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高吸盐水型树脂的合成及其影响因素 总被引:1,自引:0,他引:1
以(NH4)2S2O8和NaHSO3为氧化还原引发剂,采用水溶液法合成了丙烯酸钠-丙烯酰胺-疏水单体共聚高吸水性树脂.研究了单体聚合浓度、单体含量及引发剂用量等对共聚高吸水树脂吸水率的影响.实验表明,在单体聚合浓度为30%,丙烯酰胺、丙烯酸与疏水单体的质量比为6.7∶9∶1,丙烯酸中和度80%,引发剂用量0.25%时,该聚合物吸水率、耐盐性最好. 相似文献
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马来酸单酯聚合物复鞣加脂剂的制备与性能 总被引:1,自引:1,他引:0
以长链脂肪醇马来酸单酯为亲油单体,丙烯酸为亲水单体,过硫酸铵为引发剂,采用活泼单体滴加方式制备了马来酸单酯聚合物复鞣加脂剂。通过质谱和热重-差热分析对聚合物结构进行了表征。考察了脂肪醇种类,丙烯酸单体滴加速度,单酯与丙烯酸摩尔比和引发剂用量等因素对聚合物性能的影响。结果表明,当脂肪醇为十六醇,n(丙烯酸)/n(单酯)=2.0,过硫酸铵占单体总质量的5%,聚合温度80℃,丙烯酸滴加时间2h时,所得产品具有较好的柔软、填充和防水性能,处理革的增厚率在30%左右,静态吸水率在60%左右。 相似文献
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丙烯酸类聚合物分散剂的制备 总被引:3,自引:0,他引:3
探讨了影响丙烯酸类聚合物分散剂聚合的单体、引发剂、链转移剂以及温度、聚合时间的因素。按照分散剂溶于水后可电离出的分散剂离子的类型,将含丙烯酸的聚合物分散剂进行分类。综述了此类分散剂制备方法和工艺条件。 相似文献
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以氧化还原引发剂(NH4)2S2O8和N aHSO3为引发剂,采用水溶液法合成了丙烯酸钠—丙烯酰胺—疏水单体共聚高吸水性树脂。研究了单体聚合浓度、单体含量及引发剂用量等对共聚高吸水树脂吸水率的影响。实验证明该高吸水聚合物耐盐性较好。 相似文献
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以丙烯酸(AA)、甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)和苯乙烯(ST)为聚合单体,过氧化二苯甲酰(BPO)作引发剂,合成出一种新型丙烯酸类四元共聚破乳剂。考查了各单体配比及引发剂用量对破乳脱水效果的影响。结果表明单体质量比AA∶MMA∶BA∶ST为7∶23∶55∶15,单体总量45 g,引发剂用量1.0 g,合成的聚合物的破乳效果最好。说明丙烯酸类共聚物引入苯乙烯进行改性具有良好的破乳效果。 相似文献
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综述了合成阳离子丙烯酸系聚合物乳液的乳化剂、引发剂及单体体系和聚合方法,介绍了阳离子乳液的性质和应用。 相似文献
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水溶液聚合法合成高吸水性树脂的研究 总被引:1,自引:0,他引:1
以N,N-亚甲基双丙烯酰胺为交联剂,过硫酸钾-亚硫酸氢钠为引发剂,以丙烯酸和丙烯酰胺为单体,采用水溶液聚合法合成了丙烯酸-丙烯酰胺共聚的吸水树脂,并探讨了单体浓度、单体质量比、丙烯酸中和度、交联剂用量、引发剂用量对吸水树脂吸水量的影响,最大吸水率为799.3 g/g。 相似文献
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以醚化预处理玉米秸秆(PTCS)为基体,丙烯酸(AA)和丙烯酰胺(AM)为单体,过硫酸钾为引发剂,N,N'-亚甲基双丙烯酰胺(MBA)为交联剂,采用水溶液聚合法制备PTCS接枝AA、AM共聚物[PTCS-g-P(AA-co-AM)]。研究了合成条件对树脂吸水率的影响,考察了树脂重复吸水和保水性能,并用红外光谱(FTIR)、电子扫描电镜(SEM)表征了产物的结构和形貌。结果表明,在m(PTCS):m(AA):m(AM)= 1:5:2,丙烯酸中和度为70%,K2S2O8为0.6%,MBA为0.2%,60℃反应3h条件下,制备高吸水性树脂的吸水率最大,对蒸馏水和0.9% NaCl水溶液的吸水率分别为144.04g/g、30.60g/g,且重复吸水和保水性能良好。 相似文献
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淀粉接枝丙烯酸类超强吸水剂的结构、吸水机理和商业应用 总被引:2,自引:0,他引:2
淀粉接枝丙烯酸类超强吸水剂在各个领域的应用越来越广泛。本文简述了淀粉接枝丙烯酸类超强吸水剂的结构和吸水机理,并主要介绍了淀粉接枝丙烯酸类超强吸水剂目前的一些商业应用,包括在生理卫生用品、土木建筑、食品、农业、医药等方面的应用,同时对淀粉接枝丙烯酸类超强吸水剂的发展前景进行了展望。 相似文献
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以交联聚天冬氨酸(PAsp)、丙烯酸(AAc)为原料,以过硫酸钾为引发剂,以N,N′-亚甲基双丙烯酰胺为交联剂,采用分步法制备了聚天冬氨酸/聚丙烯酸(PAAc)互穿网络吸水性树脂(IPNAP),并对其结构进行了表征,探讨了AAc与PAsp质量比、引发剂用量(以单体质量计,下同)、交联剂用量(以单体质量计,下同)、AAc中和度对IPNAP吸液性能的影响。结果表明,当AAc与PAsp质量比为1.0∶1、引发剂用量为0.50%、交联剂用量为0.40%、AAc中和度为75%时,IPNAP的吸液性能最好,在蒸馏水和生理盐水中的吸液倍率分别达到826g·g-1和120g·g-1。 相似文献
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Converting biomass into value-added products has attracted great attention in recent years. In this paper, a facile approach for using date seed powder without delignification is introduced to convert date seed biomass into a water-absorbing polymer. The biomass of date seed as a source of polysaccharides was immersed in the emulsions of acrylic microgels with different chemical structures. Different polymer latexes based on acrylic acid (AA), sodium acrylate (SA), acrylamide (AM) and 2-acrylamide-2-methyl propane sulfonic acid (AMPS) were prepared using inverse emulsion polymerization. A chemical reaction was carried out between date seed and acrylic latex by heating, which caused the conversion of date seed into a semi-synthetic hydrogel with 60 % natural and 40 % synthetic components. The best modification of date seed to absorbing hydrogel was obtained with poly(AA–SA–AM–AMPS). The modified date seed with this latex had water absorbency of up to 71 g/g, while the unmodified date seed had only 0.2 g/g water absorbency. Date seed hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR), dynamic mechanical thermal analysis (DMTA), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), rheometric analysis and swelling measurement. The effect of several modifications of parameters such as latex type, AMPS content in latex, aquatic–organic phase ratios of latex and modification temperature on the swelling properties of hydrogel was investigated. The obtained hybrid hydrogel based on date seed biomass contained a considerable amount of biomass in its structure as well as 71 g/g water absorbency, which can be a proper candidate for agricultural applications. 相似文献
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接枝共聚法制备高吸水性树脂 总被引:4,自引:0,他引:4
以过硫酸钾为引发剂,过硫酸钾与玉米淀粉质量比为0.014,糊化的玉米淀粉与丙烯酸按质量比1:6发生接枝共聚反应,反应温度50℃,反应时间约3.0h,丙烯酸中和度为92%,制得的高吸水性树脂吸收自来水的能力可达560g/g。 相似文献
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A novel method is presented for the construction of a hierarchical microstructure/nanostructure via the chemical self‐assembly of poly(N‐isopropyl acrylamide‐co‐acrylic acid) particles on polyester fibers. The textile of the particle‐bound fibers possessed smart wettability and an oil‐absorbing capacity. The wettability was dependent on the initial contact angle and spreading time of water droplets on the particle‐bound textile, which could be controlled with the content of acrylic acid inserted into the polymer chains. The wettability of the particle‐bound textile was responsive to the pH value. In addition, the textile was superoleophilic on an air–solid surface and could absorb oil quickly from water. The oil‐absorbing capacity could be controlled by the alteration of the pH value. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46834. 相似文献
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Jihuai Wu Zhang Lan Jianming Lin Miaoliang Huang Shancun Hao Leqing Fang 《Electrochimica acta》2007,52(24):7128-7135
The influence of solvents on the property of poly (acrylic acid)-oligo-(ethylene glycol) polymer gel electrolyte and photovoltaic performance of quasi-solid-state dye-sensitized solar cells (DSSCs) were investigated. Solvents or mixed solvents with large donor number enhance the liquid electrolyte absorbency, which further influences the ionic conductivity of polymer gel electrolyte. A polymer gel electrolyte with ionic conductivity of 4.45 mS cm−1 was obtained by using poly (acrylic acid)-oligo-(ethylene glycol) as polymer matrix, and absorbing 30 vol.% N-methyl pyrrolidone and 70 vol.% γ-butyrolactone with 0.5 M NaI and 0.05 M I2. By using this polymer gel electrolyte coupling with 0.4 M pyridine additive, a quasi-solid-state dye-sensitized solar cell with conversion efficiency of 4.74% was obtained under irradiation of 100 mW cm−2 (AM 1.5). 相似文献