Phenyl Ethylammonium Iodide introduction into inverted triple cation perovskite solar cells for improved VOC and stability

The efficiency of more than 25% in organic-inorganic hybrid perovskite solar cells has made them very attractive in the pursuit of cheaper alternatives to Si-based devices. However, the stability of the perovskite solar cells was challenging, given their high susceptibility to moisture. Very few reports have emerged in this regard that investigated the influence of introducing large cations into a triple cation perovskite (TC-PVS), with several studies limited to single and dual cation perovskites. Further, the crystallization of TC-PVS on a polymer surface such as PEDOT is not straightforward, and their inclusion in inverted solar cell devices was limited. In this work, we investigated the impact of incorporating Phenyl ethyl ammonium cation into FAMACs triple cation composition. We demonstrated improvements in the crystallinity and more uniform coverage with little to no pinholes and smooth morphology for an optimum PEA amount of 1.67% in the precursor solution. The superior morphology, along with a passivation effect from a quasi 2D phase, led to increased photoluminescence and minority carrier lifetimes. Corresponding inverted photovoltaic devices prepared with PEA showed increased open-circuit voltage from 0.89 V for a control sample to 0.95 V for 1.67% PEA and 0.98 V for 5% PEA, doped devices in an inverted configuration. The efficiency, as a result, increased from 11.27% for a control device to 14.85% for a 1.67% PEA doped device. Further, PEA doped devices showed improved operational and thermal stability attributed to the higher moisture tolerance and light-soaking ability of the PEA doped TC-PVS compared to the undoped TC-PVS.     

微通道式PCR芯片温度的研究

微通道式PCR芯片是对DNA扩增的新方法，通过样品试剂在三个温区间的流动，实现对试剂中特定DNA片段的几何级数扩增。研究了一种新型微通道式PCR芯片，利用有限元技术，对芯片上热区的温度梯度和均匀性进行了计算，对影响PCR反应的三种温度因素作出了定量分析。另外，针对传感器和加热器的外形、放置以及加热区的不均匀化，采取了系列优化措施，计算了薄膜电阻功率和电阻参数，改善了芯片的热特性，提高了其倍增的效率。     

Stability of diketopyrrolopyrrole small-molecule inverted organic solar cells

Small-molecule DPP(TBFu)₂-based inverted organic solar cells were fabricated and their stability investigated. The effects of thermal annealing and solvent annealing on device performance and stability were compared. To increase the stability, mix-PCBM (PC₆₁BM and its C₇₀ analogue), which is reported to give higher device stability, was also included. Solvent-annealed devices showed the highest power conversion efficiency (PCE) of 4.62%, whereas thermally annealed devices showed a PCE of 3.94%. After the aging process, which involved thermal stress and exposure to air, thermally annealed and mix-PCBM devices retained a PCE of 3%, whereas solvent-annealed devices had a much lower PCE of 1.7%. Therefore, our results show that in the long-term stability perspective, thermal annealing is better than solvent annealing, and mix-PCBM is better than PC₆₁BM in the case of DPP(TBFu)₂. We fabricated small-molecule inverted organic solar cells that retain their performance in air for 3 weeks without encapsulation.     

Porous silicon optical cavity structure applied to high sensitivity organic solvent sensor

The present work reports the thermal annealing process, the number of layer and electrochemical process effect in the optical response quality of Bragg and microcavity devices that were applied as organic solvent sensors. These devices have been obtained by using porous silicon (PS) technology. The optical characterization of the Bragg reflector, before annealing, showed a broad photonic band-gap structure with blue shifted and narrowed after annealing process. The electrochemical process used to obtain the PS-based device imposes the limit in the number of layers because of the chemical dissolution effect. The interface roughness minimizations in the devices have been achieved by using the double electrochemical cell setup. The microcavity devices showed to have a good sensibility for organic solvent detection. The thermal annealed device showed better sensibility feature and this result was attributed to passivation of the surface devices.     

Thermal management of BioMEMS: temperature control for ceramic-based PCR and DNA detection devices

Integrated microfluidic devices for amplification and detection of biological samples that employ closed-loop temperature monitoring and control have been demonstrated within a multilayer low temperature co-fired ceramics (LTCC) platform. Devices designed within this platform demonstrate a high level of integration including integrated microfluidic channels, thick-film screen-printed Ag-Pd heaters, surface mounted temperature sensors, and air-gaps for thermal isolation. In addition, thermal-fluidic finite element models have been developed using CFDRC ACE+ software which allows for optimization of such parameters as heater input power, fluid flow rate, sensor placement, and air-gap size and placement. Two examples of devices that make use of these concepts are provided. The first is a continuous flow polymerase chain reaction (PCR) device that requires three thermally isolated zones of 94/spl deg/C, 65/spl deg/C, and 72/spl deg/C, and the second is an electronic DNA detection chip which requires hybridization at 35/spl deg/C. Both devices contain integrated heaters and surface mount silicon transistors which function as temperature sensors. Closed loop feedback control is provided by an external PI controller that monitors the temperature dependant I-V relationship of the sensor and adjusts heater power accordingly. Experimental data confirms that better than /spl plusmn/0.5/spl deg/C can be maintained for these devices irrespective of changing ambient conditions. In addition, good matching with model predictions has been achieved, thus providing a powerful design tool for thermal-fluidic microsystems.     

Reduction of self-heating effect using selective buried oxide (SELBOX) charge plasma based junctionless transistor

A junctionless transistor (JLT) having high doping concentration of the channel, suffers from the threshold voltage roll-off because of random dopant fluctuation (RDF) effect. RDF has been minimized by using charge plasma based JLT. Charge plasma is same as a workfunction engineering in which work function of the electrode is varied to create hole/electron plasma and induce doping in the intrinsic silicon. N-type doping is induced at the source and drain side due to difference of workfunction of silicon wafer. In this paper, charge plasma based junctionless MOSFET on selective buried oxide (SELBOX-CPJLT) is proposed. This approach is used to reduce the self-heating effect presented in SOI-based devices. The proposed device shows better thermal efficiency as compared to SELBOX-JLT. 2D-Atlas simulation revealed the electrostatics and analog performance of both the devices. The SELBOX-CPJLT exhibits better electrostatic performance as compared to SELBOX-JLT for the same channel length. The analog performance such as intrinsic gain, transconductance generation factor, output conductance and unity gain cut-off frequency are extracted from small signal ac analysis at 1 MHz and compared to SELBOX-JLT. The analysis of the thermal circuit model of SELBOX structure is also performed.     

Coupling efficiencies in reflective self-organized lightwave network (R-SOLNET) simulated by the beam propagation method

The reflective self-organized lightwave network (R-SOLNET) enables the formation of self-aligned waveguides in the photorefractive (PR) material between misaligned optical devices by introducing a write beam. The incident write beam from one device and the reflected write beam from the second device induce self-focusing in the PR material and construct a coupling waveguide. A wavelength filter on the waveguide edge is used to facilitate the reflected beam. The beam propagation method reveals that R-SOLNET exhibits higher coupling efficiencies and better tolerances than the one-beam-writing SOLNET and the free-space coupling. The apparent usefulness of R-SOLNET is remarkable for gaps wider than 100 /spl mu/m in 8-/spl mu/m-wide waveguide circuits. For 240-/spl mu/m gap, coupling efficiency better than 50% can be achieved even when the lateral misalignment is as large as 4 /spl mu/m. The results indicate that R-SOLNET may be useful for vertical waveguide constructions of optical z-connections in three-dimensional intrachip optical interconnects and switching systems, as well as for self-aligned optical couplings with devices that cannot emit write beams such as vertical-cavity surface-emitting lasers, photodetectors, and electrooptic switches.     

20% External Quantum Efficiency in Solution‐Processed Blue Thermally Activated Delayed Fluorescent Devices

Highly efficient solution‐processed blue thermally activated delayed fluorescent (TADF) devices are developed by designing soluble blue TADF emitters. The solubility and emission color could be managed by introducing F as an electron withdrawing unit instead of CN. Two soluble blue TADF emitters are synthesized and show a high external quantum efficiency of 20.0% with a color coordinate of (0.16,0.26), and it is the best quantum efficiency reported in solution‐processed TADF devices. The device performances of the solution‐processed blue TADF devices are comparable to those of vacuum‐processed blue TADF devices.     

Electrothermal simulation of an IGBT PWM inverter

An electrothermal network simulation methodology is used to analyze the behavior of a full-bridge, pulse-width-modulated (PWM), voltage-source inverter, which uses insulated gate bipolar transistors (IGBTs) as the switching devices. The electrothermal simulations are performed using the Saber circuit simulator and include control logic circuitry, IGBT gate drivers, the physics-based IGBT electrothermal model, and thermal network component models for the power-device silicon chips, packages, and heat sinks. It is shown that the thermal response of the silicon chip determines the IGBT temperature rise during the device switching cycle. The thermal response of the device TO247 package and silicon chip determines the device temperature rise during a single phase of the 60-Hz sinusoidal output. Also, the thermal response of the heat sink determines the device temperature rise during the system startup and after load-impedance changes. It is also shown that the full electrothermal analysis is required to accurately describe the power losses and circuit efficiency     

Enhancement of electroluminescence efficiency and stability in phosphorescent organic light-emitting diodes with double exciton-blocking layers

A high efficiency phosphorescent organic light-emitting diode (OLED) has been fabricated by introducing a double exciton-blocking layer (d-EBL) between the hole-transporting layer and the light-emitting layer in the device. The device exhibits a yellow emission with a maximum current efficiency of 58.5 cd/A at 117 cd/m², corresponding to the power efficiency of 50.9 lm/W, which is two times improved compared with that of devices having only one traditional single exciton-blocking layer (s-EBL). The efficiency improvement has been investigated through the electroluminescence (EL) spectral analyses in the phosphorescent guest-doped and the non-doped OLEDs. The results demonstrate that the electrons are blocked and the excitons are confined more effectively in the d-EBL-based devices than that in the s-EBL-based devices. In addition, over two times improvement in the lifetime is also achieved in the devices with the d-EBL compared with the devices having a traditional s-EBL.     

阴极修饰层对ZnPc/C60有机太阳能电池性能的影响

研究了ZnPc/C60有机小分子太阳能电池阴极界面的修饰,采用LiF、Alq3和ZnPc作为修饰材料,分析不同修饰材料对器件性能和稳定性的影响。研究结果表明,引入适当厚度的修饰层不仅可以提高器件的性能,而且可以提高器件的稳定性。不同修饰材料表现出了不同的优势,用LiF修饰的器件填充因子提高了44%,Alq3修饰的器件转换效率提高了5倍,ZnPc修饰的器件开路电压最高并表现出良好的稳定性。最后,对相关机理进行了讨论。     

Efficient Infrared Electroluminescent Devices Using Solution‐Processed Colloidal Quantum Dots

We report efficient electroluminescence in the near‐infrared from PbS–MEH‐PPV (poly(2‐methoxy‐5‐(2′‐ethylhexyloxy)‐1,4‐phenylenevinylene)) large‐area, solution‐cast nanocomposite devices. We employ multivariate optimization of the structural and materials components that govern the radiative, energy‐transfer, and bipolar‐injection efficiencies into the devices. As a result, we report an external electroluminescence quantum efficiency of 0.27 %, which corresponds to an internal electroluminescence quantum efficiency of 1.9 %. The very best devices exhibit internal‐radiative‐efficiency‐limited performance and not transport‐ or capture‐limited performance, indicating that further gains in efficiency may be achieved if the internal radiative efficiency of the nanocrystal–polymer composite can be further increased without compromising transfer and device bipolar‐injection efficiency.     

Enhanced efficiency of organic light emitting devices (OLEDs) by control of laser imaging condition

Laser Induced Thermal Imaging (LITI) is a laser addressed thermal patterning technology with unique advantages such as excellent uniformity of transfer film thickness, capability of multilayer stack transfer, high resolution and scalability to large-size mother glass. However, the deterioration of the device performance during imaging process has been an obstacle to use it as a commercial technology. To investigate a possibility of thermal deformation of organic materials as a transfer layer and a receptor layer during imaging process, we executed a preliminary annealing test by using standard green devices at various temperatures. By comparison of these results with those obtained from LITI devices, we found that the main reason of device deterioration could be originated from the mobility change of the organic layers. Hence, we developed the dwell time control technology to suppress the thermal impact during LITI process and we finally obtained current efficiency which is quite equivalent to that obtained from the standard evaporation devices.     

Self‐Healing,Flexible, and Tailorable Triboelectric Nanogenerators for Self‐Powered Sensors based on Thermal Effect of Infrared Radiation

Self‐healing triboelectric nanogenerators (TENGs) with flexibility, robustness, and conformability are highly desirable for promising flexible and wearable devices, which can serve as a durable, stable, and renewable power supply, as well as a self‐powered sensor. Herein, an entirely self‐healing, flexible, and tailorable TENG is designed as a wearable sensor to monitor human motion, with infrared radiation from skin to promote self‐healing after being broken based on thermal effect of infrared radiation. Human skin is a natural infrared radiation emitter, providing favorable conditions for the device to function efficiently. The reversible imine bonds and quadruple hydrogen bonding (UPy) moieties are introduced into polymer networks to construct self‐healable electrification layer. UPy‐functionalized multiwalled carbon nanotubes are further incorporated into healable polymer to obtain conductive nanocomposite. Driven by the dynamic bonds, the designed and synthesized materials show excellent intrinsic self‐healing and shape‐tailorable features. Moreover, there is a robust interface bonding in the TENG devices due to the similar healable networks between electrification layer and electrode. The output electric performances of the self‐healable TENG devices can almost restore their original state when the damage of the devices occurs. This work presents a novel strategy for flexible devices, contributing to future sustainable energy and wearable electronics.     

Solution-Processed Organic Light-Emitting Diodes for Lighting

In this paper, the vapor-deposited and solution-processed organic light-emitting diode (OLED) technology development paradigms are described and then compared with respect to their prospects for enabling general lighting applications. Two key development needs are improved device efficiency and lower cost fabrication methods. Progress in these areas for solution-processed OLEDs is illustrated by describing recent methods for attaining high efficiency blue emission and introducing novel low cost process methods for device fabrication which enable high performance devices without the need for any vacuum processing steps     

具有新型电子传输层的有机薄膜电致发光器件

将8-hydroxy-quinolinato lithium(Liq)掺入4'7-diphyenyl-1,10-phenanthroline(BPhen)作为n型电子传输层(ETL),将tetrafluro-tetracyano-quinodimethane(F4-TCNQ)掺入4,4',4"-tris(3-methylphenylphenylamono)triphenylamine(m-MTDATA)作为p型空穴传输层(HTL),制作了p-i-n结构有机电致发光器件.为了检验传输层传导率的改善情况,制备了一系列单一空穴器件和单一电子器件.在引入BPhen:33wt% Liq作为ETL后,x% F4-TCNQ:m-MTDATA作为HTL后,器件的电流和功率效率明显改善.与控制器件(未掺杂)相比,性能最佳的掺杂器件的电流及功率效率分别提高了51%和89%,电压下降了29%.这是由于传输层传导能力的提高使得载流子在发光区域达到有效平衡.     

具有新型电子传输层的有机薄膜电致发光器件

将8-hydroxy-quinolinato lithium(Liq)掺入4'7-diphyenyl-1,10-phenanthroline(BPhen)作为n型电子传输层(ETL),将tetrafluro-tetracyano-quinodimethane(F4-TCNQ)掺入4,4',4"-tris(3-methylphenylphenylamono)triphenylamine(m-MTDATA)作为p型空穴传输层(HTL),制作了p-i-n结构有机电致发光器件.为了检验传输层传导率的改善情况,制备了一系列单一空穴器件和单一电子器件.在引入BPhen:33wt% Liq作为ETL后,x% F4-TCNQ:m-MTDATA作为HTL后,器件的电流和功率效率明显改善.与控制器件(未掺杂)相比,性能最佳的掺杂器件的电流及功率效率分别提高了51%和89%,电压下降了29%.这是由于传输层传导能力的提高使得载流子在发光区域达到有效平衡.     

Thermal and package performance limitations in LDMOSFET's for RFICapplications

This paper presents a systematic study of the limitations imposed by thermal and packaging considerations on radio-frequency (RF) performance of Si bulk and silicon-on-insulator (SOI) lateral DMOSFET's (LDMOSFET's). Several bulk and SOI devices are studied with the help of measurements as well as two-dimensional device simulations incorporating electrothermal models. Model parameters are extracted and used in circuit simulators to perform RF characterization of these devices. Further, a new three-region theory for the LDMOSFET is discussed and used to evaluate the static and RF performance of the devices in a nonisothermal environment. This paper shows that the package plays an important role in RF performance of SOI and bulk devices due to self-heating effects within the device. A detailed DC and RF performance evaluation is presented. Significant drift is observed in RF performance of bulk and SOI devices due to self-heating considerations. The physical understanding of these thermal effects within the device can facilitate the design of better packages for bulk and SOI devices     

Pixels consisting of a single vertical-cavity laser thyristor and adouble vertical-cavity phototransistor

Bidirectionally cascadable optical pixels that consist of a single-vertical-cavity surface-emitting laser (VCSEL) thyristor and a double-vertical-cavity phototransistor are proposed. Despite almost identical layer structures, each device characteristic can be independently optimized by introducing a λ/2-spacer layer into the phototransistor section. A lasing threshold of 0.8 mA and a slope efficiency of 0.25 W/A are obtained for the laser thyristor, and a flat-topped photocurrent spectrum over 30 A and a photocurrent gain of 70 A/W are obtained for the phototransistor at the resonant wavelength. This work demonstrates the possibility of monolithic integration using thermal desorption and a regrowth technique and the suitability of these devices for massively parallel optical interconnections     

Mechanochromic Photonic Vitrimer Thermal Management Device Based on Dynamic Covalent Bond

Flexible self-healing thermal management devices are increasingly in demand due to their high flexibility, low driving voltage, and excellent stability of thermal property. In this paper, the design of mechanochromic self-healing thermal management devices is reported based on photonic vitrimer through self-healing dynamic covalent bond. A series of new photonic vitrimers i first prepared by dynamic disulfide covalent bond and PS@SiO₂ photonic crystals. The resulting photonic vitrimer exhibits bright structural colors, large tensile strain (>1000%), high mechanical strength (>10 MPa) and self-healing ability (>95% efficiency). More importantly, the structural color remains constant after 10000 stretching/releasing cycles, demonstrating excellent mechanical stability, creep-resistance, and durability. Taking advantage of the above features, a novel mechanochromic flexible wireless thermal management (MFW) device is developed by semi-embedding the photonic vitrimer in a thermally conductive carbon nanotube film and then integrating it with a Bluetooth module and a control chip. Interestingly, the MFW device exhibits mechanochromic property, fast thermal response, low driving voltage (103 °C, at 3 V), and precise temperature control. Notably, the device even remains electrothermal performance (105 °C) after self-healing. This work provides new insight into the self-healing photonic materials, and the device shows promising applications in wearable electronics, vitro physiotherapy, and personal heating.