共查询到19条相似文献,搜索用时 91 毫秒
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目的研究滑石粉填充改性对聚丁二酸丁二醇酯(PBS)力学性能、热稳定性与结晶性能等的影响。方法将滑石粉经过钛酸酯偶联剂表面改性后,通过双螺杆挤出机将不同份数的改性滑石粉填充到PBS基体中挤出改性。结果当滑石粉质量分数分别小于15%时,其对复合材料的拉伸强度与断裂伸长率的影响并不显著。热失重分析表明,滑石粉质量分数为5%~10%时,PBS复合材料的热稳定性得到显著提高,热分解温度由纯料的357℃增加至372℃。X射线衍射图谱表明滑石粉的加入并没有改变PBS的晶型,仅给晶胞参数带来一些微小的改变。电镜结果表明,在质量分数15%以下时,滑石粉在PBS基体中具有较为均一的分布,但是这种均一的分布会随着滑石粉质量分数的增加而逐渐变差。结论随着滑石粉质量分数的增加,复合材料的硬度逐渐增强,结晶度逐渐下降。钛酸酯偶联剂的加入能够提升复合材料的界面粘合力并给材料带来了良好的力学性能。此外,PBS/滑石粉复合材料的热稳定性与滑石粉在PBS基体中的分布状态有着密切联系。 相似文献
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聚丁二酸丁二醇酯及聚丁二酸/己二酸-丁二醇酯在微生物作用下的降解行为 总被引:8,自引:0,他引:8
研究了聚丁二酸丁二醇酯(PBS)及其共聚物聚丁二酸/己二酸-丁二醇酯(PBSA)薄膜在可控堆肥条件下的宏观生物降解行为,结果显示,PBS和PBSA薄膜具有良好的生物降解性能,降解过程经历三个阶段:诱导期、加速期和平坦期。对堆肥中的微生物进行分离和筛选,发现杂色曲霉菌对PBS和PBSA的生物降解能力最强。进一步研究PBS和PBSA薄膜在杂色曲霉菌作用下的微观生物降解行为,结果表明,PBSA薄膜比PBS薄膜具有更快的生物降解速率。 相似文献
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采用熔融共混与开炼压延制备聚丁二酸丁二醇酯(PBS)和羟基封端超支化聚氨酯(HBPU)的复合膜。使用X射线衍射(XRD)、差示扫描量热(DSC)、热重分析(TG)和万能试验机对其结晶性、热性能和力学性能进行了研究;采用土埋法在陕西花园土中对复合膜进行降解。结果表明,随着HBPU的增加,复合膜结晶度均有所降低,当HBPU的质量分数为6%时达到25.7%;DSC结果表明,HBPU提高了PBS的结晶温度;随着HBPU的增加,复合材料的热稳定性有所下降;在拉力测试中,复合材料的断裂伸长率得到了显著提高,6%时复合材料的断裂伸长率达到75%;复合膜降解后表面出现明显裂纹。HBPU对PBS改性,降低了PBS的结晶度,提高了复合材料的韧性。 相似文献
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采用双螺杆挤出机制备了聚丁二酸丁二醇酯/水滑石(PBS/HT)纳米复合材料,并详细研究了复合材料的形貌及分散、结晶和熔融行为,晶体结构和球晶形态以及力学性能。采用SEM、TEM、DSC、XRD、POM和DMA进行了表征测试,结果表明层状水滑石纳米粒子较好地分散在PBS基体中,加入HT具有明显的异相成核能力,显著地提高了PBS的结晶温度。偏光显微镜结果显示,随着HT加入量的增加PBS球晶密度增加,球晶尺寸细化。HT添加量为1%(质量分数)时复合材料的拉伸强度增大,随着HT加入量增加断裂伸长率下降而弹性模量增加。动态机械测试表明复合材料的储能模量显著提高。 相似文献
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以氢氧化钠溶液为媒介,研究了分子量、结晶度等因素对聚丁二酸丁二醇酯(PBS)降解性能的影响,并对其降解机理进行了初步探讨。结果表明,PBS的降解性能不仅与结晶度有关,还受到内部球晶形态的影响;分子量仅对降解初期有较大影响,并且随着分子量的增加,降解速率下降不明显。试样降解前后的凝胶渗透色谱(GPC)和差示扫描量热分析(... 相似文献
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PBS-g-MAH及MAH对PBS/淀粉合金力学性能的影响 总被引:2,自引:1,他引:2
通过在聚丁二酸丁二醇酯(PBS)/淀粉合金中加入PBS-g-MAH,改善合金材料的力学性能;同时通过"一步法"挤出改善材料的力学性能.研究了PBS-g-MAH和MAH的加入量对材料力学性能的变影响;通过SEM及DSC观察了合金中两相相容性的改善情况和材料熔融热行为的变化.结果表明,两种改性方法改善了合金材料的力学性能.当体系中含有5%接枝物时,合金的拉伸强度相对于不加助剂提高68%,冲击强度提高70%;当MAH加入量为PBS的1%时,其拉伸强度提高约94%,冲击强度提高143%;体系的相容性也得提高,合金的熔点也发生了不同程度的变化. 相似文献
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四针状ZnOW的微波吸收及微波-热转换特性研究 总被引:8,自引:3,他引:5
用四针状ZnOW为吸波剂主要成份制备了一种轻质高效吸波涂料,并对其在Ku波段的吸收特性作了初步研究。结果表明,在13.5~17.5GHz的Ku波段,上述材料雷达波反射率均达到-10~-20dB。进一步的研究表明,涂层的吸波效果与ZnOw针状体的长长比有关,在13.50~17.50GHz的频率范围内,控制ZnOw针状体平均长径比为30~50,可获得最佳效果。ZnOw微波-热转换的初步研究发现,ZnOw及其复合材料具有优异的微波-热转换性能,当ZnOw针状体长径比为40~60的情况下,表观比重为0.15~0.18g/cm^2,可以达到最佳发热效率。 相似文献
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采用熔融共混法制备了微晶纤维素/聚丁二酸丁二醇酯(MCC/PBS)复合材料,用高级毛细管流变仪和旋转流变仪分别测定复合材料的稳态流变性能和动态流变性能,研究了不同MCC含量、不同温度对复合材料流变行为的影响。结果表明,复合材料的黏度与剪切速率的流变曲线符合幂律流体的特征,可以用幂律模型对其进行拟合;复合材料的黏度与温度的关系可用Arrhenius方程对其进行描述。在线性黏弹区,复合材料的储能模量(G′)维持恒定,当应变(γ)超过临界值(γ_c)时,复合材料进入非线性黏弹区,出现了"Payne"效应,并且随着MCC含量的增加,γ_c下降。在角频率(ω)扫描范围内,复合材料的储能模量(G′)、损耗模量(G″)和复数黏度|η*|均随着MCC含量的增加而增大。在相同的MCC含量下,G″的值始终大于G′的值,损耗因子(tanδ)均大于1。在低频区,G′出现第二平台。MCC/PBS复合材料加工流变特性的研究,对指导MCC/PBS复合材料的成型加工具有一定的价值。 相似文献
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Qun-Ying Zhu Yi-Song HeJian-Bing Zeng Qing Huang Yu-Zhong Wang 《Materials Chemistry and Physics》2011
Multiblock copolyester (PBS-b-PES) containing poly(butylene succinate) (PBS) and poly(ethylene succinate) (PES) was successfully synthesized by chain-extension of dihydroxyl terminated PBS (HO-PBS-OH) and PES (HO-PES-OH) using 1,6-hexmethylene diisocyanate (HDI) as a chain extender. The chemical structures, molecular weights, crystallization behaviors, thermal and mechanical properties of the copolyesters were characterized by proton nuclear magnetic resonance spectroscopy (1H NMR), gel permeation chromatography (GPC), differential scanning calorimetry (DSC), thermogravimetry analysis (TGA), wide-angle X-ray diffraction (WAXD), tensile testing and hydrolytic degradation. High-molecular-weight copolyesters with Mw more than 2.0 × 105 g mol−1 were easily obtained through chain-extension. The copolyesters showed a single glass transition temperature (Tg) which increased with PES content. The melting point temperature (Tm) and relative degree of crystallinity (Xc) of the copolyesters decreased first and then increased with PES content. The copolyesters manifested excellent mechanical properties, for example, PBS5-b-PES5 had fracture stress of 61.8 MPa and fracture strain of 1173%. The chain-extension reaction provided a very effective way to produce high molecular weight multiblock copolyesters. 相似文献
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为进一步改善聚丁二酸丁二醇酯(PBS)的力学性能和耐热性能,采用硅烷偶联剂KH550改性微米六方氮化硼(h-BN),对PBS进行共混改性,通过熔融共混与开炼压延工艺制备了具有较高耐热性的h-BN-KH550/PBS复合膜。对h-BN-KH550粒子结构和复合膜的力学性能、聚集态结构、断面形貌、结晶性能及热稳定性进行了测试和表征。结果表明:与PBS相比,h-BN-KH550/PBS复合膜的力学性能得到改善,当KH550与h-BN质量比为2∶50、h-BN-KH550与PBS质量比为3∶50时,综合力学性能最优;h-BN-KH550粒子可在PBS中均匀分散;在PBS结晶过程中,h-BN-KH550作为成核剂,使PBS的结晶速率加快,结晶度增大;h-BN-KH550/PBS复合膜的热稳定性显著提高,当h-BN-KH550与PBS质量比为3∶50时,复合膜热分解过程中质量损失为5%、10%、50%时的温度(T5d、T10d、T50d)和热分解峰值温度(Tp)分别提高了30.0、22.6、9.5和10.0℃。 相似文献
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The effect of electron beam treatment on the thermomechanical and flexural properties of chopped silk fiber-reinforced poly(butylene succinate) (PBS) green composites was studied for the first time in this work. The surface topological changes in worm silk fibers before and after the electron beam irradiation at various doses (5–100?kGy) were observed. Dynamic mechanical and flexural properties and thermal expansion behavior of neat PBS and silk/PBS green composites were investigated by means of dynamic mechanical analysis, three-point flexural test, and thermomechanical analysis. The irradiated silk/PBS composite result was compared with neat PBS and un-irradiated silk/PBS counterparts. It was concluded that use of electron beam irradiation at an appropriate dosage may contribute to an enhancement of the dynamic mechanical and flexural properties as well as to the thermodimensional stability of silk-based green composites. The result revealed that the property enhancement was most profound at the electron beam absorption dose of 20?kGy. 相似文献
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The mechanical and dynamic mechanical properties, morphology, melting and crystallization behavior, as well as thermal stability of poly(butylene succinate)/distillers grains (PBS/DG) composites with different DG contents were investigated. The tensile modulus, crystallization rate, and crystallinity of PBS in the composites were efficiently enhanced in the presence of DG. The thermogravimetric analysis of the PBS/DG composites showed that their flame retardancy leveled up. The scanning electron microscopy analysis of the PBS/DG composites indicated that the DG was not damaged during the melt processing. These results supported the application of DG as fillers in polymer composites. Consequently, this study opened a new application of DG and has potential to decrease the cost of PBS-based materials with a variety of enhanced properties. 相似文献