镁合金金属型铸造涂料流变性能的研究

研究了一种镁合金金属型涂料的流变特性,并用流变模型对流变曲线进行了拟合.结果表明,试验涂料是一种带屈服值的假塑性流体,有触变性.改进Casson模型可以精确地拟合流变曲线,并且能表征涂料的悬浮性和触变性.     

砂型涂料的流变特性及触变性的研究

本文摘要阐述涂料流变性概念及测试原理.按双圆筒旋转粘度计原理,测绘了国内外几种砂型涂料的流变曲线,判定了流型.探讨了涂料流变特性与悬浮性、刷涂性、涂挂性、流平性及渗透性等工艺性能的关系;对触变性的测试方法也作了研究,本文认为:具有触变性带屈服值的假塑性流体为涂料综合性能较佳的流型.还从分析悬浮液组元、结构、质点间作用力着手,探索了获致较佳流型和调整流变参数的途径,为改善涂料有关性能从理论和实践上提供了方向和途径.     

聚丙烯酰胺/蒙脱土仿贝壳纳米复合材料的制备

研究了电泳沉积制备聚丙烯酰胺/蒙脱土纳米层状复合材料的过程中悬浮液的性能、电泳沉积的参数对材料的制备以及结构的影响.通过改变有机/无机的相对浓度、调节电压和沉积时间,制备出均匀的薄膜.结果表明,随着单体浓度的增加,溶液的zeta电位和电导率降低,溶液变得不稳定.XRD和FTIR表明,单体插层进入蒙脱土的层间后,经过紫外照射而聚合,随着单体浓度的改变,蒙脱土的层间结构发生了变化.通过SEM,可以观察到材料呈现天然贝壳的层状结构.     

APTES改性蒙脱土对镁合金表面杂化溶胶-凝胶涂层防护性能的影响

针对蒙脱土与有机-无机杂化溶胶-凝胶体系较差的相容性,使用APTES对蒙脱土进行接枝改性,通过在蒙脱土表面引入氨基建立与溶胶-凝胶体系间较强的键合,在镁合金表面制备更加致密、稳定的复合涂层.对蒙脱土的表征结果表明APTES成功接枝到了蒙脱土片层上.结果 分析表明,相比于纯溶胶-凝胶涂层,添加AP-MMT的溶胶-凝胶涂层...     

聚丙烯酰胺／蒙脱土仿贝壳纳米复合材料的制备

研究了电泳沉积制备聚丙烯酰胺／蒙脱土纳米层状复合材料的过程中悬浮液的性能、电泳沉积的参数对材料的制备以及结构的影响。通过改变有机／无机的相对浓度、调节电压和沉积时间，制备出均匀的薄膜。结果表明，随着单体浓度的增加，溶液的zeta电位和电导率降低，溶液变得不稳定。XRD和FTIR表明，单体插层进入蒙脱土的层间后，经过紫外照射而聚合，随着单体浓度的改变，蒙脱土的层间结构发生了变化。通过SEM，可以观察到材料呈现天然贝壳的层状结构。     

添加剂对水基氧化铝陶瓷料浆流变性影响

通过流变学实验分析了添加剂滑石、苏州土对水基氧化铝陶瓷料浆流变性的影响.结果表明含有滑石、苏州土水基氧化铝料浆的流变性具有明显的触变性.进一步研究表明主要与滑石、苏州土的层片状结构有关;且通过对滑石和苏州土的预先细磨,破坏其片状结构,可以减少料浆的触变性.     

半固态材料流变特性研究进展

半固态材料流变特性的研究是半固态金属加工技术研究的重要组成部分.着重介绍一些国内外半固态流变特性研究的概况和最新进展,包括试验方法、研究类别、连续冷却研究、流变性研究及建模、触变性研究及建模、高固相率研究的各项成果比较与分析.     

片层蒙脱土对溶胶-凝胶涂层防腐蚀性能的影响

为改善无机涂层脆性大、成膜性差的问题,以正硅酸四乙酯为原料,片层蒙脱土为填料,采用溶胶凝胶法在AA2024铝合金表面制备了蒙脱土溶胶-凝胶涂层。利用扫描电镜(SEM)、能谱仪(EDS)和傅里叶红外光谱仪((FT-IR))分析了涂层的微观形貌和聚合原理。通过动电位极化和电化学阻抗谱测试,研究了所制备的涂层在3.5%NaCl溶液中的电化学行为,并与纯硅溶胶涂层和基体进行比较。结果表明：制备的蒙脱土纳米片,其厚度最小约为10 nm,直径最小约为500 nm;蒙脱土在涂层中分布较为均匀,在溶胶聚合过程中,蒙脱土在溶胶中引导溶胶粒子有序聚合,提高了涂层的致密度,减少了固化时涂层产生的缺陷;蒙脱土溶胶-凝胶涂层试样的腐蚀电流密度(1.04×10^-8 A·cm^-2)比纯硅溶胶涂层试样(1.22×10^-7 A·cm^-2)低1个数量级,蒙脱土溶胶-凝胶涂层具有较高的涂层阻抗,且蒙脱土溶胶-凝胶涂层的R_ct始终远高于纯硅溶胶涂层,表明蒙脱土溶胶-凝胶涂层具有更持久的防护效果。     

水基锆英粉流涂涂料流变特性和触变性的研究

对水基锆英粉流涂涂料的流变特性和触变性进行了研究，找出了适用于流涂的流型，探讨了流涂涂料流变特性和触变性对其工艺性能的影响     

蒙脱土改性聚甲基丙烯酸甲酯复合材料的硫酸腐蚀行为

对乳液聚合法制备出的聚甲基丙烯酸甲酯/蒙脱土(PMMA/MMT)复合材料在硫酸介质中的腐蚀情况进行了研究,探讨了蒙脱土含量、硫酸浓度以及腐蚀时间对腐蚀速率的影响。结果表明,硫酸浓度较低且腐蚀时间较短时,含有2%~3%蒙脱土的复合材料的腐蚀速率比PMMA明显降低;PMMA及其复合材料的腐蚀速率随腐蚀时间的延长而下降,随硫酸浓度的增加而上升;硫酸浓度越高或腐蚀时间越长,复合材料中蒙脱土的片层阻隔作用越不明显。     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

Thermodynamics Study on the Decomposition of Chromite with KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

Influence of Heat Treatment on Damping Behaviour of the Magnesium Wrought Alloy AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Effect of Rare Earth Doping on Impedance,Modulus and Conductivity Properties of Multiferroic Composites:0.5(BiLa_xFe_(1-x)O_3)–0.5(PbTiO_3)

The Lanthanum-doped bismuth ferrite–lead titanate compositions of 0.5(Bi LaxFe1-xO3)–0.5(Pb Ti O3)(x = 0.05,0.10,0.15,0.20)(BLxF1-x-PT) were prepared by mixed oxide method.Structural characterization was performed by X-ray diffraction and shows a tetragonal structure at room temperature.The lattice parameter c/a ratio decreases with increasing of La(x = 0.05–0.20) concentration of the composites.The effect of charge carrier/ion hopping mechanism,conductivity,relaxation process and impedance parameters was studied using an impedance analyzer in a wide frequency range(102–106Hz) at different temperatures.The nature of Nyquist plot confirms the presence of bulk effects only,and non-Debye type of relaxation processes occurs in the composites.The electrical modulus exhibits an important role of the hopping mechanism in the electrical transport process of the materials.The ac conductivity and dc conductivity of the materials were studied,and the activation energy found to be 0.81,0.77,0.76 and 0.74 e V for all compositions of x = 0.05–0.20 at different temperatures(200–300 °C).     

Using Finite Element and Contour Method to Evaluate Residual Stress in Thick Ti-6Al-4V Alloy Welded by Electron Beam Welding

This work was to reveal the residual stress profile in electron beam welded Ti-6Al-4V alloy plates(50 mm thick) by using finite element and contour measurement methods.A three-dimensional finite element model of 50-mmthick titanium component was proposed,in which a column–cone combined heat source model was used to simulate the temperature field and a thermo-elastic–plastic model to analyze residual stress in a weld joint based on ABAQUS software.Considering the uncertainty of welding simulation,the computation was calibrated by experimental data of contour measurement method.Both test and simulated results show that residual stresses on the surface and inside the weld zone are significantly different and present a narrow and large gradient feature in the weld joint.The peak tensile stress exceeds the yield strength of base materials inside weld,which are distinctly different from residual stress of the thin Ti-6Al-4V alloy plates presented in references before.     

Microstructures and Tensile Properties of Ultrafine-Grained Ni–(1–3.5) wt% SiC_(NP) Composites Prepared by a Powder Metallurgy Route

Silicon carbide nanoparticle-reinforced nickel-based composites(Ni–Si CNP),with a Si CNPcontent ranged from1 to 3.5 wt%,were prepared using mechanical alloying and spark plasma sintering.In addition,unreinforced pure nickel samples were also prepared for comparative purposes.To characterize the microstructural properties of both the unreinforced pure nickel and the Ni–Si CNPcomposites transmission electron microscopy(TEM) was used,while their mechanical behavior was investigated using the Vickers pyramid method for hardness measurements and a universal tensile testing machine for tensile tests.TEM results showed an array of dislocation lines decorated in the sintered pure nickel sample,whereas,for the Ni–Si CNPcomposites,the presence of nano-dispersed Si CNPand twinning crystals was observed.These homogeneously distributed Si CNPwere found located either within the matrix,between twins or on grain boundaries.For the Ni–Si CNPcomposites,coerced coarsening of the Si CNPassembly occurred with increasing Si CNPcontent.Furthermore,the grain sizes of the Ni–Si CNPcomposites were much finer than that of the unreinforced pure nickel,which was considered to be due to the composite ball milling process.In all cases,the Ni–Si CNPcomposites showed higher strengths and hardness values than the unreinforced pure nickel,likely due to a combination of dispersion strengthening(Orowan effects) and particle strengthening(Hall–Petch effects).For the Ni–Si CNPcomposites,the strength increased initially and then decreased as a function of Si CNPcontent,whereas their elongation percentages decreased linearly.Compared to all materials tested,the Ni–Si CNPcomposite containing 1.5% Si C was found more superior considering both their strength and plastic properties.     

Directional Growth of Tin Crystals Controlled by Combined Solute Concentration Gradient Field and Static Magnetic Field

A new method was introduced to achieve directional growth of Sn crystals. Microstructures in liquid(Pb)/liquid(Sn) diffusion couples were investigated under various static magnetic fields. Results show that the β-Sn crystals mainly reveal an irregular dendritic morphology without or with a relatively low static magnetic field(B0.3 T). When the magnetic field is increased to 0.5 T, the β-Sn dendrites close to the final stage of growth begin to show some directional character. With a further increase in the magnetic field to a higher level(0.8–5 T), the β-Sn dendrites have an enhanced directional growth character, but the dendrites show a certain deflection. As the magnetic field is increased to 12 T, the directional growth of the β-Sn dendrites in the center of the couple is severely destroyed. The mechanism of the directional growth of the β-Sn crystals and the deflection of the β-Sn crystals with the application of static magnetic field was tentatively discussed.     

Quantitative Analysis of the Crystallographic Orientation Relationship Between the Martensite and Austenite in Quenching–Partitioning–Tempering Steels

The orientation relationships(ORs)between the martensite and the retained austenite in low-and medium-carbon steels after quenching–partitioning–tempering process were studied in this work.The ORs in the studied steels are identified by selected-area electron diffraction(SAED)as either K–S or N–W ORs.Meanwhile,the ORs were also studied based on numerical fitting of electron backscatter diffraction data method suggested by Miyamoto.The simulated K–S and N–W ORs in the low-index directions generally do not well coincide with the experimental pole figure,which may be attributed to both the orientation spread from the ideal variant orientations and high symmetry of the low-index directions.However,the simulated results coincide well with experimental pole figures in the high-index directions{123}_(bcc).A modified method with simplicity based on Miyamoto’s work was proposed.The results indicate that the ORs determined by modified method are similar to those determined by Miyamoto’method,that is,the OR is near K–S OR for the low-carbon Q–P–T steel,and with the increase of carbon content,the OR is closer to N–W OR in medium-carbon Q–P–T steel.     

电化学噪声数据处理方法概述

综述了常见的电化学噪声数据处理方法,介绍了直流趋势剔除、统计分析、快速傅立叶变换(FFT)法计算功率谱密度(PSD)以及小波变换处理电化学噪声信号的基本过程,并阐释了各种数学处理及所得参数的物理意义。