Temperature evaluation of the Bugok geothermal system, South Korea

Using a variety of chemical geothermometers and statistical analysis, we estimate the temperature of a possible deeper geothermal reservoir at Bugok, Southern Korea. Shallow thermal aquifers (down to about 400 m depth) are under exploitation in this area; the temperatures (up to 78 °C) of the produced fluids are the highest found in South Korea. Based on hydrochemical data and occurrence, the groundwaters at Bugok can be classified under three groups: Na-SO₄ thermal groundwaters (CTGW) occurring in the central (about 0.24 km²) part of the area; Ca-HCO₃ cold groundwater (SCGW) found in shallow peripheral parts of the CTGW; the intermediate-type groundwater (STGW). The CTGW type is typical of the Bugok thermal waters; they have the highest discharge temperatures and contain very high concentrations of Na (75.1–101.0 mg/L), K (2.9–6.9 mg/L) and SiO₂ (62.0–84.5 mg/L) and are rich in sulfates.The major ion composition of the CTGW suggests that these waters are in partial equilibrium with rocks at depth. The application of various alkali-ion geothermometers yields temperature estimates in the 88–198 °C range for the thermal reservoir. Multiple-mineral equilibrium calculations indicate a similar but narrower temperature range (from about 100 to 155 °C). These estimates for CTGW are significantly higher than the measured discharge temperatures. Considering the heat losses occurring during the ascent of the waters, one can infer the presence of a deeper (around 1.8 km) thermal reservoir in the Bugok area that could be developed for district heating or other direct applications of geothermal heat.     

New geothermometers for carbonate—evaporite geothermal reservoirs

Two new Ca/Mg and SO₄/F geothermometers specific for carbonate-evaporite geothermal reservoirs are proposed. General considerations on waters interacting with such rocks suggest that Ca²⁺, Mg²⁺, CO²⁻₃, SO²⁻₄, F⁻ and SiO₂ are compatible components of the pertinent thermodynamic system and, therefore, their activities are fixed by five solid phases at equilibrium conditions. Geothermometric elaboration is based on the assumption that the five solid phases are represented by pure calcite, dolomite, anhydrite, fluorite and an SiO₂ mineral, e.g. quartz or chalcedony or amorphous silica. Pressure and ion association effects are not taken into consideration. Preliminary applications both to thermal waters and geothermal wells are promising. These new geothermometers could be widely used in the geothermal exploration of areas with carbonate-evaporite reservoirs, such as the two main geothermal fields of Italy, Larderello and Mt. Amiata. Further calibration by experimental studies and additional data from geothermal boreholes is needed, however, to test the practical reliability of the new geothermometers.     

Sodium/lithium ratio in water applied to geothermometry of geothermal reservoirs

We propose here a new geothermometer for natural waters. Analyses from many explored geothermal fields allow us to define two empirical thermometric relationships.One is for waters of low to moderate salinity (Cl⁻< 0·3 M) log Na/Li = 1000/T −0·38 and one for marine waters and brines (Cl⁻ > 0·3 M) log Na/Li = 1195/T + 0·38 These relationships, which at present are not well understood, result mainly from the increase of Li concentrations in waters with temperature.Equation (a) proved to be adequate for spring waters from mostly known geologic origin; this is an important feature in geochemical surveys for geothermal prospecting.Furthermore, when comparison between springs and drillhole chemistry of a given geothermal field is possible, the Na/Li geothermometer gives more reliable temperature estimates from the spring compositions than do classical geothermometers.     

Revision,calibration, and application of the volume method to evaluate the geothermal potential of some recent volcanic areas of Latium,Italy

The volume method is used to evaluate the productive potential of unexploited and minimally exploited geothermal fields. The distribution of P_CO2 in shallow groundwaters delimits the geothermal fields. This approach is substantiated by the good correspondence between zones of high CO₂ flux, and the areal extension of explored geothermal systems of high enthalpy (Monte Amiata and Latera), medium enthalpy (Torre Alfina) and low enthalpy (Viterbo). Based on the data available for geothermal fields either under exploitation or investigated by long-term production tests, a specific productivity of 40 t h⁻¹ km⁻³ is assumed. The total potential productivity for the recent volcanic areas of Latium is about 28 × 10³ t h⁻¹, with 75% from low-enthalpy geothermal fields, 17% from medium-enthalpy systems, and 8% from high-enthalpy reservoirs. The total extractable thermal power is estimated to be 2220–2920 MW, 49–53% from low-enthalpy geothermal fields, 28–32% from medium-enthalpy systems, and 19–20% from high-enthalpy reservoirs.     

Hot spring activity in the Dakongbeng geothermal area, China

The Dakongbeng geothermal area, whose hot springs reach a temperature of up to 96°C, has been considered one of the potential high-temperature hydrothermal systems in south-west China. The concentration of dominant cations and anions indicates an NaHCO₃ type of thermal water, whose major constituents in decreasing order are: Na>K>Ca>Mg, HCO₃>SiO₂>Cl>SO₄. On the basis of the silica geothermometer, cation geothermometers, gas geothermometer and activity diagram, the reservoir temperature is estimated at about 200°C. All the thermal waters have originated from meteoric water of a higher altitude that circulated as ground water at considerable depth along faults. The stability of their contents of Cl, SiO₂, δD, δ¹⁸O and of the Cl/B, Na/Li ratios suggests that the main heat loss process is through steam loss. The geochemistry of the initial liquid has been estimated by single and continuous steam loss. On the basis of its geologic and geographic setting, the Dakongbeng geothermal area appears to belong to the Himalayan geothermal belt and is thus regarded as an area of interest for further study.     

CO2 distribution in the atmosphere and noise survey after blow-out in alfina 1 well, Northern Latium, Italy

A water-dominated geothermal reservoir, with a gas cap (mainly CO₂) on the reservoir roof, was individualed in Torre Alfina zone, northern Latium, about 30 km south-east of Monte Amiata.The first exploratory well (Alfina 1), drilled in 1973, blew-out spontaneously so that no production casing could be inserted.After well shut-in several surface gas manifestations appeared which were considered of some risk to the environment.This paper describes the methods used to determine the degree of pollution and the total area involved.The study of the gas dispersion in the atmosphere, the noise resulting from production, and the meteorological conditions in the area, was used in drawing up a disposal plant project; this plant will be assembled on future wells as a safety measure where large quantities of fluids are involved.     

Chemical and isotope characteristics of the Chachimbiro geothermal fluids (Ecuador)

The parent geothermal water proposed for the Chachimbiro geothermal area has calculated values of 2250 mg/L Cl and approximately 5 bar P_CO2. It comes from a reservoir having an estimated temperature of 225–235 °C, although temperatures somewhat higher than 260 °C may be present at the roots of the system. The geothermal reservoir at Chachimbiro is recharged mainly by meteoric water (about 92%) and secondarily by arc-type magmatic water. Carbon and sulfur isotope data support a magmatic origin for the C and S species entering the geothermal system from below, consistent with indications provided by He isotopes.The thermal springs of Na–Cl to Na–Cl–HCO₃ type located in the Chachimbiro area originate through dilution of the parent geothermal water and have reached different degrees of re-equilibration with country rocks at lower temperatures.     

Geochemistry of the thermal waters of Salbardi and Tatapani, India

Geochemical studies have been carried out on water samples collected from Tatapani and Salbardi hot springs. The waters of these hot springs are classified as NaHCO₃ type. Waters in deep aquifers are associated with quartz, shale and clay terrains. Activity studies of the minerals and the waters present in the aquifers suggest that the thermal waters are within equilibrium with montmorillonite, kaolinite and quartz at about 150°C. The geochemical thermometers also estimate 150 ± 10°C as aquifer temperatures for Tatapani and Salbardi.     

Fluid chemistry and temperatures prior to exploitation at the Las Tres Vírgenes geothermal field,Mexico

Generation of electricity at the Las Tres Vírgenes (LTV) geothermal field, Mexico, began in 2001. There are currently nine geothermal wells in the field, which has an installed electricity generating capacity of 10 MW_e. The chemical and temperature conditions prevailing in the field prior to its exploitation have been estimated, including their central tendency and dispersion parameters. These conditions were computed on the basis of: (i) geochemical data on waters from springs and domestic wells, and on geothermal well fluids (waters and gases); most of the sampling took place between 1995 and 1999; (ii) fluid inclusion studies; (iii) geothermometric data; and (iv) static formation temperatures computed using a modified quadratic regression Horner method.Fluid inclusion homogenization temperatures (in the 100–290 °C range) suggest that there is a high-temperature fluid upflow zone near wells LV3 and LV4 in the southern part of the field. Computed average chemical equilibrium temperatures for the geothermal fluids are ∼260 °C, based on the Na/K and SiO₂ geothermometers, and ∼265 °C, based on the H₂/Ar, and CO₂/Ar geothermometers. In general, the fluid inclusion homogenization temperatures are consistent with geothermometric data, as well as with static formation temperatures. Some of the observed differences could be related to well interference effects and different fluid production/sampling depths. The deeper geothermal waters show higher concentrations of Cl, Na, K, B, Ba, but lower concentrations of SO₄, Ca, and Mg than the shallower waters. Fluid inclusion salinities are also higher in the deeper rocks. The measured Na/Cl ratios of the geothermal well waters are more or less uniform throughout the field and are very similar to that of seawater, strongly suggesting a seawater component in the fluid of the LTV system.The heat stored in the LTV geothermal system was estimated to be at least 9 × 10¹² MJ, of which some 4 × 10¹¹ MJ (equivalent to about 148 MW_e for 30 years of operation, assuming a conversion efficiency of ∼35%) might be extracted using wells. These results indicate that the installed capacity at LTV could be safely increased from the current 10 MW_e.     

Assessment of reservoir temperatures of thermal springs of the northern areas of Pakistan by chemical and isotope geothermometry

Chemical and isotope geothermometers, i.e. the Na–K, K–Mg, quartz and δ¹⁸O(SO₄–H₂O), have been applied to estimate the reservoir temperature of the thermal springs in the northern areas of Pakistan. The chemical types of the thermal waters and the effects of mixing of shallow cold water with the thermal end-members are discussed. These waters are neutral to slightly alkaline and have low dissolved contents. Sodium is the dominant cation in almost all the cases. In terms of anions, the hot waters of Budelas are of the SO₄ type, those of Tatta Pani are of mixed character (SO₄ and HCO₃), and the waters from the remaining areas show HCO₃ domination. An absence of tritium in Tatta Pani and Tato thermal springs indicates that they do not have any contribution of shallow young water. In the case of the Murtazabad springs, the wide range of tritium concentrations, negative correlations with surface temperature and Cl, and positive correlation between Na and Cl show that the shallow cold groundwater is mixing with thermal water in different proportions. For the mixed water of Murtazabad thermal springs, ‘isochemical modelling’ using the Na–K, K–Mg and quartz geothermometers indicates an equilibrium temperature in the range 185–200 °C. The δ¹⁸O(SO₄–H₂O) geothermometer gives relatively low temperatures for three springs, whereas two samples are close to the 185–200 °C temperature interval. The reservoir temperatures of Tatta Pani springs (100–120 °C), determined by Na–K and quartz geothermometers, are in good agreement. The δ¹⁸O(SO₄–H₂O) geothermometer gives a relatively higher range (140–150 °C) for most of the Tatta Pani springs. For Tato spring, the isotope and chemical geothermometers (except for the K–Mg) agree on an equilibrium temperature of about 170 °C. Reservoir temperatures of the remaining minor fields are not conclusive due to the lack of sufficient data.     

Geochemistry of the surface and deep fluids of the Miravalles volcano geothermal system (Costa Rica)

The Miravalles high-temperature geothermal reservoir, located in the northwestern part of Costa Rica, is liquid-dominated. Reservoir temperatures generally range between 230 and 240 °C. The highest measured value is 255 °C. Bottom-hole measurements and solute geothermometry indicate that thermal conditions within the reservoir are very stable over time. The waters discharged from the wells have a neutral or slightly alkaline pH and are of the sodium-chloride type. Based on isotope data, the main recharge zone appears to be located on the northeastern side of the Guanacaste Cordillera. Several mixing trends have been identified between reservoir fluids and regional groundwaters. Gas discharges are dominated by CO₂, with minor amounts of H₂S and N₂. Relative N₂, Ar and He contents reveal a typical arc-type signature and significant inflow of meteoric-derived gases. Cl–SiO₂-enthalpy and δ¹⁸O–δ²H–Cl relationships suggest the existence of a maturation trend that is the result of both natural (i.e. direct drainage of deeper fluids) and anthropogenic causes (reinjection of Cl-rich waste waters). Acid fluids with SO₄-acidity (pH ranging between 2.4 and 3.7) have been encountered in three wells at the eastern border of the well field. Preliminary data assessment indicates two possible sources, either superficial H₂S oxidation or inflow of “immature” volcanic waters.     

Geochemistry and groundwater contamination in the La Selva geothermal system (Girona, Northeast Spain)

Hot spring waters of the La Selva geothermal system show high concentrations of Cl, F, Ca, Na, K, Li, Si, As, Ba, and Rb, whereas cold waters show low salinity, high concentrations of NO₃, and significant As content when mixed with geothermal waters.Modeling of the geothermal fluids indicates that the fluid is supersaturated with aragonite and calcite, which matches the travertine precipitation close to the present discharge areas. Moreover, the barite and fluorite are also are near equilibrium levels, indicating possible control of Ba and F solubility by these mineral phases, which also precipitate in some discharge areas. Likewise, the fluid is supersaturated with respect to quartz, indicating the possibility of siliceous precipitation near the discharge areas of the present geothermal fluids.Taking into account the Na-K, Na-K-Ca, and SiO₂-temperature geothermometers, the temperature of the reservoir may be estimated to be about 135 °C.The chemistry of the geothermal fluids has changed from a recent high-enthalpy system, which precipitated siliceous deposits, to the present low-enthalpy system, which precipitates carbonated deposits (travertine).Multivariate analysis of the groundwater shows high correlations between K, Ca, As, Br, Ag, and Ba, suggesting that As is introduced to the environment via geothermal fluids. Moreover, As concentrations in hot groundwater are associated with high concentrations of Li and Si, as has been observed in other geothermal fields. Metal concentrations in the hydrothermal deposits show high values of Ag, As, Ba, Pb, Sb, and Zn, mainly in the siliceous deposits of the town of Caldes de Malavella, where the geothermal system deposited materials with high As concentrations (123-441 ppm).The similarities between the geochemical characteristics of the hydrothermal deposits and the groundwater suggest that the metals in these deposits and fluids have the same origin.     

Hydrothermal alteration in the Aluto-Langano geothermal field, Ethiopia

The hydrothermal mineral assemblages found in eight wells (with a depth range of 1320–2500 m) of the active geothermal field of Aluto-Langano (Ethiopia) indicate a complex evolution of water-rock interaction processes. The zone of upflow is characterized by high temperatures (up to 335°C) and the presence of a propylitic alteration (epidote, calcite, quartz and chlorite, as major phases) coexisting with calcite and clay minerals. The zone of lateral outflow is characterized by mixing of deep and shallow waters and the occurrence of a calcite-clay alteration that overprints a previous propylitic assemblage. Clay minerals have a mushroom-shaped zonal distribution consistent with the present thermal structure of the field. Microprobe analyses have been carried out on chlorite and illite in order to apply several geothermometers. Most of the chlorite is iron-rich chlorite. It is found that the temperatures calculated from the chlorite geothermometer (159–292°C) after Cathelineau and Nieva [Contrib. Mineral. Petrol. 91, 235–244 (1985)] are in good agreement with in-hole measured temperatures (155–300°C). In the upflow zone, temperatures calculated from this geothermometer (217–292°C), together with fluid inclusion data of Valori et al. [Eur. J. Mineral. 4, 907–919 (1992)], and computed saturation indices of alteration minerals, indicate thermal stability or slight heating. On the other hand, evidence of a significant cooling process (up to 171°C) in the outflow zone is provided by the comparison between fluid inclusion homogenization temperature (240–326°C) and in-hole temperature (155–250°C). The apparent salinities (0.8–2.3 wt% NaCl eq.) of the fluid inclusions are generally higher than the salinity of the present reservoir fluid (0.29–0.36 wt% NaCl eq.). Clay minerals (illite, smectite, Ill/S mixed layers, vermiculite and chloritic intergrades) generally occur at temperatures consistent with their stability fields.     

A reconnaissance geochemical study of thermal waters of south and central Vietnam

Chemical and isotopic data of thermal springs and wells indicate that some thermal water circuits in central and south Vietnam can reach temperatures of geothermal interest (150–200°C) in zones of normal-to-slightly anomalous thermal gradients. The low gas content and the low CO₂ and H₂S concentrations suggest that there is no contribution from a magmatic source. The geothermometry results indicate that the geothermal resources in south and central Vietnam are of medium enthalpy. These results confirm those of previous geochemical surveys and indicate that the most promising geothermal sites in Vietnam are Le Thuy, south of Dong Hoi and Mo Duc near Quang Nghai.     

Hydrogeological and isotopic survey of geothermal fields in the Buyuk Menderes graben, Turkey

The main high and low enthalpy geothermal fields in the Buyuk Menderes graben (Western Anatolia) and their reservoir temperatures are as follows: Kizildere (242 °C), Germencik (232 °C), Aydin-Ilicabasi (101 °C), Yılmazkoy (142 °C), Salavatli (171 °C), Soke (26 °C), Denizli -Pamukkale (36 °C), Karahayit (59 °C), Golemezli (101 °C) and Yenice (70 °C). The geothermal systems are controlled by active graben faults. The reservoir rocks in the geothermal fields are the limestone and conglomerate units within Neogene sediments and the marble-quartzite units within Paleozoic metamorphic formations. There are clear δ¹⁸O shifts from the Mediterranean Meteoric Water Line (MMWL) in the Kizildere, Germencik and Aydin fields, where a good relation between high temperatures and δ¹⁸O shift has also been observed, indicating deep circulation and water rock interactions. In the Pamukkale, Karahayit, Golemezli and Yenice fields and in Soke region, low temperatures, small isotope shifts, shallow circulations and mixing with shallow cold water have been noted.     

Geochemical approach to the Bou Hadjar hydrothermal system (NE Algeria)

The Bou Hadjar low-temperature hydrothermal system is located in northeast Algeria. The four main thermal springs that are the subject of the study emerge ith temperatures between 32 and 60°C from allochthonous formations. The reservoir temperature has been estimated from chemical compositions by utilizing simultaneously the silica, gas and sulfate-water oxygen isotope geothermometers, fluid-mineral equilibrium calculations, and a mixing model. According to these thermometric methods, the most probable subsurface temperature is in the range 75–106°C. The mixing model suggests a temperature of 125°C for the parent water.     

Isotope geothermometry in the larderello geothermal field

The isotope geothermometers based on the ¹³C/¹²C fractionation between carbon dioxide and methane and on the ¹⁸O/¹⁶O fractionation between carbon dioxide and water vapour have been applied in Larderello geothermal field. The CO₂ - CH₄ thermometer gives temperatures which are 50–200°C higher than those measured at the well head. The distribution of the isotopic temperatures within the field follows more or less similar patterns to those given by the well-head temperatures. They are believed to reflect the temperatures of formation of CO₂ and CH₄.The CO₂ - H₂O thermometer gives the temperature of the geothermal reservoirs tapped, and the difference between the isotopic temperature and the temperature measured at the well head is a measure of the cooling undergone by geothermal fluid on its way up to the surface.     

Evidence for thermal mining in low temperature geothermal areas in Iceland

This study deals with thermal mining in several geothermal systems in Iceland. A number of 2500- to 3000-m deep drillholes have been drilled into low temperature geothermal areas in the country. The conductive gradient outside active geothermal areas has also been mapped, and shows a systematic variation from lower than 50°C/km in the outer parts of the Tertiary basalts to over 100°C/km on the borders of the volcanic zones (rift zones). The difference between formation temperatures inside geothermal systems and the surrounding conductive gradient can be computed as a function of depth. This difference is termed ΔT in this paper. The ΔT-curves show that the upper parts of the geothermal systems are heated and the lower parts are cooled compared to the undisturbed conductive gradient. In many cases the cooling of the lower part is greater than the heating in the upper part, so that a net thermal mining has occurred. This thermal mining is calculated for several geothermal systems, and the systems are compared. The net thermal mining in the top 3000 m appears to be much greater in formations of Pleistocene and Pliocene age. It gradually decreases to zero for formations older than 6 million years. However, the net thermal mining is critically dependent on the maximum depth of water convection in these systems, which is unknown.     

Water chemistry of San Marcos area,Guatemala

Two well-equilibrated NaCl geothermal liquids are recognizable in the San Marcos area. Both have the same Cl concentration (540 mg/kg) and the same isotopic composition (δD of −66.5‰ and δ¹⁸O of −9‰) under reservoir conditions, but they come from two distinct aquifers with different temperatures, i.e. 240°C below La Cimarrona and 185°C below La Castalia. The numerous thermal NaCl to NaClHCO₃ springs located in the San Marcos area originate through dilution and boiling of these two geothermal liquids and different degrees of re-equilibration at lower temperatures. Silica and K contents are useful in discriminating between dilution, boiling and re-equilibration phenomena. Thermal NaHCO₃ waters, generated through conductive heat transfer or input of geothermal vapor or gases from below, delineate the extent of the geothermal reservoir(s) at depth.