Hydrogen fuel as an important element of the energy storage needs for future smart cities

A considerable amount of non-dispatchable photovoltaic and wind power have always been planned in smart cities, however, the problem of massive energy storage has not yet been solved which limits the use of green energy on larger scale. At present the only battery energy storage is available, and it is effective only for storing modest quantities of energy for short periods of time. The other storage technology options are not often commercially available items; rather, they are just good concepts that need to be tested for viability. Currently, the only alternative options for turning an urban development into one that exclusively uses green energy is to use that energy to generate hydrogen through electrolyzers, then use this fuel to generate the required electricity in order to stabilize the grid. Even more appealing is the idea of using wind and photovoltaic energy to transform smart communities into a centre for producing hydrogen in addition to a city that solely uses renewable energy. The most likely solution, absent an urgent debate inside the science establishment, will be to import electricity from the burning of hydrocarbons while continuing to pay carbon offsets, which is incompatible with the goal of using only renewables. The smart city has not officially accepted this issue, just like the science establishment.     

Hydrogen storage materials for hydrogen and energy carriers

Hydrogen storage technology is essentially necessary to promote renewable energy. Many kinds of hydrogen storage materials, which are hydrogen storage alloys, inorganic chemical hydrides, carbon materials and liquid hydrides have been studied. In those materials, ammonia (NH₃) is easily liquefied by compression at 1 MPa and 298 K, and has a highest volumetric hydrogen density of 10.7 kg H₂/100 L. It also has a high gravimetric hydrogen density of 17.8 wt%. The theoretical hydrogen conversion efficiency is about 90%. NH₃ is burnable without emission of CO₂ and has advantages as hydrogen and energy carriers.     

Hydrogen carriers: Production,transmission, decomposition,and storage

Recognizing the potential role of liquid hydrogen carriers in overcoming the inherent limitations in transporting and storing gaseous and liquid hydrogen, a complete production and use scenario is postulated and analyzed for perspective one-way and two-way carriers. The carriers, methanol, ammonia and toluene/MCH (methylcyclohexane), are produced at commercially viable scales in a central location, transmitted by rail or pipelines for 2000 miles, and decomposed near city gates to generate fuel-cell quality hydrogen for distribution to refueling stations. In terms of the levelized cost of H₂ distributed to the stations, methanol is less expensive to produce ($1.22/kg-H₂) than MCH ($1.35/kg-H₂) or ammonia ($2.20/kg-H₂). Levelized train transmission cost is smaller for methanol ($0.63/kg-H₂) than ammonia ($1.29/kg-H₂) or toluene/MCH system ($2.07/kg-H₂). Levelized decomposition cost is smaller for ammonia ($0.30–1.06/kg-H₂) than MCH ($0.54–1.22/kg-H₂) or methanol ($0.43–1.12/kg-H₂). Over the complete range of demand investigated, 10–350 tpd-H₂, the levelized cost of H₂ distributed to stations is aligned as methanol « ammonia ~ MCH. With pipelines at much larger scale, 6000 tpd-H₂, the levelized cost decreases by ~1 $/kg-H₂ for ammonia and MCH and much less for methanol. Methanol is a particularly attractive low-risk carrier in the transition phase with lower than 50-tpd H₂ demand.     

Hydrogen storage in organosilicon ionic liquids

New structures of ionic liquids have been studied as liquid organic hydrogen carriers. The hydrogenation of organosilicon compounds containing a carbazole fragment was carried out for the first time. The N–(CH₂)₃–Si fragment in the composition of the hydrogen carrier based on organosilicon moieties was found to be more suitable than the N–CH₂–Si bond. Ionic liquids with a carbazole fragment containing silicon atoms were synthesized for the first time. It was possible to significantly reduce the melting point of such ionic liquids by introducing an organosilicon linker between carbazole nitrogen and imidazolium ion. The synthesized ionic liquid is a liquid at room temperature. Hydrogenation-dehydrogenation experiments demonstrated that such ionic liquids are thermally stable up to at least 220 °C, and nearly quantitative conversion can be achieved. Both the hydrogenation and dehydrogenation processes were carried out using the same Pd/C catalyst. The theoretical total gravimetric hydrogen capacities for synthesized ionic liquids are 2.05% and 1.58%.     

A review of marine renewable energy storage

Marine renewable energies are promising enablers of a cleaner energy future. Some technologies, like wind, are maturing and have already achieved commercial success. Similar to their terrestrial counterparts, marine renewable energy systems require energy storage capabilities to achieve the flexibility of the 21st century grid demand. The unique difficulties imposed by a harsh marine environment challenge the unencumbered rise of marine renewable energy generation and storage systems. In this study, the fundamentals of marine renewable energy generation technologies are briefed. A comprehensive review and comparison of state‐of‐the‐art novel marine renewable energy storage technologies, including pumped hydro storage (PHS), compressed air energy storage (CAES), battery energy storage (BES), hydrogen energy storage (HES), gravity energy storage (GES), and buoyancy energy storage (ByES), are conducted. The pros and cons, and potential applications, of various marine renewable energy storage technologies are also compiled. Finally, several future trends of marine renewable energy storage technologies are connoted.     

Liquid hydrogen,methylcyclohexane, and ammonia as potential hydrogen storage: Comparison review

Among the several candidates of hydrogen (H₂) storage, liquid H₂, methylcyclohexane (MCH), and ammonia (NH₃) are considered as potential hydrogen carriers, especially in Japan, in terms of their characteristics, application feasibility, and economic performance. In addition, as the main mover in the introduction of H₂, Japan has focused on the storage of H₂, which can be categorized into these three methods. Each of them has advantages and disadvantages compared to the other. Liquid H₂ faces challenges in the huge energy consumption that occurs during liquefaction and in the loss of H₂ through boil-off during storage. MCH has its main obstacles in requiring a large amount of energy in dehydrogenation. Finally, NH₃ encounters high energy demand in both synthesis and decomposition (if required). In terms of energy efficiency, NH₃ is predicted to have the highest total energy efficiency, followed by liquid H₂, and MCH. In addition, from the calculation of cost, NH₃ with direct utilization (without decomposition) is considered to have the highest feasibility for massive adoption, as it shows the lowest cost (20–22 JPY·Nm³-H₂ in 2050), which is close to the government target of H₂ cost (20 JPY·Nm³-H₂ in 2050). However, in the case that highly pure H₂ (such as for fuel cell) is needed, liquid H₂ looks to be promising (24–25 JPY·Nm³-H₂ in 2050), compared with MCH and NH₃ with decomposition and purification.     

Power-to-gas as an option for improving energy self-consumption in renewable energy communities

Renewable Energy Communities (RECs) have been introduced by the Renewable Energy European Directive (REDII) in order to allow their members to collectively produce, consume, store and sell renewable energy. With the distributed generation deployment, the electricity injection into power grids has to be limited. Thereby, the RES management has to maximise the local energy self-consumption (SC). The present work deals with Power-to-Gas (PtG) application for blending hydrogen in the local gas grid for maximising the energy-SC, comparing it with traditional electric batteries (PtP). Moreover, this study investigate how SC-based tariffs for RECs can represent an indirect incentive for hydrogen production. To do so, a case study, consisting of 200 dwellings, has been analysed. Four PV configuration have been considered for evaluating different RES excess conditions. PtP and PtG systems have been implemented and compared each other. The hydrogen production cost has been assessed exploiting the renewable electricity incentive scheme.     

On-board and Off-board performance of hydrogen storage options for light-duty vehicles

Leading physical and materials-based hydrogen storage options are evaluated for their potential to meet the vehicular targets for gravimetric and volumetric capacity, cost, efficiency, durability and operability, fuel purity, and environmental health and safety. Our analyses show that hydrogen stored as a compressed gas at 350–700 bar in Type III or Type IV tanks cannot meet the near-term volumetric target of 28 g/L. The problems of dormancy and hydrogen loss with conventional liquid H₂ storage can be mitigated by deploying pressure-bearing insulated tanks. Alane (AlH₃) is an attractive hydrogen carrier if it can be prepared and used as a slurry with >50% solids loading and an appropriate volume-exchange tank is developed. Regenerating AlH₃ is a major problem, however, since it is metastable and it cannot be directly formed by reacting the spent Al with H₂. We have evaluated two sorption-based hydrogen storage systems, one using AX-21, a high surface-area superactivated carbon, and the other using MOF-177, a metal-organic framework material. Releasing hydrogen by hydrolysis of sodium borohydride presents difficult chemical, thermal and water management issues, and regenerating NaBH₄ by converting B–O bonds is energy intensive. We have evaluated the option of using organic liquid carriers, such as n-ethylcarbazole, which can be dehydrogenated thermolytically on-board a vehicle and rehydrogenated efficiently in a central plant by established methods and processes. While ammonia borane has a high hydrogen content, a solvent that keeps it in a liquid state needs to be found, and developing an AB regeneration scheme that is practical, economical and efficient remains a major challenge.     

Hydrogen vector for using PV energy obtained at Esperanza Base,Antarctica

The use of solar photovoltaic (PV) is universally considered valuable for its renewable and clean nature; solar energy is especially important in regions far from urban centers and power distribution networks. It is known that the loss due to the latitude and the atmospheric layer is partially offset in very different annual distribution (i.e., by the long summer days) and in sparsely populated areas, because of the clearer atmosphere. Even with these assumptions, low temperatures (snow often combined with strong winds) and the effects of seasonality are difficult obstacles for the proper use of solar PV energy at high latitudes.In this work, both analytical and experimental data of the solar resource at Esperanza Base, Antarctica, are presented. The PV modules were installed in a vertical configuration and NW–NE orientation, which not only maximizes performance but also mitigates the adverse effects due to the latitude. In order to overcome the very asymmetric annual irradiance distribution, the use of a system of hydrogen production and accumulation, is proposed for effective energy storage.The results of two years of evaluation of PV potential at Esperanza Base show that duplicating the PV capture area in Esperanza allows to obtain the same total annual energy than the maximum acquired in Buenos Aires (PV module facing north with optimum tilt for solar capture).To effectively overcome discontinuity of solar energy and its sharp drop in four of the twelve months of the year an appropriate hydrogen vector system is proposed and analyzed.     

Comparative techno-economic assessment of a large-scale hydrogen transport via liquid transport media

A large-scale point to point hydrogen transport is one strategy for a prospective energy import scenario for certain countries. The case for a hydrogen transport from Australia to Japan has been addressed in several studies. However, most studies lack transparency and detailed insights into the made assumptions thus a fair evaluation of different transport pathways is challenging. To address this issue, we developed a model where a large-scale point to point hydrogen transport of liquid hydrogen is compared with the transport via liquid organic hydrogen carrier (LOHC), namely via methyl cyclohexane and hydrogenated dibenzyl toluene. We analyzed, where energy is required along the different pathways, where hydrogen losses do occur and how the costs are put together. Furthermore, the influence of hydrogen feed costs is also considered. For hydrogen production costs of 5 €₂₀₁₈/kg_H2 the total delivery costs are in the range of 6.40– 8.10 €₂₀₁₈/kg_H2.     

Hydrogen as an energy vector in the islands’ energy supply

Hydrogen as an energy vector can increase penetration of renewable and intermittent sources in the energy supply of the islands and it can serve as an energy vector that may allow reaching 100% renewable energy supply of island communities. This article presents summary of the results of several case studies: Island of Mljet—Croatia, Porto Santo—Madeira, Terceira—Azores, and Malta. The islands were analysed by RenewIslands methodology and it was decided to apply hydrogen as an energy vector. Different scenarios for each island were modelled by H₂RES software and required installed powers of necessary technological options are described for chosen scenarios.     

Hydrogen-based systems for integration of renewable energy in power systems: Achievements and perspectives

This paper is a critical review of selected real-world energy storage systems based on hydrogen, ranging from lab-scale systems to full-scale systems in continuous operation. 15 projects are presented with a critical overview of their concept and performance. A review of research related to power electronics, control systems and energy management strategies has been added to integrate the findings with outlooks usually described in separate literature. Results show that while hydrogen energy storage systems are technically feasible, they still require large cost reductions to become commercially attractive. A challenge that affects the cost per unit of energy is the low energy efficiency of some of the system components in real-world operating conditions. Due to losses in the conversion and storage processes, hydrogen energy storage systems lose anywhere between 60 and 85% of the incoming electricity with current technology. However, there are currently very few alternatives for long-term storage of electricity in power systems so the interest in hydrogen for this application remains high from both industry and academia. Additionally, it is expected that the share of intermittent renewable energy in power systems will increase in the coming decades. This could lead to technology development and cost reductions within hydrogen technology if this technology is needed to store excess renewable energy. Results from the reviewed projects indicate that the best solution from a technical viewpoint consists in hybrid systems where hydrogen is combined with short-term energy storage technologies like batteries and supercapacitors. In these hybrid systems the advantages with each storage technology can be fully exploited to maximize efficiency if the system is specifically tailored to the given situation. The disadvantage is that this will obviously increase the complexity and total cost of the energy system. Therefore, control systems and energy management strategies are important factors to achieve optimal results, both in terms of efficiency and cost. By considering the reviewed projects and evaluating operation modes and control systems, new hybrid energy systems could be tailored to fit each situation and to reduce energy losses.     

Hydrogen as a long-term,large-scale energy storage solution when coupled with renewable energy sources or grids with dynamic electricity pricing schemes

One of the key challenges that still facing the adoption of renewable energy systems is having a powerful energy storage system (ESS) that can store energy at peak production periods and return it back when the demand exceeds the supply. In this paper, we discuss the costs associated with storing excess energy from power grids in the form of hydrogen using proton exchange membrane (PEM) reversible fuel cells (RFC). The PEM-RFC system is designed to have dual functions: (1) to use electricity from the wholesale electricity market when the wholesale price reaches low competitive values, use it to produce hydrogen and then convert it back to electricity when the prices are competitive, and (2) to produce hydrogen at low costs to be used in other applications such as a fuel for fuel cell electric vehicles. The main goal of the model is to minimize the levelized cost of energy storage (LCOS), thus the LCOS is used as the key measure for evaluating this economic point. LCOS in many regions in United States can reach competitive costs, for example lowest LCOS can reach 16.4¢/kWh in Illinois (MISO trading hub) when the threshold wholesale electricity price is set at $25/MWh, and 19.9¢/kWh in Texas (ERCOT trading hub) at threshold price of $20/MWh. Similarly, the levelized cost of hydrogen production shows that hydrogen can be produced at very competitive costs, for example the levelized cost of hydrogen production can reach $2.54/kg-H₂ when using electricity from MISO hub. This value is close to the target set by the U.S. Department of Energy.     

Purity of hydrogen released from the Liquid Organic Hydrogen Carrier compound perhydro dibenzyltoluene by catalytic dehydrogenation

While Liquid Organic Hydrogen Carrier (LOHC) systems offer a very promising way of infrastructure-compatible storage and transport of hydrogen, the hydrogen quality released from charged LOHC compounds by catalytic dehydrogenation has been a surprisingly rarely discussed topic to date. This contribution deals, therefore, with a detailed analysis of the hydrogen purity released from the hydrogen-rich Liquid Organic Hydrogen Carrier compound perhydro dibenzyltoluene (H18-DBT). We demonstrate, that high purity hydrogen (>99.999%) with carbon monoxide levels below 0.2 ppmv can be obtained from the dehydrogenation of H18-DBT if the applied H18-DBT had been carefully pre-dried and pre-purified prior to the dehydrogenation experiment. Indeed, the largest part of relevant impurities to comply with the hydrogen quality standard for fuel cells in road vehicles (ISO 14687-2) was found to originate from water and oxygenate impurities present in the applied, technical LOHC qualities.     

Hydrogen energy storage integrated hybrid renewable energy systems: A review analysis for future research directions

Hydrogen energy storage systems (HydESS) and their integration with renewable energy sources into the grid have the greatest potential for energy production and storage while controlling grid demand to enhance energy sustainability. This paper presents a bibliometric analysis based on a comprehensive review of the highly cited articles on HydESS to provide a detailed insight into future directions and applications. The study was carried out by using the Scopus database search engine to look for filtered keywords in the HydESS and related research. It can be demonstrated that the HydESS literature expanded rapidly from 2016 to 2021 compared to 2011 to 2015. It is found that 89.17% of published articles explained control and test systems-based methods, whereas 10.83% of publications discuss review assessments. Our analysis of highly cited articles on HydESS highlights several aspects, such as methods and systems, issues, difficulties, and challenges to establishing current constraints and research gaps. This evaluation can enhance operational performance, environmental friendliness, energy savings, uninterrupted power supply service, cost benefits, on-site generation, and adaptability. It would be beneficial for technology development and the growth of the hydESS industry. This study may act as a guideline not only for academics in determining the line of research and generating additional discoveries, but also for the government in formulating financial strategies.     

Role of hydrogen storage in renewable energy management for Ontario

Effective energy storage and management is needed to manage intermittent renewable energy systems. Several jurisdictions around the world are planning to reduce or close their coal power plants to allow for renewable energy expansion, such as Ontario, Canada. Hydrogen storage, which is a promising energy storage option, is capable of meeting energy requirements that will arise from the shutdown of coal plants. In this paper, both economic and environmental feasibility of a hydrogen system linked with wind and hydroelectric plants in Ontario will be investigated. The Princefarm wind power plant and Beck1 hydro plant with production capacities of 189 MW and 490 MW, respectively, are analyzed in a case study for comparison purposes. The environmental analysis demonstrates the advantageous role of hydrogen storage and energy conversion. The overall system life-cycle yields 31.02 g CO₂ eq per 1 kW h power output of the system when hydrogen energy storage is adopted. The payback periods of the systems linked with the Princefarm and Beck1 are also analyzed and found to be about 17 years.     

An energy system for the integration of renewable energy with energy storage in a frigid plateau region

面向高原高寒地区对稳定供热和供电的迫切需求,本文提出了一种新型的可再生能源与储能集成供能系统。该系统包括风力发电、光伏发电、水力发电、槽式太阳能集热器、储热系统、储电装置以及集成控制系统,实现了多种可再生能源高效利用;制定了一种考虑热电设备性能的实时能量管理策略,并建立了以年成本为主要优化目标的容量配置方法;利用该系统与优化方法对高原高寒地带民用住宅群的供能系统进行了优化设计,通过案例对比分析,验证了该集成供能系统容量配置方法和能量管理策略的可行性。研究结果为高原高寒地区供能系统的选择提供了有益的参考。     

A highly adaptable Ni catalyst for Liquid Organic Hydrogen Carriers hydrogenation

Reducing the cost of hydrogenation/dehydrogenation catalysts and improving the catalytic activity are essential steps to promote the commercial application of Liquid Organic Hydrogen Carriers (LOHCs) technology. We reported a series of highly adaptable 70 wt% Ni supported catalysts prepared by a facile co-precipitation method. The as-prepared catalysts were used in the hydrogenation of several promising LOHCs candidates, including benzene, N-propylcarbazole, N-ethylcarbazole and dibenzyltoluene. By adjusting the ratio of Al and Si, the Ni₇₀/AlSiO-1/1 catalyst with Al and Si in a molar ratio of 1:1 presents highest catalytic activity for hydrogenation of the above LOHCs, indicating the catalyst is highly adaptable for different LOHCs. The characterization results proved that the presence of SiO₂ could significantly weaken the interaction between metal and carrier and decrease the formation of NiAl₂O₄ species, which is beneficial to the reducibility of Ni. The introduced Al₂O₃ can inhibit the agglomeration of Ni and increase the dispersion of the metal. Besides, the Ni₇₀/AlSiO-1/1 catalyst was used to hydrogenate N-propylcarbazole by 5 cycles. In the fifth cycle, the hydrogen uptake reached the theoretical hydrogenation storage within 1.5 h, which suggested the excellent stability of the catalyst. Because of its low cost, high efficiency, high adaptation and highly stable, the self-made Ni catalyst has potential prospect in large-scale LOHCs application.     

Development of large MH tank system for renewable energy storage

Metal Hydrides (MH) can absorb large quantities of hydrogen at room temperature and ordinary pressure. Because MH can store hydrogen at a pressure less than 0.1 MPa safely and compactly, it is looked to as a method of storing hydrogen produced by electricity derived from renewable energy sources. To study this method of storing renewable energy, we made a MH tank system which could store hydrogen in the range of 1000 Nm³. A Mm-NiMnCo alloy was used for this MH tank system. MH becomes pulverized with absorbing and desorbing hydrogen, and this causes the problem of MH tank transformation owing to the partial distribution of the pulverized MH powders. Our MH material, named “Hydrage?,” was made using a technique to compose the MH powders with polymer materials without decreasing the hydrogen absorption and desorption rate. With this technique, the MH powders were immobilized, and strain on the MH tank was reduced. Furthermore, this technique enabled uniform dispersion of the MH powders, and high-density filling in MH tank was achieved relative to that attainable in a conventional MH tank. An MH tank system with a capacity of 1000 Nm³ is 1,800 mm in width, 3,150 mm in length, and 2,145 mm in height. The system for renewable energy storage consists of 9 tanks. About 7.2 tons of MH were used in this system. This system could work at temperatures from 25 to 35° C, and its maximum hydrogen absorption and desorption rate is 70 Nm³/h with a medium flow rate of 30 NL/min. This type of MH tank system, which can store a large amount of hydrogen safely and compactly, has the potential to become popular with various applications in the future.     

Hydrogen storage using liquid organic carriers: Equilibrium simulation and dehydrogenation reactor design

Liquid organic hydrogen carriers (LOHC) are unsaturated organic compounds used for chemical hydrogen storage. Using an equilibrium model of the LOHC N-ethylcarbazole, we discuss potential efficiency increases of hydrogen storage systems based on N-ethylcarbazole by the integration of low-temperature waste heat. N-ethylcarbazole is well suited for pressure swing operation with heat exchange between hydrogenation and dehydrogenation. We present and discuss kinetic data of the dehydrogenation reaction gathered in a tubular reactor that was mounted in different orientations and flow configurations. Similar maximum values of power density are reached in vertical and in horizontal orientation. Vertical orientation allows the favorable operation with counter-flow of the liquid carrier and the evolved hydrogen gas and radial heat transfer is significantly better than in horizontal orientation. In vertical reactor configurations, catalyst efficiency and operational stability are impaired at high void fractions. This issue can be reduced by dehydrogenation at elevated pressure and intermediate gas separation from the catalyst bed.