共查询到20条相似文献,搜索用时 109 毫秒
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联苯二甲酸类化合物是很好的刚性桥联配体,可用于制备纳米多孔材料.设计了一条制备联苯二甲酸类新配体的合成路线,以4-氨基水杨酸为原料,经过4步反应最终合成了新配体3,3′-二羟基-4,4′-联苯二甲酸,并通过红外光谱、核磁共振氢谱和元素分析进行了表征. 相似文献
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Tobias Lehnert Yuan Shi Daniel Cepli Raouf Jemmali Thomas Wamser Andreas Lauer Jan Roßdeutscher Britta Panthen 《International Journal of Applied Ceramic Technology》2023,20(3):1804-1817
Oxide ceramic matrix composites (O-CMCs) have a high potential for usage in thermal protection systems or combustion chambers because of their low weight, temperature- and corrosion stability as well as non-brittle failure behavior. Mechanical property changes over their lifetime due to operational loads are not well understood. Moreover, mechanical properties from planar samples under laboratory conditions often differ substantially from upscaled components with complex geometries. In this work, the influences of curvature and preloading conditions were investigated experimentally using modeling to determine boundary conditions. Effects of curvature and trends among preload conditions were determined, with high-cycle-fatigue-preload (HCF) reducing strength and Young’s Modulus by 15% compared to their original values where low-cycle-fatigue-preload (LCF) had smaller effect. The low impacts of high temperatures and small-to-medium loads on the properties of O-CMCs makes them an interesting choice for high-temperature combustive environments. 相似文献
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文章应用固相萃取、液相色谱联用技术,研究了[bmim]PF6增塑PVC糊树脂膜中的[bmim]PF6在水环境及低酒精含量模拟溶剂(15%乙醇-水溶液)中的迁移规律,同时研究了[bmim]PF6迁移对薄膜力学性能的影响。结果表明:时间和温度对[bmim]PF6向水环境中迁移均有加速效应,在中性条件下迁移量较小,在酸性和碱性条件下迁移量较大。[bmim]PF6在低酒精含量模拟溶剂中与浸泡在去离子水中的薄膜迁移量相比,迁移量明显降低。增塑剂迁出后PVC糊树脂膜的断裂伸长率降低,弹性模量、拉伸强度均升高,可望用于医疗制品的开。 相似文献
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《Journal of Sulfur Chemistry》2013,34(4-5):411-427
Dithioacetals are very important and commonly used protecting groups for carbonyl compounds. Among the advantages of their use are the ease of formation, stability under both acidic and basic conditions, and umpolung reactivity. Unfortunately, their deprotection into the corresponding carbonyls is quite often difficult and requires special conditions. Hence, numerous protocols for the dithiane deprotection have been devised. In this review, various methodologies that were developed for the hydrolysis of thioacetal protecting groups are summarised and the detailed reaction conditions are presented. 相似文献
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合成了席夫碱N-亚水杨基-2-氨基吡啶,并以此为有机配体与过渡金属铕反应,得到了相应的配合物,且在一定的条件下培养得到配合物的单晶,解析出其晶体结构,并对其进行了荧光性质研究。 相似文献
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制备了单体浇铸聚酰胺(MCPA)、纤维质量占比30 %的玻璃纤维增强MC聚酰胺(GFMCPA)及体积占比35 %的碳纤维增强MC聚酰胺(CFMCPA),分别将3种材料在干摩擦、洁净水、干砂、水砂4种不同摩擦条件下进行摩擦磨损性能实验,并对实验结果进行对比分析。结果表明,干摩擦及洁净水条件下,CFMCPA的摩擦因数(fCF)fGF)fMC);干砂及水砂条件下,fMC<fCF<fGF;3种材料在不同摩擦条件下的摩擦因数排序均为:洁净水条件下的摩擦因数(fW)<水砂条件下的摩擦因数(fWS)<干摩擦条件下的摩擦因数(fD)<干砂条件下的摩擦因数(fDS);不同材料在4种摩擦条件下的体积磨损率排序均为:干摩擦条件下的磨损率(WD)<洁净水条件下的磨损率(WW)<水砂条件下的磨损率(WWS)<干砂条件下的磨损率(WDS);不同摩擦条件下3种材料的体积磨损率排序均为:GFMCPA的磨损率(WGF)WCF)WMC);4种条件下,各材料的摩擦磨损性能各有高低,可以根据具体的性能要求,选择使用。 相似文献
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G. Barceló E. García M. Sarret C. Müller J. Pregonas 《Journal of Applied Electrochemistry》1998,28(10):1113-1120
Zinc–nickel electrocoatings obtained from an industrial bath containing two additives were characterized by analysing their morphology, structure, microhardness, residual stress and corrosion resistance. Changes in deposit characteristics following the addition of saccharin were also studied. All coating, with or without saccharin, presented a good appearance, good mechanical properties and a high corrosion resistance. Moreover, by varying certain plating conditions it was observed that the deposits maintained their properties over a wide interval of experimental conditions, which suggests their suitability for use in batch bath. 相似文献
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Influence of Preparation Conditions of Alumina‐Based Refractory on the Morphological Parameters of Surface Defects
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Marija Dimitrijević Maja Gajić‐Kvaščev Radmila Jančić Heinemann Dragan Mitraković 《International Journal of Applied Ceramic Technology》2015,12(3):598-607
The surface defects on alumina‐based refractory arising from thermal shock were studied using image analysis and statistical tools. Alumina‐based refractory specimens were prepared by adding a different amount of fibers into their original composition and compacted on different pressures. Obtained specimens were subjected to thermal shock, and induced surface defects were characterized by their morphological parameters determined using the image analysis procedure. The influence of preparation conditions on the surface defects morphology was studied using principle component analysis. It was shown that morphological parameters of defects vary corresponding to the composition and preparation conditions of ceramic material. 相似文献
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Sathira Hirun Niramon Utama-ang Quan V. Vuong Christopher J. Scarlett 《Drying Technology》2014,32(1):47-54
The effects of drying conditions using a commercial microwave vacuum dryer on the physicochemical properties and antioxidant activity of Thai green tea were investigated. Nine different drying conditions (power 3200, 3600, and 4000 Watts vs. radiation time 20, 25, and 30 min) were applied in this study. The results showed that individual catechins, their total quantities, radical scavenging ability, and moisture content were significantly affected; however, total polyphenol content and color parameters were not significantly affected by these drying conditions. Based on this data, to obtain optimal physicochemical properties of green tea, drying conditions at 3600 Watts for 30 min were recommended. 相似文献