Experimental investigation of the effects of separate hydrogen and nitrogen addition on the emissions and combustion of a diesel engine

An experimental investigation of the effects of separate hydrogen and nitrogen addition on the emissions and combustion of a diesel engine was performed and the results are presented in the current paper.     

Experimental investigation of the effects of simultaneous hydrogen and nitrogen addition on the emissions and combustion of a diesel engine

Overcoming diesel engine emissions trade-off effects, especially NO_x and Bosch smoke number (BSN), requires investigation of novel systems which can potentially serve the automobile industry towards further emissions reduction. Enrichment of the intake charge with H₂ + N₂ containing gas mixture, obtained from diesel fuel reforming system, can lead to new generation low polluting diesel engines.     

Effect of hydrogen addition using on-board alkaline electrolyser on SI engine emissions and combustion

In this study, an electrolyser was used to supply hydrogen to the SI engine. Firstly, the appropriate operation point for the electrolyser was determined by adjusting the amount of KOH in the electrolyte to 5%, 10%, 20% and 30% by mass, and applying 12 V, 16 V, 20 V, 24 V and 28 V voltages. Tests were first carried out with the gasoline without the use of an electrolyser, followed by operating the electrolyser at the appropriate point and sending obtained H₂ and O₂ to the engine in addition to the gasoline. The SI engine was operated between 2500 rpm and 3500 rpm engine speeds with and without hydrogen addition. Cylinder pressure, the amount of gasoline, H₂ and O₂ consumed by the engine and the emission data were collected from the test system at the aforementioned engine speeds. Furthermore, indicated engine torque, indicated specific energy consumption, specific emissions and HRR values were calculated. According to the results obtained, improvement in ISEC values was observed, and CO and THC values were improved by up to 21.3% and 86.1% respectively. Even though the dramatic increase in NO_x emissions cannot be averted, they can be controlled by equipment such as EGR three-way catalytic converter.     

A numerical study on a hydrogen assisted diesel engine

This work aims to numerically study the performance, combustion and emission characteristics of a hydrogen assisted diesel engine under various operating conditions. Simulations were performed using multi-dimensional software KIVA4 coupled with CHEMKIN. The Kelvin–Helmholtz and Rayleigh–Taylor hybrid break up model was implemented to accurately model the spray development. A detailed reaction mechanism was constructed to take into account the chemical kinetics of diesel and hydrogen, and it was validated against the experimental results with 0% of hydrogen induction. Simulation results showed that at low engine speeds, the indicated thermal efficiency, in-cylinder pressure and apparent heat release rate increased significantly with the induction of hydrogen. On the other hand, at high engine speed and high load conditions, no tangible changes on the engine performance, combustion characteristics were observed. In terms of emissions, CO and soot emissions were shown to be reduced under most of the engine operating conditions. Whereas for NO_x emissions, a slight increase was observed at low engine speed of 1600 rpm.     

Performance and combustion characteristic of CI engine fueled with hydrogen enriched diesel

The combustion of hydrogen–diesel blend fuel was investigated under simulated direct injection (DI) diesel engine conditions. The investigation presented in this paper concerns numerical analysis of neat diesel combustion mode and hydrogen enriched diesel combustion in a compression ignition (CI) engine. The parameters varied in this simulation included: H₂/diesel blend fuel ratio, engine speed, and air/fuel ratio. The study on the simultaneous combustion of hydrogen and diesel fuel was conducted with various hydrogen doses in the range from 0.05% to 50% (by volume) for different engine speed from 1000 – 4000 rpm and air/fuel ratios (A/F) varies from 10 – 80. The results show that, applying hydrogen as an extra fuel, which can be added to diesel fuel in the (CI) engine results in improved engine performance and reduce emissions compared to the case of neat diesel operation because this measure approaches the combustion process to constant volume. Moreover, small amounts of hydrogen when added to a diesel engine shorten the diesel ignition lag and, in this way, decrease the rate of pressure rise which provides better conditions for soft run of the engine. Comparative results are given for various hydrogen/diesel ratio, engine speeds and loads for conventional Diesel and dual fuel operation, revealing the effect of dual fuel combustion on engine performance and exhaust emissions.     

Numerical energetic and exergetic analysis of CI diesel engine performance for different fuels of hydrogen,dimethyl ether,and diesel under various engine speeds

The current study addresses engine specification and second thermodynamic law analysis of the CI diesel engine fueled with hydrogen, DME, and diesel at six engine speeds. The 3-D simulation was first carried out and then the results were exploited to calculate availability through a developed in-house code. Availability analysis was performed separately for chemical and thermo-mechanical availability to highlight each fuel'0s capacity in chemical and mechanical efficiency delivery. The results indicate that hydrogen fuel prevails in chemical and thermo-mechanical availability, indicated power, and mean effective in-cylinder pressure under all crank angle and engine speeds. Temperature distribution has more extensive and intensified region developed across the cylinder, although hydrogen demonstrated the lowest ISFC (indicated specific fuel consumption) value. With regard to engine speed, 2000 rpm shows overall better IP (indicated power), IMEP (indicated mean effective pressure), chemical and thermo-mechanical availability, irrespective of fuel type. The mean irreversibility rate for PMC (pre-mixed combustion) and MCC (mixing controlled combustion) combustion phase shows a different trend. Furthermore, hydrogen fueled engine demonstrates the highest temperature distribution of 2736 K and the wall heat flux to the amount of 29160 W. The variance of chemical availability for Hydrogen from 1500 to 4000 rpm decreases by crank-angle evolution from 43.3% to 10.1% corresponding to 10–40°CA after top dead center.     

Effect of hydrogen addition on the combustion and emission of a diesel free-piston engine

The free-piston engine (FPE) is a new crankless engine, which operates with variable compression ratio, flexible fuel applicability and low pollution potential. A numerical model which couples with dynamic, combustion and gas exchange was established and verified by experiment to simulate the effects of different hydrogen addition on the combustion and emission of a diesel FPE. Results indicate that a small amount of hydrogen addition has a little effect on the combustion process of the FPE. However, when the ratio of hydrogen addition (R_H2) is more than 0.1, the R_H2 gives a positive effect on the peak in-cylinder gas pressure, temperature, and nitric oxide emission of the FPE, while soot emission decreases with the increase of hydrogen addition. Moreover, the larger R_H2 induces a longer ignition delay, shorter rapid combustion period, weaker post-combustion effect, greater heat release rate, and earlier peak heat release rate for the FPE. Nevertheless, the released heat in rapid combustion period is significantly enhanced by the increase of R_H2.     

Combustion,performance and emissions of ULSD,PME and B50 fueled multi-cylinder diesel engine with naturally aspirated hydrogen

An experimental study was conducted on a diesel engine fueled with ultra-low sulfur diesel (ULSD), palm methyl ester (PME), a blended fuel containing 50% by volume each of the ULSD and PME, and naturally aspirated hydrogen, at an engine speed of 1800 rev min⁻¹ under five loads. Hydrogen was added to provide 10% and 20% of the total fuel energy. The following results are obtained with hydrogen addition. There is little change in peak in-cylinder pressure and peak heat release rate. The influence on fuel consumption and brake thermal efficiency is engine load and fuel dependent; being negative for the three liquid fuels at low engine loads but positive for ULSD and B50 and negligible for PME at medium-to-high loads. CO and CO₂ emissions decrease. HC decreases at medium-to-high loads, but increases at low loads. NO_x emission increases for PME only but NO₂ increases for the three liquid fuels. Smoke opacity, particle mass and number concentrations are all reduced for the three liquid fuels.     

Effect of hydrogen addition on combustion and emissions performance of a spark-ignited ethanol engine at idle and stoichiometric conditions

Regarding the limited fossil fuel reserves, the renewable ethanol has been considered as one of the substitutional fuels for spark ignition (SI) engines. But due to its high latent heat, ethanol is usually hard to be well evaporated to form the homogeneous fuel–air mixture at low temperatures, e.g., at idle condition. Compared with ethanol, hydrogen possesses many unique combustion and physicochemical properties that help improve combustion process. In this paper, the performance of a hydrogen-enriched SI ethanol engine under idle and stoichiometric conditions was investigated. The experiment was performed on a modified 1.6 L SI engine equipped with a hydrogen port-injection system. The ethanol was injected into the intake ports using the original engine gasoline injection system. A self-developed hybrid electronic control unit (HECU) was adopted to govern the opening and closing of hydrogen and ethanol injectors. The spark timing and idle bypass valve opening were governed by the engine original electronic control unit (OECU), so that the engine could operate under its original target idle speed for each testing point. The engine was first fueled with the pure ethanol and then hydrogen volume fraction in the total intake gas was gradually increased through increasing hydrogen injection duration. For a specified hydrogen addition level, ethanol flow rate was reduced to keep the hydrogen–ethanol–air mixture at stoichiometric condition. The test results showed that hydrogen addition was effective on reducing cyclic variations and improving indicated thermal efficiency of an ethanol engine at idle. The fuel energy flow rate was reduced by 20% when hydrogen volume fraction in the intake rose from 0% to 6.38%. Both flame development and propagation periods were shortened with the increase of hydrogen blending ratio. The heat transfer to the coolant was decreased and the degree of constant volume combustion was enhanced after hydrogen addition. HC and CO emissions were first reduced and then increased with the increase of hydrogen blending fraction. The acetaldehyde emission from the hydrogen-enriched ethanol engine is lower than that from the pure ethanol engine. However, the addition of hydrogen tended to increase NO_x emissions from the ethanol engine at idle and stoichiometric conditions.     

Investigation on combustion and emissions characteristics of a hydrogen-blended n-butanol rotary engine

In this paper, a rotary engine equipped with an n-butanol and hydrogen port-injection system was developed to investigate the combustion and emissions characteristics of a hydrogen-blended n-butanol rotary engine at part load and stoichiometric conditions. A self-developed hybrid electronic control unit was adopted to adjust the injection durations of n-butanol and hydrogen. The rotary engine was run under the conditions of 4000 rpm, a manifold absolute pressure of 35 kPa and a fixed spark timing of 45 °CA before the top dead center during the whole testing operation. The hydrogen volumetric fraction in the total intake was varied from 0% to 6.30%. The test results manifested that the brake thermal efficiency and chamber temperature were simultaneously increased with hydrogen addition. The hydrogen supplement obviously shortened flame development and propagation periods. Both chamber pressure integral heat release fraction versus crank angle were increased when the hydrogen fraction was enhanced. HC emissions were reduced by 54.5% when hydrogen volume fraction was raised from 0% to 6.30%, CO and CO₂ emissions were also reduced after increasing hydrogen blending fraction. NOx emissions were mildly elevated due to the improved chamber temperature.     

Theoretical investigation of the combustion performance of ammonia/hydrogen mixtures on a marine diesel engine

Ammonia is a good hydrogen carrier and can be well combined with hydrogen for combustion. The combustion performance of the mixtures of ammonia and hydrogen in a medium-speed marine diesel engine was investigated theoretically. The HCCI combustion mode was selected for reducing thermal-NO_x production. The start fire characteristic of the NH₃–H₂ mixtures was studied under different equivalence ratio, hydrogen-doped ratio, and intake air temperature and pressure. Then, the combustion performance of the NH₃–H₂ mixtures (doping 30% hydrogen) was analyzed at a typical operation condition of engine. The addition hydrogen improved the laminar flame velocity of ammonia, and affected the NO_x emission. For the medium-speed marine engine fueled with NH₃–H₂, reducing combustion temperature, introducing EGR and combining with post-treatment technology would be a feasible scheme to reduce NO_x emission.     

Effect of hydrogen addition to intake air on combustion noise from a diesel engine

This study investigates the characteristics of combustion noise from a diesel engine with hydrogen added to intake air. The engine noise with hydrogen addition of 10 vol% to the intake air was lower than that with diesel fuel alone at late diesel-fuel injection timings. A transient combustion-noise-generation model was introduced to discuss noise characteristics based on energy conversion from combustion impact to noise via structure vibration. The results show that the maximum combustion impact energy had a predominant effect on the maximum engine noise power for each cycle. Therefore, the combustion noise largely contributed to the total engine noise in an early stage of the expansion stroke. The dependences of engine noise on the diesel-fuel injection timing for different hydrogen fractions are discussed considering the characteristics of maximum combustion impact energy for each frequency.     

Hydrogen effects on the diesel engine performance and emissions

In this research, effects of hydrogen addition on a diesel engine were investigated in terms of engine performance and emissions for four cylinders, water cooled diesel engine. Hydrogen was added through the intake port of the diesel engine. Hydrogen effects on the diesel engine were investigated with different amount (0.20, 0.40, 0.60 and 0.80 lpm) at different engine load (20%, 40%, 60%, 80% and 100% load) and the constant speed, 1800 rpm. When hydrogen amount is increased for all engine loads, it is observed an increase in brake specific fuel consumption and brake thermal efficiency due to mixture formation and higher flame speed of hydrogen gas according to the results. For the 0.80 lpm hydrogen addition, exhaust temperature and NOx increased at higher loads. CO, UHC and SOOT emissions significantly decreased for hydrogen gas as additional fuel at all loads. In this study, higher decrease on SOOT emissions (up to 0.80lpm) was obtained. In addition, for 0.80 lpm hydrogen addition, the dramatic increase in NOx emissions was observed.     

The effect of HRG gas addition on diesel engine combustion characteristics and exhaust emissions

Extensive studies have been dedicated in the last decade to the possibility to use hydrogen in the dual-fuel mode to improve combustion characteristics and emissions of a diesel engine. The results of these studies, using pure hydrogen or hydrogen containing gas produced through water electrolysis, are notably different.The present investigation was conducted on a tractor diesel engine running with small amounts of the gas—provided by a water electrolyzer—aspirated in the air stream inducted in the cylinder. The engine was operated at light and medium loads and various speeds.It was found that the addition of HRG gas has a slight negative impact, up to 2%, on the engine brake thermal efficiency. Smoke is significantly reduced, up to 30%, with HRG enrichment, while NO_x concentrations vary in both senses, up to 14%, depending on the engine operation mode. A relative small amount of HRG gas can be used with favorable effects on emissions and with a small penalty in thermal efficiency.     

Operating strategy for a hydrogen engine for improved drive-cycle efficiency and emissions behavior

Due to their advanced state of development and almost immediate availability, hydrogen internal combustion engines could act as a bridging technology toward a wide-spread hydrogen infrastructure. Extensive research, development and steady-state testing of hydrogen internal combustion engines has been conducted to improve efficiency, emissions behavior and performance. This paper summarizes the steady-state test results of the supercharged hydrogen-powered four-cylinder engine operated on an engine dynamometer. Based on these results a shift strategy for optimized fuel economy is established and engine control strategies for various levels of hybridization are being discussed. The strategies are evaluated on the Urban drive cycle, differences in engine behavior are investigated and the estimated fuel economy and NO_x emissions are calculated. Future work will include dynamic testing of these strategies and powertrain configurations as well as individual powertrain components on a vehicle platform, called ‘Mobile Advanced Technology Testbed’ (MATT), that was developed and built at Argonne National Laboratory.     

Numerical simulation of hydrogen combustion process in rotary engine with laser ignition system

In this paper the combustion and ignition process in the hydrogen-fueled peripheral-ported rotary engine with single and dual laser ignition systems was studied numerically. The computational method was established for the process simulation including interaction between turbulence and chemical reactions. The detailed chemical kinetic model of hydrogen combustion was used. It was shown that the ignition and combustion process in the H₂-fueled rotary engine is highly transient with specific distortion and stretching of the combustion front in the combustion chamber due to complex motion of the rotor relative to the engine housing. The single and dual laser ignition systems were simulated to compare the ignition efficiency and the rate of hydrogen burning out. The evaluation of pressure in the combustion chamber was performed and compared with the experimental data obtained for the rotary engine fueled by natural gas. It was shown that the H₂-fueled rotary engine with the dual laser ignition system has potential application in alternative automotive industry due to high efficiency and near-zero carbon-based emission.     

Assessing the effects of partially decarbonising a diesel engine by co-fuelling with dissociated ammonia

The proven feasibility of ammonia combustion in compression-ignition engines has led to it being considered as a carbon-free replacement for diesel fuel. Due to its high auto-ignition temperature, however, a more realistic strategy would be to aim for a step-change reduction in carbon emissions by co-fuelling a diesel engine with ammonia. In assessing this strategy, ammonia gas was introduced into the air-intake manifold of a compression-ignition engine, while diesel fuel was injected directly into the cylinder to ignite the mixture. By substituting only 3% of the air intake by ammonia, the diesel consumption and the CO₂ emissions decreased by 15%. The combustion and emission characteristics were then compared when the same percentage of air intake (by mass) was substituted by either dissociated ammonia (a mixture of H₂, N₂ with small percentages of NH₃) or pure hydrogen, to mimic the other possible forms in which the co-fuel can be delivered to the engine. The addition of pure hydrogen resulted in the best engine performance, both in terms of combustion efficiency and regulated emission quality. The thermal combustion efficiency declined by only ∼0.5% when the H₂ was replaced by undissociated ammonia at low load, but N₂O now appeared in the emissions. Co-fuelling the engine with dissociated ammonia may provide the ideal compromise in terms of thermal combustion efficiency and emission quality, while also providing a waste-heat recovery mechanism.     

Computational combustion and emission analysis of hydrogen–diesel blends with experimental verification

The paper discusses the effect of blending hydrogen with diesel in different proportions on combustion and emissions. A comparative study was carried out to analyze the effect of direct injection of hydrogen into the combustion chamber with that of induction through the inlet manifold for dual fueling. Percentage of hydrogen substitution varied from 20% to 80%, simultaneously reducing the diesel percentages. CFD analysis of dual fuel combustion and emissions were carried out for both the said methods using the CFD software FLUENT, meshing the combustion chamber was carried out using GAMBIT. The standard combustion and emission models were used in the analysis. In the second part of the paper, the effect of angle of injection in both the methods of hydrogen admission, on performance, combustion and emissions were analyzed. The experimental results were compared with that of simulated values and a good agreement between them was noticed.     

Effect of hydrogen nanobubble addition on combustion characteristics of gasoline engine

Hydrogen is an attractive energy source for improving gasoline engine performance. In this paper, a new hydrogen nanobubble gasoline blend is introduced, and the influence of hydrogen nanobubble on the combustion characteristics of a gasoline engine is experimentally investigated. The test was performed at a constant engine speed of 2000 rpm, and engine load of 40, 60, and 80%. The air-to-fuel equivalence ratio (λ) was adjusted to the stoichiometric (λ = 1), for both gasoline, and the hydrogen nanobubble gasoline blend. The results show that the mean diameter and concentration of hydrogen nanobubble in the gasoline blend are 149 nm and about 11.35 × 10⁸ particles/ml, respectively. The engine test results show that the power of a gasoline engine with hydrogen nanobubble gasoline blend was improved to 4.0% (27.00 kW), in comparison with conventional gasoline (25.96 kW), at the engine load of 40%. Also, the brake specific fuel consumption (BSFC) was improved, from 291.10 g/kWh for the conventional gasoline, to 269.48 g/kWh for the hydrogen nanobubble gasoline blend, at the engine load of 40%.     

Effect of Diesel/methanol compound combustion on Diesel engine combustion and emissions

This paper introduces a Diesel/methanol compound combustion system (DMCC) and its application to a naturally aspirated Diesel engine with and without an oxidation catalytic converter. In the DMCC system, there are two combustion modes taking place in the Diesel engine, one is diffusion combustion with Diesel fuel and the other is premixed air/methanol mixture ignited by the Diesel fuel. Experiments were conducted on a four cylinder DI Diesel engine, which had been modified to operate in Diesel/methanol compound combustion. Experiments were conducted at idle and at five engine loads at two levels of engine speeds to compare engine emissions from operating on pure Diesel and on operating with DMCC, with and without the oxidation catalytic converter. The experimental results show that the Diesel engine operating with the DMCC method could simultaneously reduce the soot and NOx emissions but increase the HC and CO emissions compared with the original Diesel engine. However, using the DMCC method coupled with an oxidation catalyst, the CO, HC, NOx and soot emissions could all be reduced.