导电聚苯胺电磁屏蔽复合材料专利技术综述

概述了聚苯胺的结构及特点,阐述了专利文献中掺杂聚苯胺、聚苯胺/无机、聚苯胺/有机电磁屏蔽材料的研究进展,提出了聚苯胺电磁屏蔽材料的研究方向和发展前景。     

导电高分子聚苯胺的合成及应用

聚苯胺(PANI)是研究最为广泛的导电高分子材料之一。综述了聚苯胺的结构、特性及几种合成聚苯胺的方法,介绍了聚苯胺的掺杂方法及聚苯胺的应用前景。     

聚苯胺及其复合材料研究现状

对聚苯胺的结构、合成及其机理、质子酸掺杂 ,聚苯胺的应用 ,以及聚苯胺复合材料的研究现状进行了综合阐述 ,并详细介绍了有关煤基聚苯胺的研究情况。煤基聚苯胺和纯聚苯胺相比 ,电导率下降不大 ,而且成本降低、热稳定性增强 ;同时 ,煤基聚苯胺也为煤的非能源利用提供了新途径和新机遇 ,具有一定的推广价值。     

水溶性聚苯胺合成及聚苯胺在防腐领域的应用

介绍了聚苯胺的结构,主要讨论了水溶性聚苯胺的3种合成方法,及聚苯胺在防腐领域的研究及发展,阐述了聚苯胺的防腐机理和聚苯胺防腐涂层的应用,并对其前景进行展望,认为水溶性聚苯胺的合成研究及其缓蚀理论分析还需进一步深入地开展研究。     

聚苯胺及其防腐涂料的研究进展

综述了聚苯胺及防腐涂料的研究进展,包括聚苯胺的结构、特性及聚苯胺的掺杂机理,介绍了聚苯胺防腐涂料的防腐机理和优点,展望了聚苯胺防腐涂料的未来发展。     

掺杂态聚苯胺的制备与表征

以本征态聚苯胺为原料,以盐酸、硫酸、5-磺基水杨酸、对甲苯磺酸和十二烷基苯磺酸为掺杂酸,制备出盐酸掺杂聚苯胺、硫酸掺杂聚苯胺、5-磺基水杨酸掺杂聚苯胺、对甲苯磺酸掺杂聚苯胺和十二烷基苯磺酸掺杂聚苯胺。对掺杂态聚苯胺的结构、电导率、溶解性和热稳定性进行测试,分析了掺杂酸对本征态聚苯胺的结构与性能的影响。     

导电聚苯胺的制备方法及应用

综述了导电聚苯胺的研究进展,采用对比的方法详细介绍了聚苯胺的合成方法及其改进措施,简要介绍了聚苯胺在二次电池及传感器件等方面的应用研究,指出了聚苯胺研究中存在的问题,并对聚苯胺研究的前景进行了展望。     

有机酸掺杂聚苯胺的研究进展

聚苯胺是一种非常有前途的导电聚合物。掺杂能提高聚苯胺的导电性、稳定性及其他性能,聚苯胺的掺杂受到了人们的广泛关注,尤其是有机酸的掺杂。有机酸种类众多且性能各异,能够使聚苯胺很多性质发生变化。本文重点综述了分别以单一有机酸、有机酸和金属氧化物、有机酸和无机酸、有机酸和其他无机物为掺杂剂合成聚苯胺的研究现状,详细介绍了各种掺杂态聚苯胺的性能及应用,简要介绍了影响聚苯胺性能的因素,并比较了不同掺杂态聚苯胺的优缺点。分析结果表明：与单一有机酸掺杂的聚苯胺相比,采用两种类型的掺杂剂共掺杂合成的聚苯胺具有更突出的性能及更大的应用前景。提出了采用两种或两种以上不同类型的掺杂剂共掺杂将是聚苯胺今后的主要研究方向。     

聚苯胺的发展及其防腐性能研究

聚苯胺由于其良好的性能受到广泛的关注。首先综述了聚苯胺在国内外的发展的概况,以聚苯胺的独特性能、化学结构、聚合机理以及聚合工艺作为出发点,研究了聚苯胺的防腐机理及其应用,并且对将来聚苯胺的生产工艺流程和新型的聚苯胺复合材料的防腐涂层制备技术的研究方向进行了展望。     

聚苯胺及其衍生物在防腐领域中的应用进展

概述了聚苯胺的结构、性质及其防腐机理。聚苯胺主要通过其屏蔽作用在金属表面促进形成钝化层和提高金属氧化电位,降低金属材料的腐蚀速度。因此,聚苯胺经常被用做缓蚀剂、聚苯胺防腐涂层和防腐涂层的添加剂。相较于缓蚀剂与聚苯胺涂层,聚苯胺复合涂层具有优异的防腐性能。综述了近年来聚苯胺及其衍生物在防腐领域的进展,提出了聚苯胺在防腐应用中需进一步解决的问题。     

聚苯胺防腐涂料的研究现状

聚苯胺(PANI)是一种新型的金属防腐保护材料,与常规缓蚀剂相比没有任何的环境副作用,是一种符合时代和科技发展的绿色缓蚀剂,成为当前研究最多的导电高分子材料。本文概述了国内外聚苯胺防腐蚀涂料的研究情况,具体涉及聚苯胺的结构、性能和聚苯胺防腐蚀涂层的制备方法。指出了聚苯胺研究中存在的问题,应用现状和对其发展前景的展望。     

导电聚苯胺的制备及其在防腐涂料中的应用

介绍了导电聚苯胺的结构、性能特点,概述了制备聚苯胺的常用方法：化学氧化聚合法和电化学法,并介绍了导电聚苯胺的防腐机理及其在防腐涂料中的应用研究进展。     

新型水基聚苯胺复合防腐涂料的制备及其性能研究

以原位包覆法制备的聚苯胺复合材料为主要防腐成分,以聚合物乳液为成膜物,制成新型水基聚苯胺复合防腐涂料,对其涂膜的防腐性能进行电化学测试,证明其具备优异的防腐性能。     

聚苯胺／环氧树脂共混防腐涂料的研究进展

聚苯胺具有优异的防腐蚀性,但是由于其在一般有机溶剂中的溶解性差,且其制成的涂膜附着力差等因素,通常将其与其它涂料复配,以改善涂膜性能;环氧树脂涂料具有附着力强、强度高、耐化学品、耐磨等特点,环氧树脂优异的成膜性和聚苯胺的防腐性能相结合,使聚苯胺／环氧共混涂料具有广阔的应用前景,就聚苯胺与环氧共混涂料的研究进展作了简述。     

Investigation on anticorrosion performance of nano and micro polyaniline in new water-based epoxy coating

In this research, a micro polyaniline (MicroPAni) and a dispersion of nano polyaniline particles (NanoPAni) were used as anticorrosion additive in a new water-based epoxy coating. Both materials were added directly to a new water-based hardener (RIPI-W.B.H.). The resulted mixtures were homogenized and sonicated for size reduction and better particle dispersion. The average particle size of polyaniline in the hardener was determined using dynamic light scattering (DLS). Transmission electron microscopy (TEM) was used to observe the particle size of polyaniline in the final dried film. After applying the coatings on metal surface, anticorrosion performance and adhesion properties of the coatings were compared together with a reference coating using salt spray and cross-cut adhesion tests. The results showed that anticorrosion performance of coating containing NanoPAni was better than the one for coating containing MicroPAni. In addition, investigation on the morphology of metal-coating interface by scanning electron microscopy (SEM) technique in samples containing polyaniline after salt spray test showed stable oxide layer formation on metal surface, which will enhance the corrosion resistance.     

聚苯胺/无机粒子复合材料的研究进展

主要综述了纳米聚苯胺与无机粒子(如无机磁性粒子、金属氧化物、碳基无机物等其他无机粒子)复合制备的功能性复合材料的力学、光学、电学和磁学性能以及此类功能性复合材料在金属防腐和防污、电磁屏蔽、光学催化、电池材料以及化学传感器等方面的应用前景,并介绍了近几年来各类纳米聚苯胺/无机粒子功能性复合材料在电磁屏蔽、隐身材料、抗静电材料、导电高分子电容器、发光二极管以及二次电池等方面的研究现状及未来发展趋势.     

Anticorrosion performance of polyaniline nanostructures on mild steel

Different one-dimensional nanostructured polyanilines were synthesized in sulfuric acid solutions by conventional polymerization, interfacial polymerization and direct mixed reaction, respectively. The products were characterized with SEM, UV–vis and FTIR and the anticorrosion performance of products on mild steel were studied using electrochemical measurement in 3.5% NaCl aqueous solution. Results showed that the polyaniline nanofibers synthesized by direct mixed reaction have uniform morphology with diameters of 60–100 nm and more excellent protective properties than conventional aggregated polyaniline. Comparative studies revealed that the nanostructure and morphology of polyaniline could influence its anticorrosion performance.     

Anticorrosion properties of inorganic pigments surface-modified with a polyaniline phosphate layer

The paper deals with research into the effects of treating the surface of pigment particles with polyaniline layers in anticorrosion paints. The pigments involved were tested in a form coated with a polyaniline layer and in an uncoated form. To study anticorrosion properties, mixed metal oxides with the structure of spinel and perovskite were synthesized to be later coated with polyaniline. Polyaniline was also used to coat the pigments based on iron trioxide, silicates and graphite. Water-borne, epoxy resin-based paints containing the pigments with and without the surface layer of polyaniline were formulated. The coatings were tested by means of laboratory corrosion tests. These involved corrosion tests accelerated with an increased temperature, with high atmospheric humidity, and with the presence of corroding substances such as SO₂ and NaCl.