Multistage Ozone Treatment of Dye Waste

An ozonation technology to treat lightly loaded effluents from dye manufacturing processes has been developed. The process uses airgenerated ozone and countercurrent contactors. An intermediate step is included to eliminate OH-radical scavengers and slowly reacting oxidized species from the liquid phase.

A study of ozone efficiency and yield concerning the reduction of TOC and COD levels is presented. The biological degradability.of treated water is discussed. A design and rating calculation procedure for countercurrent contactors is presented. Various waste treatment strategies using separation processes and ozone are discussed briefly. A cost estimate to treat a typical dye effluent in two stages on industrial scale is included.     

Ozone in Water Treatment—The Designer's Role

This paper presents the designer's role in providing an efficient and reliable ozone system for use in water treatment. The 789 m3/h (5 mgd) regional water plant in Avon, Colorado, USA is used as a case study. In the process design, two alternatives were evaluated. The ozone alternative was selected based on its multiple benefits. These benefits included iron and manganese removal, taste and odor control, coagulation and disinfection. Each aspect of the ozone system design is reviewed.     

Ozonation of Humic Substances: Effects on Molecular Weight Distributions of Organic Carbon and Trihalomethane Formation Potential

Four different sources of humic substances were studied to determine the effects of ozonation on molecular weight-distributions, based on dissolved organic carbon (DOC) and trihalomethane formation potential (THMFP). Solutions of two soil-derived fulvic acids and a one soil-derived humic acid, as well as dissolved organic matter (DOM) associated with a natural water source were studied. Both gel permeation chromatography (GPC) and ultrafiltration (UF) were employed to define apparent molecular weight (AMW). Applied ozone doses ranged from 2.0 to 2.5 mg O₃/mg DOC. Overall samples of untreated and ozonated waters, as well as individual molecular weight fractions, were characterized according to DOC, UV absorbance, and THMFP. Ozonation resulted in a significant disappearance of higher AMW material with a corresponding increase in lower AMW material. Although little overall reduction in DOC concentration was observed, significant overall reductions in UV absorbance and THMFP levels were observed.     

Destruction of Volatile Organic Contaminants in Drinking Water by Ozone Treatment

Controlled, pilot-plant ozone treatment tests were conducted on twenty-nine volatile organic contaminants in distilled water and groundwater. Results show that aromatic compounds and alkenes are well removed by ozone treatment, but that alkanes are poorly removed. Also, efficiency of destruction improved for the alkenes and aromatic compounds with increasing applied ozone dosage and, for some alkanes, with increasing pH. For most compounds, the efficacy of ozone was not severely affected by the background water matrix. Generally, information gathered from the literature regarding rate constants for the ozone treatment of compounds in the gaseous phase or in organic solution predicted, to a useful degree, the effectiveness of ozone in treating aqueous solutions in the present study.

Several of the test conditions selected for this preliminary study may be similar to those found in drinking water treatment plants. Consequently the findings of this research may help guide utilities in their choice of alternative treatments to meet Maximum Contaminant Levels for volatile organic contaminants such as trichloroethylene and benzene.     

Applications of Ozone in Japan for Water and Wastewater Treatment

In Japan, ozone is used for potable water treatment, night soil and industrial wastewater treatment, and for offensive gas treatment at sewage and night soil treatment plants. This paper describes its implementation, and presents experimental findings of the combined ozone and ultraviolet radiation as a new ozone utilization technology.     

Water Quality Improvements with the Use of Ozone at the Los Angeles Water Treatment Plant

At 600 mgd (2,270 ML/day), the recently completed Los Angeles Aqueduct Filtration Plant (LAAFP) is one of the world's largest water' treatment facilities utilizing ozone for pretreatment. The treatment process features direct filtration at rates of up to 13.5 gpm/ft² (33 m/h). Under the optimized full-scale operation, preozonation has resulted in significantly reduced THM levels and very low effluent turbidity with low operating costs.     

The Treatment of Spa Water with Ozone Produced by UV Light

Some North American manufacturers are selling devices which produce ozone from UV radiation, which is pumped or sucked into spas, presumably to disinfect the water, without having to use chlorine. To test this claim, a private spa used by two people at least once a day was equipped with a UV radiation unit and an ozone (generating by UV) unit. Bacterial analyses were conducted during experiments carried out using chlorine alone, ozone generated by UV radiation, unit and an ozone (generating by UV) unit. Bacterial analyses were conducted during experiments carried out using chlorine alone, ozone generaed by UV radiation, and ozoen in combination with UV radiation.

Heterotrophic plate counts, and counts of Staphyiococcus aureus and Pseudomonas aeruginosa were lowest when using chlorine, next lowest when using ozone #x002B; UV radiation, and highest when using UV-generated ozone. It is concluded that insufficient dissolved ozone is present for a sufficient reaction time to effect disinfection of these organisms by ozone generated by UV radiation. The fact that the odor of ozone was present above the spa water indicates that contacting also was inefficient.     

Ozone Treatment in Cooling Water Systems

Ozone treatment for preventing the biofouling in cooling water systems is investigated.

In the fresh water system, the separating effect of the ozonated water on the microorganisms such as the sphaerotilus and the zoogloea which adhere to the piping and form the slime is recognized. When the ozonated water is supplied intermittently to the piping without stopping the flow of the cooling water, a constant volume of cooling water can be maintained. At the velocity of 1 m/sec, the amount of metal corrosion produced by the ozonated water is reduced on the mild steel, increased on the copper and does not change on the cast iron, when compared with that produced by the water containing no ozone.

In the seawater system, since many substances are oxidized by the ozone, the same treatment as that in the fresh water system cannot be applied. However, if the seawater in the cooling system can be replaced with ozone-containing air intermittently once a week, the adhesion of organisms such as barnacles and mussels to the piping can be prevented without having a bad influence on the other living oceanic organisms.     

Ozone Swimming Pool Water Treatment Under Tropical Conditions

This paper presents the first year operation report of an ozone swimming pool water treatment system under the severe conditions of tropical climate. The system installed in a 70 m³ pool with upflow hydraulics, comprises sand filtration and ozone/bromide ion treatment. Cupric sulfate was chosen as algaecide and pH was kept between 7.5 and 7.8 by adding adequate amounts of HC1. When required, a slight flocculation (aluminum sulfate, 5 mg/L) was applied weekly. Water physicochemical analyses performed twice a week throughout the year, including microbiological tests, clearly demonstrated the remarkable efficiency of the treatment, fulfilling all water quality standards, even at high bather loads and during the summer months (at water temperature higher than 31[ddot]C and an intense sunlight) being economically feasible as well. This experience will allow the extension of ozone water treatment to larger swimming pools in similar circumstances.     

Theoretical Analysis Of Ozone Disinfection Performance In A Bubble Column

Modelling the efficiency of ozone disinfection in a bubble column was completed using two kinetic approaches: an axial dispersion model (ADM) and a back-flow cell model (BFCM). Using these models, the effects of flow directions and mixing on disinfection performance were examined. Both models predicted the concentration profiles of dissolved ozone in water equally well. However, the BFCM could be solved much more easily than the ADM with regard to the degree of inactivation without the solution being plagued by divergence.     

In-Line Ozone Dissolution Demonstration-Scale Evaluation

A demonstration-scale, in-line ozone dissolution and contacting system was constructed and operated for the Long Beach Water Department and the Metropolitan Water District of Southern California. The in-line process was assessed to determine its suitability for ozone oxidation of color in local groundwater. Results indicate that ozone utilization for color oxidation with an in-line system is more efficient than with a conventional bubble contactor.     

Experimental Results of a Cost-Effective Ozone Generator for Water Treatment in Colombia

Obtaining high-quality cost-effective water, minimizing the public health risk generated by pathogenic elements or disinfection sub-products such as trihalomethane and/or chlorophenol, has made necessary the use of technologies different to chlorination. In this paper, we present the implementation of a high-voltage, high-frequency flyback inverter to generate ozone, and outline the main characteristics and uses of a prototype of water ozonation from a well for a hospital in Colombia. With the prototype, the ozone dose can be adjusted through the duty cycle modulation; switching was done with a Mosfet and the voltage signal was increased with a ferrite technology transformer. The source is characterized by its simplicity, good performance and low cost.     

Remarks on the Research and the Application of Ozone in Poland

A review of the state of knowledge, science and technology connected to ozone in Poland in presented. Examples of research direction as well as applications are described. Some details concerning the problems of supplying water regions with high population density and having a developed heavy industry are presented. It is shown that using ozone in various water treatment systems helps to solve complicated problems connected to the management with limited water resources in Poland. The needs to develop ozone technology are large as in the next several years the Polish market will need ozonizers of various capacities and producing ozone at higher concentrations.     

Heterogeneous Catalytic Ozonation with Supported Titanium Dioxide in Model and Natural Waters

This paper presents the results obtained with heterogeneous catalytic ozonation in which model and natural waters are ozonated in the presence of supported titanium dioxide (TiC₂) as a solid catalyst. The conditions in preparing the supported catalyst are experimentally optimized. The efficiencies of three catalyst supports (attapulgyte, alumina and silica gel) for organic matter oxidation have been compared. The TiC₂ supported in alumina calcined at 500[ddot]C compacted to granular form with a particle diameter about 2-4 mm is demonstrated to be the best catalyst on the removal total organic carbon (TOC) by ozone.     

Effect of ozone pre‐treatment of colored upland water on some biological parameters of sand filters

A pilot treatment plant for potable water, consisting of an ozonating unit followed by slow sand filters, was built in order to determine the relationship between filter biomass and performance following ozonation of colored feed water of upland origin. The color is due largely to the presence of humic substances, being most prevalent after heavy rainfall in the catchment. Ozone improves color by breaking down large humic molecules to smaller organic species, thus providing more bioavailable material in the water. Slow sand filtration, applied after ozonation, removes some of this material at the expense of more rapid clogging of the filters. This study on the schmutzdecke showed that the overall biomass of ozonated filters after clogging was significantly greater compared to non‐ozonated filters. Results revealed an increase in the heterotrophic biomass, but no significant change in the autotrophic community biomass, in slow sand filters receiving pre‐ozonated water.     

Study of the Catalytic Ozonation of Humic Substances in Water and Their Ozonation Byproducts

It is shown that using transition metals, especially Mn(II) and Ag(I), during ozonation of humic substances in water allows important reductions in the content of organic matter. Characterization of the organic compounds resulting from ozonation was made by concentrating the sample through liquid-liquid extraction or derivation with PFBOA.HCl, along with the GC/MS and GC/ECD techniques. In total, 110 different organic compounds were identified using GC/MS; mainly carboxylic acids, aromatics, hydrocarbons, aldehydes, ketones, and furan-carboxylic acids. The percentages of elimination or formation levels reached during ozonation are discussed.     

Toward Elucidating Mechanism And Kinetics Of Ozone Decolorization And Dechlorination Of Pulp Mill Effluents

This study elucidated the mechanism and kinetics of ozone decolorization and dechlorination of composite wastewaters obtained from various pulp mill effluents by means of ultrafiltration and freeze drying. These raw samples had similar initial true color but varied color intensity (C.I.) and biodegradability. Both raw and ozone-treated samples were separated into four components to assess the effects of ozonation on individual components. Analytical HPSEC was employed to determine the changes induced by ozonation in molecular weight distribution of lignins and their derivatives.     

The Development Of Ozone For Potable Water Treatment Within The United Kingdom

The historical development of the application of ozone to potable water treatment within the United Kingdom is reviewed up to 1990. The impact of privatization of the water utilities on the use of ozone is discussed and the process applications currently being considered are described. The paper concludes with a survey of water treatment plants which are using ozone in 1993, and those planned for completion by the year 2000.     

An Experimental Study Of Ozonation Followed By Slow Sand Tiltration for the Removal of Colour from Water

Ozone was introduced into the water initially using a packed colum, however, in order to improve the ozone utilisation it was decided to change to a spilt ozone dosage arrangement using a counter flow bubble column followed by a packed colum. Subsequent tests showed that the bubble colum alone produced similar ozone utilisation to the split dosing arrangements and the last 6 test runs were all undertaken using the bubble ozone alone.     

The Oxidation of Manganese and Disinfection By Ozonation in Water Purification Processing

The surface water of a river has been used as the raw water by the Waterworks Bureau of Osaka City. At present, the manganese contained in the raw water is oxidized by breakpoint chlorination and all oxides are removed by coagulation, sedimentation followed by rapid sand filtration, with chlorine being used as the final disinfectant.

Prechlorination was not conducted in the ongoing pilotplant experiment of an advanced water purification process with ozone and granular activated carbon. It is necessary, therefore, to oxidize manganese by the oxidative effect of ozone instead of prechlorination.

It is important for the treatment of manganese to adjust the ozone dosage because manganese is oxidized up to the soluble septavalent state by the surplus ozone. Since ozone does not continue to exist for very long in water, though its disinfecting power is high, final disinfection by chlorine is required.