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1.
Naphthodithiophene‐Based Nonfullerene Acceptor for High‐Performance Organic Photovoltaics: Effect of Extended Conjugation
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Jingshuai Zhu Zhifan Ke Qianqian Zhang Jiayu Wang Shuixing Dai Yang Wu Ye Xu Yuze Lin Wei Ma Wei You Xiaowei Zhan 《Advanced materials (Deerfield Beach, Fla.)》2018,30(2)
Naphtho[1,2‐b:5,6‐b′]dithiophene is extended to a fused octacyclic building block, which is end capped by strong electron‐withdrawing 2‐(5,6‐difluoro‐3‐oxo‐2,3‐dihydro‐1H‐inden‐1‐ylidene)malononitrile to yield a fused‐ring electron acceptor (IOIC2) for organic solar cells (OSCs). Relative to naphthalene‐based IHIC2, naphthodithiophene‐based IOIC2 with a larger π‐conjugation and a stronger electron‐donating core shows a higher lowest unoccupied molecular orbital energy level (IOIC2: ?3.78 eV vs IHIC2: ?3.86 eV), broader absorption with a smaller optical bandgap (IOIC2: 1.55 eV vs IHIC2: 1.66 eV), and a higher electron mobility (IOIC2: 1.0 × 10?3 cm2 V?1 s?1 vs IHIC2: 5.0 × 10?4 cm2 V?1 s?1). Thus, IOIC2‐based OSCs show higher values in open‐circuit voltage, short‐circuit current density, fill factor, and thereby much higher power conversion efficiency (PCE) values than those of the IHIC2‐based counterpart. In particular, as‐cast OSCs based on FTAZ: IOIC2 yield PCEs of up to 11.2%, higher than that of the control devices based on FTAZ: IHIC2 (7.45%). Furthermore, by using 0.2% 1,8‐diiodooctane as the processing additive, a PCE of 12.3% is achieved from the FTAZ:IOIC2 ‐ based devices, higher than that of the FTAZ:IHIC2 ‐ based devices (7.31%). These results indicate that incorporating extended conjugation into the electron‐donating fused‐ring units in nonfullerene acceptors is a promising strategy for designing high‐performance electron acceptors. 相似文献
2.
Jun Yuan Yunqiang Zhang Liuyang Zhou Chujun Zhang Tsz‐Ki Lau Guichuan Zhang Xinhui Lu Hin‐Lap Yip Shu Kong So Serge Beaupr Mathieu Mainville Paul A. Johnson Mario Leclerc Honggang Chen Hongjian Peng Yongfang Li Yingping Zou 《Advanced materials (Deerfield Beach, Fla.)》2019,31(17)
Narrow bandgap n‐type organic semiconductors (n‐OS) have attracted great attention in recent years as acceptors in organic solar cells (OSCs), due to their easily tuned absorption and electronic energy levels in comparison with fullerene acceptors. Herein, a new n‐OS acceptor, Y5, with an electron‐deficient‐core‐based fused structure is designed and synthesized, which exhibits a strong absorption in the 600–900 nm region with an extinction coefficient of 1.24 × 105 cm?1, and an electron mobility of 2.11 × 10?4 cm2 V?1 s?1. By blending Y5 with three types of common medium‐bandgap polymers (J61, PBDB‐T, and TTFQx‐T1) as donors, all devices exhibit high short‐circuit current densities over 20 mA cm?2. As a result, the power conversion efficiency of the Y5‐based OSCs with J61, TTFQx‐T1, and PBDB‐T reaches 11.0%, 13.1%, and 14.1%, respectively. This indicates that Y5 is a universal and highly efficient n‐OS acceptor for applications in organic solar cells. 相似文献
3.
Fused Tris(thienothiophene)‐Based Electron Acceptor with Strong Near‐Infrared Absorption for High‐Performance As‐Cast Solar Cells
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Tengfei Li Shuixing Dai Zhifan Ke Langxuan Yang Jiayu Wang Cenqi Yan Wei Ma Xiaowei Zhan 《Advanced materials (Deerfield Beach, Fla.)》2018,30(10)
A fused tris(thienothiophene) (3TT) building block is designed and synthesized with strong electron‐donating and molecular packing properties, where three thienothiophene units are condensed with two cyclopentadienyl rings. Based on 3TT, a fused octacylic electron acceptor (FOIC) is designed and synthesized, using strong electron‐withdrawing 2‐(5/6‐fluoro‐3‐oxo‐2,3‐dihydro‐1H‐inden‐1‐ylidene)‐malononitrile as end groups. FOIC exhibits absorption in 600–950 nm region peaked at 836 nm with extinction coefficient of up to 2 × 105m –1 cm–1, low bandgap of 1.32 eV, and high electron mobility of 1.2 × 10–3 cm2 V–1 s–1. Compared with its counterpart ITIC3 based on indacenothienothiophene core, FOIC exhibits significantly upshifted highest occupied molecular orbital level, slightly downshifted lowest unoccupied molecular orbital level, significantly redshifted absorption, and higher mobility. The as‐cast organic solar cells (OSCs) based on blends of PTB7‐Th donor and FOIC acceptor without additional treatments exhibit power conversion efficiencies (PCEs) as high as 12.0%, which is much higher than that of PTB7‐Th: ITIC3 (8.09%). The as‐cast semitransparent OSCs based on the same blends show PCEs of up to 10.3% with an average visible transmittance of 37.4%. 相似文献
4.
Fuwen Zhao Shuixing Dai Yang Wu Qianqian Zhang Jiayu Wang Li Jiang Qidan Ling Zhixiang Wei Wei Ma Wei You Chunru Wang Xiaowei Zhan 《Advanced materials (Deerfield Beach, Fla.)》2017,29(18)
A new fluorinated nonfullerene acceptor, ITIC‐Th1, has been designed and synthesized by introducing fluorine (F) atoms onto the end‐capping group 1,1‐dicyanomethylene‐3‐indanone (IC). On the one hand, incorporation of F would improve intramolecular interaction, enhance the push–pull effect between the donor unit indacenodithieno[3,2‐b]thiophene and the acceptor unit IC due to electron‐withdrawing effect of F, and finally adjust energy levels and reduce bandgap, which is beneficial to light harvesting and enhancing short‐circuit current density (J SC). On the other hand, incorporation of F would improve intermolecular interactions through C? F···S, C? F···H, and C? F···π noncovalent interactions and enhance electron mobility, which is beneficial to enhancing J SC and fill factor. Indeed, the results show that fluorinated ITIC‐Th1 exhibits redshifted absorption, smaller optical bandgap, and higher electron mobility than the nonfluorinated ITIC‐Th. Furthermore, nonfullerene organic solar cells (OSCs) based on fluorinated ITIC‐Th1 electron acceptor and a wide‐bandgap polymer donor FTAZ based on benzodithiophene and benzotriazole exhibit power conversion efficiency (PCE) as high as 12.1%, significantly higher than that of nonfluorinated ITIC‐Th (8.88%). The PCE of 12.1% is the highest in fullerene and nonfullerene‐based single‐junction binary‐blend OSCs. Moreover, the OSCs based on FTAZ:ITIC‐Th1 show much better efficiency and better stability than the control devices based on FTAZ:PC71BM (PCE = 5.22%). 相似文献
5.
Jiayu Wang Wei Wang Xiaohui Wang Yang Wu Qianqian Zhang Cenqi Yan Wei Ma Wei You Xiaowei Zhan 《Advanced materials (Deerfield Beach, Fla.)》2017,29(35)
A side‐chain conjugation strategy in the design of nonfullerene electron acceptors is proposed, with the design and synthesis of a side‐chain‐conjugated acceptor (ITIC2) based on a 4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b :4,5‐b′ ]di(cyclopenta‐dithiophene) electron‐donating core and 1,1‐dicyanomethylene‐3‐indanone electron‐withdrawing end groups. ITIC2 with the conjugated side chains exhibits an absorption peak at 714 nm, which redshifts 12 nm relative to ITIC1. The absorption extinction coefficient of ITIC2 is 2.7 × 105m ?1 cm?1, higher than that of ITIC1 (1.5 × 105m ?1 cm?1). ITIC2 exhibits slightly higher highest occupied molecular orbital (HOMO) (?5.43 eV) and lowest unoccupied molecular orbital (LUMO) (?3.80 eV) energy levels relative to ITIC1 (HOMO: ?5.48 eV; LUMO: ?3.84 eV), and higher electron mobility (1.3 × 10?3 cm2 V?1 s?1) than that of ITIC1 (9.6 × 10?4 cm2 V?1 s?1). The power conversion efficiency of ITIC2‐based organic solar cells is 11.0%, much higher than that of ITIC1‐based control devices (8.54%). Our results demonstrate that side‐chain conjugation can tune energy levels, enhance absorption, and electron mobility, and finally enhance photovoltaic performance of nonfullerene acceptors. 相似文献
6.
Highly Efficient Ternary‐Blend Polymer Solar Cells Enabled by a Nonfullerene Acceptor and Two Polymer Donors with a Broad Composition Tolerance
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Xiaopeng Xu Zhaozhao Bi Wei Ma Zishuai Wang Wallace C. H. Choy Wenlin Wu Guangjun Zhang Ying Li Qiang Peng 《Advanced materials (Deerfield Beach, Fla.)》2017,29(46)
In this work, highly efficient ternary‐blend organic solar cells (TB‐OSCs) are reported based on a low‐bandgap copolymer of PTB7‐Th, a medium‐bandgap copolymer of PBDB‐T, and a wide‐bandgap small molecule of SFBRCN. The ternary‐blend layer exhibits a good complementary absorption in the range of 300–800 nm, in which PTB7‐Th and PBDB‐T have excellent miscibility with each other and a desirable phase separation with SFBRCN. In such devices, there exist multiple energy transfer pathways from PBDB‐T to PTB7‐Th, and from SFBRCN to the above two polymer donors. The hole‐back transfer from PTB7‐Th to PBDB‐T and multiple electron transfers between the acceptor and the donor materials are also observed for elevating the whole device performance. After systematically optimizing the weight ratio of PBDB‐T:PTB7‐Th:SFBRCN, a champion power conversion efficiency (PCE) of 12.27% is finally achieved with an open‐circuit voltage (V oc) of 0.93 V, a short‐circuit current density (J sc) of 17.86 mA cm?2, and a fill factor of 73.9%, which is the highest value for the ternary OSCs reported so far. Importantly, the TB‐OSCs exhibit a broad composition tolerance with a high PCE over 10% throughout the whole blend ratios. 相似文献
7.
Shengbin Shi Peng Chen Yao Chen Kui Feng Bin Liu Jianhua Chen Qiaogan Liao Bao Tu Jiasi Luo Mengyao Su Han Guo Myung‐Gil Kim Antonio Facchetti Xugang Guo 《Advanced materials (Deerfield Beach, Fla.)》2019,31(46)
Currently, n‐type acceptors in high‐performance all‐polymer solar cells (all‐PSCs) are dominated by imide‐functionalized polymers, which typically show medium bandgap. Herein, a novel narrow‐bandgap polymer, poly(5,6‐dicyano‐2,1,3‐benzothiadiazole‐alt‐indacenodithiophene) (DCNBT‐IDT), based on dicyanobenzothiadiazole without an imide group is reported. The strong electron‐withdrawing cyano functionality enables DCNBT‐IDT with n‐type character and, more importantly, alleviates the steric hindrance associated with typical imide groups. Compared to the benchmark poly(naphthalene diimide‐alt‐bithiophene) (N2200), DCNBT‐IDT shows a narrower bandgap (1.43 eV) with a much higher absorption coefficient (6.15 × 104 cm?1). Such properties are elusive for polymer acceptors to date, eradicating the drawbacks inherited in N2200 and other high‐performance polymer acceptors. When blended with a wide‐bandgap polymer donor, the DCNBT‐IDT‐based all‐PSCs achieve a remarkable power conversion efficiency of 8.32% with a small energy loss of 0.53 eV and a photoresponse of up to 870 nm. Such efficiency greatly outperforms those of N2200 (6.13%) and the naphthalene diimide (NDI)‐based analog NDI‐IDT (2.19%). This work breaks the long‐standing bottlenecks limiting materials innovation of n‐type polymers, which paves a new avenue for developing polymer acceptors with improved optoelectronic properties and heralds a brighter future of all‐PSCs. 相似文献
8.
Enhancing the Performance of Polymer Solar Cells via Core Engineering of NIR‐Absorbing Electron Acceptors
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Shuixing Dai Tengfei Li Wei Wang Yiqun Xiao Tsz‐Ki Lau Zeyuan Li Kuan Liu Xinhui Lu Xiaowei Zhan 《Advanced materials (Deerfield Beach, Fla.)》2018,30(15)
In order to utilize the near‐infrared (NIR) solar photons like silicon‐based solar cells, extensive research efforts have been devoted to the development of organic donor and acceptor materials with strong NIR absorption. However, single‐junction organic solar cells (OSCs) with photoresponse extending into >1000 nm and power conversion efficiency (PCE) >11% have rarely been reported. Herein, three fused‐ring electron acceptors with varying core size are reported. These three molecules exhibit strong absorption from 600 to 1000 nm and high electron mobility (>1 × 10?3 cm2 V?1 s?1). It is proposed that core engineering is a promising approach to elevate energy levels, enhance absorption and electron mobility, and finally achieve high device performance. This approach can maximize both short‐circuit current density ( JSC) and open‐circuit voltage (VOC) at the same time, differing from the commonly used end group engineering that is generally unable to realize simultaneous enhancement in both VOC and JSC. Finally, the single‐junction OSCs based on these acceptors in combination with the widely polymer donor PTB7‐Th yield JSC as high as 26.00 mA cm?2 and PCE as high as 12.3%. 相似文献
9.
A Twisted Thieno[3,4‐b]thiophene‐Based Electron Acceptor Featuring a 14‐π‐Electron Indenoindene Core for High‐Performance Organic Photovoltaics
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Sheng jie Xu Zichun Zhou Wuyue Liu Zhongbo Zhang Feng Liu Hongping Yan Xiaozhang Zhu 《Advanced materials (Deerfield Beach, Fla.)》2017,29(43)
With an indenoindene core, a new thieno[3,4‐b ]thiophene‐based small‐molecule electron acceptor, 2,2′‐((2Z,2′Z)‐((6,6′‐(5,5,10,10‐tetrakis(2‐ethylhexyl)‐5,10‐dihydroindeno[2,1‐a]indene‐2,7‐diyl)bis(2‐octylthieno[3,4‐b]thiophene‐6,4‐diyl))bis(methanylylidene))bis(5,6‐difluoro‐3‐oxo‐2,3‐dihydro‐1H‐indene‐2,1‐diylidene))dimalononitrile ( NITI ), is successfully designed and synthesized. Compared with 12‐π‐electron fluorene, a carbon‐bridged biphenylene with an axial symmetry, indenoindene, a carbon‐bridged E ‐stilbene with a centrosymmetry, shows elongated π‐conjugation with 14 π‐electrons and one more sp3 carbon bridge, which may increase the tunability of electronic structure and film morphology. Despite its twisted molecular framework, NITI shows a low optical bandgap of 1.49 eV in thin film and a high molar extinction coefficient of 1.90 × 105m ?1 cm?1 in solution. By matching NITI with a large‐bandgap polymer donor, an extraordinary power conversion efficiency of 12.74% is achieved, which is among the best performance so far reported for fullerene‐free organic photovoltaics and is inspiring for the design of new electron acceptors. 相似文献
10.
Zhenghao Hu Linqiang Yang Wei Gao Jinhua Gao Chunyu Xu Xiaoli Zhang Zhi Wang Weihua Tang Chuluo Yang Fujun Zhang 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(17)
Efficient organic solar cells (OSCs) are fabricated using polymer PM6 as donor, and IPTBO‐4Cl and MF1 as acceptors. The power conversion efficiency (PCE) of IPTBO‐4Cl based and MF1 based binary OSCs individually arrive to 14.94% and 12.07%, exhibiting markedly different short circuit current density (JSC) of 23.18 mA cm?2 versus 17.01 mA cm?2, fill factor (FF) of 72.17% versus 78.18% and similar open circuit voltage (VOC) of 0.893 V versus 0.908 V. The two acceptors, IPTBO‐4Cl and MF1, have similar lowest unoccupied molecular orbital levels, which is beneficial for efficient electron transport in the ternary active layer. The PCE of optimized ternary OSCs arrives to 15.74% by incorporating 30 wt% MF1 in acceptors, resulting from the simultaneously increased JSC of 23.20 mA cm?2, VOC of 0.897 V, and FF of 75.64% in comparison with IPTBO‐4Cl based binary OSCs. The gradually increased FFs of ternary OSCs indicate the well‐optimized phase separation and molecular arrangement with MF1 as morphology regulator. This work may provide a new viewpoint for selecting an appropriate third component to achieve efficient ternary OSCs from materials and photovoltaic parameters of two binary OSCs. 相似文献
11.
Efficient Semitransparent Solar Cells with High NIR Responsiveness Enabled by a Small‐Bandgap Electron Acceptor
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Feng Liu Zichun Zhou Cheng Zhang Jianyun Zhang Qin Hu Thomas Vergote Feng Liu Thomas P. Russell Xiaozhang Zhu 《Advanced materials (Deerfield Beach, Fla.)》2017,29(21)
Inspired by the remarkable promotion of power conversion efficiency (PCE), commercial applications of organic photovoltaics (OPVs) can be foreseen in near future. One of the most promising applications is semitransparent (ST) solar cells that can be utilized in value‐added applications such as energy‐harvesting windows. However, the single‐junction STOPVs utilizing fullerene acceptors show relatively low PCEs of 4%–6% due to the limited sunlight absorption because it is a dilemma that more photons need to be harvested in UV–vis–near‐infrared (NIR) region to generate high photocurrent, which leads to the significant reduction of device transparency. This study describes the development of a new small‐bandgap electron‐acceptor material ATT‐2, which shows a strong NIR absorption between 600 and 940 nm with an E gopt of 1.32 eV. By combining with PTB7‐Th, the as‐cast OPVs yield PCEs of up to 9.58% with a fill factor of 0.63, an open‐circuit voltage of 0.73 V, and a very high short‐circuit current of 20.75 mA cm?2. Owing to the favorable complementary absorption of low‐bangap PTB7‐Th and small‐bandgap ATT‐2 in NIR region, the proof‐of‐concept STOPVs show the highest PCE of 7.7% so far reported for single‐junction STOPVs with a high transparency of 37%. 相似文献
12.
Balanced Partnership between Donor and Acceptor Components in Nonfullerene Organic Solar Cells with >12% Efficiency
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Yuze Lin Fuwen Zhao Shyamal K. K. Prasad Jing‐De Chen Wanzhu Cai Qianqian Zhang Kai Chen Yang Wu Wei Ma Feng Gao Jian‐Xin Tang Chunru Wang Wei You Justin M. Hodgkiss Xiaowei Zhan 《Advanced materials (Deerfield Beach, Fla.)》2018,30(16)
Relative to electron donors for bulk heterojunction organic solar cells (OSCs), electron acceptors that absorb strongly in the visible and even near‐infrared region are less well developed, which hinders the further development of OSCs. Fullerenes as traditional electron acceptors have relatively weak visible absorption and limited electronic tunability, which constrains the optical and electronic properties required of the donor. Here, high‐performance fullerene‐free OSCs based on a combination of a medium‐bandgap polymer donor (FTAZ) and a narrow‐bandgap nonfullerene acceptor (IDIC), which exhibit complementary absorption, matched energy levels, and blend with pure phases on the exciton diffusion length scale, are reported. The single‐junction OSCs based on the FTAZ:IDIC blend exhibit power conversion efficiencies up to 12.5% with a certified value of 12.14%. Transient absorption spectroscopy reveals that exciting either the donor or the acceptor component efficiently generates mobile charges, which do not suffer from recombination to triplet states. Balancing photocurrent generation between the donor and nonfullerene acceptor removes undesirable constraints on the donor imposed by fullerene derivatives, opening a new avenue toward even higher efficiency for OSCs. 相似文献
13.
Dithieno[3,2‐b:2′,3′‐d]pyrrol Fused Nonfullerene Acceptors Enabling Over 13% Efficiency for Organic Solar Cells
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Jia Sun Xiaoling Ma Zhuohan Zhang Jiangsheng Yu Jie Zhou Xinxing Yin Linqiang Yang Renyong Geng Rihong Zhu Fujun Zhang Weihua Tang 《Advanced materials (Deerfield Beach, Fla.)》2018,30(16)
A new electron‐rich central building block, 5,5,12,12‐tetrakis(4‐hexylphenyl)‐indacenobis‐(dithieno[3,2‐b:2′,3′‐d]pyrrol) (INP), and two derivative nonfullerene acceptors (INPIC and INPIC‐4F) are designed and synthesized. The two molecules reveal broad (600–900 nm) and strong absorption due to the satisfactory electron‐donating ability of INP. Compared with its counterpart INPIC, fluorinated nonfullerene acceptor INPIC‐4F exhibits a stronger near‐infrared absorption with a narrower optical bandgap of 1.39 eV, an improved crystallinity with higher electron mobility, and down‐shifted highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels. Organic solar cells (OSCs) based on INPIC‐4F exhibit a high power conversion efficiency (PCE) of 13.13% and a relatively low energy loss of 0.54 eV, which is among the highest efficiencies reported for binary OSCs in the literature. The results demonstrate the great potential of the new INP as an electron‐donating building block for constructing high‐performance nonfullerene acceptors for OSCs. 相似文献
14.
High‐Efficiency All‐Small‐Molecule Organic Solar Cells Based on an Organic Molecule Donor with Alkylsilyl‐Thienyl Conjugated Side Chains
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Haijun Bin Jia Yao Yankang Yang Indunil Angunawela Chenkai Sun Liang Gao Long Ye Beibei Qiu Lingwei Xue Chenhui Zhu Chunhe Yang Zhi‐Guo Zhang Harald Ade Yongfang Li 《Advanced materials (Deerfield Beach, Fla.)》2018,30(27)
Two medium‐bandgap p‐type organic small molecules H21 and H22 with an alkylsily‐thienyl conjugated side chain on benzo[1,2‐b:4,5‐b′]dithiophene central units are synthesized and used as donors in all‐small‐molecule organic solar cells (SM‐OSCs) with a narrow‐bandgap n‐type small molecule 2,2′‐((2Z,2′Z)‐((4,4,9,9‐tetrahexyl‐4,9‐dihydro‐s‐indaceno[1,2‐b:5,6‐b′]dithiophene‐2,7‐diyl)bis(methanylylidene))bis(3‐oxo‐2,3‐dihydro‐1H‐indene‐2,1‐diylidene))dimalononitrile (IDIC) as the acceptor. In comparison to H21 with 3‐ethyl rhodanine as the terminal group, H22 with cyanoacetic acid esters as the terminal group shows blueshifted absorption, higher charge‐carrier mobility and better 3D charge pathway in blend films. The power conversion efficiency (PCE) of the SM‐OSCs based on H22:IDIC reaches 10.29% with a higher open‐circuit voltage of 0.942 V and a higher fill factor of 71.15%. The PCE of 10.29% is among the top efficiencies of nonfullerene SM‐OSCs reported in the literature to date. 相似文献
15.
Runnan Yu Shaoqing Zhang Huifeng Yao Bing Guo Sunsun Li Hao Zhang Maojie Zhang Jianhui Hou 《Advanced materials (Deerfield Beach, Fla.)》2017,29(26)
High‐performance ternary organic solar cells are fabricated by using a wide‐bandgap polymer donor (bithienyl‐benzodithiophene‐alt‐fluorobenzotriazole copolymer, J52) and two well‐miscible nonfullerene acceptors, methyl‐modified nonfullerene acceptor (IT‐M) and 2,2′‐((2Z ,2′Z )‐((5,5′‐(4,4,9,9‐tetrakis(4‐hexylphenyl)‐4,9‐dihydros‐indaceno[1,2‐b :5,6‐b ′]dithiophene‐2,7‐diyl)bis(4‐((2‐ethylhexyl)oxy)thiophene‐5,2‐diyl))bis(methanylylidene))bis(3‐oxo‐2,3‐dihydro‐1H ‐indene‐2,1‐diylidene))dimalononitrile (IEICO). The two acceptors with complementary absorption spectra and similar lowest unoccupied molecular orbital levels show excellent compatibility in the blend due to their very similar chemical structures. Consequently, the obtained ternary organic solar cells (OSC) exhibits a high efficiency of 11.1%, with an enhanced short‐circuit current density of 19.7 mA cm?2 and a fill factor of 0.668. In this ternary system, broadened absorption, similar output voltages, and compatible morphology are achieved simultaneously, demonstrating a promising strategy to further improve the performance of ternary OSCs. 相似文献
16.
Ning An Yunhao Cai Hongbo Wu Ailing Tang Kangning Zhang Xiaotao Hao Zaifei Ma Qiang Guo Hwa Sook Ryu Han Young Woo Yanming Sun Erjun Zhou 《Advanced materials (Deerfield Beach, Fla.)》2020,32(39):2002122
Compared with inorganic or perovskite solar cells, the relatively large non-radiative recombination voltage losses (ΔVnon-rad) in organic solar cells (OSCs) limit the improvement of the open-circuit voltage (Voc). Herein, OSCs are fabricated by adopting two pairs of D–π–A polymers (PBT1-C/PBT1-C-2Cl and PBDB-T/PBDB-T-2Cl) as electron donors and a wide-bandgap molecule BTA3 as the electron acceptor. In these blends, a charge-transfer state energy (ECT) as high as 1.70–1.76 eV is achieved, leading to small energetic differences between the singlet excited states and charge-transfer states (ΔECT ≈ 0.1 eV). In addition, after introducing chlorine atoms into the π-bridge or the side chain of benzodithiophene (BDT) unit, electroluminescence external quantum efficiencies as high as 1.9 × 10−3 and 1.0 × 10−3 are realized in OSCs based on PBTI-C-2Cl and PBDB-T-2Cl, respectively. Their corresponding ΔVnon-rad are 0.16 and 0.17 V, which are lower than those of OSCs based on the analog polymers without a chlorine atom (0.21 and 0.24 V for PBT1-C and PBDB-T, respectively), resulting in high Voc of 1.3 V. The ΔVnon-rad of 0.16 V and Voc of 1.3 V achieved in PBT1-C-2Cl:BTA3 OSCs are thought to represent the best values for solution-processed OSCs reported in the literature so far. 相似文献
17.
Bing Guo Wanbin Li Xia Guo Xiangyi Meng Wei Ma Maojie Zhang Yongfang Li 《Advanced materials (Deerfield Beach, Fla.)》2017,29(36)
In this work, high‐efficiency nonfullerene polymer solar cells (PSCs) are developed based on a thiazolothiazole‐containing wide bandgap polymer PTZ1 as donor and a planar IDT‐based narrow bandgap small molecule with four side chains (IDIC) as acceptor. Through thermal annealing treatment, a power conversion efficiency (PCE) of up to 11.5% with an open circuit voltage (V oc) of 0.92 V, a short‐circuit current density (J sc) of 16.4 mA cm?2, and a fill factor of 76.2% is achieved. Furthermore, the PSCs based on PTZ1:IDIC still exhibit a relatively high PCE of 9.6% with the active layer thickness of 210 nm and a superior PCE of 10.5% with the device area of up to 0.81 cm2. These results indicate that PTZ1 is a promising polymer donor material for highly efficient fullerene‐free PSCs and large‐scale devices fabrication. 相似文献
18.
Yamin Zhang Bin Kan Yanna Sun Yanbo Wang Ruoxi Xia Xin Ke Yuan‐Qiu‐Qiang Yi Chenxi Li Hin‐Lap Yip Xiangjian Wan Yong Cao Yongsheng Chen 《Advanced materials (Deerfield Beach, Fla.)》2018,30(18)
Fabricating solar cells with tandem structure is an efficient way to broaden the photon response range without further increasing the thermalization loss in the system. In this work, a tandem organic solar cell (TOSC) based on highly efficient nonfullerene acceptors (NFAs) with series connection type is demonstrated. To meet the different demands of front and rear sub‐cells, two NFAs named F‐M and NOBDT with a whole absorption range from 300 to 900 nm are designed, when blended with wide bandgap polymer poly[(2,6‐(4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)‐benzo[1,2‐b:4,5‐b′]dithiophene))‐alt‐(5,5‐(1′,3′‐di‐2‐thienyl‐5′,7′‐bis(2‐ethylhexyl)benzo[1′,2′‐c:4′,5′‐c′]dithiophene‐4,8‐dione))] (PBDB‐T) and narrow bandgap polymer PTB7‐Th, respectively, the PBDB‐T: F‐M system exhibits a high Voc of 0.98 V and the PTB7‐Th: NOBDT system shows a remarkable Jsc of 19.16 mA cm?2, which demonstrate their potential in the TOSCs. With the guidance of optical simulation, by systematically optimizing the thickness of each layer in the TOSC, an outstanding power conversion efficiency of 14.11%, with a Voc of 1.71 V, a Jsc of 11.72 mA cm?2, and a satisfactory fill factor of 0.70 is achieved; this result is one of the top efficiencies reported to date in the field of organic solar cells. 相似文献
19.
Lijian Zuo Jiangsheng Yu Xueliang Shi Francis Lin Weihua Tang Alex K.‐Y. Jen 《Advanced materials (Deerfield Beach, Fla.)》2017,29(34)
In this work, a highly efficient parallel connected tandem solar cell utilizing a nonfullerene acceptor is demonstrated. Guided by optical simulation, each of the active layer thicknesses of subcells are tuned to maximize its light trapping without spending intense effort to match photocurrent. Interestingly, a strong optical microcavity with dual oscillation centers is formed in a back subcell, which further enhances light absorption. The parallel tandem device shows an improved photon‐to‐electron response over the range between 450 and 800 nm, and a high short‐circuit current density (J SC) of 17.92 mA cm?2. In addition, the subcells show high fill factors due to reduced recombination loss under diluted light intensity. These merits enable an overall power conversion efficiency (PCE) of >10% for this tandem cell, which represents a ≈15% enhancement compared to the optimal single‐junction device. Further application of the designed parallel tandem configuration to more efficient single‐junction cells enable a PCE of >11%, which is the highest efficiency among all parallel connected organic solar cells (OSCs). This work stresses the importance of employing a parallel tandem configuration for achieving efficient light harvesting in nonfullerene‐based OSCs. It provides a useful strategy for exploring the ultimate performance of organic solar cells. 相似文献
20.
An Unfused‐Core‐Based Nonfullerene Acceptor Enables High‐Efficiency Organic Solar Cells with Excellent Morphological Stability at High Temperatures
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Shuixing Li Lingling Zhan Feng Liu Jie Ren Minmin Shi Chang‐Zhi Li Thomas P. Russell Hongzheng Chen 《Advanced materials (Deerfield Beach, Fla.)》2018,30(6)
Most nonfullerene acceptors developed so far for high‐performance organic solar cells (OSCs) are designed in planar molecular geometry containing a fused‐ring core. In this work, a new nonfullerene acceptor of DF‐PCIC is synthesized with an unfused‐ring core containing two cyclopentadithiophene (CPDT) moieties and one 2,5‐difluorobenzene (DFB) group. A nearly planar geometry is realized through the F···H noncovalent interaction between CPDT and DFB for DF‐PCIC. After proper optimizations, the OSCs with DF‐PCIC as the acceptor and the polymer PBDB‐T as the donor yield the best power conversion efficiency (PCE) of 10.14% with a high fill factor of 0.72. To the best of our knowledge, this efficiency is among the highest values for the OSCs with nonfullerene acceptors owning unfused‐ring cores. Furthermore, no obvious morphological changes are observed for the thermally treated PBDB‐T:DF‐PCIC blended films, and the relevant devices can keep ≈70% of the original PCEs upon thermal treatment at 180 °C for 12 h. This tolerance of such a high temperature for so long time is rarely reported for fullerene‐free OSCs, which might be due to the unique unfused‐ring core of DF‐PCIC. Therefore, the work provides new idea for the design of new nonfullerene acceptors applicable in commercial OSCs in the future. 相似文献