Energy recovery in petrochemical complexes through heat integration retrofit analysis

This paper proposes the principles of how to define a boundary for heat integration in petrochemical complexes which are composed of several interconnected processing units. In order to obtain retrofit schemes that offer significant energy saving potential and are easy to implement, heat integration strategies are also developed in this study. Two case studies based on an aniline plant and an aromatic hydrocarbon plant, each one comprising several processing units, are presented to illustrate the application of these principles and strategies. The boundary for heat integration in each plant can be the whole plant or its individual processing units, the choice of which is determined by their energy saving potentials. Based on energy saving potential, each processing unit in the aniline plant was selected as the boundary for heat integration. The boundary for heat integration in the aromatic hydrocarbon plant, by contrast, was the whole plant. Retrofit schemes for the heat exchanger networks of the two plants, developed using pinch analysis, revealed that significant heating utility savings could be realized with a small number of network structure modifications.     

Effects of coal characteristics to performance of a highly efficient thermal power generation system based on pressurized oxy‐fuel combustion

Because of its fuel flexibility and high efficiency, pressurized oxy‐fuel combustion has recently emerged as a promising approach for efficient carbon capture and storage. One of the important options to design the pressurized oxy‐combustion is to determine method of coal (or other solid fuels) feeding: dry feeding or wet (coal slurry) feeding as well as grade of coals. The main aim of this research is to investigate effects of coal characteristics including wet or dry feeding on the performance of thermal power plant based on the pressurized oxy‐combustion with CO₂ capture versus atmospheric oxy‐combustion. A commercial process simulation tool (gCCS: the general carbon capture and storage) was used to simulate and analyze an advanced ultra‐supercritical(A‐USC) coal power plant under pressurized and atmospheric oxy‐fuel conditions. The design concept is based on using pure oxygen as an oxidant in a pressurized system to maximize the heat recovery through process integration and to reduce the efficiency penalty because of compression and purification units. The results indicate that the pressurized case efficiency at 30 bars was greater than the atmospheric oxy‐fuel combustion (base line case) by 6.02% when using lignite coal firing. Similarly, efficiency improvements in the case of subbituminous and bituminous coals were around 3% and 2.61%, respectively. The purity of CO₂ increased from 53.4% to 94% after compression and purification. In addition, the study observed the effects of coal‐water slurry using bituminous coal under atmospheric conditions, determining that the net plant efficiency decreased by 3.7% when the water content in the slurry increased from 11.12% to 54%. Copyright © 2016 John Wiley & Sons, Ltd.