Aqueous Tape Casting Process with Styrene-acrylic Latex Binder

A commercial styrene-acrylic latex binder has been investigated as a good binder for aqueous Al₂O₃ suspensions tape-casting process. This paper focuses on the forming film mechanism of latex binder, the rheological behaviors of the suspensions, physical properties of green tapes and drying process of aqueous slurries with latex binder system. The drying process of the alumina suspensions is shown to follow a two-stage mechanism (the first stage: evoporation controlled process; and the second stage: diffusion controlled process). During the drying stage of the suspensions, the compressive force presses the latex particles and makes them be distorted, which results in cross-linking structure in contacted latex particles of the solidified tapes. A smooth-surface and high-strength green tape was fabricated by aqueous tape casting with latex binder system. The results from the SEM images of the crossing section microstructure of green tapes show that the latex is a very suitable binder for aqueous tape casting. CUI Xue-min: Born in 1971 Funded by “973” Program (No. G2000067204-01)     

流延成型法制备三氧化二铝陶瓷膜基体 (Ⅰ)浆体的制备和流延成型

采用水基浆体流延成型法制备陶瓷膜基体。讨论了分散剂、乳胶液粘结剂、塑化剂对三氧化二铝浆体流动性、韧性和机械强度的影响。实验结果表明 :不加乳液粘结剂 ,分散剂质量分数 0 1 %时 ,浆体的流动性较好 ;采用醋丙和苯丙乳液作粘结剂 ,分散剂质量分数 0 3 %时 ,浆体的流动性好 ,粘度较低 ,适合流延成型 ;用醋叔乳液作粘结剂 ,分散剂质量分数 0 7%时 ,浆体的流动性最好 ,但浆体粘度较高 ;用苯丙乳液粘结剂和邻苯二甲酸二丁酯塑化剂并用 (塑化剂质量分数 1 % ) ,得到的生坯具有较好的塑性、韧性和机械强度。     

流延工艺对生瓷带结构和微波特性的影响

基于低温共烧陶瓷技术流延工艺的特点,通过研究粘合剂、分散剂和增塑剂等在浆料体系中的力学效应对生瓷带中陶瓷成分颗粒的几何排列及所产生的孔隙排斥等力学特性的影响,以及优化热处理温度对生瓷带的质量损失、延展率和拉伸强度的关系,深入分析了流延过程的关键技术及工艺参数对生瓷带结构和微波特性的影响。研究后提出:通过调整流延浆化浆料中粘合剂、分散剂和增塑剂配比,采用梯度缓变的热处理烘干温度曲线和消除生瓷带累积应力等方法,可明显改善流延工艺过程,最终获得质量稳定、可靠性高和功能满足于微波应用要求的生瓷带。     

流延成型法制备三氧化二铝陶瓷膜基体(Ⅱ)——陶瓷膜基体的性能及结构表征

以苯丙乳胶液为粘接剂,水为分散介质,采用流延成型法制备了氧化铝陶瓷膜生坯体。通过对生坯体烧结后气孔率及断裂强度的测定,讨论了烧结温度及粘接剂含量对气孔率和断裂强度的影响。结果表明,随烧结温度的升高,基体的断裂强度增加,而气孔率有降低的趋势。在同一烧结温度下,随着粘结剂含量的增加,基体的气孔率增加,在添加了增稠剂羟乙基纤维素(HEC)后,气孔率进一步增加,但增加量不大,并且导致浆体粘度增加,不易流延成型。通过对不同烧结温度的基体的扫描电镜观察发现,氧化铝粒子分布比较均匀,随着温度的升高,晶粒明显长大,致密性提高,气孔率下降。     

含有定向排列颗粒的氮化硅陶瓷各向异性研究

通过添加α—Si3N4晶须,利用流延成型和热压烧结技术制备舍有定向排列颗粒、各向异性的Si3N4陶瓷。研究α-Si3N4相在流延膜及烧结块体中的分布状态,并通过XRD、SEM和力学性能对流延膜和烧结块体的各向异性进行表征。结果表明,1550℃下烧结制备的块体T（与流延方向平行的平面）、N（与流延方向垂直的平面）、P（侧面）三个面的I（210）／I（102）值与等轴状α-Si3N4粉体的相应值比较,其中T面的值较大,N面和P面的值较小;在T面的显微结构中存在平行于流延方向排列的大颗粒;试样不同面的力学性能（断裂韧性和抗弯强度）中,T面最好,P面次之,N面最差;I（210）／I（102）值、显微结构、力学性能测试结果表明所制备的氮化硅陶瓷存在各向异性。     

第三级存储器中的磁带选择算法

提出最多请求个数优先和最小请求优先磁带选择算法,用于优化磁带装载次序．为了进一步降低磁带交换代价,在如上两个算法中引入权重因子,得到加权磁带选择算法使得在线磁带卸载之前服务更多请求．实验表明,最多请求个数优先和最小请求优先磁带选择算法以及相应的加权算法均优于经典的RoundRobin方法,尤其加权最多请求个数优先磁带选择算法效率最高．     

Modified-starch consolidation of alumina ceramics

The alumina ceramics with the homogeneous microstructure and the higher density were fabricated via the modified-starch consolidation process by 1.0 wt% of a modified starch as a consolidator/ binder. The swelling behavior of the modified oxidized tapioca starch was analyzed by optical microscope, and two other corn starches （common corn starch and high amylose corn starch） were also analyzed for comparison. The modified starch used as a binder for the consolidation swelled at about 55 ℃, began to gelatinize at 65 ℃ and then was completely gelatinized at 75 ℃. But the corn starches could not be completely gelatinized even at 80 ℃ for 1 h. The high-strength green bodies （10.6 MPa） with the complex shapes were produced. The green bodies were sintered without any binder burnout procedure at 1 700 ℃ and a relative density of 95.3% was obtained for the sintered bodies, which is similar to that of the sintered sample formed by conventional slip casting. In addition, the effect of temperature on the apparent viscosity of the starch/alumina slurry in the process was investigated, and the corresponding mechanism for the starch consolidation was discussed.     

烧结混合料干燥过程的解析研究

建立了烧结混合料的一维错流干燥解析模型,并通过穿流干燥实验进行了验证,在此基础上,分析了烧结混合料干燥过程的规律以及主要影响因素。研究结果表明：烧结混合料的干燥过程由较短的恒速干燥段和较长的降速干燥段组成,且降速干燥段的干燥速率近似为直线;热风温度和风速对烧结混合料干燥过程的影响明显大于孔隙率和颗粒平均直径的影响;热风温度控制在200～250℃之间,风速控制在1.5m/s左右利于烧结混合料获得适宜的含水率。     

Abrasive Wear Map of Polymer Tapes in Sand Dust Environment

To make clear the wear conditions of ATM （Automatic Teller Machine） tribosystem when servicing in Chinese sand dust environment, abrasive wear of two kinds of polymer tapes specified for ATM, PI （Polyimide） and PEN （Polyethylene-2, 6-naphthalenedicarboxylate）, was investigated in simulated sand dust environment with ATM tape-scraper tribosystem under various conditions of loads and sliding distances. The surface profiles of worn tape were measured with a surface profiler in order to calculating the wear cross-section areas and the wear volumes. The specific wear rates of polymer tapes were calculated under load conditions of 0.6, 1 and 1.5 N, and wear mechanisms were in- vestigated with optical topography photos. As main results, the specific wear rates show stage variations in the wear process and the wear resistance of polymer tape shows good relationship with the mechanical deformation factors. In consideration of the service life, four wear models are generalized according to the magnitude of specific wear rates, which include no wear, mild wear, normal wear and severe wear model and the corresponding wear mechanisms for the four wear models are discussed with typical worn topographies. Based on the wear models and corresponding wear mechanisms, the abrasive wear maps of two polymer tapes servicing in sand dust environments are concluded for its industrial applications.     

陶瓷流延异形件烧结变形的定量图像分析

利用图像定量分析法对陶瓷流延异形件烧结变形规律进行分析。结果表明,流延坯体在流延方向和垂直于流延方向上出现两个明显不同的收缩率而导致异形件烧结变形,且内外孔轮廓从圆形变为椭圆形,但其相对中心位置保持不变。     

砂型铸造的环境特征及铸造粘结剂的发展趋势

研究分析了目前广泛采用的几种典型砂型铸造方法（湿型粘土砂、呋喃自硬树脂砂、碱酚醛自硬树脂砂、CO2硬化水玻璃砂、酯硬化水玻璃砂）的环境特征,主要从产生的气体挥发物和旧砂回用性两方面分析它们的区别,从铸造粘结剂的角度讨论实现清洁生产、绿色铸造存在的问题,概述铸造粘结剂的发展趋势与方向。笔者认为,相当长时间内砂型铸造仍然是我国铸造生产的主要方式,少污染的无机粘结剂大量采用、低成本无排放的旧砂再生回用技术开发利用、铸造有害气体少量化及其无害化排放,应是我国铸造材料与技术进步的发展方向。     

Experimental Investigation on Flow and Drying Characteristics of Impinging Stream Drying

Based on the experimental investigation of one-stage semi-circular impinging stream drying, the experiments with the two- stage semi-circular, as well as the vertical and semi-circular combined impinging stream drying were conducted. The variations of system pressure drop, the mean residence time of particles with the mass flow-rate ratio and air velocity ate. were determined. The influences of inlet air temperature, mass now-rate ratio, initial moisture content of particles and air velocity ate. on drying characteristics were also studied. The results indicate that the vertical and semi-circular combined impinging stream drying can make full use of the advantages of both the vertical and semi-circular impinging stream drying. Reasonable mass flow-rate ratio, air velocity, and higher inlet air tem- perature should be used for less energy consumption and cost during drying process.     

聚氯乙烯胶粘带基材膜的制备

聚氯乙烯胶粘带是以通用塑料聚氯乙烯膜为基材,以压敏胶为胶料的一种新型胶粘带.本文将对其基材制造技术进行探讨.     

陶瓷微滤膜过滤微米级颗粒体系的模拟

通过对陶瓷膜错流过滤微米级颗粒悬浮液过程中颗粒的受力分析,获得了可沉积在膜表面颗粒的临界粒径,结合传统的滤饼阻力模型,可获得膜表面污染层的阻力,从而计算出过滤过程的渗透能量,与实验结果相比,模型的模拟结果良好。     

基于响应面法优选消炎抗菌颗粒的成型工艺

本试验旨在优选出消炎抗菌颗粒制剂最佳的成型工艺。通过采用单因素试验法,研究消炎抗菌颗粒最佳药物辅料构成及制备条件,利用综合评分筛选出最佳的辅料种类、最佳的润湿剂浓度及颗粒的最佳干燥温度,然后其制剂成型工艺通过使用响应面星点设计进行优化。结果表明:消炎抗菌颗粒最佳制剂成型工艺的条件为浸膏∶辅料质量比为1∶2.54,润湿剂为质量分数60%的乙醇,颗粒干燥温度为50℃,并且消炎抗菌颗粒制备贮存的临界相对湿度应控制在66%以下。经重复性试验可知,消炎抗菌颗粒的最佳制剂成型工艺是稳定、可行的。     

铸造用CO2硬化碱性酚醛树脂的试验研究

铸造业中广泛使用的树脂材料基本上都是一些有毒、污染环境的，因此开发出高质、高效、节能、环保的新型粘结剂是当前铸造绿色集约化发展的迫切需要.针对此粘结剂的特点，以抗压强度为主要考察目标，通过对其碱加入量、硼砂加入量和硅烷加入量进行正交试验，得出优化结果，并对树脂砂的可使用时间、发气性、溃散性和树脂加入量等工艺性能进行了试验研究.试验表明，此粘结剂制得的树脂砂具有良好的工艺性能，吹CO₂气体硬化后，可获得较高的初强度和终强度.     

透气性多孔陶瓷材料制备工艺的研究

以硅酸乙脂水解液为粘结剂,以莫来石、铁粉为原料,通过粉浆浇注、干燥及烧结等工艺过程,制备了多孔透气性莫来石基陶瓷材料。研究了成型及干燥工艺对成型坯体质量及烧结体性能的影响。     

Computer Simulation of Distribution of Reinforced Particles in Functionally Graded Materials Fabricated by Centrifugal Casting

A mathematic model is developed with viscosity of molten matrix,centrifugalforce,casting temperature,mold temperature and other parameters taken intoconsideration for preditction of the distribution of reinforced particles during centrifugalcasting of FGM,and the simulation of distribution of reinforced particles and thesolidification process during centrifugal casting is performed with the aid of computergraphics.SiC_p/A356 FGM is fabricated by centrifugal casting.The results of computersimulation of distribution of reinforced particles are in good agreement with experimentalobservations.     

双轴织构金属基带上沉积YBCO高温超导膜的研究

制备了立方织构和｛１１０｝双轴织构的银基带,通过准分子激光方法在所制备的双轴织构的银基带上直接沉积了ＹＢＣＯ超导薄膜,其中在｛１１０｝双轴织构的银基带上沉积的超导满膜的临界电流密度Ｊｃ值达到２×１０５～５×１０５Ａ／ ｃｍ２（７７Ｋ, ０Ｔ）．     

闪锌矿的微波干燥规律研究

研究了利用微波加热干燥闪锌矿的新工艺,对微波干燥闪锌矿的失水特性进行了研究,实验证实微波干燥闪锌矿全过程分为加速、恒速和降速三个阶段;通过对试验数据的回归分析,获得了微波干燥闪锌矿的数学模型,采用Boltzmann模型拟合最佳,同时对该模型的参数进行了分析和讨论,结果表明干燥速率先逐渐增加;然后逐渐减少,与根据试验数据分析出的结果相吻合.