Modeling and physical interpretation of photocatalytic oxidation efficiency in indoor air applications

Volatile organic compounds (VOCs) are the major pollutants in indoor air, which significantly impact indoor air quality (IAQ). As a promising technique to remove VOCs, photocatalytic oxidation (PCO) takes the advantages of oxidation of a large range of VOCs with low energy consumption. In this study, the mass transports and reaction mechanism involved in the PCO process have been studied. In addition, the kinetic models of PCO on the different conditions of elementary reactions have been critically reviewed. Moreover, the factors that may affect the efficiency of PCO were interpreted based on the established fundamental mechanism of PCO. Some recommendations were made for future work to improve the efficiency of PCO system for building applications.     

Application of a molecular biology concept for the detection of DNA damage and repair during UV disinfection

As nucleic acids are major targets in bacteria during standardised UV disinfection (254 nm), inactivation rates also depend on bacterial DNA repair. Due to UV-related DNA modifications, PCR-based approaches allow for a direct detection of DNA damage and repair during UV disinfection. By applying different primer sets, the correlation between amplicon length and PCR amplification became obvious. The longer the targeted DNA fragment was, the more UV-induced DNA lesions inhibited the PCR. Regeneration of Pseudomonas aeruginosa, Enterococcus faecium, and complex wastewater communities was recorded over a time period of 66 h. While phases of intensive repair and proliferation were found for P. aeruginosa, no DNA repair was detected by qPCR in E. faecium. Cultivation experiments verified these results. Despite high UV mediated inactivation rates original wastewater bacteria seem to express an enhanced robustness against irradiation. Regeneration of dominant and proliferation of low-abundant, probably UV-resistant species contributed to a strong post-irradiation recovery accompanied by a selection for β-Proteobacteria.     

Photoinitiated oxidation of geosmin and 2-methylisoborneol by irradiation with 254 nm and 185 nm UV light

The degradation of geosmin and 2-methylisoborneol (2-MIB) by UV irradiation at different wavelengths was investigated under varying boundary conditions. The results showed that conventional UV radiation (254 nm) is ineffective in removing these compounds from water. In contrast to the usual UV radiation UV/VUV radiation (254 + 185 nm) was more effective in the removal of the taste and odour compounds. The degradation could be described by a simple pseudo first-order rate law with rate constants of about 1.2 × 10⁻³ m² J⁻¹ for geosmin and 2-MIB in ultrapure water. In natural water used for drinking water abstraction the rate constants decreased to 2.7 × 10⁻⁴ m² J⁻¹ for geosmin and 2.5 × 10⁻⁴ m² J⁻¹ for 2-MIB due to the presence of NOM. Additionally, the formation of the by-product nitrite was studied. In the UV/VUV irradiation process up to 0.6 mg L⁻¹ nitrite was formed during the complete photoinitiated oxidation of the odour compounds. However, the addition of low ozone doses could prevent the formation of nitrite in the UV/VUV irradiation experiments.     

斜长角闪岩累积损伤特性的围压效应研究

利用带围压装置的SHPB设备对不同围压等级下斜长角闪岩在冲击荷载循环作用下动态力学性能进行试验研究,通过对试验过程的能量计算和不同循环作用次数下试件应力-应变曲线的分析,研究斜长角闪岩在冲击荷载循环作用下的累积比能量吸收值与入射能量,损伤度与围压等参量之间的关系。研究结果表明,当入射波能量相同时,斜长角闪岩的比能量吸收值随围压的增加而减小,且斜长角闪岩的比能量吸收值与围压和入射波能量具有良好的规律性。当围压逐渐增大时,斜长角闪岩损伤度的增加随累积比能量吸收值增加的趋势变缓,即围压越高,试件达到相同损伤度所需耗散的能量越多。得到损伤度D与累积比能量吸收值和围压之间的关系表达式。     

强震下钢框架动力时程分析模型应用对比分析

为比较几种有限元模型计算钢框架动力时程分析的精度以及效率,采用通用有限元软件ABAQUS,分别建立壳单元模型、多尺度模型、考虑损伤退化的纤维梁模型以及不考虑损伤退化的传统两折线模型,比较几种模型在计算结构变形、结构破坏形态等方面的特征,检验等效本构模型的计算精度,深入探讨考虑损伤退化对钢框架抗震性能的影响。同时,对比几种模型的计算效率,考察等效本构模型的改良作用。研究结果表明:在一开始损伤退化没有出现的时候,四种模型的计算结果基本一致。一旦由于塑性应变累积导致损伤退化的发生,考虑损伤退化的纤维模型、壳单元模型和多尺度模型的计算结果吻合良好,说明等效本构模型能够反映结构出现损伤对结构变形的放大作用。而没有考虑损伤退化的两折线杆系模型与三者的计算结果差别较大,计算得到的变形结果偏小,低估了结构的层间位移角和层位移,导致计算结果偏于不安全。计算效率上,等效本构模型的计算时间远小于壳单元模型和多尺度模型,比两折线模型略高,实现计算精度和计算效率的平衡。     

The effect of a photocatalytic air purifier on indoor air quality quantified using different measuring methods

The effect on indoor air quality of an air purifier based on photocatalytic oxidation (PCO) was determined by different measuring techniques: sensory assessments of air quality made by human subjects, Proton-Transfer-Reaction Mass Spectrometry (PTR-MS) and chromatographic methods (Gas Chromatography/Mass Spectrometry and High-Pressure Liquid Chromatography with UV detection). The experiment was conducted in a simulated office, ventilated with 0.6 h⁻¹, 2.5 h⁻¹ and 6 h⁻¹, in the presence of additional pollution sources (carpet, chipboard and linoleum). At the lowest air change rate, additional measurements were made with no pollution sources present in the office. All conditions were tested with the photocatalytic air purifier turned on and off. The results show that operation of the air purifier in the presence of pollutants emitted by building materials and furniture improves indoor air quality, as documented by sensory assessments made by human subjects. It also reduces concentrations of many chemical compounds present in the air as documented by the PTR-MS technique. For the lowest ventilation, results from measurements using the chromatographic methods have similar tendency, however many of the 50 compounds that were targeted for analysis were not detected at all, independent of whether the purifier was on or off. For the two conditions with higher ventilation the results were inconclusive.     

Photocatalysis of p-chlorobenzoic acid in aqueous solution under irradiation of 254 nm and 185 nm UV light

The photolytic and photocatalytic degradation of p-chlorobenzoic acid (p-CBA) in aqueous solution were investigated using two kinds of low-pressure mercury lamps: one emitted at 254 nm and the other emitted at 254 nm and 185 nm. Both the photolytic and photocatalytic degradations of p-CBA followed pseudo first-order reaction rate form. The rate constants decreased with increase of initial concentration in VUV and TiO2/VUV. The TiO2/VUV was the most efficient process, in which rate constants was 3.0-6.5 times as that in TiO2/UV depending on the initial concentration. The gas bubbling efficiently improved the mass transfer and the kind of bubbling gas had evident influence on the reaction rate except in UV photolysis. TOC reduction rate was greatly reduced in VUV and TiO2/VUV processes when bubbled with nitrogen gas, it was no more than one third of that when bubbled with oxygen, however, the degradation rate of p-CBA was not affected by bubbled nitrogen so greatly.     

Effects of UV 254 irradiation on residual chlorine and DBPs in chlorination of model organic-N precursors in swimming pools

Ultraviolet (UV) irradiation is commonly applied as a secondary disinfection process in chlorinated pools. UV-based systems have been reported to yield improvements in swimming pool water and air chemistry, but to date these observations have been largely anecdotal. The objectives of this investigation were to evaluate the effects of UV irradiation on chlorination of important organic-N precursors in swimming pools.Creatinine, L-arginine, L-histidine, glycine, and urea, which comprise the majority of the organic-N in human sweat and urine, were selected as precursors for use in conducting batch experiments to examine the time-course behavior of several DBPs and residual chlorine, with and without UV₂₅₄ irradiation. In addition, water samples from two natatoria were subjected to monochromatic UV irradiation at wavelengths of 222 nm and 254 nm to evaluate changes of liquid-phase chemistry. UV₂₅₄ irradiation promoted formation and/or decay of several chlorinated N-DBPs and also increased the rate of free chlorine consumption. UV exposure resulted in loss of inorganic chloramines (e.g., NCl₃) from solution. Dichloromethylamine (CH₃NCl₂) formation from creatinine was promoted by UV exposure, when free chlorine was present in solution; however, when free chlorine was depleted, CH₃NCl₂ photodecay was observed. Dichoroacetonitrile (CNCHCl₂) formation (from L-histidine and L-arginine) was promoted by UV₂₅₄ irradiation, as long as free chlorine was present in solution. Likewise, UV exposure was observed to amplify cyanogen chloride (CNCl) formation from chlorination of L-histidine, L-arginine, and glycine, up to the point of free chlorine depletion. The results from experiments involving UV irradiation of chlorinated swimming pool water were qualitatively consistent with the results of model experiments involving UV/chlorination of precursors in terms of the behavior of residual chlorine and DBPs measured in this study.The results indicate that UV₂₅₄ irradiation promotes several reactions that are involved in the formation and/or destruction of chlorinated N-DBPs in pool settings. Enhancement of DBP formation was consistent with a mechanism whereby a rate-limiting step in DBP formation was promoted by UV exposure. Promotion of these reactions also resulted in increases of free chlorine consumption rates.     

不同养护条件对钢矿粉掺合料活化效应的影响研究

制备了钢矿粉复合掺合料,通过测试掺合料胶砂活性指数和混凝土抗压强度,研究标准养护和蒸汽养护对钢矿粉掺合料活化效应的影响,并对不同养护条件下掺合料混凝土的胶凝系数K进行对比。结果表明:不论是胶砂活性还是混凝土强度,蒸汽养护更有利于体系中水化反应,高温条件下矿粉和激发剂中的活性物质能更大程度地参与活化反应,加速水化产物的生成,使体系的活性和强度大幅度提高;胶凝系数K也侧面证实了这一观点:在蒸养条件下K值比标准养护条件的高,说明蒸汽养护时钢矿粉掺合料对混凝土强度贡献更大。     

Effect of different organotins on DNA of mollusk (Scapharca inaequivalvis) erythrocytes assessed by the comet assay

The alkaline comet assay, employing a single-cell gel-electrophoresis, is a rapid, simple and sensitive technique for visualizing and measuring DNA damage leading to strand breakage in individual cells. In this study, we report data about the effect of different organotin compounds (MBTC, DBTC and TBTC) on DNA from erythrocytes of the Scapharca inaequivalvis bivalve mollusc. Our results show significant DNA damage after 30 min in vitro incubation with 10microM of organotins. Since TBTC turned out to be the most genotoxic compound, followed by MBTC and DBTC, we exposed the molluscs to 50ppb of TBTC for 11 days. A significant increase of comet parameters was measured in our experimental conditions. The use of the comet test as a high-throughput screening assay to monitor the effect of environmental pollutants on marine organisms has been proposed.     

不同竖向荷载下PHC管桩水平承载性能研究

在桩基设计中通常分别确定单桩的竖向和水平向承载力,而不考虑竖向荷载与水平荷载之间的相互作用对桩承载力的影响,这显然不能反映桩的真实受力状况。本文通过现场的载荷试验,分析了PHC管桩在不同竖向荷载下的水平承载性能,利用有限元软件ANSYS对该实例进行数值模拟,结果表明：在先施加竖向荷载再施加水平荷载时,存在一个最优的竖向...     

Removal of particle-associated bacteriophages by dual-media filtration at different filter cycle stages and impacts on subsequent UV disinfection

This bench-scale study investigated the passage of particle-associated bacteriophage through a dual-media (anthracite-sand) filter over a complete filter cycle and the effect on subsequent ultraviolet (UV) disinfection. Two model viruses, bacteriophages MS2 and T4, were considered. The water matrix was de-chlorinated tap water with either kaolin or Aldrich humic acid (AHA) added and coagulated with alum to form floc before filtration. The turbidity of the influent flocculated water was 6.4+/-1.5 NTU. Influent and filter effluent turbidity and particle counts were measured as well as headloss across the filter media. Filter effluent samples were collected for phage enumeration during three filter cycle stages: (i) filter ripening; (ii) stable operation; and (iii) end of filter cycle. Stable filter operation was defined according to a filter effluent turbidity goal of <0.3 NTU. Influent and filter effluent samples were subsequently exposed to UV light (254 nm) at 40 mJ/cm(2) using a low pressure UV collimated beam. The study found statistically significant differences (alpha=0.05) in the quantity of particle-associated phage present in the filter effluent during the three stages of filtration. There was reduced UV disinfection efficiency due to the presence of particle-associated phage in the filter effluent in trials with bacteriophage MS2 and humic acid floc. Unfiltered influent water samples also resulted in reduced UV inactivation of phage relative to particle-free control conditions for both phages. Trends in filter effluent turbidity corresponded with breakthrough of particle-associated phage in the filter effluent. The results therefore suggest that maintenance of optimum filtration conditions upstream of UV disinfection is a critical barrier to particle-associated viruses.     

Biological hydrolysis and acidification of sludge under anaerobic conditions: the effect of sludge type and origin on the production and composition of volatile fatty acids

New wastewater treatment processes resulting in considerably reduced sludge production and more effective treatment are needed. This is due to the more stringent legislations controlling discharges of wastewater treatment plants (WWTPs) and existing problems such as high sludge production. In this study, the feasibility of implementing biological hydrolysis and acidification process on different types of municipal sludge was investigated by batch and semi-continuous experiments. The municipal sludge originated from six major treatment plants located in Denmark were used. The results showed that fermentation of primary sludge produced the highest amount of volatile fatty acids (VFAs) and generated significantly higher COD- and VFA-yields compared to the other sludge types regardless of which WWTP the sludge originated from. Fermentation of activated and primary sludge resulted in 1.9-5.6% and 8.1-12.6% COD-yields, soluble COD (SCOD)/total COD (TCOD), in batch experiments, respectively. The COD-yields for primary, activated and mixed sludge were 19.1%, 6.5% and 21.37%, respectively, in semi-continuous experiments operated at solids retention time (SRT) of 5d and temperature of 37 degrees C. The benefit of fermentation for full-scale application was roughly estimated based on the experiments performed in semi-continuous reactors. The results revealed that even though the VFA production of primary sludge was higher compared to activated sludge, substantial amounts of VFA could be produced by fermentation of activated sludge due to the substantially higher production of activated sludge in WWTPs.     

Feasibility investigation for a bridge damage identification method through moving vehicle laboratory experiment

This paper investigated the feasibility of the pseudo-static damage identification method derived from a bridge–vehicle interaction system through a moving vehicle laboratory experiment. The element stiffness index, defined as the ratio of flexural rigidity of a damaged member to that of an intact member, serves as the damage indicator. Three vehicle models and two travelling speeds were considered in the experiment to examine the effect of vehicle's dynamic characteristic and travelling speed on identified results. It is demonstrated that locations and severities of damages are detectable using the proposed method in spite of the probable changes of roadway roughness and environmental conditions. In addition, adopting higher vehicle speed as well as the vehicle with frequency close to that of the bridge increased the probability of detecting damages.     

考虑地震耦合效应的单元式玻璃幕墙地震作用研究

对一种隐框单元式玻璃幕墙进行了研究,考虑单元式玻璃幕墙与主体结构的相互关系,建立了单元式玻璃幕墙地震耦合作用的振动控制微分方程,以简谐波为实际工程的输入波,研究了结构自振周期、单元式玻璃幕墙系统自振和地面运动周期对幕墙耦合动力响应的影响。以El-Centro波作为输入,研究了单元式玻璃幕墙的地震反应现象,分析了单元式玻璃幕墙在地震作用下的破坏机理,为单元式玻璃幕墙的抗震设计提供些参考。     

The effect of pH on the competition between polyphosphate-accumulating organisms and glycogen-accumulating organisms

In enhanced biological phosphorus removal (EBPR) processes, glycogen-accumulating organisms (GAOs) may compete with polyphosphate-accumulating organisms (PAOs) for the often-limited carbon substrates, potentially resulting in disturbances to phosphorus removal. A detailed investigation of the effect of pH on the competition between PAOs and GAOs is reported in this study. The results show that a high external pH ( approximately 8) provided PAOs with an advantage over GAOs in EBPR systems. The phosphorus removal performance improved due to a population shift favouring PAOs over GAOs, which was shown through both chemical and microbiological methods. Two lab-scale reactors fed with propionate as the carbon source were subjected to an increase in pH from 7 to 8. The phosphorus removal and PAO population (as measured by quantitative fluorescence in situ hybridisation analysis of "Candidatus Accumulibacter phosphatis") increased in each system, where the PAOs appeared to out-compete a group of Alphaproteobacteria GAOs. A considerable improvement in the P removal was also observed in an acetate fed reactor, where the GAO population (primarily "Candidatus Competibacter phosphatis") decreased substantially after a similar increase in the pH. The results from this study suggest that pH could be used as a control parameter to reduce the undesirable proliferation of GAOs and improve phosphorus removal in EBPR systems.     

混凝土养护效果评价方法研究进展

养护是保证施工现场和实验室配制混凝土性能一致的重要环节,养护方式不同,其养护效果相差很大,有必要研究养护效果评价方法。分析了各种评价方法的局限和不足,总结了各种评价方法的应用情况,提出了适合于施工现场方便、简单的养护效果评价方法。     

Calibration of coupled hydro-mechanical properties of grain-based model for simulating fracture process and associated pore pressure evolution in excavation damage zone around deep tunnels

The objective of this paper is to develop a methodology for calibration of a discrete element grain-based model(GBM)to replicate the hydro-mechanical properties of a brittle rock measured in the laboratory,and to apply the calibrated model to simulating the formation of excavation damage zone(EDZ)around underground excavations.Firstly,a new cohesive crack model is implemented into the universal distinct element code(UDEC)to control the fracturing behaviour of materials under various loading modes.Next,a methodology for calibration of the components of the UDEC-Voronoi model is discussed.The role of connectivity of induced microcracks on increasing the permeability of laboratory-scale samples is investigated.The calibrated samples are used to investigate the influence of pore fluid pressure on weakening the drained strength of the laboratory-scale rock.The validity of the Terzaghi’s effective stress law for the drained peak strength of low-porosity rock is tested by performing a series of biaxial compression test simulations.Finally,the evolution of damage and pore pressure around two unsupported circular tunnels in crystalline granitic rock is studied.     

Production of polyhydroxyalkanoates (PHA) by activated sludge treating municipal wastewater: effect of pH,sludge retention time (SRT), and acetate concentration in influent

In this paper, the production of biodegradable plastics polyhydroxyalkanoates (PHA) by activated sludge treating municipal wastewater was investigated. The effect of three operational factors, i.e. the acetate concentration in influent, pH, and sludge retention time (SRT) were studied. Sludge acclimatized with municipal wastewater supplemented with acetate could accumulate PHA up to 30% of sludge dry weight, while sludge acclimatized with only municipal wastewater achieved 20% of sludge dry weight. It was found that activated sludge with an SRT of 3 days possessed better PHA production capability than sludge with an SRT of 10 days. Sludge acclimatized under pH 7 and 8 conditions in sequencing batch reactors (SBRs) exhibited similar PHA production capability. However, in PHA production batch experiments, pH value influenced significantly the PHA accumulation behavior of activated sludge. When pH of batch experiments was controlled at 6 or 7, a very low PHA production was observed. The production of PHA was stimulated when pH was kept at 8 or 9.     

Evaluation of a turbine driven CCHP system for large office buildings under different operating strategies

Combined cooling, heating, and power (CCHP) systems use waste heat from on-site electricity generation to meet the thermal demand of the facility. This paper models a CCHP system for a large office building and examines its primary energy consumption (PEC), operational costs, and carbon dioxide emissions (CDE) with respect to a reference building using conventional technologies. The prime mover used in this investigation is a load share turbine, and the CCHP system is evaluated under three different operation strategies: following the electric demand of the facility, following the thermal demand of the facility, and following a seasonal strategy. For the various strategies, the percentages of total carbon dioxide emissions by source are presented. This paper explores the use of carbon credits to show how the reduction in carbon dioxide emissions that is possible from the CCHP system could translate into economic benefits. In addition, the capital costs available for the CCHP system are determined using the simple payback period. Results indicate that for the evaluated office building located in Chicago the CCHP operation reduces the operational cost, PEC, and CDE from the reference building by an average of 2.6%, 12.1%, and 40.6%, respectively, for all the different operational strategies.