共查询到18条相似文献,搜索用时 109 毫秒
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硬段含量对聚酯型聚氨酯弹性体形态与性能的影响 总被引:4,自引:0,他引:4
采用本法合成了一系列不同硬段含量的聚(1,4-丁二醇己二酸)酯型聚氨酯(简称PBA型PU)弹性体,并用DSC,WAXD,TEM,SEM,SAXS测试手段对其微相分离程度和结晶形态进行了表征,测定了材料的拉伸性能,讨论了硬段含量对材料形态与性能的影响。结果表明:PBA型PU弹性体中微相分离程度以及软,硬链段的结晶性随硬段含量的提高而变化。拉伸性能受其内部微相分离程度和链段结晶性的相互影响。 相似文献
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交联聚乙酸乙烯脂胶乳的合成 总被引:1,自引:0,他引:1
分别以二乙烯基苯、双甲基丙烯酸乙二醇酯和甲基丙烯酸烯丙基酯(AMA)为交联剂,十二烷基硫酸钠(SLS)为乳化剂,过硫酸铵为引发剂,合成了交联聚乙酸乙烯酯(PVAc)胶乳。结果表明,AMA是乙酸乙烯酯乳液聚合最理想的交联剂,其用量为单体量的2%时,交联度可达到85%以上。所用SLS的浓度为11.6mmol/L时,合成了交联度为87.4%、粒径为84.5nm的交联PVAc胶乳。 相似文献
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PE—MAH的合成及其对PE/NBR的增容作用 总被引:5,自引:0,他引:5
聚乙烯(PE),马来酸酐(MAH)和过氧化二异丙苯(DCP)在溶液中反应,其产物经多次纯和红外光谱分析证明,MAH以化学链连接到PE分子链上,接枝率达0.5MAH/100E,即相当平均每个PE上接枝有10个MAH。用不同接枝率的聚乙烯接枝马来酸酐聚物(PE-MAH)作为极性差别较大的PE和丁腈橡胶(NBR)的相容剂,分别研究其接枝率和用量对共混物的拉伸强度和低温冲击强度的影响,结果发现:PE-MA 相似文献
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用热重法,微商法重法和差热分析研究了不同硫化体系天胶乳胶膜的热氧降解过程。试验结果表明,胶乳胶膜的降解反应均分三步进行,但降解过程存在较大差异,过氧化物预硫化胶乳胶膜的热氧降解最为彻底,而硫黄/促进剂TMTD=氧化锌体系硫化胶乳胶膜的热氧稳定性最好。 相似文献
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Patjaree Suksawad Kenichiro Kosugi Yoshimasa Yamamoto Keiichi Akabori Hirofumi Kuroda Seiichi Kawahara 《应用聚合物科学杂志》2011,122(4):2403-2414
High‐proton‐conductive polymer electrolyte with a nanomatrix channel was prepared by graft copolymerization of styrene onto deproteinized natural rubber followed by sulfonation with chlorosulfonic acid. First, natural rubber latex was purified with urea in the presence of surfactant to remove almost all proteins present in the rubber. Second, graft copolymerization of styrene onto deproteinized natural rubber was carried out with tert‐butyl hydroperoxide/tetraethylenepentamine as an initiator at 30°C in latex stage. The graft‐copolymerized natural rubber (DPNR‐graft‐PS) was sulfonated with chlorosulfonic acid in chloroform solution at an ambient temperature. The resulting sulfonated DPNR‐graft‐PS was characterized by FTIR spectroscopy, solid state 13C CP/MAS NMR spectroscopy, elemental analysis, and transmission electron microscopy. High proton conductivity of about 0.1 S/cm, less water uptake of 24 wt % and comparatively good stress at break of 9 MPa were accomplished at suitable contents of styrene units and sulfur, i.e., 32 wt % and 75 mol %, respectively. The high proton conductivity, excellent stability, and good mechanical properties were associated with not only the formation of the nanomatrix channel but also a specific concentration of sulfuric acid group. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. 相似文献
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Nguyen Thu Ha Keisuke Kaneda Yoshitaka Naitoh Lina Fukuhara Kenichiro Kosugi Seiichi Kawahara 《应用聚合物科学杂志》2015,132(34)
Preparation and graft‐copolymerization of hydrogenated natural rubber are performed in latex stage after removal of proteins from the rubber with urea and surfactant. Hydrogenation of deproteinized natural rubber (DPNR) latex is carried out with palladium catalyst under hydrogen atmosphere. The hydrogenated DPNR (HDPNR) is crosslinked with a peroxide followed by graft‐copolymerization of styrene (Sty) and acrylonitrile (AN) in latex stage in order to prepare a graft‐copolymer of crosslinked HDPNR with poly(Sty‐co‐AN) (HDPNR‐graft‐PSAN). Characterization of the products is performed by nuclear magnetic resonance spectroscopy. The conversion of hydrogenation is investigated with respect to the catalyst feed, acidity (pH), and dry rubber content. In the resulting HDPNR‐graft‐PSAN, mole fraction of AN and Sty is 1.4 and 5.8 mol %, respectively. The graft‐copolymer is used to improve properties of PSAN as an impact modifier. The Charpy impact strength of crosslinked HDPNR‐graft‐PSAN/PSAN is about eight times as high as that of PSAN. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42435. 相似文献
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Siti Hajjar Che Man Azanam S. Hashim Hazizan Md. Akil 《Journal of Polymer Research》2008,15(5):357-364
The graft copolymerization of styrene/methyl methacrylate (MMA) onto deproteinized natural rubber (DPNR) latex was carried
out using ammonium peroxy disulfate (N2H8O8S2) as the initiator. The presence of the grafted polystyrene (PS) and polymethyl methacrylate (PMMA) on the rubber backbone
was confirmed by FTIR spectroscopy. The effects of monomer concentrations on curing characteristics and mechanical properties
were studied. It was found that the cure time and scorch time were increased with increasing monomer concentration whereas
the torquemax–min value was slightly decreased. It was also noted that the increase in the monomer concentration resulted in stiffer rubber
with increased modulus and reduced elongation at break. 相似文献
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In natural rubber/high styrene resin microcellular sheets, part of natural rubber was replaced by latex reclaim prepared from waste latex products. The mechanical properties and cell structure of the products were evaluated. It was found that latex reclaim can replace about 30% of natural rubber without affecting the technical properties of the microcellular sheets. 相似文献