超音速火焰喷涂两种WC-17%Co涂层的组织和性能研究

采用超音速火焰喷涂法制备纳米和普通WC-17%Co涂层,借助于SN-3400型扫描电镜(SEM)、D8型X射线衍射仪(XRD)、HXD-1000TM型显微硬度计、SHT4605型拉伸试验机和TRB型球盘磨损试验机对涂层组织结构、相组成、显微硬度、结合强度及耐磨性能进行了分析.结果表明,两种WC-17%Co涂层形成过程中WC发生了分解,并形成了W2C、W和CoxWyCz(Co3W3C、Co3W9C4)等一些新相,纳米涂层的组织形态明显好于普通涂层,组织晶粒细小,WC晶粒保持在120~150 nm的纳米尺度范围;纳米涂层的显微硬度、结合强度和耐磨性都高于普通涂层,相比之下,纳米涂层的显微硬度、结合强度比普通涂层高出近30%,在相同的试验条件下普通涂层的磨损体积是纳米涂层的2倍.     

HVOF喷涂Co基WC涂层的耐锌腐蚀行为

为了提高热镀锌用辊件的耐腐蚀性,试验采用超音速火焰喷涂方法制备WC-12Co涂层,研究了涂层在450 ℃锌液中的耐腐蚀性能以及失效机制.将316L/WC-12Co涂层进行液锌腐蚀,以扫描电镜能谱分析、x-射线衍射方式分析对比了未经过腐蚀试件、腐蚀5天试件、腐蚀10天试件的组织变化和相组成,结果显示涂层基体Co受液锌腐蚀生成Co与Zn化合物,引发横向裂纹,导致涂层剥落.涂层全部剥落后保护失效,使母材被液锌直接严重腐蚀,最终生成锌渣FeZn₁₃.     

超音速火焰喷涂涂层耐磨性能研究进展

从超音速火焰喷涂工艺特点和涂层耐磨性能,综述了超音速火焰喷涂耐磨涂层研究进展.指出超音速火焰喷涂技术在航空航天、石油机械、液压传动、燃气涡轮机轴类零部件制造和修复中的应用,并展望了超音速火焰喷涂的发展方向.     

Q235钢表面硬质合金喷涂层的磨损特性研究

用超音速火焰喷涂方法在Q235钢表面进行了WC硬质合金粉末的喷涂.在MRH-5A型滑动磨损试验机上,对涂层进行室温下的干滑动摩擦磨损性能测验,借助于扫描电镜观察磨损试样磨面形貌.通过对摩擦磨损数据进行分析,结果表明：Q235钢表面用WC硬质合金喷涂后,耐磨性大大提高,涂层磨损机理主要表现为磨粒磨损和粘着磨损.     

APS/HVOF热喷涂WC基金属陶瓷涂层的微观组织与性能

WC基涂层由于具有较高的硬度、优异的耐磨性、较好的抗腐蚀性,广泛应用于石油等工业中提高零件的磨损和腐蚀性能。随着现代化工业中工件服役环境日趋复杂,对制备性能优异的WC基涂层要求越来越高。在热喷涂技术中,热喷涂大气等离子热喷涂(APS) 喷涂温度范围广,可以提高至数万温度,在喷涂难容材料方面具有无与伦比的优势,而超音速火焰喷涂(HVOF)由于具有较高的焰流速度,粒子动能较高,同时由于喷涂过程中N2等冷却喷涂材料,近来在涂层制备中具有广泛的应用。本文利用APS与HVOF两种热喷涂方法在45钢表面制备WC-10Co-4Cr、WC-17Co两种涂层,对不同方式制备的涂层截面硬度、金相组织、与基体结合能力、涂层脱碳情况进行分析。结果表明：HVOF 涂层在喷涂中粒子未充分熔化,但粒子动能较高,表面相比于APS喷涂方式更加平整,与基体的结合性能好于APS制备的涂层。通过HVOF制备的两种涂层的孔隙率均低于APS制备的涂层,其中HVOF 制备的WC-17Co具有最小的孔隙率(0.65%)。此外,HVOF涂层的硬度均高于APS制备的涂层,由于具有较少的粘结相,通过HVOF制备的WC-10Co-4Cr涂层具有最高的截面硬度。相比于HVOF,APS具有较高的喷涂温度和较低的焰流速度导致涂层在喷涂过程中氧化脱碳现象较为严重,出现大量的W2C及少量的Co3W3C、Co6W6C等脆性η相。因此,HVOF更适合于喷涂WC-10Co-4Cr、WC-17Co两种涂层。     

超音速火焰喷涂WC-10Co4Cr 涂层组织及耐磨耐蚀性研究

采用超音速火焰喷涂工艺在不同喷涂距离下制备了WC-10Co4Cr涂层,并对其组织结构及耐磨耐腐蚀性能进行了研究。利用金相显微镜、扫描电子显微镜、X射线衍射仪分析了涂层的组织结构和相组成,并测试了涂层显微硬度、孔隙率;对涂层磨损表面进行了观察分析,探讨了涂层的失效形式。结果表明,喷涂距离对涂层的组织结构及耐磨性具有一定影响。适当增加喷涂距离,粒子由于在焰流中停留时间增加而使熔化程度加大,撞击基体后扁平化现象明显。因此,涂层的致密度、耐磨性、耐腐蚀性都有所提高。当喷涂距离为380mm 时,涂层呈现出较好的耐磨性及耐腐蚀性。     

重熔温度对Ni60/WC定向结构涂层微结构演变的影响

为了改善定向结构涂层的微观组织性能,本文采用火焰喷涂、感应重熔和强制冷却复合技术制备了碳化钨强化的Ni60/WC定向结构涂层.通过金相显微镜、扫描电子显微镜、X射线衍射仪、显微硬度计对其微观组织、物相及显微硬度等进行对比研究,探讨感应重熔温度对定向结构复合涂层微观结构演变及性能的影响,并揭示涂层的形成机理和强化机制.结...     

等离子喷涂参数对镍基合金涂层组织及冲蚀磨损性能的影响

采用SEM、XRD、LSCM和冲蚀磨损试验机研究了等离子喷涂参数(氢气流量HFR、喷涂电流I)对Ni60涂层组织与冲蚀磨损性能的影响。结果表明,Ni60涂层主要由γ-Ni、Ni3B、Cr2B、CrB、M7C3、M23C6相构成;增加HFR、I有利于减小涂层中层片厚度,增加涂层结晶度、平均晶粒尺寸、微观应变量及残余应力,提高涂层显微硬度及抗冲蚀磨损性能。但过大的HFR、I(15ft3/h、600A)导致涂层孔隙率增加,显微硬度及抗冲蚀磨损性能降低。等离子喷涂参数HFR=12.5ft3/h、I=500A时,在小角度冲蚀条件下,Ni60涂层具有更高的抗冲蚀磨损性能。     

NiCoCrAlY/Al_2O_3-13%TiO_2复合涂层的耐锌铝腐蚀性

为了解决热镀锌铝工艺中沉没辊受到熔融锌铝液腐蚀的问题,采用超音速火焰喷涂技术在316L基体上制备了NiCoCrAlY粘结层,并利用等离子喷涂技术制备了NiCoCrAlY/Al_2O_3-13%TiO_2复合涂层.结果表明,复合涂层界面处的热膨胀系数突变减缓,使得界面处的应力集中减少,从而对裂纹扩展起到延缓和抑制作用,因而复合涂层的抗裂性能增强.复合涂层在锌铝液中的使用寿命可以达到9 d,高于传统Al_2O_3-13%TiO_2涂层.复合涂层的结合强度也高于传统Al_2O_3-13%TiO_2涂层,但复合涂层的最终失效形式依然是由两种材料的热胀系数不匹配所导致的涂层开裂.     

PPS/SiO2纳米复合涂层弹性模量的理论计算

采用细观力学的方法,计算了自制的PPS/SiO2纳米复合涂层、普通涂层的弹性模量。结果表明纳米复合涂层的弹性模量小于普通涂层,与文献所述涂层的弹性模量越小抗冲蚀磨损性能越好是吻合的。理论计算也表明,通过减小纳米涂层中纳米粒子的体积分数（即降低其颗粒尺寸）,可以减小纳米涂层的弹性模量,从而提高其抗冲蚀磨损性能。     

Oxidation performance of Fe-Al/WC composite coatings produced by high velocity arc spraying

Fe-Al intermetallics with remarkable high-temperature intensity and excellent erosion, high-temperature oxidation and sulfuration resistance are potential low cost high-temperature structural materials. But the room tem perature brittleness induces shape difficult and limits its industrial application. The Fe-Al intermetallic coatings were prepared by high velocity arc spraying technology with cored wire on 20G steel, which will not only obviate the problems faced in fabrication of these alloys into useful shapes, but also allow the effective use of their outstanding high-temperature performance. The Fe-Al/WC intermetallic composite coatings were prepared by high velocity arc spraying technology on 20G steel and the oxidation performance of Fe-Al/WC composite coatings was studied by means of thermogrativmetic analyzer at 450, 650 and 800 ℃. The results demonstrate that the kinetics curve of oxidation at three temperatures approximately follows the logarithmic law. The composition of the oxidized coating is mainly composed of Al2 O3, Fe2 O3, Fe3 O4 and FeO. These phases distribute unevenly. The protective Al2 O3 film firstly forms and preserves the coatings from further oxidation.     

High temperature behaviors of high velocity arc sprayed Fe-Al/Cr3C2 composite coatings

Fe-Al/Cr3C2 composite coatings were manufactured using high velocity arc spraying （HVAS） technology. The high temperature erosion, wear and corrosion resistance of the coatings were investigated. The coating properties such as bonding strength, porosity, hardness as well as microstructures were characterized. The results show that the coatings have relatively high heat tremble bond strength, hardness, and typical layer-shaped coatings＇ microstructures. With the rise of temperature, the coating erosion resistance increases too; the impingement angel does effects on erosion properties, and the erosion mechanism changes from ductile to brittle behaviors at 450℃. The coatings have good room temperature wear resistance and relatively good high temperature resistance. The wear mechanism of the coatings is peeling wear behavior. The coatings have excellent high temperature corrosion resistance because of the produce of oxides during corrosion.     

Influence of oxides on high velocity arc sprayed Fe-Al/Cr_3C_2 composite coatings

1INTRODUCTION Arcspraying(AS)isatechniquethatthemet alisheatedtodropletsbyanelectricarcandthensprayedontosubstratesbythecompressedair. Highvelocityarcspraying(HVAS)technologyisdevelopedonthebasisofAS.Aspecialtubede signedaccordingtotheprincipleofaerodynamicsis mountedattheexitofcompressedair.Theveloci tyanddistributionofmelteddropletsbecomehigh erandmoreuniform,respectively.Asaresult,acoatingwithlowporosity(2%)andhighdensity andbondstrengthcanbeobtained[15].Fe Alin termetalliccompound…     

Oxidation performance of Fe-Al/WC composite coatings produced by high velocity arc spraying

Fe-Al intermetallics with remarkable high-temperature intensity and excellent erosion, high-temperature oxidation and sulfuration resistance are potential low cost high-temperature structural materials. But the room temperature brittleness induces shape difficult and limits its industrial application. The Fe-Al intermetallic coatings were prepared by high velocity arc spraying technology with cored wire on 20G steel, which will not only obviate the problems faced in fabrication of these alloys into useful shapes, but also allow the effective use of their outstanding high-temperature performance. The Fe-Al/WC intermetallic composite coatings were prepared by high velocity arc spraying technology on 20G steel and the oxidation performance of Fe-Al/WC composite coatings was studied by means of thermogrativmetic analyzer at 450, 650 and 800°C. The results demonstrate that the kinetics curve of oxidation at three temperatures approximately follows the logarithmic law. The composition of the oxidized coating is mainly composed of Al₂O₃, Fe₂O₃, Fe₃O₄ and FeO. These phases distribute unevenly. The protective Al₂O₃ film firstly forms and preserves the coatings from further oxidation. Foundation item: Project(50235030) supported by the National Natural Science Foundation of China; Project(98BK014) supported by the Foundation of State Economy Trade Committee of China     

Influence of oxides on high velocity arc sprayed Fe-Al／Cr3C2 composite coatings

Fe-Al/Cr3C2 coatings were sprayed on low steel by high velocity arc spraying(HVAS) technology. The influences of oxides on erosion, corrosion and wear behavior for high velocity arc sprayed Fe-Al/Cr3C2 coatings were studied. The results show that HVAS-sprayed Fe-Al/Cr3C2 coatings have good erosion, heat corrosion and wear resistance. The erosion resistance improves with the increase of the temperature. On one hand, the ferrous oxides are incompact, so they peel off the surface of the coatings easily during the high temperature erosion. On the other hand, compact Al2O3 films on the surface can protect the coatings.     

高速电弧喷涂7Cr13涂层冲蚀磨损性能及其机理研究

采用高速电弧喷涂技术,在45钢表面制备了7Cr13涂层。利用气砂型冲蚀磨损试验机研究了涂层在不同温度和不同冲击角度下的冲蚀磨损性能,借助SEM、EDS和XRD分析了涂层的冲蚀磨损机理。结果表明,高速电弧喷涂7Cr13涂层的冲蚀磨损率随温度的升高而升高;在30℃时,冲蚀磨损率随冲击角度的增加而增加,而在450℃时,冲蚀磨损率则随冲击角度的增加而降低;且不同条件下的冲蚀磨损机理各不相同。     

Erosion-Corrosion Behaviors of High Velocity Arc Sprayed Fe-Al/Cr3 C2 Coating

1 IntroductionArc Spraying (AS) is a technique that utilizes anelectric arc as the heat source to melt wires into droplets ,which are subsequentlysprayed ontosubstrates bytheflowof compressed air . High Velocity Arc Spraying (HVAS)technology was developed on the basis of AS. Aspecialtube designed according to the principle of aerodynamicswas mounted at the exit of compressed air .Thenthe hightemperature fuel air or compressed air was accelerated bythe tube .Hence ,a higher velocityand be…     

高速火焰喷涂多功能梯度玻璃涂层的工艺研究

针对船舶部分管件的耐海洋腐蚀,又减少小剂量的^y射线与中子照射的要求,研究了高速火焰喷涂一种新型多功能梯度玻璃涂层,其组成依次为WC—Co—Ni／B—cr—Fe／B—cr—Ni／WC—Ni—B—Cr!玻璃．通过对工艺参数的分析研究,即可以保证此玻璃涂层的制备,又保障涂层与基材、涂层之间的结合性能,具有广阔的应用前景．