共查询到19条相似文献,搜索用时 93 毫秒
1.
有机/无机酸复合掺杂导电聚苯胺的合成及性能研究 总被引:1,自引:0,他引:1
采用化学氧化聚合法以苯胺为单体,过硫酸胺为氧化剂,在有机/无机混合酸的水溶液中合成导电聚苯胺.考察了有机/无机混合酸对聚苯胺性能的影响,并通过四探针、差热分析、红外光谱及拉曼光谱研究聚苯胺掺杂前后结构的变化.结果表明,当聚合温度为20℃、磺基水杨酸和硫酸的摩尔浓度比为0.25:1时,掺杂态聚苯胺电导率和溶解度达到最大值;其中电导率可达13.5 S·cm~(-1),在氮甲基吡咯烷酮(NMP)中溶解度可达85%.差热分析表明,有机/无机酸复合掺杂聚苯胺热稳定性较单一酸掺杂聚苯胺热稳定性有很大的提高;红外光谱和拉曼光谱表明;掺杂后聚苯胺具有导电性是因为其分子链上电荷离域形成了共轭结构. 相似文献
2.
3.
4.
用原位聚合法,以十二烷基苯磺酸(DBSA)/HC l混酸为掺杂剂,过硫酸胺(APS)为氧化剂,制备了聚苯胺/掺锑二氧化锡(ATO)导电复合材料。探讨了ATO用量对导电复合材料电导率的影响。在n(苯胺)∶n(APS)∶n(DBSA)=1∶1∶0.7,m(ATO)∶m(苯胺)=0.1∶1时,复合材料室温25℃的电导率最高可达8.35 S/cm,比通常方法合成的聚苯胺和nano-ATO的电导率分别提高约1至2个数量级。通过FTIR、XRD、SEM和TEM对目标物进行了表征,结果表明,苯胺优先在ATO纳米粒子表面聚合,形成聚苯胺包覆ATO的导电复合材料。 相似文献
5.
6.
7.
8.
9.
本研究采用氧化聚合方法制备了具有高电导率的导电聚苯胺。并以这种聚苯胺为导电填料,以丙稀酸为成膜物,制备了一种电导率为10-8~10-5s/m的导电涂料。并研究了聚苯胺含量对导电涂料电导率及涂膜性能的影响。 相似文献
10.
11.
12.
Anurag Lodha S. Michael Kilbey Praveen C. Ramamurthy Richard V. Gregory 《应用聚合物科学杂志》2001,82(14):3602-3610
We report structure–property relationships of polyaniline emeraldine base (EB) films that were produced by combining different processing steps in various sequences. The effect of annealing and doping processes on the surface structure of the films was investigated by atomic force microscopy (AFM), and the corresponding changes to the chemical structure of the EB films were monitored by Fourier transform infrared spectroscopy. AFM results indicate that after doping polyaniline (EB) films with HCl, the root mean square (rms) roughness of the surface of EB film increased ~ 46%. When the doped films were annealed at 180°C under a nitrogen atmosphere for 3 h, the rms roughness was essentially unchanged from that of the initial, undoped films. The electrical conductivity of the films also showed a significant dependence on the processing sequence. When the doped polyaniline (EB) films were annealed, no electrical conductivity was observed. When these films were redoped, only ~ 6% of the initial conductivity could be recovered. In another processing sequence in which the polyaniline (EB) films were first annealed and then doped, the electrical conductivity was only ~ 12% relative to the film that was doped immediately after being cast. From this work, a strategy to reduce the surface roughness of films made from electrically conducting polyaniline (EB) is proposed. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 3602–3610, 2001 相似文献
13.
以硫酸铜(CuSO4)为催化剂,H2O2为氧化剂,通过"无模板"化学氧化聚合制备出聚苯胺纳米纤维。研究了温度、H2O2的浓度、催化剂的浓度对聚苯胺的产率、电导率、反应速度的影响,确定出最佳聚合反应条件为:苯胺0.1 mol/L,盐酸1 mol/L,H2O2 0.15 mol/L,CuSO40.05 mol/L,反应时间为24小时。在此条件下合成聚苯胺的产率为58.2%,电导率为1.98 S/cm。红外光谱和紫外-可见光谱确定了合成聚苯胺的结构,扫描电镜图中发现制备导电聚苯胺呈纤维状,直径大约为60~80 nm,长度大约为400 nm。 相似文献
14.
Polyaniline salt was synthesized through the chemical oxidation of aniline with sodium persulfate as the oxidant and didecyl ester of 4‐sulfophthalic acid via three different polymerization pathways (aqueous, emulsion, and interfacial). In these polymerization processes, the ester acted as a novel plast dopant and as an emulsifier. The yield, conductivity, and number of ester units present in the polyaniline salts were determined. A polyaniline salt prepared by emulsion polymerization was soluble in chloroform and showed excellent solution‐processing properties. Polyaniline samples prepared by aqueous or interfacial polymerization were not soluble in chloroform. A soluble polyaniline salt was successfully synthesized through the washing of an organic layer containing the polyaniline salt with water in emulsion polymerization. X‐ray diffraction spectra of polyaniline salts prepared by the three different methods showed an ordered, layer‐type supramolecular structure. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
15.
Aqueous conducting polyaniline dispersion was prepared employing acidic phosphate ester bearing hydrophilic ethylene glycol segment as dopant, and conducting film with electrical conductivity of 25 S/cm was obtained from the dispersion. Ordered self-assembly lamellar structure with interlamellar distance of 1.2 nm was observed in the film, which consisted of alternating layers of rigid polyaniline chain and flexible phosphate ester side chains, where the phosphate side chain layer was separated by two rigid polyaniline layers. The lamellar structure leading to high conducting film was formed due to the confinement of polyaniline chain by crystallizable phosphate side chain, since the electrical conductivity decreased by four orders of magnitude once the dopant side chain crystalline was destroyed. The crystallizable side chain forced lamellar structure is expected to be a new chance for highly conducting polyaniline. 相似文献
16.
Polyaniline was prepared by chemical methods. Its electrical conductivity was measured. The electrical conductivity of polyaniline salt and polyaniline base were compared with composites prepared by the hot press of polyaniline base with KBr, Co(CH3COO)2, and picric acid. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 1658–1665, 2000 相似文献
17.
PbS/polyaniline core–shell nanocomposites were successfully synthesized via in situ chemical oxidation polymerization of aniline based on the octahedral PbS nanocrystals colloid. The morphology and structure of the products were characterized by transmission electron microscopy, X‐ray diffraction, Fourier transform infrared spectra, UV–vis spectra, and conductivity measurement. A possible formation mechanism of the PbS/polyaniline core–shell nanocomposites was also proposed. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers 相似文献
18.
F. Z. Silveira G. W. Duarte C. G. Tachinski R. Piletti J. Fiori Jr. M. Peterson H. G. Riella M. A. Fiori 《应用聚合物科学杂志》2013,128(1):430-435
This work focuses on the comparison between the morphological, chemical, and electrical properties of polyaniline doped with fluoridric and polyaniline, and doped with sulfuric acid. The FT‐IR, XRD, and SEM/EDS results indicate that the use of hydrofluoric acid as doping agent does not provide meaningful changes in the crystalline and morphological structure of polyaniline. Although, the inclusion of F? type counter‐ions from the doping process with HF provide more compact, denser, and with higher electrical conductivity polymeric matrices. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2013 相似文献