of liquid fuel combustion systems is excellent fuel vaporization, which is accomplished by using porous medium. Instead of heterogeneous combustion, which occurs in free space of a conventional sprayed burner, a homogeneous combustion of vaporized kerosene and air takes place within a porous medium. The liquid kerosene is preheated and completely vaporized in the first porous medium before being mixed with preheated air in the mixing chamber (i.e., a small space between two porous media). Then the combustion occurs in the second porous medium. A subcooled boiling, single global reaction combustion, and local nonthermal equilibrium between fluid and solid phases with phase change under complex radiative heat transfer are considered. The model accuracy is validated by the experimental data before parametric study—that is, equivalence ratio and firing rate are performed. Result show that a self-sustaining evaporation without atomization and matrix-stabilized flame can be achieved in the NSPB by providing the radiant output efficiency in the same range as a conventional premixed gaseous porous burner. This indicates that the NSPB is one possible technology to replace conventional spray burners for future requirements.     

Numerical and experimental investigation of a mild combustion burner

An industrial burner operating in the MILD combustion regime through internal recirculation of exhaust gases has been characterized numerically. To develop a self-sufficient numerical model of the burner, two subroutines are coupled to the CFD solver to model the air preheater section and heat losses from the burner through radiation. The resulting model is validated against experimental data on species concentration and temperature. A 3-dimensional CFD model of the burner is compared to an axisymmetric model, which allows considerable computational saving, but neglects some important burner features such as the presence of recirculation windows. Errors associated with the axisymmetric model are evaluated and discussed, as well as possible simplified procedures for engineering purposes. Modifications of the burner geometry are investigated numerically and suggested in order to enhance its performances. Such modifications are aimed at improving exhaust gases recirculation which is driven by the inlet air jet momentum. The burner is found to produce only 30 ppm_v of NO when operating in MILD combustion mode. For the same air preheating the NO emissions would be of approximately 1000 ppm_v in flame combustion mode. It is also shown that the burner ensures more homogeneous temperature distribution in the outer surfaces with respect to flame operation, and this is attractive for burners used in furnaces devoted to materials' thermal treatment processes. The effect of air excess on the combustion regime is also discussed.     

Numerical study of the effects of material properties on flame stabilization in a porous burner

Development of porous burners has been encouraged by lower emission standards as well as the advantages these burners offer; such as fuel flexibility, the ability to operate at low equivalence ratios, and effective flame speeds greater than the laminar flame speed. Although a burner may be constructed from a single section of porous media, a burner consisting of two sections with different characteristics has received significant attention in the last decade. Through proper selection of the properties of the two sections, the interface between the two sections serves as a flame holder preventing flashback for a range of conditions. In this paper, we present the results from a one-dimensional computational study on flame stabilization in a two section porous burner. The stable operating limits are predicted for a range of equivalence ratios and are compared to experimental values. A parametric study, in which the properties of the two sections are varied independently, is presented. The results indicate that matrix properties significantly affect the stable operating range. In addition, the upstream section acts primarily as a flashback arrestor and for the widest operating range, it should have a low conductivity, low volumetric heat transfer coefficient, and high radiative extinction coefficient. The downstream section acts primarily to recirculate heat through the matrix; it should have a high conductivity, high volumetric heat transfer coefficient, and an intermediate radiative extinction coefficient.     

Testing of gas and liquid fuel burners for power and process industries

The object of the present paper is a review of issues related to the testing of gas and liquid fuel burners which are amongst the most important items of equipment in materials processing and energy producing industries. The text gives basic information about fuels, types of burners and their testing and also about modelling of combustion and formation of pollutants, mainly nitrogen oxides. The first two sections of the text provide an overview of fuels and burner types. The most part of the paper deals with an assessment of conditions and equipment required for testing of gas and liquid fuel burners. Conditions that must be satisfied in burner tests in order to preserve comparable operating conditions as in the real application are stressed. Last part provides an outline of the utilisation of statistical analysis methods and modelling by computational fluid dynamics (CFDs) including the formation of pollutants.     

Combustion of methane in catalytic honeycomb monolith burners

The heat transfer efficiency, stability, and pollutant emissions characteristics of ultra‐lean methane–air combustion in some precious metal‐based honeycomb monoliths were investigated. The interpretation of the experimental results was assisted using numerical modelling of the gas‐phase combustion process. The thermal radiation output of the monoliths varied between 27 and 30 per cent of the thermal input, and this compared favourably with equivalent porous inert media burners. The minimum fuel concentrations for very‐low emission stable combustion were found to be significantly lower than for conventional gas‐phase combustion and were shown to vary with the nature and loading of the catalyst, as well as with flow rates. The palladium catalyst was found to have a larger window of mixture strengths and flow rates for stable operation than the platinum one. During all the runs under stable combustion conditions, only extremely small amounts of CO, NO_x and unburnt hydrocarbons were detected. Thus, the operating conditions verified ‘near‐zero’ pollutant emissions that only a catalytic combustion process can achieve at present. Temperature profiles inside the monoliths channels proved that the catalyst's role was not only to enable the ignition of fuel mixtures below flammability limits, but also to ensure the complete oxidation of the fuel to CO₂ via surface reactions in the steady state. The reaction zone inside the catalysts was found to end at about 10 mm from the monolith's entrance. The effect of monolith length was investigated and a reduction of 70 per cent in the original length was found possible. Copyright © 2000 John Wiley & Sons, Ltd.     

Enhanced radiation output from foam burners operating with a nonpremixed flame

An enhancement in the radiation flux from porous medium burners operating with nonpremixed flames was obtained by a vane-rotary burner, in which the swirling fuel flow was confined by an air duct. By optimizing the gap distance between the swirling flow and the base of the porous medium, the relative enhancement in radiation flux reached 5.7 times. This improvement is attributed to the superior fuel-air swirl mixing, with the resulting flame efficiently transferring the heat to the solid phase, as been substantiated by the exhaust gas analysis, the radiation spectrum, flame, and solid temperatures. A significant reduction in CO and UHC concentrations was obtained at high swirl numbers, whereas the NOx emission was decreased to a level below 10 ppm.     

Determination of laminar burning velocities for lean low calorific H2/N2 and H2/CO/N2 gas mixtures

Combustion of lean and ultra-lean synthetic H₂/CO mixtures that are highly diluted in inert gases is of great importance in several fields of technology, particularly in the field of post combustion for combined heat and power (CHP) systems based on fuel cell technology. In this case H₂/CO mixtures occur via hydrocarbon reforming and their complete conversion requires efficient, compact and low emission combustion systems. In order to design such systems, knowledge of global flame properties like the laminar burning velocity, is essential. Using the heat flux burner method, laminar burning velocities were experimentally determined for highly N₂ diluted synthetic H₂ and H₂/CO mixtures with low calorific value, burning with air, at ambient temperature and atmospheric pressure. Furthermore, numerical 1-D simulations were performed, using a series of different chemical reaction mechanisms. These numerical predictions are analysed and compared with the experimental data.     

Effects of radiation and compression on propagating spherical flames of methane/air mixtures near the lean flammability limit

Large discrepancies between the laminar flame speeds and Markstein lengths measured in experiments and those predicted by simulations for ultra-lean methane/air mixtures bring a great concern for kinetic mechanism validation. In order to quantitatively explain these discrepancies, a computational study is performed for propagating spherical flames of lean methane/air mixtures in different spherical chambers using different radiation models. The emphasis is focused on the effects of radiation and compression. It is found that the spherical flame propagation speed is greatly reduced by the coupling between thermal effect (change of flame temperature or unburned gas temperature) and flow effect (inward flow of burned gas) induced by radiation and/or compression. As a result, for methane/air mixtures near the lean flammability limit, the radiation and compression cause large amounts of under-prediction of the laminar flame speeds and Markstein lengths extracted from propagating spherical flames. Since radiation and compression both exist in the experiments on ultra-lean methane/air mixtures reported in the literature, the measured laminar flame speeds and Markstein lengths are much lower than results from simulation and thus cannot be used for kinetic mechanism validation.     

Influence of nozzle design parameters on exhaust gas characteristics in practical-scale flameless hydrogen combustion

Considering the trend toward decarbonization, hydrogen is expected to be used as a fuel in industrial furnace burners. One of the challenges in using hydrogen as a fuel is the increase in thermal-NOx emission compared to hydrocarbon fuel owing to its high flame temperature. This study experimentally evaluated the combustion characteristics of flameless combustion, which is a low-NO_x combustion technology, with hydrogen as a fuel in a practical-scale experimental furnace as well as the effect of nozzle design parameters on the combustion characteristics. Through comparative tests with city gas by considering parameters, such as the fuel gas velocity, combustion air velocity, and air nozzle pitch, the low-NO_x effect of flameless combustion was confirmed in hydrogen combustion with appropriate nozzle design parameters. The optimal nozzle design parameters to achieve this effect differ from those for city gas, and the design guidelines are summarized.     

多孔介质特性参数对燃烧温度及压力影响的数值模拟研究

考查了两段式多孔介质内预混气燃烧的温度与压力分布情况。建立了甲烷／空气预混气体在多孔介质内燃烧的二维数学模型,运用FLUENT软件求解瞬态控制方程的方法计算出燃烧稳定后多孔介质内的温度、与压力分布,并考查了不同当量比、多孔介质辐射衰减系数和导热系数对温度和压力分布的影响。结果表明,甲烷／空气预混气体在多孔介质中燃烧,当量比越大温度峰值越高,压力梯度越大;小孔介质辐射衰减系数的改变对温度分布和压力分布没有明显的影响,而大孔介质辐射衰减系数对温度分布和压力分布有较大的影响;增加多孔介质的导热系数,会使固相与气相温度均有所升高,燃烧区域压力降低。     

Small scale porous medium combustion system for heat production in households

For heating purposes in modern households, gas burners are normally applied due to their simplicity, low cost and easy handling. On the other hand, practical experience showed that conventional, open flame gas burners compared to porous medium systems have low dynamic range, i.e. low power modulation capability and, additionally, higher production of pollutants such as carbon monoxide (CO) and nitrogen oxides (NO_x). This is especially notable when the burner operates at low thermal power regimes. In order to avoid the above-mentioned difficulties and disadvantages of conventional burners, new porous medium gas burner system with maximum thermal output of 8 kW has been developed. The objective of the presented work is focussed on better understanding and enabling further developing of porous medium burners (PMB) for household heating systems. The aim of the work is also to develop a compact and highly efficient combined heating system based on the 8 kW gas PM burner coupled with a new heat exchanger incorporated into an electro-fossil fuel system considering space and domestic water heating in one-family house. The final result was the heating system with modulation of the thermal power up to approximately 1:8 and low emissions of CO and NO_x.