功能性地坪涂料的发展及应用

介绍了弹性地坪涂料、导静电地坪涂料、彩色耐磨涂料、耐强化学腐蚀涂料及水性环氧涂料等功能性涂料的性能、应用及发展。     

高分子功能性导静电涂料现状及应用

从导静电涂料的分类、机理和功能开始阐述,详细介绍了导静电涂料的组成、相关标准和发展现状,并提出了我国导静电涂料现存的3个问题。     

油罐导静电涂料研究进屣

油罐导静电涂料是为杜绝油罐静电起火爆炸事故而设计的涂料,因油罐材质为钢板,导静电涂料除了导电性外还需兼具防腐性。介绍了油罐导静电涂料的分类、相关标准、研究现状和未来发展方向。     

本征型与添加型导静电防腐涂料的性能对比和应用

介绍了钢质油罐内壁导静电防腐涂料的性能要求。通过本征型导静电涂料与添加型导静电涂料的性能对比，以及两者的实际应用情况对比，得出本征型导静电涂料更适用于钢质油罐内壁的结论。     

喷气燃料罐用浅色导静电防腐蚀涂料研究

针对喷气燃料罐用导静电防腐蚀涂料的特殊要求,研制出一种浅色导静电防腐蚀涂料。对浅色导静电材料种类、用量以及分散剂对涂膜导静电性能的影响进行了试验。试验结果表明:不同种类浅色导静电材料对涂膜导静电性能影响程度不同;导静电材料用量对涂膜导静电性能的影响与导静电填料在涂料配方中的颜料体积浓度有关,综合考虑涂膜导静电和防腐蚀性能之间的关系,确定了导静电填料的最佳颜料体积浓度范围。性能测试表明:所研制涂料各项性能指标均达到国家标准。通过对浸泡过涂膜的喷气燃料的性能指标测试表明,该涂料各组分对喷气燃料无污染,可广泛用于喷气燃料舱、运油车、输送管线内壁。     

分散剂对碳纳米管导静电涂料性能的影响

以碳纳米管作为导电填料,制备了导静电涂料,并研究了分散剂对碳纳米管导静电涂料性能的影响。酸化处理能很好地去除碳纳米管中的杂质。分别添加2%十八醇和2%Disponer 983时,涂膜的力学性能和导静电性能较好;1%十八醇和2%Disponer 983复配时,涂膜导静电性最优,表面电阻率达到1×108Ω。     

浅色油罐导静电涂料的研制

介绍了以环氧树脂为基料,导电云母粉为导电体制成的浅色环氧油罐导静电涂料,该涂料具有良好的导电性、耐腐蚀性和机械性能.讨论了影响涂层导电性、耐腐蚀性的主要因素.     

导电涂料

一种复合导电体导静电涂料及其制备方法；一种碳纤维导静电涂料及其制备方法；[编者按]     

无溶剂环氧导静电防腐涂料的研制及性能测试（Ⅰ）

根据国家相关部门对储油罐导静电防腐涂料的新的要求,针对石化工业传统的溶剂型导静电防腐涂料存在的技术问题,阐述了我国石化工业对储油罐导静电防腐涂料的新的发展趋势。着重介绍一种超高压水射流表面处理新工艺和长效重防腐无溶剂环氧导静电涂料体系的研制,以及该涂料系统在密闭的原油储罐中使用的性能测试报告。     

聚氨酯油罐导电涂料

以环氧聚氨酯为基料、导电云母粉等为颜填料制备了浅色聚氨酯导静电涂料,给出了油罐内壁导电涂料的配方,并分析了树脂、导电粉的种类和用量等与导电性的关系.     

掺杂型白色抗静电涂料的性能研究

介绍了掺杂型白色抗静电涂料所用原料、制备方法和性能测试,并着重讨论了成膜物质、掺杂剂、固化剂以及抗静电剂对涂料性能的影响。     

Preparation and characterization of antistatic coatings with modified BaTiO3 powders as conductive fillers

The antistatic coatings were prepared by using rare earths modified BaTiO₃ powders as conductive fillers instead of the traditional metal additives. The composition and preparation technology of the antistatic coatings were researched. The effects of thinner, curing agent, dispersant, and conductive fillers on surface resistance and performances of the antistatic coatings were studied. The determined composition of the antistatic coatings was that of epoxy resin 10.00?g with curing agent 13%, BaTiO₃ powders 5%, dispersant 2%, and thinner 4?ml?g^?1. FTIR and SEM analyses illustrated that the dispersant agent and ultrasonic can make modified BaTiO₃ powders in the coatings to disperse completely. The parameters of antistatic coatings were as following: surface resistance is 1.18?×?10¹⁰?Ω, dry time is 6.0?h, solid content is 94.0%, stiffness is 0.419, viscosity is 255?s, adhesive force is 3, and flexibility is 2. The antistatic coatings were prepared by using rare earths modified BaTiO₃ powders will be prospective candidates for reducing static electricity.     

浅色水性环氧导静电防腐涂料的研制

研制的水性环氧导静电防腐涂料为双组分涂料,甲组分由水性胺加成物固化剂、导电填料、防锈颜填料及助剂组成;乙组分由环氧树脂E51或OER-95、活性稀释剂、掺杂聚苯胺及偶联剂组成,按环氧/胺当量比为1.1∶1配漆,涂层具有优异的导静电性和防腐蚀性能。     

Multifunctional antistatic and scratch resistant UV-cured acrylic coatings

Organic–inorganic antistatic hybrid acrylic coatings were prepared. Trialkoxy-silyl ammonium salt was added to the photocurable formulations in order to introduce an antistatic additive which could be covalently linked to the hybrid network through a co-condensation reaction involving the alkoxy groups. The influence of the antistatic additive on the radical photopolymerization reaction of the acrylic resin was evaluated by real time FTIR, keeping the inorganic precursor content constant at 20 phr and increasing the trialkoxy-silyl ammonium salt in the range between 5 and 15 phr. When the samples were cured under nitrogen atmosphere, a complete conversion of acrylic double bonds was achieved after 90 s of irradiation both for the acrylic resin and the formulations containing the ammonium salt. The scratch behavior of coatings was investigated by carrying out of progressive load scratch test. The penetration depth (Pd) and the residual depth patterns were investigated for all the hybrid films. A consistent improvement of penetration resistance by increasing alkoxy-ammonium salt content was noted in terms of Pd. Inorganic component and antistatic additives increase ε′ and σ_AC values of the hybrid coatings and decrease the resistivity ones, showing their efficiency for increasing antistatic properties of coatings, improved with respect to the pure acrylic resin.     

浅谈浅色环氧防静电涂科固化剂的选用

使用导电云母粉研制浅色环氧防静电涂料，不仅导电粉的选择至关重要，环氧固化剂的选择也非常关键。指出浅色环氧防静电涂料选用芳脂胺类型的固化剂，所得漆膜的电阻率、防腐蚀性和耐化学品性均优于传统的聚酰胺固化剂。     

高分子分散剂在抗静电涂料中的应用研究

研究了分散剂种类及其用量对自制抗静电涂料的粘度、分散稳定性及涂层电阻的影响，确定了合适的分散剂及其最佳用量。     

浅色厚浆型导静电环氧涂料的研制

研制成一种浅色厚浆型导静电环氧涂料。介绍了该涂料的配方和制备工艺。讨论了导电填料和颜填料用量,以及助剂对涂层电阻率的影响。实验结果表明：该涂料与同类产品性能相当,但它的应用范围更广,可在苛刻环境条件下使用,经济优势明显。     

机壳外表面用弹性手感涂料的配方设计及应用

通过选用合适的弹性树脂为主体,配合助剂和固化剂的选择进行配方设计,阐述了弹性手感涂料的配制及其施工工艺。测试结果表明该涂料具有附着力佳、手感细腻滑爽、抗划伤力强、优异的耐腐蚀等性能。     

弹性聚氨酯固化剂在高寒地区高铁动车组外风挡胶囊用特种涂料中的应用研究

在现有CTN系列弹性耐磨涂料的基础上,以聚己内酯型弹性聚氨酯固化剂(ST固化剂)替代聚碳酸酯型固化剂(SF固化剂),制备了高寒地区高铁动车组外风挡胶囊用新型弹性耐磨涂料。重点探讨了弹性聚氨酯固化剂的种类及用量、固化条件等对涂料力学性能、耐温性能、耐磨性能以及回黏性能的影响。研究结果表明:在不影响涂料耐磨性能与回黏性能的前提下,ST固化剂能够显著改善涂料的低温力学性能与耐温性能,其所制备的涂料能够满足高寒地区高铁动车组外风挡胶囊的设计与使用要求。     

碳纳米管/苯丙乳液导电内墙涂料的制备

先利用混酸体系和3-氨丙基三乙氧基硅烷偶联剂(KH550)对多壁碳纳米管(MWCNTs)进行表面修饰,然后将修饰后的MWCNTs加入苯丙乳液中,成功制备了具有良好抗静电性能和力学性能的碳纳米管/苯丙乳液改性内墙涂料。利用透射电镜,对修饰前后的MWCNTs进行了热重分析。结果表明:KH550成功地接枝到MWCNTs表面,修饰后的MWCNTs能实现很好的分散。研究了MWCNTs用量对所制备涂料的导电性能、力学性能的影响。研究表明当MWCNTs添加量达到2.50%时,涂料的表面电阻最小,为1.42×107Ω,力学性能最佳。