Atmospheric air dielectric barrier discharge excited by nanosecond pulse and AC used for improving the hydrophilicity of aramid fibers

In this paper, a long line-shape dielectric barrier discharge excited by a nanosecond pulse and AC is generated in atmospheric air for the purpose of discussing the uniformity, stability and ability of aramid fiber treatment. The discharge images, waveforms of current and voltage,optical emission spectra, and gas temperatures of both discharges are compared. It is found that nanosecond pulsed discharge has a more uniform discharge morphology, higher energy efficiency and lower gas temperature, which indicates that nanosecond pulsed discharge is more suitable for surface modification. To reduce the water contact angle from 96° to about 60°, the energy cost is only about 1/7 compared with AC discharge. Scanning electron microscopy,Fourier transform infrared spectroscopy and x-ray photoelectron spectroscopy are employed to understand the mechanisms of hydrophilicity improvement.     

Theoretical analysis of mass transfer and reaction in a porous medium applied to the gasification of graphite by water vapor

The theories of mass transfer and reaction in porous medium were applied to investigate the gasification of graphite by water vapor in reactor. Based on several logical assumptions, the gasification of graphite by water vapor was investigated. Different shapes of graphite were analysed: semi-infinite blocks, planks and cylinders. Analysis reveals that the reaction rate varies with the location, which can explain the intense gasification that occurs at upstream during experiments. The temperature dependence of the reaction rate expressed different ranges. At low temperatures, the reaction rates depend greatly on the reaction temperature, and the influence of shape is more pronounced. At high temperatures, the dependence weakens due to the limit of gas transfer, and the influence of shape disappears. The water vapor pressure at exterior surface decreases with temperature, but the pressure gradients (both inside and outside of porous media) increases with temperature. For the platelike and cylindrical porous media, the reaction rate decreases with the thickness or radius because of the increase in specific surface. When the penetrating depth of water vapor is larger than the half-thickness or radius of porous media, the water vapor would cumulate in porous media so that the pressure of reacting gas increases.     

Characteristics of Electrode-Water-Electrode Discharge and its Application to Water Treatment

Atmospheric air discharge above the surface of water is an effective method for water treatment.The leakage current and Joule heating of water are reduced by the air gap,which raises the energy efficiency of the water treatment.However,the application of this kind of discharge is limited by a pair of conflicting factors：the chemical efficiency grows as the discharge gap distance decreases,while the spark breakdown voltage decreases as the gap distance decreases.To raise the spark breakdown voltage and the chemical efficiency of atmospheric pressure water surface discharge,both the high-voltage electrode and the ground electrode are suspended above the water surface to form an electrode-water-electrode discharge system.For this system,there are two potential discharge directions：from one electrode to another directly,and from the electrodes to the water surface.The first step in utilizing the electrode-water-electrode discharge is to find out the discharge direction transition criterion.In this paper,the discharge direction transition criterions of spark discharge and streamer discharge are presented.By comparing the discharge characteristics and the chemical efficiencies,the discharge propagating from the electrodes to the water surface is proved to be more suitable for water treatment than that propagating directly between the electrodes.     

Physicochemical properties of the AC-excited helium discharges using a water electrode

In this paper, the AC-excited helium discharges generated between the powered needle electrode enclosed in a conical quartz tube and the grounded de-ionized water electrode are investigated.The current and voltage waveforms exhibit a transition from the glow-like to streamer-like mode discharges, which forms a stable cone-shaped structure at the gas–liquid interface. In this region,the air and water vapor diffusion initiate various physical–chemical processes leading to substantial changes of the primary species emission intensities(e.g., OH, N_2, NO, and O) and the rotational temperatures. The experimentally measured rotational temperature at the gas–liquid interface is 870 K from the N_2(C–B) band with a power input of 26 W. With the prolongation of the discharge time, significant changes in the discharge voltage and current, discharge emission patterns, instantaneous concentrations of the secondary species(e.g., H_2O_2,NO_2~-, and NO_3~-) in the liquid phase, p H values and electrical conductivities of the liquids are observed experimentally. The present study is helpful for deepening the understandings to the basic physical–chemical processes in the discharges in contact with liquids, especially to those occurring in the vicinity of the gas–liquid interface, and also for promoting existing and potential applications of such type of discharges in the fields of environmental protection, biomedicine,agriculture, and so on.     

Various concentric-ring patterns formed in a water-anode glow discharge operated at atmospheric pressure

Pattern formation is a very interesting phenomenon formed above a water anode in atmospheric pressure glow discharge. Up to now, concentric-ring patterns only less than four rings have been observed in experiments. In this work, atmospheric pressure glow discharge above a water anode is conducted to produce diversified concentric-ring patterns. Results indicate that as time elapses, the number of concentric rings increases continuously and up to five rings have been found in the concentric-ring patterns. Moreover, the ring number increases continuously with increasing discharge current. The electrical conductivity of the anode plays an important role in the transition of the concentric patterns due to its positive relation with ionic strength. Hence, the electrical conductivity of the water anode is investigated as a function of time and discharge current. From optical emission spectrum, gas temperature and intensity ratio related with density and temperature of electron have been calculated. The various concentric-ring patterns mentioned above have been simulated at last with an autocatalytic reaction model.     

Plasma propagation in single-particle packed dielectric barrier discharges: joint effects of particle shape and discharge gap

In this work, a single Al₂O₃ particle packed dielectric barrier discharge (DBD) reactor with adjustable discharge gap is built, and the influences of the particle shape (ball and column) and the residual gap between the top electrode and particle on the electrical and optical characteristics of plasma are studied. Our research confirms that streamer discharge and surface discharge are the two main discharge patterns in the single-particle packed DBD reactor. The strong electric field distortion at the top of the ball or column caused by the dielectric polarization effect is an important reason for the formation of streamer discharge. The length of streamer discharge is proportional to the size of the residual gap, but the number of discharge times of a single voltage cycle shows an opposite trend. Compared to the column, a smooth spherical surface is more conducive to the formation of large and uniform surface discharges. The surface discharge area and the discharge intensity reach a maximum when the gap is equal to the diameter of the ball. All in all, the results of this study will provide important theoretical support for the establishment of the synergistic characteristics of discharge and catalysis in plasma catalysis.     

The Characteristics of Dielectric Barrier Discharge and its Influence on the Excimer XeCl* Emission

1. IntroductionThere are many reports concerning the dischargemodes at high pressure. The modes of dielectricbarrier discharge (DBD) could be divided mainlyinto two kinds f filament discharge or micro-dischargeand glow discharge or diffused discharge. The fila-ment discharge is a typical characteristic of traditional ozone generator [l], but the characteristics ofDBD in monoatomic gases such as helium, neon andargon at high pressure are'Pfglow-like diffused dis-charge [2]. For air, three co…     

Pattern Formation in a Dusty Plasma System

A rich variety of dust patterns have been observed in a capacitively coupled rf discharge dusty plasma system. Dust particles are synthesized through chemical reaction of the filled gas mixture during discharge. Different patterns are formed in different stages of particle growth. In the early stage of particle growth, dust cloud can be formed by a large number of small particles, and its behavior appears to be fluid-like. Such interesting nonlinear phenomena as dust void and complex dust cloud patterns are observed in this stage. As dust particles grow, the particle size and structure can be controlled to follow two different routes. In one of the routes, the particles grow up in a ball-like shape and can be formed into regular lattice and cluster patterns. In the other, the particles grow up in a fractal shape.     

Square grid pattern with direction-selective surface discharges in dielectric barrier discharge

A new phenomenon that a filament discharged only once instead of twice in a cycle of the applied voltage is observed in a square grid pattern in a dielectric barrier discharge(DBD) with a larger gas gap, which is named intermittent discharge. Its spatiotemporal dynamics and the formation mechanism are studied by the multiple photomultiplier tubes and an intensified charge-coupled device.Corresponding to the positions of spots in the picture with an exposure time of 40 ms, there are some bright s...     

Investigation of flame structure in plasma-assisted turbulent premixed methane-air flame

The mechanism of plasma-assisted combustion at increasing discharge voltage is investigated in detail at two distinctive system schemes (pretreatment of reactants and direct in situ discharge).OH-planar laser-induced fluorescence (PLIF) technique is used to diagnose the turbulent structure methane-air flame,and the experimental apparatus consists of dump burner,plasma-generating system,gas supply system and OH-PLIF system.Results have shown that the effect of pretreatment of reactants on flame can be categorized into three regimes:regime Ⅰ for voltage lower than 6.6 kV;regime Ⅱ for voltage between 6.6 and 11.1 kV;and regime Ⅲ for voltage between 11.1 and 12.5 kV.In regime Ⅰ,aerodynamic effect and slower oxidation of higher hydrocarbons generated around the inner electrode tip plays a dominate role,while in regime Ⅲ,the temperature rising effect will probably superimpose on the chemical effect and amplify it.For wire-cylinder dielectric barrier discharge reactor with spatially uneven electric field,the amount of radicals and hydrocarbons are decreased monotonically in radial direction which affects the flame shape.With regard to in situ plasma discharge in flames,the discharge pattern changes from streamer type to glow type.Compared with the case of reactants pretreatment,the flame propagates further in the upstream direction.In the discharge region,the OH intensity is highest for in situ plasma assisted combustion,indicating that the plasma energy is coupled into flame reaction zone.     

Characteristics of a radio-frequency cold atmospheric plasma jet produced with a hybrid cross-linear-field electrode configuration

Cold atmospheric plasma (CAP) jet has wide applications in various fields including advanced materials synthesis and modifications, biomedicine, environmental protection and energy saving, etc. Appropriate control on the volume, temperature and chemically reactive species concentrations of the CAP jet is of great importance in actual applications. In this paper, an radio-frequency atmospheric-pressure glow discharge (RF-APGD) plasma generator with a hybrid cross-linear-field electrode configuration is proposed. The experimental results show that, with the aid of the copper mesh located at the downstream of the traditional co-axial-type plasma generator with a cross-field electrode configuration, a linear field between the inner powered electrode of the traditional plasma generator and the copper mesh can be established. This liner- field can, to some extent, enhance the discharges at the upstream of the copper mesh, resulting in small increments (all less than 12.5%) of the species emission intensities, electron excitation temperatures and gas temperatures by keeping other parameters being unchanged. And due to the intrinsic transparent and conducting features of the grounded copper mesh to the gas flowing, electric current and heat flux of the plasma plumes, a plasma region with higher concentrations of chemically reactive species and larger plasma plume diameters is obtained at the downstream of the grounded copper mesh on the same level of the gas temperature and electron excitation temperature compared to those of the plasma free jet. In addition, the charged particle number densities at the same downstream axial location of the grounded copper mesh decrease significantly compared to those of the plasma free jet. This means that the copper mesh is also, to some extent, helpful for separating the chemically reactive neutral species from the charged particles inside a plasma environment. The preceding results indicate that the cross-linear-field electrode configuration of the plasma generator is an effective approach for tuning the characteristics of the RF-APGD plasma jet in order to obtain an appropriate combination of the plasma jet properties with higher chemically reactive species concentrations, especially relative higher number densities of neutral species, larger plasma volumes and lower gas temperatures.     

Mode transition induced by gas pressure in dusty acetylene microdischarges: two-dimensional simulation

Radio-frequency microdischarge in acetylene is investigated by use of a fluid model and an aerosol dynamics model in a cylindrical discharge chamber. In this article, the results at a pressure of 100–500 Torr, a voltage of 80–150 V, and an electrode gap of 400–1000 μm are carefully analyzed and discussed. It is shown that two electron heating modes α and γ appear in the microdischarge, and the pressure-dependent transition from α to γ was accompanied by the abrupt decrease of electron density and electron temperature. The mode transition phenomenon is further confirmed by the variation of the electron temperature axial profiles, the profiles vary continuously from a center high at the pressure of 100 Torr to an edge high at the pressure of500 Torr. Furthermore, in the α mode(100 Torr) the plasma density increases linearly with the increase of electrode gap, but decreases sharply with the increase of electrode gap in the γ mode(100 Torr). The gas pressure and applied voltage effects on the nanoparticle density and degree of nonuniformity are also investigated. It has been shown that the gas pressure greatly influences the axial profiles of nanoparticle density and the values of the degree of nonuniformity, while the values of the plasma parameters(electron density and nanoparticle density) strongly depend on the applied voltage.     

The etch mechanisms of magnetic materials in an HCl plasma

The etch rates of CoNbZr and Fe/FeCrB soft-magnetic materials have been determined in an RF HC1 plasma as a function of pressure. The bombardment energy flux towards the powered electrode and the surface temperature of the material being etched, are both dependent on applied power and pressure. At lower surface temperatures the etch mechanism is shown to be chemically-assisted sputter etching (CASE). At higher temperatures a temperature dependent etch rate is observed, with an activation energy that can be ascribed to the desorption of metal chlorides. When using an alumina mask, selectivities up to 8 and steep side walls can be obtained. A general two-step etch mechanism is proposed, which correlates the side wall profile to the rate-determining step and explains the observed temperature dependencies of the etch rates.     

Spatial Evolution Study of EEDFs and Plasma Parameters in RF Stochastic Regime by Langmuir Probe

An RF compensated cylindrical Langmuir probe system has been developed and used to characterize an RF capacitive two temperature plasma discharge in a stochastic mode. The novelty of the work presented here is the use of the driven electrode （cathode） without ground shield. Measurements of the electron energy distribution function （EEDF） and plasma parameters were achieved under the following conditions： 50 W of RF power and 5× 10-2 mbar of argon pressure. The probe measurements are performed at 3 cm above the electrode and the probe was shifted radially （r direction） from the center （r = 0 cm） of the inter-electrodes region towards the chamber wall （R = 10.75 cm）. The results show that the EEDF is bi-Maxwellian and its shape remains the same through the scanned region. The farther the probe from the central region, the lower the EEDF maximum. The plasma density is observed to decrease according to a Gaussian profile along the radial direction and falls to 50% of its maximum when close to the cathode edge （r = 5.5 cm）. At the same time the effective electron temperature remains constant for r〈4 cm and increases for r≥4 cm. The high-temperature and low-temperature electrons＇ densities and temperatures are also discussed in the article.     

Degradation of Microcystin-LR by Gas-Liquid Interfacial Discharge Plasma

In this study, we report on the degradation of microcystin-LR （MC-LR） by gas- liquid interracial discharge plasma. The influences of operation parameters such as average input voltage, electrode distance and gas flow rate are investigated. Experimental results indicate that the input voltage and gas flow rate have positive influences on MC-LR degradation, while the electrode distance has a negative one. After 6 min discharge with 25 kV average input voltage and 60 L/h air aerati by discharge both in on, the degradation rate of MC-LR achieves 75.3%. distilled water and MC-LR solution are measured H202 and 03 generated Moreover, an emission spectroscopy is used as an indicator of the processes that take place on the gas-liquid boundary and inside plasma. Varied types of radicals （O, .OH, CO, 03, etc.） are proved to be present in the gas phase during gas-liquid interfacial discharge.     

Effect of Segmented Electrode Length on the Performances of an Aton-Type Hall Thruster

The influences of the low-emissive graphite segmented electrode placed near the channel exit on the discharge characteristics of a Hall thruster are studied using the particlein-cell method.A two-dimensional physical model is established according to the Hall thruster discharge channel configuration.The effects of electrode length on the potential,ion density,electron temperature,ionization rate and discharge current are investigated.It is found that,with the increasing of the segmented electrode length,the equipotential lines bend towards the channel exit,and approximately parallel to the wall at the channel surface,the radial velocity and radial flow of ions are increased,and the electron temperature is also enhanced.Due to the conductive characteristic of electrodes,the radial electric field and the axial electron conductivity near the wall are enhanced,and the probability of the electron-atom ionization is reduced,which leads to the degradation of the ionization rate in the discharge channel.However,the interaction between electrons and the wall enhances the near wall conductivity,therefore the discharge current grows along with the segmented electrode length,and the performance of the thruster is also affected.     

Novel electrode structure in a DBD reactor applied to the degradation of phenol in aqueous solution

Phenol degradation experimental results are presented in a similar wastewater aqueous solution using a non-thermal plasma reactor in a coaxial dielectric barrier discharge. The novelty of the work is that one of the electrodes of the reactor has the shape of a hollow screw which shows an enhanced efficiency compared with a traditional smooth structure. The experimentation was carried out with gas mixtures of 90% Ar–10% O_2, 80% Ar–20% O_2 and 0% Ar–100% O_2. After one hour of treatment the removal efficiency was 76%, 92%, and 97%, respectively, assessed with a gas chromatographic mass spectrometry technique. For both reactors used, the ozone concentration was measured. The screw electrode required less energy, for all gas mixtures, than the smooth electrode, to maintain the same ozone concentration. On the other hand, it was also observed that in both electrodes the electrical conductivity of the solution changed slightly from~0.0115 S m~(-1) up to ~0.0430 S m~(-1) after one hour of treatment. The advantages of using the hollow screw electrode structure compared with the smooth electrode were:(1) lower typical power consumption,(2) the generation of a uniform plasma throughout the reactor benefiting the phenol degradation,(3) a relatively lower temperature of the aqueous solution during the process, and(4) the plasma generation length is larger.     

The influence of grounded electrode positions on the evolution and characteristics of an atmospheric pressure argon plasma jet

An atmospheric pressure plasma jet (APPJ) in Ar with various grounded electrode arrangements is employed to investigate the effects of electrode arrangement on the characteristics of the APPJ.Electrical and optical methods are used to characterize the plasma properties.The discharge modes of the APPJ with respect to applied voltage are studied for grounded electrodepositions of 10 mm,40 mm and 80 mm,respectively,and the main discharge and plasma parameters are investigated.It is shown that an increase in the distance between the grounded electrode and high-voltage electrode results in a change in the discharge modes and discharge parameters.The discharges transit from having two discharge modes,dielectric barrier discharge (DBD) and jet,to having three,corona,DBD and jet,with increase in the distance from the grounded to the high-voltage electrodes.The maximum length of the APPJ reaches 3.8 cm at an applied voltage of 8 kV.The discharge power and transferred charges and spectral line intensities for species in the APPJ are influenced by the positions of the grounded electrode,while there is no obvious difference in the values of the electron excited temperature (EET) for the three grounded electrode positions.     

Simulation of the Effect of a Metal Vapor Arc on Electrode Erosion in Liquid Metal Current Limiting Device

The effect of arc plasma on electrode erosion in a liquid metal current limiter(LMCL)is studied.Based on a simplified two-dimensional magnetohydrodynamic model,the elongated GaInSn metal vapor arc and its contraction process in a liquid metal current limiter are simulated.The distributions of temperature,pressure and velocity of the arc plasma are calculated.The simulation results indicate that the electrode erosion is mainly caused by two high temperature gas jet flows arising from the pressure gradient,which is a result of the non-uniform arc temperature distribution.The gas flows,which act as jets onto the electrode surface,lead to the evaporation of the electrode material form the surface.A redesign structure of the electrode is proposed and implemented according to the analysis,which greatly increased the service life of the electrode.     

Removal of NO and SO2 in Corona Discharge Plasma Reactor with Water Film

In this paper, a novel type of a corona discharge plasma reactor was designed, which consists of needle-plate-combined electrodes, in which a series of needle electrodes are placed in a glass container filled with flue gas, and a plate electrode is immersed in the water. Based on this model, the removal of NO and SO2 was tested experimentally. In addition, the effect of streamer polarity on the reduction of SO2 and NO was investigated in detail. The experimental results show that the corona wind formed between the high-voltage needle electrode and the water by corona discharge enhances the cleaning efficiency of the flue gas because of the presence of water, and the cleaning efficiency will increase with the increase of applied dc voltage within a definite range. The removal efficiency of SO2 up to 98%, and about 85% of NO~ removal under suitable conditions is obtained in our experiments.