共查询到18条相似文献,搜索用时 62 毫秒
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氧化钙催化活性在焦油裂解过程中的变化规律 总被引:3,自引:0,他引:3
在以循环床锅炉循环灰为热载体、部分气化产生的半焦为锅炉燃料的煤的部分气化技术中,循环灰中的氧化钙对降低焦油产率、提高煤气产率是有利的。以焦油中的苯和甲苯为对象,用固定床反应器实验研究了焦油裂解过程中反应对氧化钙催化活性的影响,测定了失活系数,探讨了失活机理。实验结果表明,随着积碳量的增加,氧化钙颗粒的比表面积和空隙率减小,裂解反应速率下降,裂解产物中碳的总产率增加。 相似文献
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针对煤快速热解研究中样品添加量少(mg级)、焦油收集难等问题,本研究利用压片法制备微薄厚度(mm级)的煤层,并采用红外加热装置考察大添加量(g级)、微薄煤层的快速热解特性。对比堆积煤样和不同煤压片厚度(1.5~3 mm)与个数(1~2)的压片煤样热解特性发现,压片煤层热解过程的二次反应受到明显抑制,焦油产率急剧增加,在1000℃时达9.96%,为格金分析的1.5倍,实现油气产量的同步增长。模拟蒸馏分析发现,堆积状态下焦油以沥青质为主,而微薄煤层制焦油含大量轻油、酚油、萘油、洗油和蒽油。GC-MS和FTIR分析表明,随煤层厚度和个数的减少,焦油组分和含量提高,芳香烃类和含氧官能团吸收增加,进一步验证煤快速热解过程中煤层厚度对焦油产率和品质的影响,揭示在二次反应充分抑制下煤高温热解的初级反应特性。 相似文献
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生物质热解焦油的热裂解与催化裂解 总被引:18,自引:0,他引:18
生物质气化过程中产生的焦油对气化系统和用气设备都有极大的危害。为了开发适合于商业应用的焦油缩减方法,探索达到最优焦油脱除效果的操作条件,在固定床反应器上,利用石灰石、白云石、高铝砖作为催化剂研究了生物质(稻秆、稻壳、木屑等)热解焦油的催化裂解反应,利用炭化硅作为热载体研究了焦油的热裂解反应,对热解煤气中焦油含量的变化以及热解煤气组成和热值的变化进行了比较,并对裂解温度、气相停留时间等因素对裂解效果的影响进行了探讨。实验发现,600-900℃范围内ηtar随裂解温度升高而升高,900℃时热裂解条件下可达60%,而催化裂解条件下可达90%以上。0.5~1s范围内,ηtar随停留时间增加而升高,幅度约7%~10%。相比于原始煤气,裂解后煤气组成出现了较大变化,热裂解后煤气热值增加,而催化裂解后煤气热值下降,且热裂解与催化裂解处理后煤气组成也有较大差异。 相似文献
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结合煤加氢热解最新研究进展,从煤加氢热解焦油形成机理出发,综合论述了提高热解焦油产量的6条途径和方法。提出煤-焦炉气催化加氢热解的新构想,以期实现“煤→热解煤气内循环→焦油”新工艺。 相似文献
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煤热解富产焦油的工艺评述 总被引:1,自引:0,他引:1
本文在综合评述煤加氢热解工艺、煤甲烷共热解工艺及煤焦炉气共热解工艺的基础上,提出煤焦炉气催化热解新方法,以期实现煤催化热解富产焦油的新工艺,为煤非燃料利用开辟一条新的途径。 相似文献
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1 INTRODUCTIONWhen an exothermic reaction is carried out in a fixed bed reactor,there exists an axialtemperature profile exhibiting a maximum,known as the hot spot.In certain regions ofthe parametric sensitivity,the hot spot temperature undergoes very large increases forsmall changes in one or more inlet parameters,and this phenomenon is called runawayand the corresponding inlet condition is known as the critical.The reactor will be outof controlled beyond this condition and brings about a bad influence on process con- 相似文献
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<正>一些研究者基于简化机理模型,讨论了固定床反应器的推断控制。然而,工业过程中有许多固定床反应器的机理模型尚难以建立,而且由于固定床反应器特性的复杂性,模型简化和状态估计器的设计等具有较大的困难。因此,基于“黑箱”模型研究固定床反应器的推断控制可能是一条十分有效的途径。Budman等人提出用部分最小二乘法(PLS)以改进回归模型的性能。他们对实验室固定床反应器,假设沿反应器轴向的十点温度可以测量,并据此建立回归模型,然而由于固定床反应器具有严重非线性和时变等特性,用PLS法建立估计器仍有局限性。另外,实际的固定床反应器可能只有少数几个温度可以测量。因此其面向应用的推断控制策略的研究有十分重要的意义。 相似文献
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Katica Sertić-Bionda Zoran Gomzi Marko Mužic 《Chemical Engineering Communications》2013,200(3):275-288
A five-lump kinetic model had been developed for modeling of gas oil catalytic cracking. The experiments were carried out in a standard fixed bed micro-activity test (MAT) reactor. Distribution of the cracking product components was determined as a function of temperature. The sequential step optimization method was used to estimate the kinetic constants. A MAT reactor nonisothermal and the unsteady-state model was proposed. The overall heat of the reactions was established from the macroscopic difference of the products' and the reactants' enthalpies. The influence of the feedstock and the reactor temperature was discussed. The reactor and the kinetic models were validated using the experimental MAT results. Simulation results were in good agreement with the experimental data. 相似文献
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A new application of the fixed bed catalytic reactor with flow reversal for combustion of natural gas is investigated by mathematical modeling and computer simulation. Comparison between the results obtained for this new reactor and those for a classic catalytic fixed bed is made. Inexpensive perovskite type catalysts containing no noble metals were used. It is shown that an appropriate choice of operating parameters (concentration and temperature of input gas mixture, superficial gas velocity, size and shape of catalyst and inert material, volumetric ratio between catalyst and inert material in the bed) allows for a methane combustion at must lower temperatures in the reactor with flow reversal than in a classic catalytic reactor. Under such a low temperature combustion, no nitrogen oxides are produced. 相似文献
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A restricted diffusion model was used to investigate the optimal design for the residual oil hydrodemetallation in a fixed bed reactor. Based on the total lifetime activity, the optimal catalyst pore sizes and their corresponding optimal division locations in the bed were determined. The results indicate that the total amount of demetallation could be significantly improved by using a multi-layers reactor and the nonuniform activity catalysts. In addition, the influence of the Thiele modulus on the optimal designs were illustrated. 相似文献