共查询到19条相似文献,搜索用时 125 毫秒
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研究了硫化剂过氧化二异丙苯(DCP)和增塑剂聚己二酸乙二醇酯(QS-1)用量对氢化丁腈橡胶(HNBR)硫化特性、力学性能、耐老化性能及动态力学性能的影响,并对其进行了差示扫描量热分析。结果表明,QS-1对胶料的焦烧时间、正硫化时间及硫化速率基本没有影响。DCP用量相同时,随着QS-1用量的增加,硫化胶的邵尔A硬度和200%定伸应力降低,扯断伸长率和压缩永久变形增大,但对拉伸强度影响不大;DCP用量对胶料扯断伸长率和压缩永久变形的影响远高于QS-1;高交联密度的胶料具有较好的耐热、耐油老化性能;QS-1对HNBR硫化胶的玻璃化转变温度以及耐热、耐油老化性能影响不大,但可降低胶料的Payne效应,进而改善炭黑在HNBR中的分散性。DCP用量在3.5份左右、QS-1用量在3~5份时可获得性能优异的密封胶料。 相似文献
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Konstantinos G. Gatos Nikolaos S. Sawanis Anton A. Apostolov Ralf Thomann Jzsef Karger‐Kocsis 《大分子材料与工程》2004,289(12):1079-1086
Summary: Hydrogenated acrylonitrile butadiene rubber (HNBR) was melt compounded with montmorillonite (MMT) and organophilic modified MMTs prior to sulfur curing. In contrast to the micro‐composite formation resulting from the compounding of the HNBR and pristine MMT, the modified MMTs (i.e., octadecylamine: MMT‐ODA, octadecyltrimethylamine: MMT‐ODTMA, methyltallow‐bis(2‐hydroxyethyl) quaternary ammonium: MMT‐MTH intercalants) produced nanocomposites. It was found that the organoclay with primary amine intercalant (cf. MMT‐ODA) gave confined structures along with the exfoliated/intercalated structures. This was traced to its reactivity with the curatives. By contrast, the organoclays containing less reactive quaternary ammonium compounds (cf. MMT‐ODTMA, MMT‐MTH) were exfoliated and intercalated based on X‐ray diffraction (XRD) and transmission electron microscopy (TEM) results. The hydroxyl functional groups of the MMT‐MTH supported the clay dispersion. The better adhesion between MMT‐MTH and HNBR was explained by hydrogen bonding between the hydroxyl groups of the intercalant and the acrylonitrile group of the HNBR matrix. This HNBR/MMT‐MTH nanocomposite showed the best mechanical properties as verified by tensile mechanical tests and dynamic mechanical thermal analysis (DMTA). The high tensile strength along with the high elongation at break for the rubber nanocomposites were attributed to the ability of the ‘clay network’ to dissipate the input energy upon uniaxial loading.
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氢化羧基丁腈橡胶/环氧化POSS复合材料的硫化反应和性能研究 总被引:1,自引:0,他引:1
通过溶液共混和硫化成型制备了氢化羧基丁腈橡胶(HXNBR)/环氧环己基POSS复合材料,并进行了硫化性能、动态力学性能、FTIR谱图和交联密度测试。结果表明,环氧化环己基POSS和HXNBR发生交联反应并产生醇羟基;在实验温度范围内,200℃时复合材料硫化效率最佳,正硫化时间(t90)约为10min;复合材料高弹储能模量和交联密度随POSS用量的增大而明显增大,损耗因子降低,玻璃化转变温度提高;交联密度在20~40min区间增加幅度较大,当硫化时间为60min时交联密度有所降低。 相似文献
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The use of thermally depolymerised liquid natural rubber as a plasticiser in nitrile rubber has been investigated with special reference to the rheological aspects. A comparative evaluation has been made with dibutylphthalate, the ester-type plasticiser commonly used with nitrile rubber. The study revealed that the use of liquid natural rubber as a plasticiser and viscosity modifier improved the processability of the compounds and also enhanced many of the vulcanisate properties. © of SCI. 相似文献
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Rubber blends based on epichlorohydrin rubber and carboxylated nitrile rubber can be used as adhesives for aluminium-aluminium bonding. The bond strength depends on blend composition and moulding conditions, such as time, temperature and pressure. Lewis acid/base type interaction is responsible for this type of adhesion. The failure mechanism of the composites was studied by SEM. 相似文献
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Rubber blends based on epichlorohydrin rubber and carboxylated nitrile rubber can be used as adhesives for aluminium-aluminium bonding. The bond strength depends on blend composition and moulding conditions, such as time, temperature and pressure. Lewis acid/base type interaction is responsible for this type of adhesion. The failure mechanism of the composites was studied by SEM. 相似文献
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汽车发动机密封用丁腈橡胶涂料的研制 总被引:1,自引:0,他引:1
介绍了汽车发动机密封用丁腈橡胶涂料的制备方法,讨论了溶剂、填料、酚醛树脂、硫化剂及其他助剂的选用对涂层性能的影响,得出了丁腈橡胶涂料最佳配方:丁腈橡胶N41 100份,酚醛树脂2402 50~55份,炭黑N330 30份,氧化锌5份,硫磺1~3份,促进剂CZ 0.5~2份,促进剂DM 0.5~1.5份,DOP 5份,防老剂RD 2份,醋酸乙酯200~270份,丁酮30~100份。讨论了不同的底涂剂对涂层的影响,结果表明:Chem lok 205对丁腈橡胶与金属板材粘接效果最佳。采用辊涂的方式对丁腈涂料进行施工,硫化温度150℃,硫化时间为1 h。在此条件下生产的丁腈橡胶涂料垫片,可满足汽车发动机的工况要求。 相似文献