Thermodynamic properties of lithium bromide–water solutions at high temperatures

Emerging triple-effect LiBr–water absorption chillers operate at higher temperatures and pressures than traditional double-effect chillers. However, there is not enough data about thermodynamic properties of LiBr–water solutions at such high temperatures. Using recently measured data of vapor pressure and heat capacity, we have developed the equations which can calculate the vapor pressure, enthalpy and entropy of LiBr solutions at such high temperatures. The developed equations are valid from concentrations of 40–65 wt.% and also from temperatures of 40–210°C. These equations will be very helpful for the modeling and design of triple-effect LiBr–water chillers.     

An experimental solar-powered adsorptive refrigerator tested in Burkina-Faso

An adsorptive solar refrigerator was built and tested in May 1999 in Ouagadougou, Burkina-Faso. The adsorption pair is activated carbon + methanol. The adsorber is also the solar collector (2 m², single glazed), the condenser is air-cooled (natural convection) and the evaporator contains 40 l of water that can freeze into ice. This amount of ice acts as a cold storage for the cold cabinet (available volume of 440 l). Elements such as valves and a graduated bottle are installed, but only for experimental purposes. Apart from these valves, and also ventilation dampers which are open at night time and closed at daytime, the machine does not contain any moving parts and does not consume any mechanical energy. Within the requirement of vacuum technology, the machine is relatively easy to manufacture, so that construction in Burkina-Faso is feasible. Experimental performance is presented in terms of gross solar COP. During the test period, irradiance were quite good (between 19 and 25 MJ m⁻²), but the ambient temperature was relatively warm (averagely 27.4 °C at sunrise and 37.4 °C at mid-afternoon). The experimental values of the gross solar COP lie between 0.09 and 0.13. Despite a warm climate, the performance of the machine compares favourably to previously published results.

Résumé

An adsorptive solar refrigerator was built and tested in May 1999 in Ouagadougou, Burkina-Faso. The adsorption pair is activated carbon + methanol. The adsorber is also the solar collector (2 m², single glazed), the condenser is air-cooled (natural convection) and the evaporator contains 40 l of water that can freeze into ice. This amount of ice acts as a cold storage for the cold cabinet (available volume of 440 l). Elements such as valves and a graduated bottle are installed, but only for experimental purposes. Apart from these valves, and also ventilation dampers which are open at night time and closed at daytime, the machine does not contain any moving parts and does not consume any mechanical energy. Within the requirement of vacuum technology, the machine is relatively easy to manufacture, so that construction in Burkina-Faso is feasible. Experimental performance is presented in terms of gross solar COP. During the test period, irradiance were quite good (between 19 and 25 MJ m⁻²), but the ambient temperature was relatively warm (averagely 27.4 °C at sunrise and 37.4 °C at mid-afternoon). The experimental values of the gross solar COP lie between 0.09 and 0.13. Despite a warm climate, the performance of the machine compares favourably to previously published results.     

The role of surfactant adsorption rate in heat and mass transfer enhancement in absorption heat pumps

The importance of heat and mass transfer additives in absorption chillers and heat pumps has been recognized for over three decades. However, a universally accepted model for the mechanisms responsible for enhanced absorption rates has yet to be proposed. The Marangoni effect—an instability arising from gradients in surface tension at the liquid-vapor interface—is generally accepted as the cause of the convective flows that enhance transfer rates. Certain surfactant additives can significantly improve absorption rates and thus reduce the overall transfer area required by a given machine. Any means available that can increase the efficiency and acceptability of absorption machines is to be welcomed, as this technology provides an alternative to vapor compression systems which is both environmentally friendly and more versatile with regards to energy sources. This study investigates the rate at which a surfactant additive adsorbs at a liquid-vapor interface. The residence time of the falling liquid solution in an absorber is quite short. An effective additive must not only reduce the surface tension of the solution; it must do so quickly enough to cause the Marangoni instability within the short absorption process time. The entrance region of an absorber features a freshly exposed interface at which no surfactant has adsorbed. A numerical model is used to analyze surfactant relaxation rates in a static film of additive-laced solution. Kinetic parameters for the combination of the working pair LiBr-H₂O and the additive 2-ethyl-1-hexanol are derived from data in the literature for static and dynamic surface tension measurements. Bulk, interfacial and boundary parameters influencing relaxation rates are discussed for surfactant adsorption occurring in the absence of absorption, as well as for concurrent adsorption and stable vapor absorption. Initial solution conditions and absorption driving force are shown to impact the potential for instability in the effect they have on the rate of interfacial additive adsorption.     

Multi-bed regenerative adsorption chiller — improving the utilization of waste heat and reducing the chilled water outlet temperature fluctuation

A multi-bed regenerative adsorption chiller design is proposed. The concept aims to extract the most enthalpy from the low-grade waste heat before it is purged into the drain. It is also able to minimise the chilled water temperature fluctuation so that downstream temperature smoothing device may be downsized or even eliminated in applications where tighter temperature control may be required. The design also avoids a master-and-slave configuration so that materials invested are not under-utilised. Because of the nature of low-grade waste heat utilization, the performance of adsorption chillers is measured in terms of the recovery efficiency, η instead of the conventional COP. For the same waste heat source flowrate and inlet temperature, a four-bed chiller generates 70% more cooling capacity than a typical two-bed chiller. A six-bed chiller in turn generates 40% more than that of a four-bed chiller. Since the beds can be triggered into operation sequentially during start-up, the risk of ice formation in the evaporator during start-up is greatly reduced compared with that of a two-bed chiller.     

Experimental investigation on R134a vapour ejector refrigeration system

The experimental investigation of the performance of a vapour ejector refrigeration system is described. The system uses R134a as working fluid and has a rated cooling capacity of 0.5 kW. The influence of generator, evaporator and condenser temperatures on the system performance is studied. This kind of system can be operated with low grade thermal energy such as solar energy, waste heat, etc. The operating conditions are chosen accordingly as, generator temperature between 338 K and 363 K, condenser temperature between 299 K and 310.5 K, and evaporator temperature between 275 K and 285.5 K. Six configurations of ejectors of different geometrical dimensions are selected for the parametric study. The performance of the refrigeration system at different operating temperatures is presented.     

Influence of adsorption cycle limitations on the system performance

The economics of heat driven heat pumps are governed by two thermodynamic quantities: the performance on the one hand and the size of the heat exchangers, which is required to obtain this performance, on the other hand. The aim of this paper is to discuss the influence of the main features of adsorption cycles in comparison to absorption cycles on these quantities. In our case, a Zeolite UCC16×40-type 13X has been taken as the adsorbent. The analysis has already been used for absorption heat pumps. In the case of adsorption and other solid sorption chillers, additional limitations appear, e.g. identical design of all adsorbers, incomplete heat recovery between adsorbers, cycling of inert mass, etc., which all contribute to a lowering of the system performance or to an increase of the exchange area required. To show the basic differences between absorption and adsorption cycle optimization, and also to show the impact of physical or technical limitations on the adsorption chiller performance, a detailed analysis has been performed. It is confirmed that it is mainly the lack of a solution heat exchanger which lowers the adsorption system COP and not physical properties of the working pair, so there is still a lot of room for improvement in the solid-sorption of heat pumps.     

State of the art in sorption heat pumping and cooling technologies

Heat transformation with sorption systems has received increased attention in recent years. In this review it is intended to discuss current trends as well as forthcoming applications with the respective appropriate technology as it is deduced from activities in the field. Especially, we report about the papers and discussions of the International Sorption Heat Pump Conference (ISHPC'99) which was held in March 1999 in Munich, Germany. The review is grouped into a fundamentals part, a part about thermodynamic cycles, and an applications part. In the fundamentals part the discussion about working pairs and heat and mass transfer is reflected. Thermodynamic cycles which are being discussed are special solid sorption cycles, cycles fit for low-temperature driving heat, compression-sorption hybrids, and open cycles. In the applications part the classical cooling business is the main issue. The review comprises chillers and refrigerators which may be direct fired or waste heat driven. Interest is given to the improvement of efficiency on the one hand as well as to adaptation to low temperature waste heat use on the other hand — two very different developments. The use of solar energy as a heat source belongs to that area also. An additional important role — for decades — is played by automotive application. The area of heat pumping for heating purposes is less prominent but not negligible. Systems with a large capacity are being installed every once in a while, but the small scale domestic market still is not really covered with appropriate technology. Finally, industrial heat pumping involves the reverse cycle (heat transformer) also. Activity in this field is rather small. In summary, no unexpected developments can be reported on, but progress is steady and the market increases continuously, especially in the far east.     

Model development and validation of a solar cooling plant

This paper describes the dynamic model of a solar cooling plant that has been built for demonstration purposes using market-available technology and has been successfully operational since 2001. The plant uses hot water coming from a field of solar flat collectors which feed a single-effect absorption chiller of 35 kW nominal cooling capacity. The work includes model development based on first principles and model validation with a set of experiments carried out on the real plant. The simulation model has been done in a modular way, and can be adapted to other solar cooling-plants since the main modules (solar field, absorption machine, accumulators and auxiliary heater) can be easily replaced. This simulator is a powerful tool for solar cooling systems both during the design phase, when it can be used for component selection, and also for the development and testing of control strategies.     

A dynamic simulation model for transient absorption chiller performance. Part I: The model

This paper is the first of two which presents the development of a dynamic model for single-effect LiBr/water absorption chillers. The model is based on external and internal steady-state enthalpy balances for each main component. Dynamic behaviour is implemented via mass storage terms in the absorber and generator, thermal heat storage terms in all vessels and a delay time in the solution cycle. A special feature is that the thermal capacity is partly connected to external and partly to internal process temperatures.In this paper, the model is presented in detail. For verification, the model has been compared to experimental data. The dynamic agreement between experiment and simulation is very good with dynamic deviations around 10 s. General functionality of the model and a more detailed comparison with experimental data are presented in Part II of this paper.     

Review of advanced absorption cycles: performance improvement and temperature lift enhancement

The objective of this study is to propose and evaluate advanced absorption cycles for the coefficient of performance (COP) improvement and temperature lift enhancement applications. The characteristics of each cycle are assessed from the viewpoints of the ideal cycle COP and its applications. The advanced cycles for the COP improvement are categorized according to their heat recovery method: condensation heat recovery, absorption heat recovery, and condensation/absorption heat recovery. In H₂O–LiBr systems, the number of effects and the number of stages can be improved by adding a third or a fourth component to the solution pairs. The performance of NH₃–H₂O systems can be improved by internal heat recovery due to their thermal characteristics such as temperature gliding. NH₃–H₂O cycles can be combined with adsorption cycles and power generation cycles for waste heat utilization, performance improvement, panel heating and low temperature applications. The H₂O–LiBr cycle is better from the high COP viewpoints for the evaporation temperature over 0°C while the NH₃–H₂O cycle is better from the viewpoint of low temperature applications. This study suggests that the cycle performance would be significantly improved by combining the advanced H₂O–LiBr and NH₃–H₂O cycles.     

Absorption chiller crystallization control strategies for integrated cooling heating and power systems

The concept of an air-cooled absorption chiller system is attractive because the cooling tower and the associated installation and maintenance issues can be avoided. However, crystallization of the LiBr–H₂O solution then becomes the main challenge in the operation of the chiller, since the air-cooled absorber tends to operate at a higher temperature and concentration level than the water-cooled absorber due to the relative heat transfer characteristics of the coolant. This leads to crystallization of the working fluid. The paper focuses on the crystallization issues and control strategies in LiBr–H₂O air-cooled absorption chillers. As a result a novel application opportunity is proposed for the integration of absorption chillers into cooling, heating and power (CHP) systems. This new methodology allows for air cooler operation while avoiding crystallization.     

Theoretical and experimental study on characteristics of a novel silica gel–water chiller under the conditions of variable heat source temperature

In this paper, a transient model of a silica gel–water adsorption chiller, which is developed in Shanghai Jiao Tong University (SJTU), is developed in order to simulate the evaporating, condensing, and adsorption temperature. Furthermore, this model is verified by a series of experiments. The theoretical studies and experimental data show that the coefficient of performance (COP) is influenced significantly by the variation rates of the heat source temperatures. The results also show that when this chiller is driven by solar energy, a buffer tank should be adopted in the system in order to get better performance when solar insolation is low, and should not be utilized when solar insolation is high, otherwise low COP will be gotten for the reason of the consumption of high electric energy.     

Simulation results of triple-effect absorption cycles

A simulation analysis was carried out for three kinds of triple-effect absorption cycles of parallel-flow, series-flow and reverse-flow using a newly developed simulation program. The cycles investigated in this paper are similar to the alternate double-condenser coupled cycles of Grossman. The coefficient of performance, the maximum pressure and the maximum temperature of each cycle were calculated. The sensitivity analysis of UA of each component was also carried out. The results show that the parallel-flow cycle yields the highest coefficient of performance among the cycles, while the maximum pressure and temperature in the reverse-flow cycle are lower than those of other cycles.     

Numerical simulation of an advanced energy storage system using H2O–LiBr as working fluid, Part 1: System design and modeling

The advanced energy storage technology proposed and patented by authors can be applied for cooling, heating, dehumidifying, combined cooling and heating, and so on. It is also called the variable mass energy transformation and storage (VMETS) technology in which the masses in one or two storage tanks change continuously during the energy charging and discharging processes. This paper presents an advanced energy storage system using aqueous lithium bromide (H₂O–LiBr) as working fluid. As one of VMETS systems, this system is a closed system using two storage tanks. It is used to shift electrical load and store energy for cooling, heating or combined cooling and heating. It is environmental friendly because the water is used as refrigerant in the system. Its working principle and process of energy transformation and storage are totally different from those of the traditional thermal energy storage (TES) systems. The electric energy in off-peak time is mostly transformed into the chemical potential of the working fluid and stored in the system firstly. And then the potential is transformed into cold or heat energy by absorption refrigeration or heat pump mode when the consumers need the cold or heat energy. The key to the system is to regulate the chemical potential by controlling the absorbent (LiBr) mass fraction or concentration in the working fluid with respect to time. As a result, by using a solution storage tank and a water storage tank, the energy transformation and storage can be carried out at the desirable time to shift electric load efficiently. Since the concentration of the working solution in the VMETS cycle varies continuously, the working process of the VMETS system is dynamic. As the first part of our study, the working principle and flow of the VMETS system were introduced first, and then the system dynamic models were developed. To investigate the system characteristics and performances under full-storage and partial-storage strategies, the numerical simulation will be performed in the subsequent paper. The simulation results will be very helpful for guiding the actual system and device design.     

Solar cooling with water–ammonia absorption chillers and concentrating solar collector – Operational experience

Concentrating solar collectors provide high efficiency at high driving temperatures favourable for thermally driven chillers. Therefore, they offer applications for hot climates and industrial process integration, especially in combination with NH₃–H₂O chillers that provide refrigeration temperatures below 0 °C. The presented solar cooling installation comprises a linear concentrating Fresnel collector that provides the driving heat for two NH₃–H₂O absorption chillers at temperatures up to 200 °C. Chilled water temperatures are produced in the range between −12 °C and 0 °C. Collector capacities reached up to 70 kW at peak times and the total cooling capacity of both chillers showed peak values up to 25 kW. For good operating conditions, the thermal system EER was 0.8 and an electrical system EER of 12 was easily achieved. The system showed a sound operating behaviour. The performance of different operation and control strategies was analysed, evaluated and enhanced within the two year operation phase.     

A theoretical study of a novel regenerative ejector refrigeration cycle

There has been a demand for developments of the ejector refrigeration systems using low grade thermal energy, such as solar energy and waste heat. In this paper, a novel regenerative ejector refrigeration cycle was described, which uses an auxiliary jet pump and a conventional regenerator to enhance the performance of the novel cycle. The theoretical analysis on the performance characteristics was carried out for the novel cycle with the refrigerant R141b. Compared with the conventional cycle, the simulation results show that the coefficient of performance (COP) of the novel cycle increases, respectively, by from 9.3 to 12.1% when generating temperature is in a range of 80–160 °C, the condensing temperature is in a range of 35–45 °C and the evaporating temperature is fixed at 10 °C. Especially due to the enhanced regeneration with increasing the pump outlet pressure, the improvement of COP of the novel cycle is approached to 17.8% compared with that in the conventional cycle under the operating condition that generating temperature is 100 °C, condensing temperature is 40 °C and evaporating temperature is 10 °C. Therefore, the characteristics of the novel cycle performance show its promise in using low grade thermal energy for the ejector refrigeration system.     

Performance improvement of adsorption cooling by heat and mass recovery operation

An adsorption cooling system was developed and tested and various operation procedures have been tried. The experimental results show that the heat recovery operation between two adsorption beds will increase the COP by about 25% if compared with one adsorber basic cycle system. It was also proved that mass recovery is very effective for heat recovery adsorption cooling operation, which may help to obtain a COP increase of more than 10%. Theoretical analyses on the COP have been completed for various heat and mass recovery cycles, such as basic intermittent adsorption cycle, continuous two-adsorber heat recovery cycle, mass recovery cycle, mass recovery with sensible heat recovery, and mass recovery with both sensible heat and heat of adsorption recovery. The theoretical results are in good agreement with experimental values. Based upon the developed theoretical model, it is possible to predict the COP for various operation procedures of a real adsorption cooling system.     

Experimental results of a solar powered cooling system at low temperature

A solar thermochemical prototype producing low-temperature cold has been built and tested during the summer and autumn 2005 in Perpignan, France. It cools a 560 L cold box down to about −25 °C using only low-grade heat produced by two simple flat plate solar collectors. The process involves two cascaded thermochemical systems using BaCl₂ salt reacting with ammonia. Its working mode is discontinuous, as it alternates between one decomposition mode at high pressure (daytime) and one cold production mode at low pressure (nighttime). Experimental results prove the feasibility of this new concept of solar cold production, with temperatures as low as −30 °C, demonstrate its potential use in housing, by the acceptable size and weight of the system and show the system performances during the sunniest months of the year, with a rough solar coefficient of performance (COP) of about 0.031 over the test period. The major meteorological parameters influencing the process efficiency are the solar irradiation and the outside temperature.     

A year-round dynamic simulation of a solar-driven ejector refrigeration system with iso-butane as a refrigerant

In this paper, the performance of the solar-driven ejector refrigeration system with iso-butane (R600a) as the refrigerant is studied. The effects that both the operating conditions and the solar collector types have on the system's performance are also examined by dynamic simulation. The TRNSYS and EES simulation tools are used to model and analyze the performance of a solar-driven ejector refrigeration system. The whole system is modelled under the TRNSYS environment, but the model of the ejector refrigeration subsystem is developed in the Engineering Equations Solver (EES) program. A solar fraction of 75% is obtained when using the evacuated tube solar collector. In the very hot environment, the system requires relatively high generator temperature, thus a flat plate solar collector is not economically competitive because the high amount of auxiliary heat needed to boost up the generator temperature. The results from the simulation indicate that an efficient ejector system can only work in a region with decent solar radiation and where a sufficiently low condenser temperature can be kept. The average yearly system thermal ratio (STR) is about 0.22, the COP of the cooling subsystem is about 0.48, and the solar collector efficiency is about 0.47 at T_e 15 °C, T_c 5 °C above the ambient temperature, evacuated collector area 50 m² and hot storage tank volume 2 m³.     

Effects of metal mass on the performance of adsorption heat pumps utilizing zeolite 4A coatings synthesized on heat exchanger tubesEffets de la masse métallique sur la performance des pompes à chaleur à adsorption utilisant des revêtements en zéolite 4A synthétisé sur les tubes de l'échangeur de chaleur

The effects of the wall thickness of stainless steel heat exchanger tubes on the performance of adsorption machines, employing zeolite 4A coatings synthesized on metal heat exchanger tubes, are investigated. A recently developed mathematical model is used to determine the cycle durations when various wall thicknesses of the heat exchanger tubes as well as different zeolite layer thicknesses are utilized. For each case, the power and the COP_cycle values of the system are estimated. In general, very high power and quite low COP_cycle values are obtained when the proposed arrangement is utilized in the adsorption heat pumps. The zeolite layer thicknesses that may result in obtaining high COP_cycle values are generally much higher than the optimum layer thickness value that maximizes the power and the utilization of layers thicker than the optimum value may lead to significant extensions in the cycle durations and hence to a decrease in the power obtained from the system. Decreasing the wall thickness of the heat exchanger tubes increases both the power and the COP_cycle values when the optimum zeolite layer thickness for each wall thickness is taken into account. The possibility of such an enhancement will most probably be limited by the minimum wall thickness value that can actually be obtained by the available technology. The COP values of adsorption heat pumps may also be increased by using regenerative processes. Due to the generally low COP values obtained, the proposed arrangement seems especially suitable to be employed in adsorption machines utilizing energy sources of low economical value, such as waste heat. An optimum compromise between the COP value, which is closely related to the operating costs, and the power of the system should be provided, in case more valuable energy sources are utilized.