An experimental investigation of NO2 emission characteristics of a heavy-duty H2-diesel dual fuel engine

This paper investigated the nitrogen dioxide (NO₂) emissions of a heavy-duty diesel engine operated in hydrogen (H₂)-diesel dual fuel combustion mode with H₂ supplemented into the intake air. Preliminary measurements using the 13-mode European Stationary Cycle (ESC) demonstrated the significant effect of H₂ addition on the emissions of NO₂. The detailed effects of H₂ addition and engine load on NO₂ emissions were examined at 1200 RPM. The addition of a small amount of H₂ increased substantially the emissions of NO₂ and the NO₂/NO_x ratio, especially at low load. Increasing the engine load was found to inhibit the enhancing effect of H₂ on the conversion of NO to NO₂ with the maximum NO₂/NO_x ratio observed at lower H₂ concentration. The maximum NO₂ emissions of the H₂-diesel dual fuel operation were three (at 70% load) to five (at 10% load) times that of diesel operation. Further increasing the addition of H₂ beyond the point with maximum NO₂ emissions still produced more NO₂ than for diesel-only operation. Based on the experimental data obtained, the engine load and maximum averaged bulk mixture temperature were not the main factors dominating the formation of NO₂ in the H₂-diesel dual fuel engine. A preliminary analysis demonstrated the significant effect of the unburned H₂ on NO₂ emissions. When mixed with the hot combustion product, the unburned H₂ that survived the main combustion process might further oxidize to raise the HO₂ levels and enhance the conversion of NO to NO₂. In comparison, the changes in the combustion process including the start of combustion, combustion duration and maximum heat release rate may not contribute substantially to the increased NO₂ emissions observed.     

Effects of ammonia substitution on combustion stability limits and NOx emissions of premixed hydrogen–air flames

The combustion stability limits and nitrogen oxide (NO_x) emissions of burner-stabilized premixed flames of ammonia (NH₃)-substituted hydrogen (H₂)–air mixtures at normal temperature and pressure are studied to evaluate the potential of partial NH₃ substitution to improve the safety of H₂ use. The effects of NH₃ substitution, nitrogen (N₂) coflow and mixture injection velocity on the stability limits and NO_x emissions of NH₃–H₂–air flames are experimentally determined. Results show a reduction of stability limits with NH₃ substitution and coflow, supporting the potential of NH₃ as a carbon-free, green additive in H₂–air flames and indicating a different tendency from that for no coflow condition. The NO_x emission index is almost constant even with enhanced NH₃ substitution, though the absolute value of NO_x emissions increases in general. At fuel-rich conditions, the NO_x emission index decreases with increasing mixture injection velocity and the existence of coflow. The thermal deNO_x process in the post-flame region is involved in reducing NO_x emissions for the fuel-rich flames.     

Impact of nitrogen oxides (NO,NO2, N2O) on the formation of soot

The emission of both nitrogen oxides and soot from combustion processes is still a matter of concern. When a flue gas recirculation (FGR) technique is applied, the presence of a given nitrogen oxide in the recirculated mixture can affect the emissions of other pollutants, such as soot, and be used for its control in a combustion process. In this context, the present work is focused on the identification of the effect of the main nitrogen oxides (NO, NO₂ and N₂O) present in combustion systems on soot and main product gases formation from the pyrolysis of ethylene, at atmospheric pressure and in the 975–1475 K temperature range. The experimental results are examined to assess the effectiveness of each nitrogen oxide in suppressing or boosting soot formation, to achieve the possible nitrogen oxides reduction, and to identify the elementary steps involved in the nitrogen oxides and ethylene conversion as function of the different nitrogen oxides. This analysis is supported on model calculations.     

Computational fluid dynamics investigation of alternative nitric oxide emission mechanisms in a hydrogen-fueled spark-ignition engine

In the present work, the reaction mechanisms of nitric oxide (NO) are investigated in a hydrogen-fueled, spark-ignition engine during load variation by mixture leaning. As these exhaust emissions are practically the only ones emitted from such engines, there is an obvious vivid interest for their reliable prediction under different operating conditions and modes, in order to investigate the potential future use of hydrogen in engines. For that purpose, a 3D-CFD (three dimensional – computational fluid dynamics) code is applied, which has been developed by the authors and validated extensively in the past under both motoring and firing conditions, being capable to simulate in high detail the in–cylinder processes. The CFD simulation has been accomplished using different sets of constants of the thermal NO mechanism, widely known as “Zeldovich mechanism”, to provide insight into the NO production pattern at each location in the cylinder during the combustion and expansion periods. The NO emission modeling has been enhanced here with the addition of alternative production paths, such as via the NNH and N₂O species formation. The NNH path has been shown to be favored at lean and low-temperature combustion conditions for hydrogen flames, whereas the N₂O path becomes important for lean flames irrespectively of the fuel used. The calculations are compared with available measurements, in order to quantify the applicability of the different sets of constants and the use of these alternative production paths at such conditions and applications. For the high load cases the NO predictions have good accuracy, since the constants used have been mainly derived at such high temperature conditions where additionally the thermal NO is almost the exclusive production path. On the contrary at mid and low engine loads, when the combustion temperature is lower and leaner mixtures are used, a significant discrepancy exists between the calculations and the measured data, which is however improved especially when the NNH route is taken into consideration.     

Combustion and NOx emissions characteristics of a down-fired 660-MWe utility boiler retro-fitted with air-surrounding-fuel concept

Air-surrounding-fuel is a well-known concept used within tangential and wall-fired boilers. Here, we report for the first time on industrial experiments performed to study the effects of this concept on a 660 MW_e full-scale down-fired boiler. Data are reported for the gas temperature distributions along the primary air and coal-mixed flows, furnace temperatures, gas compositions, for example O₂, CO and NO_x, and gas temperatures in the near-wall region. The influence of concentration control valve (CCV) opening on combustion and NO_x emission in the furnace were determined. The results show that the flame stability, temperature distribution, unburnt carbon are influenced by both concentration ratios and fuel-rich flow velocities. As CCV opening increases, NO_x emissions decrease from 2594 mg/m³ to 1895 mg/m³. Considering altogether economic benefits and environmental protection issues, 30% is the optimal value for the CCV opening.     

废液焚烧炉内燃烧过程及污染物排放特性数值模拟

应用FLUENT软件对某炼化企业处理量为10t?h–1的废液焚烧炉燃烧过程进行三维数值模拟,获得了焚烧炉炉膛内流场、温度场、各组分浓度分布、污染物生成及火焰形状等信息,揭示了炉膛内燃烧、流动以及传热与传质的特点。模拟不同过量空气系数下工业有机废液在炉内燃烧情况,结果表明：随着过量空气系数（EA）的增加,炉膛内温度峰值逐渐减小,炉膛温度分布更加均匀,燃烧区域增大,炉膛出口截面平均NOx浓度逐渐升高;在EA=1.25的情况下,炉膛出口排烟温度合理,氮氧化物排放浓度较低;模拟结果与试验数据吻合,验证了模型的可靠性,为优化设计操作工况及污染物的控制提供可靠依据。     

基于CFD分析的某四缸机进气EGR混合均匀性研究

各缸EGR率的均匀一致性控制,对于发动机NO_x排放达标至关重要。针对某四缸柴油机设计了4种不同EGR结构方案,并采用AVL FIRE软件分别对其进行EGR混合均匀性模拟分析。分析表明:进气接管朝发动机中间,EGR管从进气接管侧方伸入的结构,其EGR均匀一致性最好。为后续的设计奠定了基础。     

Experimental investigation of the combustion characteristics,emissions and performance of hydrogen port fuel injection in a diesel engine

Diesel engines are indispensable in daily life. However, the limited supply of petroleum fuels and the stringent regulations on such fuels are forcing researchers to study the use of hydrogen as a fuel. In this study, a diesel engine is operated using hydrogen–diesel dual fuel, where hydrogen is introduced into the intake manifold using an LPG-CNG injector and pilot diesel is injected using diesel injectors. The energy contents of the total fuel, 0%, 16%, 36% and 46% hydrogen (the 0% hydrogen energy fraction represents neat diesel fuel), were tested at 1300 rpm of constant engine speed and 5.1 kW of constant indicated power. According to test results, the indicated thermal efficiency of the engine decreases and the isfc increases with an increasing hydrogen energy fraction. Additionally, indicated specific CO, CO₂ and smoke emissions decrease with an increasing percentage of hydrogen fuel. However, indicated specific NO_x emissions do not change at the 16% hydrogen energy fraction, in other words, with an increase in the hydrogen amount (36% and 46% hydrogen energy fraction of total fuel), a dramatic increase (58.8% and 159.7%, respectively) is observed. Additionally, the peak in-cylinder pressure and the peak heat release rate values increase with the increasing hydrogen rate.     

An experimental study of a cylindrical multi-hole premixed burner for the development of a condensing gas boiler

This study experimentally examined a cylindrical multi-hole premixed burner for its potential use for a condensing gas boiler, which produces less NO_x emissions and performs better. In this study, the hole diameters and the arrangement of a multi-hole burner were investigated using a flat burner model. The combustion characteristics for the flame stability as well as the NO_x and CO emissions were examined using a cylindrical burner. For an optimal operating condition, the equivalence ratio for the cylindrical burner was between 0.70 and 0.75. For this condition, the turn-down ratio was 3:1 or higher, which was suitable for appropriate control of the boiler operation. The NO_x and CO emissions were less than 40 ppm and less than 30 ppm, respectively, for a 0% O₂ basis. The LPG and LNG were able to be used in this type of burner because there was no phenomenal difference in the stable combustion region between them.     

Performances of a heat exchanger and pilot boiler for the development of a condensing gas boiler

In this research, design factors for a heat exchanger and boiler were investigated using a simplified model of a heat exchanger and pilot condensing boiler, respectively. Specifications of each heat exchanger component (e.g., upper heat exchanger (UHE) and lower heat exchanger (LHE); coil heat exchanger (CHE); baffles) were investigated using a model apparatus, and the comprehensive performance of the pilot gas boiler was examined experimentally. The heating efficiency of the boiler developed was about 90% when using the optimal designed heat exchangers. Compared to a conventional Bunsen-type boiler, the heating efficiency was improved about 10%. Additionally, NO_x and CO emissions were about 30 ppm and 160 ppm, respectively, based on a 0% O₂ basis at an equivalence ratio of 0.70, which is an appropriate operating condition. However, the pollutant emission of the boiler developed is satisfactory considering the emission performance of a condensing boiler, even though CO emission must be reduced.     

Wood ash dilemma-reduced quality due to poor combustion performance

Recycling of wood ash is based on the presumption that moderate concentrations of environmentally harmful elements are a part of the nutrient cycle and do not increase in net concentrations in the forest soil. It is assumed that the same quantities of harmful elements are harvested from the forest and recycled back. This principle does not apply to polycyclic aromatic hydrocarbons (PAHs) since these pollutants are formed during the combustion process, especially when the combustion performance is poor. Additionally, industrial combustors are adjusted in order to reduce NO_x-emissions, indirectly causing formation of PAHs. This study examined fly ash from combustion of pulverized wood for its elemental and PAH concentrations during a period of 9 weeks. The 16 EPA-PAH concentrations range between 40 and 300 mg kg⁻¹. Re-burning of the ash reduces the PAH concentrations to 0.24 mg kg⁻¹ and organic carbon concentration from 40% to 5%, enhancing its composition significantly. It is important to determine the amount and fate of PAHs spread on forest soils with wood ash to ensure the improvement of the health of the forest ecosystem. Maximized energy efficiency of industrial boilers is the key to reducing anthropogenic emissions of greenhouse gases and enabling a sustainable nutrient recycling system.     

Merging of energy and environmental analyses for district heating systems

District heating (DH) systems, together with combined heat and power (CHP) plants, have been increasing both in number and interest over the last decade, but the environmental improvements are still controversial, because although there is usually a reduction in CO₂ emissions, a positive effect concerning other pollutants is not always certain. A limited number of works that pay particular attention to the local environmental effect due to DH plants have been found in a brief overview of DH papers. The energetic and environmental impact of a new DH+CHP plant has been investigated in the present paper, where this plant has been proposed to substitute the existing heating systems. The environmental aspects concerning the local variations due to some pollutants, such as sulfur oxides (SO_x), particulate matter (PM) and nitrogen oxides (NO_x), are in particular taken into account. The main data necessary for the analysis and the hypotheses that are useful to simulate the behavior of the local heating plant and DH plants (e.g. efficiency, the heating demand, etc.) are discussed. A dispersion model (Gaussian model) has been used to evaluate the effect at a local scale. Finally, a case study concerning a new DH+CHP plant in Northern Italy is presented and discussed.     

NOx emissions in n-heptane/air partially premixed flames

NO_x emissions in n-heptane/air partially premixed flames (PPFs) in a counter-flow configuration have been investigated. The flame is computed using a detailed mechanism that combines the Held’s mechanism for n-heptane and the Li and Williams’ mechanism for NO_x. The combined mechanism contains 54 species and 327 reactions. Based on a detailed analysis, dominant mechanisms responsible for NOx formation and destruction in PPFs are found to be thermal, prompt, and reburn mechanisms. The dominant reactions associated with these mechanisms are also identified. The effects of strain rate (a_s) and equivalence ratio (φ) on NO_x emissions are characterized for conditions in which the flame contains two spatially separated reaction zones; a rich premixed zone on the fuel side and a non-premixed zone on the air side. For most conditions, except for relatively high level of partial premixing, the NO formation rate in the non-premixed zone is significantly higher than that in the rich premixed zone. Within the rich premixed zone, the contribution of thermal NO to total NO_x is higher than that of prompt NO, while in the non-premixed zone, the prompt NO is the major contributor. The behavior is related to the transport of acetylene from the rich premixed to the non-premixed zone, and higher concentrations of CH, O, and OH radicals in the latter zone. A notable result in this context is that the existence of CH does not automatically imply that prompt NO will form. The existence of O and OH is also necessary, in addition to CH, to form prompt NO. The relative contributions of thermal and prompt mechanisms to total NO_x are generally insensitive to variations in a_s, but show strong sensitivity to variations in φ. There is a NO_x destruction region sandwiched between the rich premixed and the non-premixed reaction zones. The NO_x destruction occurs mainly through the reburn mechanism. The NO_x emission index (EINOx) is computed as a function of φ and a_s. These results are qualitatively in accord with previous numerical and experimental results for methane-air PPFs.     

Time-averaged characteristics of a reacting fuel jet in vitiated cross-flow

This paper describes an experimental study of reacting jets in a high-temperature (1775 K) vitiated crossflow at 6 atm. We present an extensive data set based on high speed chemiluminescence imaging and exhaust gas sampling showing the characteristics of the time-averaged trajectory, width of the flame, flame standoff (or ignition) location, and NO_x emissions over a momentum flux ratio range of 0.75 < J < 240. Key observations are: (1) Depending upon ignition times, reaction can initiate uniformly around the jet, initiate on the leeward side of the jet and spread around to the windward side farther downstream, or initiate further downstream. (2) The time-averaged trajectory generally follows nonreacting trajectories, but penetrates further in the far-field than for what would be expected of a nonreacting jet. (3) The width of heat release zone increases monotonically with downstream location, J, and flame flapping amplitude, but seems to be dominated by the size of the counter-rotating vortex pair. (4) The measured ignition locations were of the same order of magnitude as values based on calculated ignition time scales and mean jet exit velocities, but with some additional variability. (5) The incremental NO_x emissions were controlled primarily by the global temperature rise associated with burning the jet fuel (for the fixed crossflow conditions studied here), and the NO_x emissions increased roughly linearly with the temperature rise.     

130t·h~(-1)循环流化床锅炉低氮燃烧改造实践

为达到锅炉污染物排放标准的要求,并实现在役循环流化床锅炉可采用选择性非催化还原(SNCR)方式低成本脱除NOx的目标,对NOx的生成、降低NOx原始生成的炉内条件、脱硝工艺的选择等方面进行了阐释.从工程实践出发,对1台130 t·h-1高温高压循环流化床锅炉的相应结构进行了分析,提出了改造方案.该方案实施后达到了良好的改造效果.     

Uncatalysed and catalysed soot combustion under NOx + O2: Real diesel versus model soots

In this work, the uncatalysed and catalysed combustion of two commercial carbon blacks and three diesel soot samples were analysed and related to the physico-chemical properties of these carbon materials. Model soot samples are less reactive than real soot samples, which can be attributed, mainly, to a lower proportion in heteroatoms and a higher graphitic order for the case of one of the carbon blacks. Among the diesel soot samples tested, the most relevant differences are the volatile matter/fixed carbon contents, which are directly related to the engine operating conditions (idle or loaded) and to the use of an oxidation catalyst or not in the exhaust. The soot collected after an oxidation catalyst (A-soot) is more reactive than the counterpart virgin soot obtained under the same engine operating modes but before the oxidation catalyst. The reactivity of the different soot samples follows the same trend under uncatalysed and catalysed combustion, the combustion profiles being always shifted towards lower temperatures for the catalysed reactions. The differences between the soot samples become less relevant in the presence of a catalyst. The ceria-zirconia catalysts tested are very effective not only to oxidise soot but also to combust the soluble organic fraction emitted at low temperatures. The most reactive soot (A-soot) exhibits a T_50% parameter of 450 °C when using the most active catalyst.     

Homogeneous Charge Compression Ignition (HCCI) combustion: Implementation and effects on pollutants in direct injection diesel engines

Homogeneous Charge Compression Ignition (HCCI) combustion is a combustion concept which offers simultaneous reductions in both NO_x and soot emissions from internal combustion engines. In light of increasingly stringent diesel emissions limits, research efforts have been invested into HCCI combustion as an alternative to conventional diesel combustion. This paper reviews the implementation of HCCI combustion in direct injection diesel engines using early, multiple and late injection strategies. Governing factors in HCCI operations such as injector characteristics, injection pressure, piston bowl geometry, compression ratio, intake charge temperature, exhaust gas recirculation (EGR) and supercharging or turbocharging are discussed in this review. The effects of design and operating parameters on HCCI diesel emissions, particularly NO_x and soot, are also investigated. For each of these parameters, the theories are discussed in conjunction with comparative evaluation of studies reported in the specialised literature.     

Emission of impinging swirling and non-swirling inverse diffusion flames

The overall pollutants emission from impinging swirling and non-swirling inverse diffusion flames (IDFs) was evaluated quantitatively by the ‘hood’ method. The results of in-flame volumetric concentrations of CO and NO_x and overall pollutants emission of CO and NO_x in terms of emission index were reported. The in-flame volumetric concentrations of CO and NO_x were measured through a small hole drilled on the impingement plate. In comparison with the corresponding open flame, the CO and NO_x concentrations for the impinging swirling IDF are greatly lowered due to the entrainment of much more ambient air which is related to the increased flame surface area. For the swirling and non-swirling IDFs, the EINO_x increases as the nozzle-to-plate distance (H) increases because more space is available for the development of the high-temperature zone in the free jet portion of the impinging flame, which favors the thermal NO formation. The variation of EICO with H is different for the impinging swirling and non-swirling IDFs because they have different flame structures. For both flames, the EICO is high when their main reaction zone or inner reaction cone is impinged and quenched by the copper plate. The parameters of air jet Reynolds number, overall equivalence ratio and nozzle-to-plate distance have significant influence on the overall pollutants emission of the impinging swirling and non-swirling IDFs and the comparison shows that the swirling IDF emits less NO_x and CO under most of the experimental conditions tested. Furthermore, it is found that compared with the open flames, the impinging flames emit lower level of NO_x and higher level of CO.     

Study on the NOx release rule along the boiler during pulverized coal combustion

Numerical simulation and experimental study on NO _x release along the boiler during pulverized coal combustion have been conducted. With the increase of temperature the NO _x emission increased and the peak value of NO _x release moved forward. But when the temperature increased to a certain degree, NO _x emission began to reduce. NO _x emission increased with the increase of nitrogen content of coal. The peak value of NO _x release moved backwards with the increase of coal rank. NO _x emission increased obviously with the increase of stoichiometric ratio. There existed a critical average diameter of the pulverized coal (d _c ). If d ⩽ d _c , NO _x emission reduced with the decrease of pulverized coal size. If d > d _c , NO _x emission reduced with the increase of the pulverized coal size. The results showed that the simulation results are in agreement with the experimental results for concentration distribution of NO _x along the axis of the furnace. Translated from Proceeding of the CSEE, 2006, 26(1): 35–39 [译自: 中国电机工程学报]