共查询到20条相似文献,搜索用时 140 毫秒
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1,4-二羟基-2-萘甲酸以改进的Homeger法进行制备,具有操作方便,溶剂耗费少,不使用苯及乙醚的萃取步骤,总反应时间也缩短到原来的1/4,而且产品纯度和产率都有提高。改进后的方法用于大规模工业生产将产生较好的经济效益。 相似文献
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水相催化法制备1-苯基-3-羟基-1,2,4-三唑汪传木(安徽省池州农药厂,247100)1-苯基-3-羟基-1.2.4-三唑(以下简称苯唑醇)是合成新型杀虫杀螨剂三唑磷的重要中间体。目前,国内生产三唑磷的厂家较多,均采用溶剂法制备苯唑醇,该方法制备... 相似文献
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1,4-二羟基-2-萘甲酸以改进的Homeger法进行制备,具有操作方便,溶剂耗费少,不使用苯及乙醇的萃取步骤,总反应时间也缩短到原来的1/4,而且产品纯度和产率都有提高。改进后的方法用于大规模工业生产将产生较好的经济效益。 相似文献
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采用μ-BondapakC(18)固定相、甲醇/水(90/10)和0.5mol/LNa2HPO4流动相,300nm检测波长和1.2ml/min流速,对2-羟基-3-萘甲酸中小量2-萘酚进行高效液相色谱测定,取得了较满意的结果。 相似文献
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介绍了N,N-双(2-羟基乙基)-N-(3-十二烷氧基-2-羟丙基)甲铵硫酸酯盐的定量分析方法,该法操作简便,分析结果准确,为生产和应用该表面活性剂的厂家提供了可靠的分析手段。 相似文献
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研究了在不同的溶剂和后处理方式下3-硝基-N-乙基中文唑单溴化的三种方法:(1)冰醋酸-水稀释法;(2)冰醋酸-蒸馏法;(3)1,2-二氯乙烷-蒸馏法。比较了三种方法各自的优缺点,认为(3)法是较佳的工业化路线。 相似文献
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A clean, simple and efficient method for the synthesis of 3,3′-(arylmethylene)bis(2-hydroxynaphthalene-1,4-dione) derivatives has been developed which uses the reaction of 2-hydroxynaphthalene-1,4-dione and aromatic aldehydes in the presence of a catalytic amount of LiCl in aqueous media. To the best of our knowledge, this is the first report on such a synthesis of 3,3′-(arylmethylene)bis(2-hydroxynaphthalene-1,4-dione). 相似文献
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A low-cost adsorbent was prepared from sludge and straw by pyrolysis in a dried state with the surface area of the adsorbent of 829.49 ma. g-l, micropore volume of 0.176 cm2·g-1 and average pore radius of 5.0 nm. The kinetic, equilibrium isotherm and thermodynamic characteristics of trisodium 1-(1-naphthylazo)-2-hydroxynaphthalene- 4',6,8-trisulphonate (acid scarlet 3R) onto the adsorbent from sludge and straw were investigated. The results indicated that the pseudo second order adsorption was the predominant adsorption mechanism of acid scarlet 3R. Thus, the adsorption phenomenon was suggested as a chemical process. The adsorption data were fitted better with Langmuir model than Freundlich model, indicating that the adsorption of acid scarlet 3R belonged to the monolayer adsorption and mainly occurred in micropores. 相似文献
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Afshin Yazdani-Elah-Abadi Razieh Mohebat Reza Heydari 《Polycyclic Aromatic Compounds》2018,38(1):92-101
Silica sulfuric acid (SiO2–SO3H) has been used as an effective and reusable solid catalyst for the one-pot, two-step, four-component microwave-assisted synthesis of benzo[a]chromeno[2,3-c]phenazine derivatives by the condensation reaction of 2-hydroxynaphthalene-1,4-dione, o-phenylenediamine, aldehydes, and cyclic 1,3-dicarbonyl compounds. This new procedure has a number of advantages such as: high yields, very short reaction time, operational simplicity, simple work-up procedures and avoidance of hazardous or toxic catalysts, and organic solvents and is devoid of inessential derivatization and generation of hazardous substances. Moreover, the catalyst shows high thermal stability and can be recovered and reused without loss of reactivity. 相似文献
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《Dyes and Pigments》2009,80(3):273-275
An efficient method for the synthesis of 13-aryl-5H-dibenzo[b,i]xanthene-5,7,12,14(13H)-tetraone derivatives by the reaction of 2-hydroxynaphthalene-1,4-dione and aldehydes in the presence of a catalytic amount of p-toluene sulfonic acid under solvent-free conditions at 100 °C is described. 相似文献
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6-羟基-2-萘磺酸钠分别和CuSO4,MgSO4,ZnSO4、Co(phen)3Cl2反应,物质的量比为5∶1,得到一系列铜、镁、锌、钴、镍配合物并通过红外和元素分析确定结构。测定了钴的配合物的单晶结构,结果表明,钴配合物1属于三斜晶系,P-1空间群,a=12.4120(15),b=12.4711(16),c=20.090(2),α=90.0450(10)°,β=103.161(2)°,γ=113.519(2)°,V=2761.9(6)3,Z=2。 相似文献
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D. Yu. Marchenko S. I. Petrov D. A. Sandzhieva A. G. Dedov 《Theoretical Foundations of Chemical Engineering》2016,50(4):648-654
The possibilities of using new reagent compositions based on diazo and azo dyestuff components that contain sulfonic groups are considered to determine nitrites in the presence of the contents of chlorides. New reagent compositions based on 1-hydroxynaphthalene-3,6-disulfonic acid in combination with 2,6- nitroorthanilic and 2,6-dichlorosulfanilic acids have been used to create indicator powders and indicator papers for the quantitative test determination of nitrite ions. Test methods based on sustainable indicator powders and indicator papers have been developed with the use of the ilPro portable spectrophotometer and PlustekSmartPhoto P60 compact mobile scanner combined with the Vuescan universal scan program. It has been shown that the sensitivity of the visual determination of nitrites in liquids using indicator papers is 0.5 mg/L. The sensitivity of the test method that uses indicator papers, the PlustekSmartPhoto P60 mobile scanner, and the ilPro portable spectrophotometer is 0.2 mg/L. Upon using the indicator powder and i1Pro portable spectrophotometer, the range of defined concentrations of nitrite ions is 0.01–5 mg/L. 相似文献
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氯虫苯甲酰胺的合成及表征 总被引:1,自引:0,他引:1
以3-甲基-2-硝基苯甲酸为原料通过RaneyNi加氢还原制得3-甲基-2-氨基苯甲酸,接着与N-氯代丁二酰亚胺(NCS)反应制得3-甲基-2-氨基-5-氯苯甲酸,然后3-甲基-2-氨基-5-氯苯甲酸与氯化亚砜在75~80℃下回流3h后,接着缓慢滴加甲胺水溶液,在室温下搅拌反应12h,得到2-氨基-5-氯-N,3-二甲基甲酰胺。然后再与3-溴-1-(3-氯吡啶-2-吡啶基)-1 H-吡唑-5-甲酸在-5~0℃下滴加甲基磺酰氯反应得到产品氯虫苯甲酰胺,四步总收率37.0%,产品HPLC纯度是96.05%。 相似文献
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以Ni(NO3)2?6H2O、Zn(NO3)2?6H2O、Fe Cl3?6H2O为原料,采用均相沉淀法制备了层状形貌的Zn~(2+)-Ni~(2+)-Fe~(3+)-LDHs催化剂材料。吡啶作为分子探针,通过原位红外技术对Zn~(2+)-Ni~(2+)-Fe~(3+)-LDHs的酸性中心和酸量进行了研究。研究表明该材料同时存在路易斯酸(L酸)和布朗克(B酸)酸性中心,其酸量分别为4.4 mmol/g、2.6 mmol/g,L酸酸强度强B于酸。 相似文献