Thermodynamic analysis of an integrated power generation system driven by solid oxide fuel cell

A new integrated power generation system driven by the solid oxide fuel cell (SOFC) is proposed to improve the conversion efficiency of conventional energy by using a Kalina cycle to recover the waste heat of exhaust from the SOFC-GT. The system using methane as main fuel consists an internal reforming SOFC, an after-burner, a gas turbine, preheaters, compressors and a Kalina cycle. The proposed system is simulated based on the developed mathematical models, and the overall system performance has been evaluated by the first and second law of thermodynamics. Exergy analysis is conducted to indicate the thermodynamic losses in each components. A parametric analysis is also carried out to examine the effects of some key thermodynamic parameters on the system performance. Results indicate that as compressor pressure ratio increases, SOFC electrical efficiency increases and there is an optimal compressor pressure ratio to reach the maximum overall electrical efficiency and exergy efficiency. It is also found that SOFC electrical efficiency, overall electrical efficiency and exergy efficiency can be improved by increasing air flow rate. Also, the largest exergy destruction occurs in the SOFC followed by the after-burner, the waste heat boiler, the gas turbine. The compressor pressure ratio and air flow rate have significant effects on the exergy destruction in some main components of system.     

Thermodynamic analysis and assessment of novel ORC- DEC integrated PEMFC system for liquid hydrogen fueled ship application

Proton-exchange membrane fuel cell (PEMFC) and liquid hydrogen are gaining attention as a power generation system and alternative fuel of ship. This study proposes a novel PEMFC system, integrated with the organic Rankine cycle–direct expansion cycle (ORC-DEC), which exploits cold exergy from liquid hydrogen and low temperature waste heat generated by the PEMFC for application in a liquid hydrogen fueled ship. A thermodynamic model of each subsystem was established and analyzed from the economic, energy, and exergy viewpoints. Moreover, parametric analysis was performed to identify the effects of certain key parameters, such as the working fluid in the ORC, pressure exerted by the fuel pump, cooling water temperature of the PEMFC, and the stack current density on the system performance. The results showed that the proposed system could generate 221 kW of additional power. The overall system achieved an exergy and energy efficiency of 43.52 and 40.45%, respectively. The PEMFC system had the largest exergy destruction, followed by the cryogenic heat exchanger. Propane showed the best performance among the several investigated ORC working fluids and the system performance improved with the increase in the cooling water temperature of the PEMFC. The economic analysis showed that the average payback time of ORC-DEC was 11.2 years and the average net present value (NPV) was $295,268 at liquid hydrogen costing $3 to $7, showing the potential viability of the system.     

Thermodynamic and electrochemical analyses of a solid oxide electrolyzer for hydrogen production

In this paper, a modeling of the Solid Oxide Electrolysis Cell (SOEC), through energetic, exergetic and electrochemical modeling approaches, is conducted, and its performance, particularly through exergy efficiency, is analyzed under various operating conditions and state properties for optimum hydrogen production. In a comprehensively performed parametric study, at a single electrolysis cell scale, the effects of varying some operating conditions, such as temperature, pressure, steam molar fraction and the current density on the cell potential and hence the performance are investigated. In addition, at the electrolyzer system scale, the overall electrolyzer performance is investigated through energy and exergy efficiencies, in addition to the system's power density consumption, hydrogen production rate, heat exchange rates and exergy destruction parameters. The present results show that the overall solid oxide electrolyzer energy efficiency is 53%, while the exergy efficiency is 60%. The exergy destruction at a reduced operating temperature increases significantly. This may be overcome by the integration of this system with a source of steam production.     

Analysis and assessment of a novel hydrogen liquefaction process

In the present study, a novel supercritical hydrogen liquefaction process based on helium cooled hydrogen liquefaction cycles to produce liquid hydrogen is thermodynamically analyzed and assessed. The exergy analysis approach is used to study the exergy destruction rates in each component and the process efficiency. The energy and exergy efficiencies of liquefaction process are found to be 70.12% and 57.13%, respectively. In addition, to investigate the process efficiency more comprehensively to see how it is affected by varying process parameters and operating conditions, some parametric studies are undertaken to examine the impacts of different design variables on the energy efficiency, exergy efficiency and exergy destruction rates of the hydrogen liquefaction process. The results show that the increases in the cycle pressure of hydrogen and helium result in increasing hydrogen liquefaction process exergy efficiency and providing a smaller pinch point temperature difference of catalyst beds related with the heat transfer surface area and more efficiently process.     

Thermodynamic analysis of an LNG fuelled combined cycle power plant with waste heat recovery and utilization system

This paper has proposed an improved liquefied natural gas (LNG) fuelled combined cycle power plant with a waste heat recovery and utilization system. The proposed combined cycle, which provides power outputs and thermal energy, consists of the gas/steam combined cycle, the subsystem utilizing the latent heat of spent steam from the steam turbine to vaporize LNG, the subsystem that recovers both the sensible heat and the latent heat of water vapour in the exhaust gas from the heat recovery steam generator (HRSG) by installing a condensing heat exchanger, and the HRSG waste heat utilization subsystem. The conventional combined cycle and the proposed combined cycle are modelled, considering mass, energy and exergy balances for every component and both energy and exergy analyses are conducted. Parametric analyses are performed for the proposed combined cycle to evaluate the effects of several factors, such as the gas turbine inlet temperature (TIT), the condenser pressure, the pinch point temperature difference of the condensing heat exchanger and the fuel gas heating temperature on the performance of the proposed combined cycle through simulation calculations. The results show that the net electrical efficiency and the exergy efficiency of the proposed combined cycle can be increased by 1.6 and 2.84% than those of the conventional combined cycle, respectively. The heat recovery per kg of flue gas is equal to 86.27 kJ s^?1. One MW of electric power for operating sea water pumps can be saved. The net electrical efficiency and the heat recovery ratio increase as the condenser pressure decreases. The higher heat recovery from the HRSG exit flue gas is achieved at higher gas TIT and at lower pinch point temperature of the condensing heat exchanger. Copyright © 2006 John Wiley & Sons, Ltd.     

Energetic and exergetic performance analyses of a combined heat and power plant with absorption inlet cooling and evaporative aftercooling

In this paper, exergy method is applied to analyze the gas turbine cycle cogeneration with inlet air cooling and evaporative aftercooling of the compressor discharge. The exergy destruction rate in each component of cogeneration is evaluated in detail. The effects of some main parameters on the exergy destruction and exergy efficiency of the cycle are investigated. The most significant exergy destruction rates in the cycle are in combustion chamber, heat recovery steam generator and regenerative heat exchanger. The overall pressure ratio and turbine inlet temperature have significant effect on exergy destruction in most of the components of cogeneration. The results obtained from the analysis show that inlet air cooling along with evaporative aftercooling has an obvious increase in the energy and exergy efficiency compared to the basic gas turbine cycle cogeneration. It is further shown that the first-law efficiency, power to heat ratio and exergy efficiency of the cogeneration cycle significantly vary with the change in overall pressure ratio and turbine inlet temperature but the change in process heat pressure shows small variation in these parameters.     

Performance and parametric investigation of a binary geothermal power plant by exergy

Exergy analysis of a binary geothermal power plant is performed using actual plant data to assess the plant performance and pinpoint sites of primary exergy destruction. Exergy destruction throughout the plant is quantified and illustrated using an exergy diagram, and compared to the energy diagram. The sites with greater exergy destructions include brine reinjection, heat exchanger and condenser losses. Exergetic efficiencies of major plant components are determined in an attempt to assess their individual performances. The energy and exergy efficiencies of the plant are 4.5% and 21.7%, respectively, based on the energy and exergy of geothermal water at the heat exchanger inlet. The energy and exergy efficiencies are 10.2% and 33.5%, respectively, based on the heat input and exergy input to the binary Rankine cycle. The effects of turbine inlet pressure and temperature and the condenser pressure on the exergy and energy efficiencies, the net power output and the brine reinjection temperature are investigated and the trends are explained.     

Exergetic Optimization of Shell-and-Tube Heat Exchangers Using NSGA-II

In this article, a multi-objective exergy-based optimization through a genetic algorithm method is conducted to study and improve the performance of shell-and-tube type heat recovery heat exchangers, by considering two key parameters, such as exergy efficiency and cost. The total cost includes the capital investment for equipment (heat exchanger surface area) and operating cost (energy expenditures related to pumping). The design parameters of this study are chosen as tube arrangement, tube diameters, tube pitch ratio, tube length, tube number, baffle spacing ratio, and baffle cut ratio. In addition, for optimal design of a shell-and-tube heat exchanger, the method and Bell–Delaware procedure are followed to estimate its pressure drop and heat transfer coefficient. A fast and elitist nondominated sorting genetic algorithm (NSGA-II) with continuous and discrete variables is applied to obtain maximum exergy efficiency with minimum exergy destruction and minimum total cost as two objective functions. The results of optimal designs are a set of multiple optimum solutions, called “Pareto optimal solutions.” The results clearly reveal the conflict between two objective functions and also any geometrical changes that increase the exergy efficiency (decrease the exergy destruction) lead to an increase in the total cost and vice versa. In addition, optimization of the heat exchanger based on exergy analysis revealed that irreversibility like pressure drop and high temperature differences between the hot and cold stream play a key role in exergy destruction. Therefore, increasing the component efficiency of a shell-and-tube heat exchanger increases the cost of heat exchanger. Finally, the sensitivity analysis of change in optimum exergy efficiency, exergy destruction, and total cost with change in decision variables of the shell-and-tube heat exchanger is also performed.     

Energy and exergy analyses of a hybrid molten carbonate fuel cell system

This study deals with the energy and exergy analysis of a molten carbonate fuel cell hybrid system to determine the efficiencies, irreversibilities and performance of the system. The analysis includes the operation of each component of the system by mass, energy and exergy balance equations. A parametric study is performed to examine the effect of varying operating pressure, temperature and current density on the performance of the system. Furthermore, thermodynamic irreversibilities in each component of the system are determined. An overall energy efficiency of 57.4%, exergy efficiency of 56.2%, bottoming cycle energy efficiency of 24.7% and stack energy efficiency of 43.4% are achieved. The results demonstrate that increasing the stack pressure decreases the overpotential losses and, therefore, increases the stack efficiency. However, this increase is limited by the remaining operating conditions and the material selection of the stack. The fuel cell and the other components in which chemical reactions occur, show the highest exergy destruction in this system. The compressor and turbine on the other hand, have the lowest entropy generation and, thus, the lowest exergy destruction.     

Performance assessment and optimization of a biomass-based solid oxide fuel cell and micro gas turbine system integrated with an organic Rankine cycle

Rice straw is a potential energy source for power generation. Here, a biomass-based combined heat and power plant integrating a downdraft gasifier, a solid oxide fuel cell, a micro gas turbine and an organic Rankine cycle is investigated. Energy, exergy, and economic analyses and multi-objective optimization of the proposed system are performed. A parametric analysis is carried out to understand the effects on system performance and cost of varying key parameters: current density, fuel utilization factor, operating pressure, pinch point temperature, recuperator effectiveness and compressors isentropic efficiency. The results show that current density plays the most important role in achieving a tradeoff between system exergy efficiency and cost rate. Also, it is observed that the highest exergy destruction occurs in the gasifier, so improving the performance of this component can considerably reduce the system irreversibility. At the optimum point, the system generates 329 kW of electricity and 56 kW of heating with an exergy efficiency of 35.1% and a cost rate of 10.2 $/h. The capability of this system for using Iran rice straw produced in one year is evaluated as a case study, and it is shown that the proposed system can generate 6660 GWh electrical energy and 1140 GWh thermal energy.     

Exergy analysis of Joule–Thomson cryogenic refrigeration cycle with an ejector

In this paper, exergy method is applied to analyze the ejector expansion Joule–Thomson (EJT) cryogenic refrigeration cycle. The exergy destruction rate in each component of the EJT cycle is evaluated in detail. The effect of some main parameters on the exergy destruction and exergetic efficiency of the cycle is also investigated. The most significant exergy destruction rates in the cycle are in the compressor and ejector. The ejector pressure ratio and compressor isothermal efficiency have a significant effect on the exergetic efficiency of the EJT cycle. The exergy analysis results show the EJT cycle has an obvious increase in the exergetic efficiency compared to the basic Joule–Thomson refrigeration cycle. A significant advantage from the use of the ejector is that the total exergy destruction of the EJT cycle can be reduced due to much more decreasing of the exergy destruction rates in the compressor and expansion valve. The exergy analysis also reconfirms that applying an ejector is a very important approach to improve the performance of the Joule–Thomson cryogenic refrigeration cycle.     

Parametric optimization design for supercritical CO2 power cycle using genetic algorithm and artificial neural network

Supercritical CO₂ power cycle shows a high potential to recover low-grade waste heat due to its better temperature glide matching between heat source and working fluid in the heat recovery vapor generator (HRVG). Parametric analysis and exergy analysis are conducted to examine the effects of thermodynamic parameters on the cycle performance and exergy destruction in each component. The thermodynamic parameters of the supercritical CO₂ power cycle is optimized with exergy efficiency as an objective function by means of genetic algorithm (GA) under the given waste heat condition. An artificial neural network (ANN) with the multi-layer feed-forward network type and back-propagation training is used to achieve parametric optimization design rapidly. It is shown that the key thermodynamic parameters, such as turbine inlet pressure, turbine inlet temperature and environment temperature have significant effects on the performance of the supercritical CO₂ power cycle and exergy destruction in each component. It is also shown that the optimum thermodynamic parameters of supercritical CO₂ power cycle can be predicted with good accuracy using artificial neural network under variable waste heat conditions.     

Exergetical analysis of organic flash cycle with two-phase expander for recovery of finite thermal reservoirs

In this work exergetical performance analysis is carried out based on the second law of thermodynamics for organic flash cycle（OFC） using a two-phase expander instead of throttle expansion in order to recover efficiently finite thermal reservoirs.The exergy destructions（anergies） at various components of the system are theoretically investigated as well as the exergy efficiency.Results show that the anergy of heat exchanger or two-phase expander decreases while the anergy of throttle valve increases with increasing flash temperature,and the exergy efficiency has an optimum value with respect to the flash temperature.Under the optimal conditions with respect to the flash temperature,exergy efficiency increases with the heating temperature and the component having the largest exergy destruction varies with the flash temperature or heating temperature.     

Component exergy analysis of solar powered transcritical CO<Subscript>2</Subscript> rankine cycle system

In this paper,exergy analysis method is developed to assess a Rankine cycle system,by using supercritical CO2 as working fluid and powered by solar energy.The proposed system consists of evacuated solar collectors,throttling valve,high-temperature heat exchanger,low-temperature heat exchanger,and feed pump.The system is designed for utilize evacuated solar collectors to convert solar energy into mechanical energy and hence electricity.In order to investigate and estimate exergy performance of this system,the energy,entropy,exergy balances are developed for the components.The exergy destructions and exergy efficiency values of the system components are also determined.The results indicate that solar collector and high temperature heat exchanger which have low exergy efficiencies contribute the largest share to system irreversibility and should be the optimization design focus to improve system exergy effectiveness.Further,exergy analysis is a useful tool in this regard as it permits the performance of each process to be assessed and losses to be quantified.Exergy analysis results can be used in design,optimization,and improvement efforts.     

Comparing exergy losses and evaluating the potential of catalyst-filled plate-fin and spiral-wound heat exchangers in a large-scale Claude hydrogen liquefaction process

Detailed heat exchanger designs are determined by matching intermediate temperatures in a large-scale Claude refrigeration process for liquefaction of hydrogen with a capacity of 125 tons/day. A comparison is made of catalyst filled plate-fin and spiral-wound heat exchangers by use of a flexible and robust modeling framework for multi-stream heat exchangers that incorporates conversion of ortho-to para-hydrogen in the hydrogen feed stream, accurate thermophysical models and a distributed resolution of all streams and wall temperatures. Maps of the local exergy destruction in the heat exchangers are presented, which enable the identification of several avenues to improve their performances.The heat exchanger duties vary between 1 and 31 MW and their second law energy efficiencies vary between 72.3% and 96.6%. Due to geometrical constraints imposed by the heat exchanger manufacturers, it is necessary to employ between one to four parallel plate-fin heat exchanger modules, while it is possible to use single modules in series for the spiral-wound heat exchangers. Due to the lower surface density and heat transfer coefficients in the spiral-wound heat exchangers, their weights are 2–14 times higher than those of the plate-fin heat exchangers.In the first heat exchanger, hydrogen feed gas is cooled from ambient temperature to about 120 K by use of a single mixed refrigerant cycle. Here, most of the exergy destruction occurs when the high-pressure mixed refrigerant enters the single-phase regime. A dual mixed refrigerant or a cascade process holds the potential to remove a large part of this exergy destruction and improve the efficiency. In many of the heat exchangers, uneven local exergy destruction reveals a potential for further optimization of geometrical parameters, in combination with process parameters and constraints.The framework presented makes it possible to compare different sources of exergy destruction on equal terms and enables a qualified specification on the maximum allowed pressure drops in the streams. The mole fraction of para-hydrogen is significantly closer to the equilibrium composition through the entire process for the spiral-wound heat exchangers due to the longer residence time. This reduces the exergy destruction from the conversion of ortho-hydrogen and results in a higher outlet mole fraction of para-hydrogen from the process.Because of the higher surface densities of the plate-fin heat exchangers, they are the preferred technology for hydrogen liquefaction, unless a higher conversion to heat exchange ratio is desired.     

Energy and exergy analyses of a solar driven Mg–Cl hybrid thermochemical cycle for co-production of power and hydrogen

Analysis and performance assessment of a solar driven hydrogen production plant running on an Mg–Cl cycle, are conducted through energy and exergy methods. The proposed system consists of (a) a concentrating solar power cycle with thermal energy storage, (b) a steam power plant with reheating and regeneration, and (c) a hybrid thermochemical Mg–Cl hydrogen production cycle. The results show that higher steam to magnesium molar ratios are required for full yield of reactants at the hydrolysis step. This ratio even increases at low temperatures, although lowering the highest temperatures appears to be more favorable for linking such a cycle to lower temperature energy sources. Reducing the maximum cycle temperature decreases the plant energy and exergy efficiencies and may cause some undesirable reactions and effects. The overall system energy and exergy efficiencies are found to be 18.8% and 19.9%, respectively, by considering a solar heat input. These efficiencies are improved to 26.9% and 40.7% when the heat absorbed by the molten salt is considered and used as a main energy input to the system. The highest exergy destruction rate occurs in the solar field which accounts for 79% of total exergy destruction of the integrated system.     

Parametric analysis of a coal based combined cycle power plant

In the present paper thermodynamic analyses, i.e. both energy and exergy analyses have been conducted for a coal based combined cycle power plant, which consists of pressurized circulating fluidized bed (PCFB) partial gasification unit and an atmospheric circulating fluidized bed (ACFB) char combustion unit. Dual pressure steam cycle is considered for the bottoming cycle to reduce irreversibilities during heat transfer from gas to water/steam. The effect of operating variables such as pressure ratio, gas turbine inlet temperature on the performance of combined cycle power plant has been investigated. The pressure ratio and maximum temperature (gas turbine inlet temperature) are identified as the dominant parameters having impact on the combined cycle plant performance. The work output of the topping cycle is found to increase with pressure ratio, while for the bottoming cycle it decreases. However, for the same gas turbine inlet temperature the overall work output of the combined cycle plant increases up to a certain pressure ratio, and thereafter not much increase is observed. The entropy generation, the irreversibilities in each component of the combined cycle and the exergy destruction/losses are also estimated. Copyright © 2005 John Wiley & Sons, Ltd.     

Exergy modeling of a new solar driven trigeneration system

In this paper, exergy modeling is used to assess the exergetic performance of a novel trigeneration system using parabolic trough solar collectors (PTSC) and an organic Rankine cycle (ORC). Four cases are considered: electrical-power, cooling-cogeneration, heating-cogeneration, and trigeneration. In this trigeneration system a single-effect absorption chiller is utilized to provide the necessary cooling energy and a heat exchanger is utilized to provide the necessary heating energy. The trigeneration system considered is examined using three modes of operation. They are: solar mode during the low-solar radiation time of the day, solar and storage mode during the high-solar radiation time of the day, and storage mode during night time. The storage mode is operated through the heat collected in a thermal storage tank during the solar and storage mode. The exergy efficiencies and exergy destruction rates are examined under the variation of the ORC evaporator pinch point temperature, ORC pump inlet temperature, and turbine inlet pressure. This study reveals that the maximum electrical-exergy efficiency for the solar mode is 7%, for the solar and storage mode is 3.5%, and for the storage mode is 3%. Alternatively, when trigeneration is used, the exergy efficiency increases noticeably. The maximum trigeneration-exergy efficiency for the solar mode is 20%, for solar and storage mode is 8%, and for the storage mode is 7%. Moreover, this study shows that the main sources of exergy destruction rate are the solar collectors and ORC evaporators. Therefore, careful selection and design of these two components are essential to reduce the exergy destructed by them and, thus, increase the exergy efficiencies of the system.     

Thermodynamic viability of a new three step high temperature Cu-Cl cycle for hydrogen production

A new three step high temperature Cu-Cl thermochemical cycle for hydrogen production is presented. The performance of the proposed cycle is investigated through energy and exergy approaches. Furthermore, the effects of various parameters, such as the temperatures of the steps of the cycle and power plant efficiency, on various energy and exergy efficiencies are assessed with parametric studies. The results show that the exergy and energy efficiencies of the proposed cycle are 68.3% and 32.0%, respectively. In addition, the exergy analysis results reveal that the hydrogen production step has the maximum specific exergy destruction with a value of 150.9 kJ/mol. The results suggest that proposed cycle may provide enhanced options for high temperature thermochemical cycles by improving thermal management without causing a sudden temperature jump/fall between the hydrogen production step and other steps.     

Energy and exergy analysis of hydrogen production by solid oxide steam electrolyzer plant

Energy and exergy analysis has been conducted to investigate the thermodynamic–electrochemical characteristics of hydrogen production by a solid oxide steam electrolyzer (SOSE) plant. All overpotentials involved in the SOSE cell have been included in the thermodynamic model. The waste heat in the gas stream of the SOSE outlet is recovered to preheat the H₂O stream by a heat exchanger. The heat production by the SOSE cell due to irreversible losses has been investigated and compared with the SOSE cell's thermal energy demand. It is found that the SOSE cell normally operates in an endothermic mode at a high temperature while it is more likely to operate in an exothermic mode at a low temperature as the heat production due to overpotentials exceeds the thermal energy demand. A diagram of energy and exergy flows in the SOSE plant helps to identify the sources and quantify the energy and exergy losses. The exergy analysis reveals that the SOSE cell is the major source of exergy destruction. The energy analysis shows that the energy loss is mainly caused by inefficiency of the heat exchangers. The effects of some important operating parameters, such as temperature, current density, and H₂O flow rate, on the plant efficiency have been studied. Optimization of these parameters can achieve maximum energy and exergy efficiencies. The findings show that the difference between energy efficiency and exergy efficiency is small as the high-temperature thermal energy input is only a small fraction of the total energy input. In addition, the high-temperature waste heat is of high quality and can be recovered. In contrast, for a low-temperature electrolysis plant, the difference between the energy and exergy efficiencies is more apparent because considerable amount of low-temperature waste heat contains little exergy and cannot be recovered effectively. This study provides a better understanding of the energy and exergy flows in SOSE hydrogen production and demonstrates the importance of exergy analysis for identifying and quantifying the exergy destruction. The findings of the present study can further be applied to perform process optimization to maximize the cost-effectiveness of SOSE hydrogen production.