Hydrodynamic Study of Gas–Solid Internally Circulating Fluidized Bed Using Multiphase CFD Model

In the present work, hydrodynamic study of gas and solid flow in an internally circulating fluidized bed (ICFB) was carried out using the CFD multiphase model. Two- (2D) and three-dimensional (3D) computational meshes were used to represent physical ICFB geometries of 0.186-m and 0.3-m diameter columns. The model approach uses the two-fluid Eulerian model with kinetic theory of granular flow options to account particle–particle and particle–wall interactions. The model also uses various drag laws to account the gas–solid phase interactions. The 2D simulation results by various drag laws show that the Arastoopour and Gibilaro drag models predict the fluidization dynamics in terms of flow patterns, void fractions, and axial velocity fields in close agreement with the Ahuja et al. (2008 Ahuja, G. N., and A. W. Patwardhan. 2008. CFD and experimental studies of solids hold-up distribution and circulation patterns in gas–solid fluidized beds. Chemical Engineering Journal 143:147–160.[Crossref], [Web of Science ®] , [Google Scholar]) experimental data. Three dimensional simulations were also carried out for a large-scale ICFB. The effects of superficial gas velocity and the presence of draft tube on solid holdup distribution, solid recirculation pattern, and gas bypassing dynamics for the 3D ICFB were investigated extensively. The mechanism governing the solid circulation and the pressure losses in an ICFB has been explained based on gas and solid dynamics obtained from these simulations. Predicted total granular temperature distributions in 3D ICFB draft tube and the annular zone are qualitatively in agreement with the experimental data. The total granular temperature tends to increase with the increase in solids concentration in the dilute region (? < 0.1) and decrease with an increase of solids concentration in the dense region (? > 0.1).     

Investigation of Waves Interaction in Annular Gas–Liquid Flow Using High-Speed Fluorescent Visualization Technique

High-speed fluorescent visualization complex has been developed for quantitative investigation of the process of interaction of waves on liquid film in annular two-phase flow. Evolution of ripples on disturbance waves surface and disturbance waves coalescence are investigated. It is shown that all the ripples in presence of disturbance waves appear at the base of the back front of disturbance waves and then either decelerate, travel on substrate and are overtaken by the following disturbance wave or accelerate, grow and then disappear at the front of disturbance wave. The disappearance happens due to entrainment of liquid into the core of gas stream. Several scenarios of coalescence of disturbance waves were identified. For disturbance waves with close velocities different types of remote interaction were observed.     

Estimation of the Heat Transfer Coefficient in a Liquid–Solid Fluidized Bed Using an Artificial Neural Network

A non-iterative procedure has been developed using an artificial neural network (ANN) for estimating the fluid–particle heat transfer coefficient, h_fp, in a liquid–solid fluidized system. It is assumed that in a liquid–solid system, the liquid temperature is time dependent, and the input parameters and output parameters for the ANN are considered on a linear scale. The output configuration yields an optimal ANN model with 10 neurons in each of the three hidden layers. This configuration is capable of predicting the value of Bi in the range of 0.1–10 with an error of less than 3%. The heat transfer coefficient estimated using the ANN has been compared with the data reported in the literature and found to match satisfactorily.© Koninklijke Brill NV, Leiden and Society of Powder Technology, Japan, 2008     

Bubble Coalescence in Gas–Liquid Flow at Microgravity Conditions

Bubbly flow at microgravity conditions is investigated experimentally. The evolution of bubble size has been measured in tubes of various diameters (6 to 40 mm). It is shown that the bubble size significantly increases along the tube due to coalescence. To predict the bubble size distribution along the tube a mechanistic model based on the transport equations of the moment of the bubble-diameter distribution has been developed. In these equations the coalescence rate is modeled in taking into account the two mechanisms of bubble coalescence encountered in microgravity: the turbulence-induced coalescence and the shear-induced coalescence. The results of the model are then compared to the experimental data.     

The Study of Performance in a Novel Gas–Solid Separator

The three slit-type separator is a new separator which can shorten the residence time of oil & gas and improve the separation efficiency. In this study, a critical validation was carried out to examine the separation performances of the three slit-type separator with different inlet velocity and inlet concentration. According to the experimental results, the separation efficiency and pressure drop of the three slit-type separator increase with the increase of inlet velocity and inlet concentration. Numerical simulation of the gas–solid flow field in the three slit-type separator was carried out by the use of Fluent 15.0 platform. The simulated results coincide with the experimental results. The particles move along the inside wall of the separator in the vaulted space, meanwhile, more gas enters into the exhaust pipe through slots, which can improve the separation efficiency. The study shows that the residence time of oil and gas is less than 0.6 and the separation efficiency is up to 99% in the separator, in addition, the pressure drop could be controlled in 4 kPa below.     

Investigation of Secondary Waves Dynamics in Annular Gas–Liquid Flow

Annular gas–liquid flow was investigated using high-speed modification of LIF technique. The evolution of liquid film surface was studied with high spatial and temporal resolution. It was found that all waves may be classified into primary and secondary waves; all the secondary waves arise due to instability of the back fronts of primary waves. The areas of inception and velocity of secondary waves were compared for annular flow with and without entrainment. The similarities and differences of wavy structure in both cases were demonstrated.     

Experimental Study of Gas–Liquid Two-Phase Flow in Glass Micromodels

To estimate the most important flow variables in reservoir engineering, such as the relative permeability, it is required to know with high precision, other variables such as saturation, pressure drop of each phase, and porous media data such as porosity and absolute permeability. In this study, experimental tests were performed inside a glass micromodel using gas–liquid two-phase flow in steady-state conditions. The liquid-phase flow and the pressure drop of the porous media were determined. Additionally, the flow development inside the porous media was visualized using a high-speed video camera system. These pictures were recorded at 500 fps, and they were used to compute the phase saturation and the gas velocity in the glass micromodel. The visualization was performed in three regions of the glass micromodel demonstrating that saturation gradients were not present. The effect of the capillary number was studied over the gas–liquid relative permeability curves and on the flow mechanisms. It was concluded that high flow rates minimize edge effects, that the capillary number modifies the relative permeability values and the flow patterns inside the micromodel, and that the high-speed visualization is an efficient and accurate technique to determine saturation values and to study the flow patterns in transparent porous media such as glass micromodels.     

Evaluation of Erosion Corrosion in Liquid–Solid and Liquid–Gas via Experimental Analysis Inside 90° Copper Elbow

Erosion–corrosion experiments of copper elbow were performed by acidified dichromate. Mass transfer coefficient inside 90° copper elbow has been investigated. The results showed that the mass transfer coefficient increases as solution velocity increases in both cases of one- and two-phase flow. The mass transfer coefficient can be related to the solution velocity in case one-phase flow by the following equations:

$$k \, \alpha \, v^{ 0. 4 4}\quad{\text{for\,Sc\,from\,678 to 845}}$$

$$k \, \alpha \, v^{ 0. 3}\quad{\text{for\,Sc\,from\,1040\,to\,1445}}$$

In case of liquid–solid flow

$$k \, \alpha \, v^{ 0. 3 3}$$

In case of liquid–gas flow

$$k \, \alpha \, vg^{ 0. 2 4}$$

The importance of these equations is to understand and predict erosion corrosion inside 90^o copper elbow.

     

Erosion–Corrosion Behavior of 20Cr Steel in Corrosive Solid–Liquid Two-Phase Flow Conditions

Journal of Failure Analysis and Prevention - An experimental study was conducted on erosion–corrosion (E–C) properties of 20Cr (Chinese steel grade) steel. Three corrosive...     

Optical and Electron Spin Resonance Studies of Destruction of Porous Structures Formed by Nitrogen–Rare Gas Nanoclusters in Bulk Superfluid Helium

We studied optical and electron spin resonance spectra during destruction of porous structures formed by nitrogen–rare gas (RG) nanoclusters in bulk superfluid helium containing high concentrations of stabilized nitrogen atoms. Samples were created by injecting products of a radio frequency discharge of nitrogen–rare gas–helium gas mixtures into bulk superfluid helium. These samples have a high energy density allowing the study of energy release in chemical processes inside of nanocluster aggregates. The rare gases used in the studies were neon, argon, and krypton. We also studied the effects of changing the relative concentrations between nitrogen and rare gas on thermoluminescence spectra during destruction of the samples. At the beginning of the destructions, \(\alpha \)-group of nitrogen atoms, Vegard–Kaplan bands of \(\hbox {N}_2\) molecules, and \(\beta \)-group of O atoms were observed. The final destruction of the samples were characterized by a series bright flashes. Spectra obtained during these flashes contain M- and \(\beta \)-bands of NO molecules, the intensities of which depend on the concentration of molecular nitrogen in the gas mixture as well as the type of rare gas present in the gas mixture.     

Solid state phase transformations in Ti–Al–C and Ti–Al–Nb–C alloys

Abstract

Results are reported of an investigation of solid state transformations in a series of α₂ based alloys having an aluminium content of 26 at.-% with carbon up to 3 at.-%; two α₂ basedquaternary Ti–Al–Nb–C alloys with 5 and 12 at.-%Nb and 3 at.-%C were also studied. Ordering occurs in the ternary Ti–Al–C alloys and also in the 23Al–5Nb–3C alloy on quenchingfrom 1250°C. Additional carbide precipitation was not observed in the ternary Ti–Al–C alloys on reheating to 750°C. Additions of niobium resulted in the presence of the β phase at 1050°C in the 5%Nb alloy and at 1050 and 750°C in the 12%Nb alloy. In the quaternary Ti–Al–Nb–C alloys, (Ti, Nb)₃AlC was found to be the primary phase and was present in the microstructure over the temperature range studied. In the 21Al–12Nb–3C alloy, the ordered β phase transformed to α″₂ martensite on quenching from 1250;amp;#x00B0;C.

MST/1306     

Heat and Mass Transfer in a Two‐Component Developed Turbulent Gas‐Vapor‐Droplet Flow

A calculation model is developed and a numerical study is made of the heat and mass transfer characteristics in a turbulent gas–vapor–droplet flow moving in a round tube. The model takes into account the evaporation of droplets, the diffusion of vapor into air, and the acceleration of a carrier flow. Distributions of the parameters of the twophase flow are obtained with respect to the tube radius for different initial concentrations of the gas phase. Heat and masstransfer calculations are compared to the experimental and numerical works. On the whole, the evaporation of the droplets in the vaporgas flow leads to the intensification of heat transfer as compared to a onecomponent vapordroplet flow and singlephase flow of vapor.     

Experimental Observation of 2 – Anion and its para → ortho Conversion in Solid para hydrogen Using High–Resolution ESR Spectroscopy

We present experimental observations and study of in solid parahydrogen. Since the parahydrogen molecule does not produce local magnetic fields, high–resolution ESR spectra of trapped radicals can be observed in the solid parahydrogen matrices. Using this high–resolution ESR spectroscopy, new quartet ESR signals were observed in –rays irradiated solid parahydrogen and assigned as In addition, para– was observed to convert into ortho– on the storage at 4.2 K. On the other hand, ortho–H ₂ molecule converts into para– at cryogenic temperatures. The difference in the conversion between the H ₂ molecule and the anion is explained by the parity conservation law of wavefunctions on exchanging the protons in homonuclear diatomic molecules such as the anion and H ₂ molecule.     

Thermophysical Properties of a Chromium–Nickel–Molybdenum Steel in the Solid and Liquid Phases

Numerical simulation of vacuum arc re-melting, pressurized or protective electro-slag re-melting, and ingot casting have become quite important in the metal industry. However, a major drawback of these simulation techniques is the lack of accurate thermophysical properties for temperatures above 1,500 K. Heat capacity, heat of fusion, density, and thermal conductivity are important input parameters for the heat transfer equation. Since, direct measurements of thermal conductivity of alloys in the liquid state are almost impossible, its estimation from electrical conductivity using the Wiedemann–Franz law is very useful. The afore-mentioned thermophysical properties of several steels are investigated within the context of an ongoing project. Here, we present a full set of thermophysical data for the chromium–nickel–molybdenum steel meeting the standard DIN 1.4435 (X2CrNiMo18-14-3); these values will be used by our partner to simulate various re-melting and solidification processes. Wire-shaped samples of the steel are resistively volume-heated, as part of a fast capacitor discharge circuit. Time-resolved measurements with sub-μs resolution of current through the specimen are performed with a Pearson probe. The voltage drop across the specimen is measured with knife-edge contacts and ohmic voltage dividers, the temperature of the sample with a pyrometer, and the volumetric expansion of the wire with a fast acting CCD camera. These measurements enable the heat of fusion, the heat capacity, and the electrical resistivity to be determined as a function of temperature in the solid and liquid phases. The thermal conductivity and thermal diffusivity are estimated via the Wiedemann–Franz law.