Green hydrogen-based E-fuels (E-methane,E-methanol,E-ammonia) to support clean energy transition: A literature review

Renewable power-to-fuel (PtF) is a key technology for the transition towards fossil-free energy systems. The production of carbon neutral synthetic fuels is primarily driven by the need to decouple the energy sector from fossil fuels dependance which are the main source of environmental issues. Hydrogen (H₂) produced from water electrolysis powered by renewable electricity and direct carbon dioxide (CO₂) captured from the flue gas generated by power plants, industry, transportation, and biogas production from anaerobic digestion, are used to convert electricity into carbon-neutral synthetic fuels. These fuels function as effective energy carriers that can be stored, transported, and used in other energy sectors (transport and industry). In addition, the PtF concept is an energy transformation that is capable of providing services for the balancing of the electricity grid thanks to its adaptable operation and long-term storage capacities for renewable energy surplus. As a consequence, it helps to potentially decarbonize the energy sector by reducing the carbon footprint and GHG emissions. This paper gives an overview on recent advances of renewable PtF technology for the e-production of three main hydrogen-based synthetic fuels that could substitute fossil fuels such as power-to-methane (PtCH₄), power-to-methanol (PtCH₃OH) and power-to-ammonia (PtNH₃). The first objective is to thoroughly define in a clear manner the framework which includes the PtF technologies. Attention is given to green H₂ production by water electrolysis, carbon capture & storage (CCS), CO₂ hydrogenation, Sabatier, and Haber Bosch processes. The second objective is to gather and classify some existing projects which deal with this technology depending on the e-fuel produced (energy input, conversion process, efficiency, fuel produced, and application). Furthermore, the challenges and future prospects of achieving sustainable large-scale PtF applications are discussed.     

Techno-economic analysis of hydrogen transportation infrastructure using ammonia and methanol

The transformation from a fossil fuels economy to a low carbon economy reshapes how energy is transmitted. Since most renewable energy is harvested in the form of electricity, hydrogen obtained from water electrolysis using green electricity is considered a promising energy vector. However, the storage and transportation of hydrogen at large scales pose challenges to the existing energy infrastructures, both regarding technological and economic aspects. To facilitate the distribution of renewable energy, a set of candidate hydrogen transportation infrastructures using methanol and ammonia as hydrogen carriers were proposed. A systematical analysis reveals that the levelized costs of transporting hydrogen using methanol and ammonia in the best cases are $1879/t-H₂ and $1479/t-H₂, respectively. The levelized cost of energy transportation using proposed infrastructures in the best case is $10.09/GJ. A benchmark for hydrogen transportation infrastructure design is provided in this study.     

Renewislands—Renewable energy solutions for islands

Increase of the global energy demand and environmental problems relating to fossil energy utilization request the new energy sources to replace the traditional fossil fuels. With respect to energy production, most of the islands in European Union and in the other parts of the world, depend on importation, mainly from oil and its related products. The global development of renewable energy technologies can assure sustainable supply of power for islands. To overcome the limitation of the sources of renewable energy, hydrogen is utilized as a storage medium integrated with intermittent renewable energy sources such as wind and solar. This paper introduces the programme of “Renewislands—Renewable Energy Solutions for Islands”, the work tasks, details of the design of the activities to develop solutions integrating intermittent renewable energy supply (RES), fuel cell (FC) and hydrogen infrastructure to promote RES and innovative decentralized power systems penetration in islands; main results achieved in each work packages are presented; in addition, the development of intermittent renewable energy penetration in specific European Islands are reviewed briefly.     

Solar thermal hybrids for combustion power plant: A growing opportunity

The development of technologies to hybridise concentrating solar thermal energy (CST) and combustion technologies, is driven by the potential to provide both cost-effective CO₂ mitigation and firm supply. Hybridisation, which involves combining the two energy sources within a single plant, offers these benefits over the stand-alone counterparts through the use of shared infrastructure and increased efficiency. In the near-term, hybrids between solar and fossil fuelled systems without carbon capture offer potential to lower the use of fossil fuels, while in the longer term they offer potential for low-cost carbon-neutral or carbon-negative energy. The integration of CST into CO₂ capture technologies such as oxy-fuel combustion and chemical looping combustion is potentially attractive because the same components can be used for both CO₂ capture and the storage of solar energy, to reduce total infrastructure and cost. The use of these hybrids with biomass and/or renewable fuels, offers the additional potential for carbon-negative energy with relatively low cost. In addition to reviewing these technologies, we propose a methodology for classifying solar-combustion hybrid technologies and assess the progress and challenges of each. Particular attention is paid to “direct hybrids”, which harness the two energy sources in a common solar receiver or reactor to reduce total infrastructure and losses.     

Energy and environmental policies in China and Taiwan

Given the environmental problems, especially in developing countries, as well as new environmental laws limiting the use of fossil fuels, governments seek to replace fossil fuels with clean energies like renewable energies. The purpose of this study was to assess the development of renewable energy as well as reviewing the laws and policies of China and Taiwan in this regard. We also constructed different scenarios based on national sources, in consideration of a significant increase in the electrical power generation and a reduction in the CO₂ emission. Focus is placed on the renewable energy development and a significant reduction in the CO₂ emission. The results showed that the photovoltaic solar systems have the greatest benefits in energy production and CO₂ emission reduction in China and Taiwan. However, due to economic consideration and technical problems, there is still a long way to go.     

Economic evaluation of renewable energy systems under varying scenarios and its implications to Korea’s renewable energy plan

This paper studies economics of renewable energy systems with consideration of future prospects on costs and uncertain external conditions that may affect competitiveness in the power plant market. The concept of learning curve is adopted to compute estimates on the costs of installing and operating renewable energy systems in the future; fuel costs and carbon price are modeled as scenario-dependent variables to analyze their impact on total costs under different scenarios. The proposed approach allows evaluation and comparison of total costs necessary in implementing renewable energy plans under varying technological, and/or economical conditions that face uncertainty at present. Moreover, analyzing the evaluation results further with techniques like sensitivity analysis can identify factors central to reducing the total costs. As an illustrative case-study, the Korean government’s renewable energy plan has been evaluated accordingly, under three different scenarios defined by International Energy Agency (IEA). The evaluation results indicate minor changes in total costs of achieving the plan among three scenarios, mainly due to counterbalancing between the price of fossil fuels and carbon price. Further analyses revealed factors central to lowering the total costs necessary in implementing the plan—hybridization between renewable energy systems, reduction of biomass production costs via technological innovation, increasing learning rates by focusing on R&D and international cooperation.     

Elementary science teacher candidates’ views on hydrogen as future energy carrier

Current energy infrastructure is not sustainable due to highly dependence to fossil fuels. Increasing energy usage obliges people to find new, economic, environmental friendly and safe energy options. Recent studies indicate that there are many alternative ways for fossil fuels such as solar, geothermal, wind and biomass. By using these renewable sources in tri-generation or multigeneration energy systems, the desired energy infrastructure can be set. On the other hand, hydrogen is seen as future energy carrier because of its advantages. There are many options to benefit from hydrogen such as fuel cells, direct combustion, or store as gas or liquid. However, awareness of society of the renewable energy usage and also hydrogen as energy carrier is not sufficient. In order to increase the awareness of the society, teachers have high responsibility. In this study, views of elementary science teacher candidates on hydrogen as future energy carrier are evaluated by using qualitative phenomenological research. Ten students from elementary science teacher department in Afyon Kocatepe University are selected for semi structured interview. The results of these interviews are analyzed by using content analysis method.     

Application,comparative study,and multi-objective optimization of a hydrogen liquefaction system utilizing either ORC or an absorption power cycle

Environmental degradation and global warming are presently two of the most pressing global concerns. According to the (IAE), around 80% of global energy demand has been met by fossil fuels in recent years, resulting in an increase in CO₂ emissions as the primary greenhouse gas. Switching to renewable energy sources and using more energy-efficient energy systems are vital for mitigating environmental challenges and reducing our reliance on fossil fuels, among other things. Hydrogen fuels are primary renewable resources because of their reduced cost and ability to produce net-zero CO₂ emissions. In the present study, a system is designed to generate power and liquid hydrogen from geothermal sources. The generated power by employing either the organic Rankin cycle (ORC) or absorption power cycle (APC) is compared to seek the best cycle performance from power generation standpoint. A comprehensive thermodynamic and economic modeling is carried out for the proposed system. In addition, a parametric study is applied to see which parameters affect the performance of the system. Multi-objective optimization is carried out to find the best operating point of the hydrogen liquefaction energy system. The system demonstrates better performance when APC is applied for power generation. The cost of generated liquid hydrogen by ORC and APC is 3.8 $/kg.LH₂ and 3.6 $/kg.LH₂, respectively. Furthermore, 0.014 $/kWh of electricity cost is reached by ORC compared to 0.012 $/kWh of APC. Parametric analysis shows that the higher the temperature and flow rate of the brine of geothermal fluid, the higher the efficiency and the lower cost. Finally, the multi-objective optimization pinpoints that the system's efficiency and unit product cost at the optimal ORC-based design is 33.85% and 0.0121 $/kWh. In comparison, the APC demonstrates better performance by 34.5% and 0.011 $/kWh.     

“Green” path from fossil-based to hydrogen economy: An overview of carbon-neutral technologies

While the dominant role of hydrogen in a sustainable energy future is widely accepted, the strategies for the transition from fossil-based to hydrogen economy are still actively debated. This paper emphasizes the role of carbon-neutral technologies and fuels during the transition period. To satisfy the world's growing appetite for energy and keep our planet healthy, at least 10 TW (or terawatt) of carbon-free power has to be produced by mid-century. Three prominent options discussed in the literature include: decarbonization of fossil energy, nuclear energy and renewable energy sources. These options are analyzed in this paper with a special emphasis on the role of hydrogen as a carbon-free energy carrier. In particular, the authors compare various fossil decarbonization strategies and evaluate the potential of nuclear and renewable energy resources to meet the 10 TW target. An overview of state-of-the-art technologies for production of carbon-free energy carriers and transportation fuels, and the assessment of their commercial potential is provided. It is shown that neither of these three options alone could provide 10 TW of carbon-neutral power without major changes in the existing infrastructure, and/or technological breakthroughs in many areas, and/or a considerable environmental risk. The authors propose a scenario for the transition from current fossil-based to hydrogen economy that includes two key elements: (i) changing the fossil decarbonization strategy from one based on CO₂ sequestration to one that involves sequestration and/or utilization of solid carbon, and (ii) producing carbon-neutral synthetic fuels from bio-carbon and hydrogen generated from water using carbon-free sources (nuclear, solar, wind, geothermal). This strategy would allow taking advantage of the existing fuel infrastructure without an adverse environmental impact, and it would secure a smooth carbon-neutral transition from fossil-based to future hydrogen economy.     

A transition toward a market expansion phase: Policies for promoting wind power in Taiwan

Considering the significant issues on global warming and environmental protection, the energy sector needs a long-term policy, by which renewable energies gradually replace conventional fossil fuels. In terms of an energy system, the development of renewable energies implies a challenge to existing energies like fossil fuels and nuclear power that have been for decades equipped with sound infrastructure and regulations. And a transformation of the energy system cannot expect any achievement without overcoming considerable opposition from vested interests involved with the fossil fuels technologies.     

Renewable energy resources and technologies applicable to Ireland

The energy consumed in Ireland is primarily achieved by the combustion of fossil fuels. Ireland's only indigenous fossil fuel is peat; all other fossil fuels are imported. As fossil fuels continually become more expensive, their use as an energy source also has a negative impact on the environment. Ireland's energy consumption can be separated into three divisions: transportation, electricity generation and heat energy. Ireland however has a vast range of high quality renewable energy resources. Ireland has set a target that 33% of its electricity will be generated from renewable sources by 2020 [I. Government. Delivering a Sustainable Energy Future for Ireland; 2007.]. The use of biomass, wind and ocean energy technologies is expected to play a major part in meeting this target. The use of renewable energy technologies will assist sustainable development as well as being a solution to several energy related environmental problems. This paper presents the current state of renewable energy technologies and potential resources available in Ireland. Considering Ireland's present energy state, a future energy mix is proposed.     

Scaling up carbon dioxide capture and storage: From megatons to gigatons

Carbon dioxide (CO₂) capture and storage (CCS) is the only technology that can reduce CO₂ emissions substantially while allowing fossil fuels to meet the world's pressing energy needs. Even though the technological components of CCS—separation of CO₂ from emissions, transport, and secure storage—are all in use somewhere in the economy, they do not currently function together in the manner required for large-scale CO₂ reduction. The challenge for CCS to be considered commercial is to integrate and scale up these components. Significant challenges remain in growing CCS from the megaton level where it is today to the gigaton level where it needs to be to help mitigate global climate change. These challenges, none of which are showstoppers, include lowering costs, developing needed infrastructure, reducing subsurface uncertainty, and addressing legal and regulatory issues. Progress will require a series of demonstration projects worldwide, an economically viable policy framework, and the evolution of a business model.     

Standalone hybrid system energy management optimization for remote village considering methane production from livestock manure

Recently, many efforts have been done to overcome increasing fuel consumption. One of the vital solutions is utilization of standalone renewable energy resources hybrid systems. This paper attempts to develop a cost-effective methodology to ascertain optimal design and energy management for a remote village. Different energy resources such as wind and solar, fuel cell, and energy storage systems are employed to satisfy total demands including agriculture, residential, school, and health center. Different hydrogen production methods are proposed to verify the efficiency of the developed methodology. In the proposed village, different waste types such as rice husk, maize straw, livestock, and residential wastes are used to generate the required hydrogen for fuel cells to generate electricity. The main objective of the proposed methodology is minimizing the total cost of the village including total costs of each Distributed Generation (DG), cost of natural gas consumption, penalty for interruption the demands, and cost of CO₂ emission. A Particle Swarm Optimization (PSO) algorithm is employed to solve the optimization problem by minimizing the total system costs while the customers required Loss of Power Supply Probability (LPSP) is satisfied. The suggested hybrid system not only increases the renewable energy penetration but also decreases the natural gas consumption. The results achieved in the course of the present study depict that utilization of energy produced from different types of wastes plays a significant role in conserving fossil fuels and overcoming the fossil fuels depletion. It is concluded from the results that there is about a 17.46% reduction in natural gas consumption when all available waste is utilized. In addition, considering 100% availability for the animal manure reduces the natural gas consumption by reformer from 2.373 to 1.605 million liters which means reduction of the natural gas consumption is 32.35%. The results conclude that H₂ produced by livestock waste is dominating among available wastes. However, there is about 18% reduction in the Cost of Energy (COE), when 100% availability is considered for this type of waste.     

Co-benefit analysis of incentives for energy generation and storage systems; a multi-stakeholder perspective

In this work, we are analyzing the advantages of energy incentives for all the stakeholders in an energy system. The stakeholders include the government, the energy hub operator, and the energy consumer. Two streams of energy incentives were compared in this work: incentives for renewable energy generation technologies and incentives for energy storage technologies. The first type aims increasing the share of renewable energies in the electricity system while the second type aims development of systems which use clean electricity to replace fossil fuels in other sectors of an energy system such as the transportation, residential and industrial sector. In this work, we are analyzing the advantages of energy incentives for all the stakeholders in an energy system. The stakeholders include the government, the energy hub operator, and the energy consumer. Two streams of energy incentives were compared in this work: incentives for renewable energy generation technologies and incentives for energy storage technologies. The first type aims to increase the share of renewable energies in the electricity system while the second type aims the development of systems which use clean electricity to replace fossil fuels in other sectors of an energy system such as the transportation, residential and industrial sector. The results of the analysis showed that replacing fossil fuel-based electricity generation with wind and solar power is a less expensive way for the energy consumer to reduce GHG emissions (60 and 92 CAD/ tonne CO_2e for wind and solar, respectively) compared to investing on energy storage technologies (225 and 317 CAD/ tonne CO_2e for Power-to-Gas and battery powered forklifts, respectively). However, considering the current Ontario's electricity mix, incentives for the Power-to-Gas and battery powered technologies are less expensive ways to reduce emissions compared to replacing the grid with wind and solar power technologies (1479 and 2418 CAD/ tonne CO_2e for wind and solar, respectively). Our analysis also shows that battery storage and hydrogen storage are complementary technologies for reducing GHG emissions in Ontario.     

Multi-objective optimal design of hybrid renewable energy systems using PSO-simulation based approach

Recently, the increasing energy demand has caused dramatic consumption of fossil fuels and unavoidable raising energy prices. Moreover, environmental effect of fossil fuel led to the need of using renewable energy (RE) to meet the rising energy demand. Unpredictability and the high cost of the renewable energy technologies are the main challenges of renewable energy usage. In this context, the integration of renewable energy sources to meet the energy demand of a given area is a promising scenario to overcome the RE challenges. In this study, a novel approach is proposed for optimal design of hybrid renewable energy systems (HRES) including various generators and storage devices. The ε-constraint method has been applied to minimize simultaneously the total cost of the system, unmet load, and fuel emission. A particle swarm optimization (PSO)-simulation based approach has been used to tackle the multi-objective optimization problem. The proposed approach has been tested on a case study of an HRES system that includes wind turbine, photovoltaic (PV) panels, diesel generator, batteries, fuel cell (FC), electrolyzer and hydrogen tank. Finally, a sensitivity analysis study is performed to study the sensibility of different parameters to the developed model.     

The achievement,significance and future prospect of China's renewable energy initiative

China's high-speed economic growth and ambitious urbanization depend heavily on the massive consumption of fossil fuel. However, the over-dependence on the depleting fossil fuels causes severe environmental problems, making China the largest energy consumer and the biggest CO₂ emitter in the world. Faced with significant challenges in terms of managing its environment and moving forward with the concept of sustainable economic development, the Chinese government plans to move away from fossil fuels and rely on renewables such as hydropower, wind power, solar power, biomass power and nuclear power. In this paper, the current status of China's renewable energy deployment and the ongoing development projects are summarized and discussed. Most recent developments of major renewable energy sources are clearly reviewed. Additionally, the renewable energy development policies including laws and regulations, economic encouragement, technical research and development are also summarized. This study showcases China's achievements in exploiting its abundant domestic renewable energy sources to meet the future energy demand and reducing carbon emissions. To move toward a low carbon society, technological progress and policy improvements are needed for improving grid access (wind), securing nuclear fuel supplies and managing safety protocols (nuclear), integrating supply chains to achieve indigenous manufacture of technologies across supply chains (solar). Beyond that, a preliminary prediction of the development of China's future renewable energy developments, and proposes targeted countermeasures and suggestions are proposed. The proposal involves developing smart-grid system, investing on renewable energy research, improving the feed-in tariff system and clarifying the subsidy system.     

Strategic trends for future energy policy: Evidence from China

In addition to taking advantage of clean technologies for energy from fossil fuels, China’s current policy is to focus on renewable energy especially hydropower and wind. However, this policy is not practical due to climatic problems for installing wind turbines and solar collectors in some Chinese provinces. In this study, China’s regional policy is examined in terms of renewable energy sources and solutions are provided. Based on the data available in the literature, it was found that the hydropower systems account for a significant share of energy required in China, except for Henan. Inner Mongolia was also introduced as the most important Chinese province for developing wind energy systems because over 30% of wind power capacity of China belongs to this province.     

Prospects of renewable energy - a feasibility study in the Australian context

Given the recent increasing public focus on climate change issues, there is a need for robust, sustainable and climate friendly power transmission and distribution systems that are intelligent, reliable, and green. Current power systems create environmental impacts as well as contributing to global warming due to their utilization of fossil fuels, especially coal, as carbon dioxide is emitted into the atmosphere. In contrast to fossil fuels, renewable energy is starting to be used as the panacea for solving climate change or global warming problems. This paper describes a feasibility study undertaken to investigate the potentialities of renewable energy including the prospective locations in Australia for renewable energy generation, in particular solar and wind energy. Initially, a hybrid model has been developed to investigate the prospects of wind energy for typical Australian region considering production cost, cost of energy, emission production and contribution from renewable energy using the Hybrid Optimization Model for Electric Renewable (HOMER), a computer model developed by the USA’s National Renewable Energy Laboratory (NREL). This model also explores suitable places around Australia for wind energy generation using statistical analysis. Subsequently, the usefulness of solar energy in the Australian context and suitable locations for solar energy generation are also investigated using a similar hybrid model. Finally, the model has been developed to investigate the prospects of renewable energy in particular wind and solar energy including specific locations in Australia that would be suitable for both wind and solar energy generation. From simulation analysis it is clearly observed that Australia has enormous potentialities for substantially increased use of renewable energy; a large penetration of renewable energy sources into the national power system would reduce CO₂ emissions significantly, contributing to the reduction of global warming.     

Generation of green hydrogen using self-sustained regenerative fuel cells: Opportunities and challenges

The ever-increasing energy demand, depleting fossil fuel reserves, and rising temperatures due to greenhouse gas emissions have necessitated the transition towards the generation of green and clean energy through renewable energy sources. Solar energy is one such renewable energy source that has received significant attention owing to its abundance and inexhaustibility. However, solar energy alone cannot replace fossil fuels in the energy portfolio. There exists a need to develop another clean energy source that can potentially act as an alternative to conventional fuels. Hydrogen proves to be an ideal candidate in this domain and can be sustainably generated by water electrolysis by powering the electrolyzer using solar energy. The hydrogen thus synthesized has net zero carbon emissions and is a suitable asset for decarbonizing the environment. This review encompasses the generation of hydrogen using PV-Electrolyzer systems and addresses the challenges associated with the same. Overcoming these drawbacks can ensure a strong position for hydrogen as an alternative fuel in the energy infrastructure. By employing electrolyzers that are fueled by renewable energy and then using that hydrogen to feed a fuel cell, this study aims to clarify the potential and constraints of producing green hydrogen. Since this area of research has not yet been fully investigated, a review article that enables and encourages academics to develop original solutions is urgently needed.     

Stakeholder perceptions of CO2 capture and storage in Europe: Results from a survey

During 2006, a survey was conducted of European energy stakeholders (industry, government, environmental non-governmental organizations (NGOs), researchers and academicians and parliamentarians). A total of 512 responses was received from 28 countries as follows: industry (28%), research (34%), government (13%), NGOs (5%) and parliamentarians (4%). Three-quarters of the sample thought that widespread use of CO₂ capture and storage (CCS) was ‘definitely’ or ‘probably necessary’ to achieve deep reductions in CO₂ emissions between now and 2050 in their own country. Only one in eight considered that CCS was ‘probably’ or ‘definitely not necessary’. For a range of 12 identified risks, 20–40% thought that they would be ‘moderate’ or ‘very serious’, whilst 60–80% thought that there would be no risks or that the risks would be ‘minimal’. A particular risk identified by nearly half the sample is the additional use of fossil fuels due to the ‘energy penalty’ incurred by CCS. Further concerns are that development of CCS would detract from investment in renewable energy technologies. Half of the respondents thought that incentives for CCS should be set either at the same level as those for renewables or at a higher level. Environmental NGOs were consistently less enthusiastic about CCS than the energy industry.