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W. HALLER D. H. BLACKBURN F. E. WAGSTAFF R. J. CHARLES 《Journal of the American Ceramic Society》1970,53(1):34-39
Opalescence and clearing techniques were used to determine the metastable immiscibility surface for sodium borosilicate solutions. These results indicate that a three-liquid region, which may or may not be metastable to two-liquid regions, underlies the immiscibility surface. 相似文献
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With the aid of the transient hot‐wire method, the thermal conductivity of molten B2O3, B2O3–SiO2, Na2O–SiO2, and Na2O–B2O3 systems was measured along with their temperature and composition. It was observed that the thermal conductivity of pure B2O3 increased with temperature, until about 1400 K, and then decreased subsequently. Using the MAS‐NMR, 3Q‐MAS, and Raman spectroscopy, the structure of B2O3 and SiO2 in the B2O3–SiO2 system was confirmed. Findings show that an addition of B2O3 into the pure SiO2 system causes a significant decrease in thermal conductivity, due to the formation of boroxol rings. The thermal conductivity of the Na2O–SiO2 system was measured and its phonon mean free path was calculated. In addition, a positive linear relation between viscosity and thermal conductivity was observed. In the Na2O–B2O3 system, it was found that a change in the relative fraction of 4‐coordinated boron has an influence on the thermal conductivity when the concentration of Na2O is between 10 and 30 mol%, in which case the tetraborate unit is dominant. 相似文献
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The vapor composition, partial pressures of the molecular species of the vapor, and activities of the melt components in the Na2O–B2O3–SiO2 system at temperatures of 1300 and 1350 K are studied using the Knudsen effusion mass-spectrometric method. It is shown that the vapor composition depends on the concentration ratio of sodium and boron oxides in the condensed phase. When the content of boron oxide is larger than the content of sodium oxide in the condensed phase, the vapor contains NaBO2, (NaBO2)2, and B2O3 molecules. At the ratio [Na2O] : [B2O3] > 1, the gas phase contains atomic sodium. The activities obtained for NaBO2 and B2O3 indicate substantial negative deviations from an ideal behavior. 相似文献
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R. J. CHARLES 《Journal of the American Ceramic Society》1966,49(2):55-62
A search was made for evidence of metastable phase separation in binary alkali metal oxide-silica glasses which had been subjected to the usual glassmaking procedures of melting, relatively fast cooling, and annealing. Electron microscopy and electrical properties measurements were the principal tools of investigation. Evidence for phase separation in Li2 O and Na2 O silica systems is given together with critical temperature estimates. Although K2 O-SiO2 glasses showed some slight evidences of structural segregation it is concluded that binary K2 O, Rb2 O, and Cs2 O silica glasses generally show simple solution behavior and allow reasonable correlations of properties with cation size, type, and separation. 相似文献
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The structure of glasses of a local area of the Na2O - Fe2O3 -B2O3 - SiO2 system is studied. The sequence of formation of oxygen-containing tetrahedral groups in the presence of nonbridge oxygen
ions is established. Formation of groups of a six-coordinated into cation facilitates crystallization of sodium-boron-silicate
glass melts in cooling.
Translated from Steklo i Keramika, No. 1, pp. 11–13, January, 2000. 相似文献
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Metastable glass-in-glass separation was observed on rapid quenching of A12O3-SiO2 melts containing from 10 to 50 mol% A12O3. Nucleation and subsequent crystallization of mullite within the high-alumina-dispersed glass phase may occur either during cooling from the melt or on reheating. The metastable binary two-liquid region is compositionally defined, and a structural interpretation of the phase separation and the effects of small oxide additions on it is offered. Evidence for both classical and possible spinodal nucleation mechanisms during liquid segregation in this system is presented. 相似文献
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Elien Haccuria Tijl Crivits Peter C. Hayes Evgueni Jak 《Journal of the American Ceramic Society》2016,99(2):691-704
The Al2O3–CaO–SiO2 system provides the basis for describing many important chemical processes. Although the system has previously been extensively studied, recent advances in experimental technique have provided the opportunity to obtain accurate liquidus measurements in the low‐silica region at fixed temperatures. The experimental procedures involve equilibration of high‐purity oxide powder mixtures at selected temperatures, rapid quenching, and accurate measurement of phase compositions using electron probe X‐ray microanalysis. The liquidus isotherms have been determined at selected temperatures between 1503 and 1873 K in the anorthite, gehlenite, pseudowollastonite, corundum, CaAl12O19, CaAl2O6, lime, Ca3SiO3, and Ca2SiO4 primary phase fields. The results are compared with currently available thermodynamic model predictions of the phase chemistry. 相似文献
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Silicon - Glasses of compositions 50.4B2O3 - 30SiO2- $$(19.6-x)$$ Li2O - $$x$$ Fe2O3, $$x$$ = (0 ≤ $$x$$ ≤ 2) were fabricated with molar fraction utilizing the conventional process.... 相似文献
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Glasses within the ternary system Li2O-B2O2SiO2 containing less than 25.6% Li2Ocan be broadly classified into three groups according to their behavior during cooling or heating. One group, containing either more than 18% Li2Oor less than 20% SiO2, yields clear glasses during slow or rapid cooling. The second group, containing approximately 5 to 15% Li2O and 26 to 90% SiO2, yields dense white opal glass during slow or rapid cooling. The third group, located at the outer edge of the second group, cools to room temperature as clear glasses but develops opacity when reheated to temperatures between 550° and 8800°C. It has been shown by electron microscopy that the opacity is due to liquid immiscibility, the matrix glass containing well-formed spheres of the dispersed phase. Some of the clear glasses of both groups have been shown to consist of two immiscible phases. The size of the dispersed units in the spontaneous opal glasses and also the reheat opal glasses can be controlled by the variation of the reheat treatments. The phase separation reported here is beyond the resolution of the petrographic microscope and can be detected only with the high resolution of the electron microscope. Accessory evidence is given to show that the phases are non-crystalline. 相似文献
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通过大量的配方实验,利用OM,TEM和XRD分析,研究了0.20R2O-0.45CaO-0.35ZnO-Al2O3-SiO2系统的分相与析晶,研究结果表明,在Al2O3含量高于0.30-0.45mole的区域可以获得乳浊程度和光泽度各异的析晶乳浊釉,在低铝区可获得分相乳浊和分相玻璃,且乳浊程度随Al2O3含量的降低,SiO2含量的提高而提高,用Na2O取代K2O不利于系统的分相,试样中析出的晶体主要为硅锌矿,锌黄长石,白榴石笔锌铝尖晶石,当R2O全部由K2O引入且Al2O3含量较低时,主要为硅锌矿,白榴石和锌黄长石,Al2O3含量较高时则主要为白榴石,锌黄长石和锌铝尖晶石,用Na2O等摩尔取代K2O炒利于白榴石和硅 矿的析晶,而有利于锌黄长石的析晶,锌黄长石的析晶主要受组成的影响,对析晶保温度不敏感,通过设计合理的配方,采用适当的烧成温芳制度,可以获得结晶良好的析晶乳浊釉,分相乳浊釉,分相玻璃,硅锌矿或锌黄长石分相结晶釉或微晶玻璃。 相似文献
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Sodium borosilicate melts containing 60 mol % SiO2 are investigated in the temperature range T
g–1100°C by the small-angle X-ray scattering (SAXS) technique. The temperature dependences of the SAXS intensity for the studied melts consist of two linear portions. A change in the slope of these portions is observed at temperatures that coincide, to within the accuracy of the SAXS experiment (±5–10 K), with the liquidus temperatures, which are usually determined to approximately identical accuracy. The change in the slope is associated with the change in the temperature coefficients of the isothermal compressibility upon transition from a liquid state to a supercooled liquid state. Similar results were obtained earlier for binary melts in the sodium borate system and a number of other systems. On this basis, it is assumed that the transition from a liquid state to a supercooled liquid state for melts in any glass-forming system can be revealed from the temperature dependences of the SAXS intensity, and the SAXS technique can be used to determine the liquidus temperatures, primarily for glass-forming melts with a low crystallization ability. 相似文献
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借助魔角旋转核磁共振技术,探讨掺Sm2O3后BaO-B2O3-Al2O3-SiO2(BBAS)玻璃(BBASS玻璃)的形成、结构及热处理条件下玻璃结构的变化情况.研究表明:随着稀土掺量的增加,BBASS玻璃的形成区域先扩大后缩小.在Sm2O3外掺摩尔分数为30%时BBASS玻璃具有最大的形成区域.在BBAS玻璃结构中,随着BaO含量的增加,硼氧三角体[BO3]逐渐向[BO4]转变,原先[AlO4],[AlO5],[AlO6]共存的铝氧多面体结构逐渐转变为大量[AlO4]和少量[AlO5]共存的结构.在BBASS玻璃结构中,随着5m2O3掺入量的增加,Sm2O3对铝氧多面体结构变化的影响与BaO类似;对硼氧多面体而言,Sm3 强大的积聚作用使玻璃结构中硼氧多面体形成了巨大的网络.以上差异说明了Al3 比B3 更容易进入稳定的四面体结构.热处理对玻璃结构影响甚微. 相似文献
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选择SiO2-BaO-Fe2O3玻璃体系,采用分步晶化热处理方法制备出了以BaFe12O19为磁性主晶相的无变形硬盘用微晶玻璃,并利用XRD、SEM、VSM等测试手段对微晶玻璃进行了分析和性能检测。研究结果表明:采用分步晶化热处理方法制备的微晶玻璃性能优于传统的一步晶化热处理方法,并且样品在分步晶化热处理过程中不会产生变形。经700℃/5h 850℃/10h分步晶化热处理所制备出的微晶玻璃的主晶相为BaSiO3,BaFe12O19,晶粒尺寸在1.0μm以内,其比饱和磁化强度可达248.89Am2/kg,矫顽力可达142.44kA/m。 相似文献