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 共查询到10条相似文献,搜索用时 62 毫秒
1.
为了研究HA在溶液中的光学非线性特性,通过简并四波混频的实验,利用瞬态光栅技术,分别研究了HA及其弱极性和非极性溶剂的瞬态光栅特性,指出HA的瞬态光栅是一个衰减过渡态TS*的质子转移超快过程,其瞬态光栅的寿命为10.5PS。  相似文献   

2.
HA在纳米分子筛MCM-41中的光谱特性研究   总被引:3,自引:0,他引:3  
详细研究了HA在分子筛MCM-41中的光谱特性,指定其在强激光脉冲激发下产生了双光子吸收,指认长波荧光发射带为激发态质子转移荧光。结果表明只有在强光作用下才发生激发态质子转移。  相似文献   

3.
详细研究了HA(竹红菌甲素)在分子筛MCM-41中的光谱特性。观察到HA在强激光脉冲激发下产生了双光子吸收,指认长波荧光发射带为激发态质子转移荧光。结果表明,只有在强光作用下才会发生激发态质子转移。  相似文献   

4.
Intrinsic characteristics of organic semiconductor-based hole transport materials (HTMs) such as facile synthesizability, energy level tunability, and charge transport capability have been highlighted as crucial factors determining the performances of perovskite photovoltaic (PV) cells. However, their properties in the excited state have not been actively studied, although PVs are operated under solar illumination. Here, the characteristics of organic HTMs in their excited state such as transition dipole moment can be a decisive factor that can improve built-in potential of PVs, consequently enhancing their charge extraction property as well as reducing carrier recombination. Moreover, the aggregation property of organic semiconductors, which has been an essential factor for high-performance organic HTMs to improve their carrier transport property, can induce a synergistic effect with their excited state property for the high-efficiency perovskite PVs. Additionally, it is also confirmed that their optical bandgaps, manipulated to have their absorption in the UV region, are beneficial to block UV light that degrades the quality of perovskite, consequently improving the stability of perovskite PV in p–i–n configuration. As a proof-of-concept, a model system, composed of triarylamine and imidazole-based organic HTMs, is designed, and it is believed that this strategy paves a way toward high-performance and stable perovskite PV devices.  相似文献   

5.
NdYVO_4晶体的偏振激发荧光光谱及其LD泵浦激光特性   总被引:3,自引:0,他引:3  
分别利用π和σ偏振光激发,测量并对比了NdYVO4晶体的非偏振及偏振荧光光谱。研究了LD泵浦NdYVO4激光器的输出特性,当泵浦功率为1900mW时,获得了1012mW的1064nm激光输出,斜效率为53.6%。  相似文献   

6.
脉冲激光辐照金属材料表面瞬态温度场研究   总被引:1,自引:0,他引:1  
建立了脉冲激光辐照金属材料表面的热学模型,通过拉普拉斯变换法求解了热传导方程,得出金属材料在激光辐照下加热和冷却过程瞬态温度场分布的精确解析解.基于Visual C++编程并实现界面化,实现对于具体材料激光辐照下瞬态温度场的预测和分析.并以纯铝的激光熔覆和镁合金的激光熔凝实验为例,验证了瞬态温度场的分布.结果表明,金属材料在一个脉冲时间内温度随激光辐照时间的增加而升高,辐照结束后,表面温度迅速下降,内部温度下降较慢.分析结论与相关实验结果基本吻合,证实了所建模型的合理性.该结论对其它激光表面处理过程具有一定的指导作用.  相似文献   

7.
New emitters that can harvest both singlet and triplet excited states to give 100% internal conversion of charge into light, are required to replace Ir based phosphors in organic light emitting diodes (OLEDs). Molecules that have a charge transfer (CT) excited state can potentially achieve this through the mechanism of thermally activated delayed fluorescence (TADF). Here, it is shown that a D–A charge transfer molecule in the solid state, can emit not only via an intramolecular charge transfer (ICT) excited state, but also from exciplex states, formed between the molecule and the host material. OLEDs based on a previously studied D–A–D molecule in a host TAPC achieves >14% external electroluminescence yield and shows nearly 100% efficient triplet harvesting. In these devices, it is unambiguously established that the triplet states are harvested via TADF, but more interestingly, these results are found to be independent of whether the emitter is the ICT state or the D–A–D/host exciplex.  相似文献   

8.
姜本学  赵志伟  徐军  邓佩珍 《中国激光》2004,31(12):1465-1468
用提拉法生长了掺钕的钆镓石榴石(Nd3+∶GGG)激光晶体,晶体的干涉条纹证明它有良好的光学均匀性,晶体(444)面的双晶摇摆曲线表明晶体的质量非常好。研究了室温下的吸收谱和发射谱性质。分析了Nd3+∶GGG晶体4F3/2→4I11/2能级跃迁与1.06 μm附近的荧光谱线之间的关系。Nd3+∶GGG激光晶体的吸收截面、发射截面、荧光寿命分别为4.32×10-20 cm2,2.3×10-19 cm2,240 μs。比较了Nd3+∶GGG和Nd3+∶YAG的物理参数,实验表明Nd3+∶GGG较Nd3+∶YAG有一系列的优点。  相似文献   

9.
高功率固体激光晶体Nd3+:Gd3Ga5O12的生长和光谱性能的研究   总被引:3,自引:4,他引:3  
姜本学  赵志伟  徐军  邓佩珍 《中国激光》2004,31(12):465-1468
用提拉法生长了掺钕的钆镓石榴石(Nd3+:GGG)激光晶体,晶体的干涉条纹证明它有良好的光学均匀性,晶体(444)面的双晶摇摆曲线表明晶体的质量非常好。研究了室温下的吸收谱和发射谱性质。分析了Nd3+:GGG晶体4F3/2→4I11/2能级跃迁与1.06μm附近的荧光谱线之间的关系。Nd3+:GGG激光晶体的吸收截面、发射截面、荧光寿命分别为4.32×10-20cm2,2.3×10-1cm2,240μs。比较了Nd3+:GGG和Nd3+:YAG的物理参数,实验表明Nd3+:GGG较Nd3+:YAG有一系列的优点。  相似文献   

10.
Organic solar cells (OSCs) based on small molecular acceptors (SMAs) have made great development with a power conversion efficiency (PCE) over 16% due to the design of novel materials and advances in device preparation technology. This work fabricates two bulk-heterojunction photovoltaic devices containing the same wide-bandgap donor PM6, respectively, matched with popular Y6 and ITIC SMAs. The PM6:Y6-based device achieves a much higher PCE of 15.21% than the PM6:ITIC-based device of 9.02%. On the basis of comparisons of macroscopic performances in the quasistatic regime, transient absorption spectroscopy (TAS) is further performed to better understand the microscopic dynamics difference in charge separation processes between the two photovoltaic blends. According to the TAS results, the calculated hole transfer efficiency in PM6:Y6 is 71.4%, far greater than the efficiency of 13.1% in PM6:ITIC, demonstrating favorable charge separation at donor/acceptor interfaces via hole transfer channel in PM6:Y6. The favorable hole transfer in PM6:Y6 is accounted for by its better mutual miscibility between the donor and acceptor, and the formation of long-lived delocalized intramoiety excimer state in the acceptor. These results highlight the important role of proper molecular design strategy with strong intermolecular coupling and beneficial film morphology on facilitating charge generation in OSCs adopting SMAs.  相似文献   

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