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1.
Formation of mesoglobules in aqueous media from thermo-sensitive poly(ethoxytriethyleneglycol acrylate) 总被引:1,自引:1,他引:0
Natalia Toncheva-Moncheva Philip Dimitrov Christo B. Tsvetanov Barbara Robak Barbara Trzebicka Andrzej Dworak Stanislav Rangelov 《Polymer Bulletin》2011,67(7):1335-1346
A series of six poly(ethoxytriethyleneglycol acrylate) (PETEGA) homopolymers were synthesized by atom transfer radical polymerization,
reversible addition-fragmentation transfer polymerization, and anionic polymerization in order to cover a molecular weight
range from 7,000 to 40,000 Da. The polymers exhibited a lower critical solution temperature (LCST) behavior in water, which
was observed by the occurrence of a cloud point (CP) at around 35 °C. The transmittance of visible light versus temperature
dependence overlapped during the cooling and the heating cycles, showing almost a complete lack of hysteresis. Moreover, instead
of the occurrence of an uncontrolled macroscopic phase separation, stable colloidal aggregates (mesoglobules) of narrow distribution
in particle size were formed in water at temperatures above the LCST of PETEGA at 1 g L−1 solutions. The dimensions of the mesoglobules ranged from 91 to 235 nm, and particle size was not influenced by the molecular
weight of PETEGA. Temperature changes caused considerable variations of the mesoglobules dimensions, which were smaller at
higher temperatures. The addition of an anionic surfactant simultaneously increased the CP values by 4–6 °C and lowered the
dimensions of the mesoglobules. 相似文献
2.
Gui-Jun Zhang Zhong-Hua Chen Xing-Rong Zeng Fei Yu Jin Wang 《Journal of Coatings Technology and Research》2011,8(4):505-511
The poly(methyl methacrylate–n-butyl acrylate)/nano-antimony-doped tin oxide (ATO) hybrid latices were prepared successfully via miniemulsion polymerization
in the presence of emulsifier sodium dodecyl sulfate (SDS) and costabilizer hexadecane (HD). Several factors affecting the
encapsulation efficiency of nano-ATO were studied. The prepared hybrid latices were characterized using transmission electron
microscopy, dynamic light scattering particle size analysis, thermogravimetric analysis, and ultraviolet–visible-near infrared
(NIR) spectra. The results show that the encapsulation efficiency of nano-ATO reaches the maximum value of 78.0% with 3 wt%
of nano-ATO, 4 wt% of SDS, and 4 wt% of HD, and the mean diameter of hybrid latex particles is 87.5 nm. Both the weight loss
ratio and the transmittance in NIR region of hybrid film decrease with the increasing nano-ATO amount. The prepared hybrid
film containing nano-ATO exhibits excellent ability for shielding IR light with high transmittance in visible region, which
can be used as transparent a heat-insulating coating for energy savings. 相似文献
3.
Jian-Wen Jiang Xue-Liang Pei Shou-Ri Sheng Xiao-Yan Wu Xiao-Ling Liu Cai-Sheng Song 《Polymer Bulletin》2011,67(2):263-274
A series of new fluorine-containing polyamides were prepared directly by polycondensation of 2-(4-trifluoromethylphenoxy)terephthalic
acid with four trifluoromethyl-substituted aromatic bis(ether amine)s in N-methyl-2-pyrrolidone (NMP) solution containing dissolved calcium chloride using triphenyl phosphite and pyridine as condensing
agents. All the polymers showed excellent solubility in solvents such as NMP, N,N-dimethylacetamide, N,N-dimethylformamide, dimethyl sulfoxide, pyridine, tetrahydrofuran, and acetone at room temperature. These polymers had inherent
viscosities between 0.67 and 1.09 dL/g, and their weight-average molecular weights and number-average molecular weights were
in the range of 48,200–68,000 and 29,500–39,400, respectively. The resulting polymers showed glass-transition temperatures
between 189 and 214 °C and 10% weight loss temperatures ranging from 475 to 483 °C, and char yields at 800 °C higher than
50% in nitrogen. All polymers were amorphous and could be cast into transparent, flexible, and strong films from DMAc solutions
with tensile strengths of 71–115 MPa, elongations at break of 6–9%, and tensile moduli of 2.7–3.2 GPa. These polymers had
low dielectric constants of 3.14–3.31 (1 MHz), low moisture absorption in the range of 0.88–1.60%, and high transparency with
an ultraviolet–visible absorption cut-off wavelength in the 320–340 nm range. 相似文献
4.
A novel potassium humate–acrylic acid–acrylamide (KHA–AA–AM) superabsorbent polymer was prepared from the reaction among leonardite
potassium humate, acrylic acid and acrylamide by free radical initiating process using ammonium persulfate as the initiator
and N, N′-methylene bisacrylamide as the crosslinker. Various effects of synthesis conditions on superabsorbent polymer were
studied and the optimal reaction condition was obtained with crosslinker concentration 0.44–0.74 wt%, initiator concentration
1.12–2.22 wt%, n(KOH)/n(AA) 0.51–0.70, monomer concentration 10.95–12.59 wt%, graft reaction temperature 83 ± 1°C, monomer
mole ratio of acrylic acid to acrylamide 1.42–2.30, and potassium humate content 17.54 wt%. Under the optimal conditions,
the solution absorbency of KHA–AA–AM superabsorbent polymer to deionized water, tap water, 0.5% carbamide solution and 0.9%
NaCl solution were 733–756, 161–284, 786–825, and 76–83 g/g, respectively. 相似文献
5.
Jingxia Wang Xiaodong Fan Wei Tian Yanli Wang Juanli Li 《Journal of Polymer Research》2011,18(6):2133-2139
Ring-opening polymerizations of γ-glycidoxypropyltrimethoxysilane (GPTMS) were carried out by using multi-metal cyanide (MMC) catalyst and the synthesized
homopolymer was a comb-shaped polymer with regular structure. The structure of the polymer obtained (P-GPTMS) was characterized
by FTIR, 1H-NMR, and 29Si-NMR spectroscopy, and the molecular weight and its distribution were analyzed by size-exclusion chromatography with multi-angle
laser light scattering (SEC-MALLS). The thermal behavior of P-GPTMS was investigated by differential scanning calorimetry
(DSC) and thermogravimetric analysis (TGA). P-GPTMS with high molecular weight (M
n = 18,000–80,000) and narrow molecular weight distribution (1.10–1.35) were synthesized when the dosage of MMC catalyst was
0.1% and polymerization temperature was 130 °C. The molecular weight of the product could be adjusted by controlling the polymerization
time. The T
g of P-GPTMS is in the range of −34 to −30 °C. On the basis of the TGA data, the decomposition rate of P-GPTMS reached its
peak at 374.14 °C and the entire decomposition stopped at 600 °C. 相似文献
6.
Gang Zhang Guang-shun Huang Xiao-jun Wang Sheng-ru Long Jie Yang 《Journal of Polymer Research》2011,18(6):1261-1268
Two kinds of aromatic dibenzoyl chloride monomer containing thioether unit 4,4′-Bis(4-chloroformylphenylthio)benzophenone
(BP-DC) and 4,4′-thiodibenzoyl chloride (T-DC) were synthesized with two steps, which was reacted with diamine monomer containing
thioether and amide unit to prepare a new kind of polyamide containing high quantity thio-ether group. The intrinsic viscosity
of the polyamides was 0.76–0.90 dl/g obtained with optimum synthesis conditions. The polymers were found to have good optical
properties: the optical transmittance of the aromatic polyamide film at 450 nm is higher than 80%, meantime the high quantity
thio-ether unit provided the polymer with a high refractive index ranging from 1.691 to 1.696 and low birefringence of 0.007–0.008.
At the same time the polymers had excellent thermal performance with glass transition temperature (Tg) of 226 °C–278 °C, initial degradation temperature (Td) of 427 °C–439 °C. They showed improved solubility in polar aprotic solvents. 相似文献
7.
Víctor M. Ovando-Medina Piedad S. Pi?a-García Miguel A. Corona-Rivera Paola E. Díaz-Flores René D. Peralta Hugo Martínez-Gutiérrez Tania E. Lara-Ceniceros 《Polymer Bulletin》2012,68(9):2313-2322
Semicontinuous heterophase polymerization was used to copolymerize methyl methacrylate (MMA) with reactive surfactant HITENOL
BC10 (HBC10) at 60 °C using sodium dodecyl sulfate as pre-stabilizing agent and potassium persulfate as initiator. The mixture
of MMA and HBC10 was added at constant rate in continuous mode varying the MMA/HBC10 ratio. High-polymerization rates were
observed, decreasing as the MMA/HBC10 ratio decreased. Latexes with polymer content near 20% and polymer to surfactant (P/S)
weight ratios between 5 and 15 were obtained. Particle sizes distribution were bimodal in all cases with a tendency to be
monomodal as HBC10 concentration increased which was ascribed to enhanced particle stabilization by the presence of HBC10.
The average particle diameters at the end of polymerizations for the first and second populations were around 10 and 50 nm,
respectively. Very high average molecular weights were observed (1.4 × 106 ≤ M
w
≤ 2.1 × 106 g/mol), which decreased when HBC10 concentration increased. The corresponding polydispersity indexes (M
w
/M
n
) were in the range of 1.45–2.24. 相似文献
8.
Colorless and transparent polymers with high refractive indices and high temperature resistance have aroused great interest
in the industrial community. Here, a series of polyimides (PIs) were prepared from a newly synthesized thioether-containing
dianhydride, 1,4-bis(3,4-dicarboxy-phenylenesulfanyl)-benzene dianhydride, and various diamines by a two-step polycondensation
reaction. Some flexible and tough films were obtained by casting solutions of them in poly(amic acid) (PAA). The tensile strengths
and elongations at break of these PI films were greater than 58 MPa and 10%, respectively. All of them were thermally stable
up to 500 °C in both air and nitrogen. Their glass transition temperatures were in the range from 204.5 to 265.8 °C. PI films
with a thickness of 10–20 μm showed good optical transparency in the visible light region. Their cutoff wavelengths were lower
than 400 nm and their transmittance was higher than 80% at 460 nm. The thioether linkages in the PIs endowed them with high
average refractive indices (n
AV) of 1.68–1.74 and low birefringence values (Δn) of 0.0085–0.0120. 相似文献
9.
This paper presents an experimental study on the influence of anionic surfactant sodium dodecyl sulfate (SDS), pH, substrate
finishing and annealing temperature on the corrosion resistance of electroless nickel phosphorus (Ni–P) coatings using electrochemical
techniques and optimization of process parameters based on the Taguchi method. Parameters were selected in three levels and
L9 from orthogonal robust array design was used. Corrosion performance of the electroless Ni–P coatings was evaluated by polarization
and electrochemical impedance spectroscopy (EIS). Scanning electron microscope (SEM), Energy dispersive X-ray spectroscopy
(EDS) and X-ray diffraction (XRD) analysis were used for studying surface morphology and chemical composition of the electroless
Ni–P coatings. The results showed that SDS surfactant causes increasing of corrosion resistance and improves surface morphology.
Finally, optimum conditions were achieved as, surfactant concentration: 1.5 g L−1, pH: 5.5, substrate finishing provided with emery paper no, 2000, and annealing temperature of 200 °C. 相似文献
10.
Jie Shen Ying Zhang Mingfu Huang Wenhao Wang Zushun Xu Kelvin W. K. Yeung Changfeng Yi Ming Xu 《Journal of Polymer Research》2012,19(5):9857
Novel reactive polyimides (PIs) containing phenolic hydroxyl functionalities were prepared from 4-(4-hydroxyphenyl)-2,6-bis[3-(4-aminophenoxy)phenyl]pyridine
(m,p-HAPP) with various aromatic dianhydrides via one-step polycondensation procedure. The inherent viscosities of the PIs were
0.54–0.63 dL/g in DMF solution and most of them were readily soluble in common organic solvents such as DMF, DMAc, NMP, and
m-Cresol, etc. Meanwhile, the PIs also had good thermal stability, with the glass transition temperature (T
g) of 221.7–310.5 °C, the temperature at 10 % weight loss of 524.1–579.3 °C in nitrogen atmosphere. Then commercial epoxy resin
was cured in the presence of different ratios of the reactive polyimide, giving a series of polyimide modified epoxy films.
Thermogravimetric analysis showed the increase of the temperature at 5 % weight loss of the films with the increase of the
polyimide content; 296 °C for 0 %, 309 °C for 1.95 %, 337 °C for 3.85 % and 350 °C for 5.63 %. 相似文献
11.
Hydrophobically modified polyacrylamide (HMPAM), with a molecular weight of 104 g/mol, was studied using a range of rheological methods and dynamic light scattering (DLS). DLS measurements indicate that the association of the modified polymer begins at low concentration. The modified polymer with high substitution forms transient networks below the critical concentration, but the networks are disrupted by the micelles formed by the polymer itself, and the networks do not contribute to viscosity enhancement. The modified polymers exhibited surface activity, and so they may be regarded as nonionic polymeric surfactants rather than thickeners. On the other hand, HMPAM is shown to interact with the surfactant SDS while PAM is inert to SDS. In the hydrophobic domains, it undergoes a surfactant‐induced association process; in the hydrophobe‐surfactant transition regions, the surfactant binds to the polymer in a noncooperative way and forms a polymer–surfactant complex. Contracted polymer chains begin to extend because of electrostatic repulsion, which can overcome the association at surfactant domains. The conformation of HMPAM polymer chains could be controlled by adding a specific amount of surfactant. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4348–4360, 2006 相似文献
12.
Siddhartha G. V. A. O. Costa Sandro R. de Souza Marcia Nitschke Sandra Mara M. Franchetti Miguel Jafelicci Jr Roberta B. Lovaglio Jonas Contiero 《Journal of surfactants and detergents》2009,12(2):125-130
The wetting behavior of rhamnolipids produced by Pseudomonas aeruginosa LBI strain grown on waste oil substrate and sodium dodecyl sulfate (SDS) on glass, polyethylene terephthalate (PET), poly(vinyl
chloride) (PVC), poly(ε-caprolactone) (PCL) and polymer blend (PVC–PCL) was investigated by the measuring contact angle of
sessile drops, to determine the wetting characteristics of rhamnolipids. The comparison of the wetting profiles showed that
at low SDS and rhamnolipid concentrations, the contact angle increased and when the concentration of the surfactant increased
further, the contact angle decreased. The blend surface (PVC–PCL) showed better wettability than the homopolymers themselves
and the blend changed the surface hydrophobicity of the polymer, making it more hydrophilic. The rhamnolipids produced by
the LBI strain exhibited superior wetting abilities than the chemical surfactant SDS one. This is the first work that evaluates
the wetting properties of rhamnolipids on polymer blends.
相似文献
Jonas ContieroEmail: |
13.
A. Farzaneh M. Ehteshamzadeh M. Ghorbani J. Vazifeh Mehrabani 《Journal of Coatings Technology and Research》2010,7(5):547-555
In this research, the influence of anionic surfactant sodium dodecyl sulfate (SDS), pH, substrate finishing, and annealing
temperature on the surface morphology and hardness of the electroless nickel phosphorus (ENi–P) coatings were studied. Taguchi’s
experimental design method was used. Parameters selected in three levels and L9 from orthogonal robust array design were employed.
Surface roughnesses of the deposits were measured using a stylus instrument. Scanning electron microscope and x-ray diffraction
analysis were implemented to study surface morphologies and phase composition, respectively. Microhardness of the ENi–P deposits
was measured using a microhardness tester at three trials per sample. The results showed that addition of the SDS increases
the microhardness and improves surface morphology. Finally, optimum condition was achieved as, surfactant concentration equal
to 1.5 g/L, pH 5.5, substrate finishing provided with emery paper no. 2000, and annealing temperature equal to 400°C. 相似文献
14.
Zheng-gang Cui Hong-xing Song Jun-jie Yu Jian-zhong Jiang Feng Wang 《Journal of surfactants and detergents》2011,14(3):317-324
Alkali-surfactant-polymer (ASP) flooding has been considered to be one of the useful tertiary oil recovery techniques. However,
field tests in China have revealed that serious side effects may occur due to using alkali. Thus alkali-free SP flooding is
more favorable in China. Unfortunately, surfactants effective in ASP flooding are usually ineffective in the absence of alkali
and new surfactants need to be designed. In this paper N-(3-Oxapropanoxyl)dodecanamide as a pure compound and a mixture of homologues with narrow EO number distribution, synthesized
by the reaction of lauroyl chloride with diglycolamine and addition of one ethylene oxide to coconut monoethanolamide respectively,
are examined for their adaptability in SP flooding. It is found that, when mixed with betaines, both products can reduce Daqing
crude oil/connate water interfacial tension to a magnitude of 10−3–10−4 mNm−1 at 45 °C in a wide surfactant concentration range, 0.01–0.5 wt%, and oil displacement tests using natural cores indicates
that a tertiary oil recovery of 18.6 ± 0.4% OOIP can be achieved by SP flooding with the N-(3-Oxapropanoxyl)dodecanamide as the main surfactant without adding any alkaline agent and neutral electrolyte. N-(3-Oxapropanoxyl)dodecanamide, as a nonionic surfactant without a cloud point and producible industrially from renewable
materials, is an ideal surfactant for SP flooding in the absence of an alkaline agent. 相似文献
15.
A. S. Patil M. M. Sayyed N. S. Bhairamadgi S. H. Han N. N. Maldar 《Polymer Bulletin》2011,66(9):1207-1218
New aromatic diamine containing preformed amide, ether, and methylene; bis-[(4′-aminobenzyl)-4-benzamide] ether (BABE), was
synthesized and characterized by FT-IR, NMR, and mass spectrometry. Aromatic–aliphatic polyamides were prepared from BABE
with aliphatic/aromatic diacids via Yamazaki’s polymerization. The polyamides were characterized by FT-IR, 1H NMR, inherent viscosity [ηinh], solubility tests, differential scanning calorimetry [DSC], thermogravimetric analysis [TGA], and X-ray diffraction [XRD].
Polyamides had inherent viscosities 0.35–0.84 dL/g, soluble in aprotic polar solvents like N-methyl-2-pyrrolidone, N, N-dimethyl acetamide and dimethyl sulphoxide containing LiCl due to an amorphous to partially crystalline morphology; as XRD
patterns indicated. DSC analysis of polyamides showed glass transition temperatures 166–268 °C. Polyamides showed high thermal
stability as they did not degrade below 300 °C, had 10% weight loss temperature higher than 375 °C, and the char yields at
900 °C were 22–55%; indicating potential applications as engineering materials. 相似文献
16.
?smet Kaya 《Journal of Inorganic and Organometallic Polymers and Materials》2010,20(2):369-379
Oxidative polycondensation reaction conditions of [(2-mercaptophenyl)iminomethyl]-2-naphthol (2-MPIM-2N) were studied using
oxidants such as air and NaOCl in an aqueous alkaline medium between 40 °C and 90 °C. The structure of poly-[(2-mercaptophenyl)iminomethyl]-2-naphthol
(P-2-MPIM-2N) was characterized by 1H- 13C NMR, FT-IR, and UV–Vis spectroscopy, size exclusion chromatography (SEC), and elemental analysis. At optimum reaction conditions,
the yield of P-2-MPIM-2N was found to be 78 and 82% for air and NaOCl oxidants, respectively. From SEC measurements, the number-average
molecular weight (M
n
), weight-average molecular weight (M
w
) and polydispersity index (PDI) of P-2-MPIM-2N are 2900, 3500 g mol−1 and 1.207; 2200, 2500 g mol−1 and 1.136, for air and NaOCl oxidants, respectively. Polymer–metal complexes were synthesized by the reaction of P-2-MPIM-2N
with Co2+, Cu2+, Zn2+, Pb2+ and Cd2+ ions. The highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO), and electrochemical
band gaps (E¢g E^{\prime}_{g} ) of 2-MPIM-2N and P-2-MPIM-2N were −5.97, −2.66 and 3.31 eV and −5.82, −2.68 and 3.14 eV, respectively. The conductivity
of polymer and polymer–metal complexes were determined in the solid state. Conductivity measurements of doped and undoped
Schiff base polymer and polymer–metal complexes were carried out at room temperature and atmospheric pressure by the four-point
probe technique using an electrometer. The conductivities of the polymer and polymer–metal complexes increased when iodine
was used as doping agent. 相似文献
17.
Novel surfactants for ultralow interfacial tension in a wide range of surfactant concentration and temperature 总被引:2,自引:0,他引:2
Mohamed Aoudia Mohamed Nasser Al-Shibli Liali Hamed Al-Kasimi Rashid Al-Maamari Ali Al-bemani 《Journal of surfactants and detergents》2006,9(3):287-293
This work investigates the possibility of injecting dilute aqueous solutions of novel surfactants into the Yibal field (Sultanate
of Oman). This was accomplished through an experimental protocol based on the following criteria: (i) compatibility of the
surfactants with the high-saline reservoir water (∼200 g/L); (ii) low interfacial tension (IFT) between crude oil and reservoir
water (less than 10−2 mN m−1); and (iii) maintaining the low IFT behaviour during the entire surfactant flooding. Novel surfactants selected in this study
consist of a series of ether sulfonates (AES-205, AES-128, AES-506, and 7–58) and an amphoteric surfactant (6–105). These
surfactants were found to be compatible with reservoir water up to 0.1% surfactant concentration, whereas 6–105 and 7–58 showed
compatibility within the full range of surfactant concentration investigated (0.001–0.5%). All surfactant systems displayed
dynamic IFT behavior, in which ultralow transient minima were observed in the range 10−4–10−3 mN m−1, followed by an increase in the IFT to equilibrium values in the range 10−3–10−1 mN m−1. The results also showed that with respect to concentration (0.05–0.5%) and temperature (45–80°C), AES-205 and 7–58 surfactants
exhibit a wide range of applicability, with the IFT remaining below 10−2 mN m−1, as required for substantial residual oil recovery. In addition, ultralow IFT were obtained at surfactant concentrations
as low as 0.001%, making the use of these surfactants in enhanced oil recovery extremely cost-effective. 相似文献
18.
Furfuryl alcohol (FA) was polymerized in aqueous solutions consisting of polyvinyl pyrrolidone (PVP) as a surfactant together
with hydrochloric acid, phosphoric acid, or acetic acid as a catalyst, respectively. The polymerization degree of FA and the
resulting structural difference after carbonization were examined. Experiments revealed that the presence of acids does indeed
promote polymerization of FA, leading to a reduced defect population and an eventual formation of a more ordered structure
in the carbonized products. This is particularly pronounced when hydrochloric acid was used as a catalyzer, forming “nonstick”
polyfurfuryl alcohol (PFA) particles with a diameter ca. 0.5–1 μm. The polymeric particles were then converted into microporous
carbon spheres with a specific surface area of 297 m2/g when calcined at 600 °C in argon atmosphere. On the contrary, FA in the rest of catalyst systems showed aggregated form
with a pronouncedly reduced specific surface area ranging from 0.3 to 5.2 m2/g. 相似文献
19.
Marioara Nechifor 《Journal of Polymer Research》2011,18(6):2477-2485
A dicarboxylic acid bearing two cinnamic acids units linked in their para positions by a methylene bridge was synthesized by the reaction of 4,4′-methylene-bis(benzaldehyde) and malonic acid, characterized
by spectral and elemental analysis and used to prepare a series of novel photocrosslinkable aromatic polyamides through its
reaction with various ether-bridged aromatic diamines. 1H and 13C NMR, IR and UV spectroscopy confirmed the structure of the monomer and photopolymers. The resulting polymers with inherent
viscosities of 0.65–1.14 dL/g were soluble in polar aprotic solvents, such as DMF, DMSO, DMAc and NMP, and showed good film-forming
properties. Their weight-average and number-average molecular weights, determined by GPC (polystyrene standard), were in the
range 57,400–84,300 and 24,000–40,900, respectively. The percent of water absorbed at 65% relative humidity varied between
1.57% and 2.35%. The polyamides exhibited glass transition temperatures between 202 and 239 °C, and they were stable up to
a temperature of 350 °C in air. Wide-angle X-ray scattering diagrams did not show any crystalline reflection and no endothermic
peak attributable to polymer melting was observed in DSC curves of the polymers. These photosensitive polymers exhibited strong
UV absorption maxima both in solution and film state, and displayed three photochemical transformations under the UV exposure,
viz. a trans-cis isomerization, favored in the early stage of UV irradiation, a bimolecular cyclodimerization, leading to the generation of
a cyclobutane ring, and a photo-Fries rearrangement evidenced only in polymer solutions. 相似文献
20.
Synthesis and characterization of poly(aryl ether ketone)s with fluorinated phenyl in the side chain
New bisphenol monomers, (4-fluorophenyl)hydroquinone (3b) and (3,4-difluoro phenyl)hydroquinone (3c), were synthesized in a two-step synthesis. Poly(aryl ether ketone)s (PAEKs) (4a–c) were derived from these fluorinated bisphenols and nonfluorinated bisphenol—phenylhydroquinone (3a) with 4,4′-diflourobenzophenone via a nucleophilic aromatic substitution polycondensation. The obtained polymers had inherent
viscosities of 0.50–0.92 dL/g. Thermal analysis showed that the obtained PAEKs had excellent thermal properties, the glass
transition temperatures ranged from 148 to 160 °C, and the temperatures at 5% weight loss (Td5) were above 527 °C and the temperatures at 10% weight loss (Td10) were above 544 °C in nitrogen. All the polymers showed excellent solubility and could dissolve in common organic solvents,
such as DMSO, NMP, DMF, etc. So the films of them were easily cast from their solutions, which possessed good mechanical properties,
with tensile strengths of 95.2–104.0 MPa, Young’s moduli of 2.68–3.06 GPa, and elongation at break of 15–32%. Furthermore,
the prepared PAEKs displayed low dielectric constants (2.75–2.95 at 1 MHz) and hydrophobic character (contact angles for water:
83.9o–98.4o). 相似文献