Implications of the new National Energy Basic Plan for nuclear waste management in Korea

The Korean National Energy Committee has recently adopted a new National Energy Basic Plan according to which the electricity generated by nuclear power plants is to increase from the current 35.5% of total electricity production to 59% by 2030. This large increase in nuclear power will inevitably accelerate the accumulation of spent fuel; if the direct disposal option is pursued, spent fuel arisings in Korea are expected to exceed 100,000 tHM in 2100. It is estimated that the country will require between 10–22 disposal sites, each with an area equal to the Gyeongju low- and intermediate-level radioactive waste (LILW) disposal site, to accommodate this amount of spent fuel. However, considering Korea's geographic profile, securing this number of sites will be almost impossible, and will ultimately create a serious problem for the sustainability of nuclear energy in the country. In view of this dilemma, this paper recommends that the volume of Korean nuclear waste for disposal be significantly reduced, and offers sodium fast reactor (SFR)-based recycling as a potentially viable solution.     

Fluctuation of redox conditions in radioactive waste disposal cell: characterisation of corrosion layers formed on archaeological analogues

Abstract

Oxygen trapped during the operational phase in disposal cells of an underground radioactive waste repository is often considered to be quickly consumed, notably by corrosion of metallic materials or reducing microorganisms. This would lead to anoxic conditions in most of each disposal cell. In addition to this, a shift from anoxic to oxic conditions could not be excluded locally in disposal cells after their closure due to the ventilation in handling drifts that could contribute to the regeneration of oxygen at the head of each disposal cell. The impact of these transient phases on corrosion processes may affect the confinement properties of metallic components and should thus be assessed. To this end, ferrous archaeological analogues are studied. The present paper focuses on the characterisation of nails that have undergone such transient phases. First, a sample exposed for several hundred years to an aerated environment and then to an anoxic carbonated environment in laboratory for 3 years has been analysed. Corrosion layers after the oxic phase contain mostly oxihydroxides (such as goethite) and some layers perpendicular or parallel to the interface, which is in good agreement with an aerated corrosion. After 3 years under anoxic conditions, the main phase of the corrosion layer is siderite. Second, a sample exposed to an anoxic environment for several hundred years has been immersed in an aerated solution for 5 weeks. The main phases of the corrosion layer after the anoxic phase are iron carbonates and a goethite layer formed on the outer part of the corrosion layer after the immersion in an aerated solution. In both cases, the formation of new phases in the corrosion layer is in good agreement with predictions of thermodynamic modelling based on the respective environmental conditions.     

Life cycle analysis of retrofitting with high energy efficiency air-conditioner and fluorescent lamp in existing buildings

Life cycle analysis of mercury in discarded low energy efficiency fluorescent lamps (36 W) and of HCFC in air-conditioners (12,000 Btu) removed from service has been conducted in this study. The objective was to find out the environmental impact (EDIP 1997 category, waste evaluation) of the products that appear in the waste stream as a result of facility upgrades. The scope of the study starts from retrofitting of the lamps and air-conditioners through recycling and disposal. For a 36 W fluorescent lamp, the bulk waste 1.64E−5 kg, hazardous waste 1.11E−4 kg, radioactive waste 1.09E−9 kg, and slag–ash 6.02E−7 kg occurred at the end of life of the retrofitting cycle. For a 12,000 Btu air-conditioner, the bulk waste 0.58 kg, hazardous waste 0.11 kg, radioactive waste 0.0002 kg, and slag–ash 0.01 kg also occurred at the end of life of the retrofitting cycle. These small amounts become important when viewed at the country level. These quantities imply that the policy makers who deal with hazardous waste should be aware of this waste-generating characteristic before issuing any pertinent policy. Consideration of this characteristic and planning for appropriate waste management methods at the beginning stage will reduce any future problem of contamination by the hazardous waste.     

Evidence for internal diffusion of sulphide from groundwater into grain boundaries ahead of crack tip in Cu OFP copper

Abstract

Copper canister is a central technical barrier for radioactive release from high level nuclear waste in the so called KBS-3 concept planned to be used in Finland and Sweden for disposal of spent nuclear fuel. Canisters will be placed in the granitic bedrock at about 400–500 m depth and surrounded by a layer of bentonite clay planned to protect the canister from any chemical and mechanical damage, and especially acting as a diffusion barrier. While researching for the possibility of stress corrosion cracking in phosphorus microalloyed copper in presence of sulphides in the groundwater, indications were found for a new potential degradation mechanism involving internal diffusion of sulphide. This paper describes the evidence for the new mechanism and discusses the scenarios involving diffusion of sulphide onto the copper canister surface.     

Application of biochar derived from used cigarette filters in direct carbon solid oxide fuel cell

As a typical waste, used cigarette filters (UCFs) are difficult to biodegrade and harmful to the environment. The direct carbon solid oxide fuel cell (DC-SOFC) is an energy conversion device that can utilize carbon directly, including biochar, as fuel. We report a superior DC-SOFC powered by Fe-loaded UCF biochar in this paper. The microstructure and composition are characterized, indicating that the UCF biochar is micron-sized and contains metal elements such as K and Ca that are beneficial to the performance of DC-SOFC. The peak power density of the cell fueled by pure UCF biochar is 308 mW cm^?2 and increases to 341 mW cm^?2 after loading Fe as the catalyst, which is comparable to that of the cell with Fe-loaded activated carbon (368 mW cm^?2). It proves the feasibility of the UCF biochar as fuel for DC-SOFCs, providing a theoretical basis and technical demonstration for the disposal and transformation of solid waste.     

The development of a sustainable development model framework

The emergence of the “sustainable development” concept as a response to the mining of natural resources for the benefit of multinational corporations has advanced the cause of long-term environmental management. A sustainable development model (SDM) framework that is inclusive of the “whole” natural environment is presented to illustrate the integration of the sustainable development of the “whole” ecosystem. The ecosystem approach is an inclusive framework that covers the natural environment relevant futures and constraints. These are dynamically interconnected and constitute the determinates of resources development component of the SDM. The second component of the SDM framework is the resources development patterns, i.e., the use of land, water, and atmospheric resources. All of these patterns include practices that utilize environmental resources to achieve a predefined outcome producing waste and by-products that require disposal into the environment. The water quality management practices represent the third component of the framework. These practices are governed by standards, limitations and available disposal means subject to quantity and quality permits. These interconnected standards, practices and permits shape the resulting environmental quality of the ecosystem under consideration. A fourth component, environmental indicators, of the SDM framework provides a measure of the ecosystem productivity and status that may differ based on societal values and culture. The four components of the SDM are interwoven into an outcome assessment process to form the management and feedback models. The concept of Sustainable Development is expressed in the management model as an objective function subject to desired constraints imposing the required bounds for achieving ecosystem sustainability. The development of the objective function and constrains requires monetary values for ecosystem functions, resources development activities and environmental cost. The feedback model ensures policy and resources use changes required for sustainability. An iterative process would be required to define the optimum ecosystem development plan that satisfies sustainable outcome.     

Effects of deep geological environments for nuclear waste disposal on the hydrogen entry into titanium

The surface of nuclear waste container will be completely wetted by the groundwater infiltrating through the bentonite or concrete buffer after the closure of its deep geological disposal. Because of its excellent corrosion resistance, titanium is one of the candidates for the container materials for high-level nuclear waste (HLNW) disposal. However, once oxygen depleted in the large time scale deep geological disposal, titanium container will suffer from hydrogen embrittlement (HE). Therefore, in order to predict the potential danger of the HLNW container caused by HE, the hydrogen entry into titanium was studied at different temperatures in simulated deep geological environment of Beishan, which is the preselected HLNW disposal area in China. Devanathan-Stachurski cell methods were firstly implemented in measuring apparent hydrogen diffusivity in titanium with hydrides being formed during hydrogen charging at low temperature ranges (298–373 K). Given the characteristic of the Devanathan-Stachurski cell method's capable of getting apparent diffusivity with combined influencing factors easily, the technique provides a simple way to measure the parameter that is necessary for the estimation of hydrogen penetration depth, facilitating the design of HLNW containers.     

West Germany's efforts to close the nuclear fuel cycle: Strategies for radioactive waste management

West Germany's efforts to reach a mature nuclear economy by [closing] the [back end] of the nuclear fuel cycle are discussed with special emphasis on radioactive waste management strategies. the radioactive wastes that would be generated in a closed nuclear fuel cycle are described. A brief discussion is given of the motives that underlie the current international disagreement regarding the desirability of, and the need for, closing the nuclear fuel cycle. West Germany's concept for closing the nuclear fuel cycle is outlined including institutional arrangements and responsibilities. A discussion of radioactive waste classification follows. Expected volumes and inventories of radioactive wastes are pointed out. Current practices, and research and development work in the treatment and disposal of radioactive wastes are outlined. A final section is devoted to the history, circumstances and implications of the current requirement for a [solution] for the back end of the nuclear fuel cycle as a precondition for continued expansion of nuclear power in West Germany.     

A review on the utilization of fly ash

Fly ash, generated during the combustion of coal for energy production, is an industrial by-product which is recognized as an environmental pollutant. Because of the environmental problems presented by the fly ash, considerable research has been undertaken on the subject worldwide. In this paper, the utilization of fly ash in construction, as a low-cost adsorbent for the removal of organic compounds, flue gas and metals, light weight aggregate, mine back fill, road sub-base, and zeolite synthesis is discussed. A considerable amount of research has been conducted using fly ash for adsorption of NO_x, SO_x, organic compounds, and mercury in air, dyes and other organic compounds in waters. It is found that fly ash is a promising adsorbent for the removal of various pollutants. The adsorption capacity of fly ash may be increased after chemical and physical activation. It was also found that fly ash has good potential for use in the construction industry. The conversion of fly ash into zeolites has many applications such as ion exchange, molecular sieves, and adsorbents. Converting fly ash into zeolites not only alleviates the disposal problem but also converts a waste material into a marketable commodity. Investigations also revealed that the unburned carbon component in fly ash plays an important role in its adsorption capacity. Future research in these areas is also discussed.     

Disposal of by-products in olive oil industry: waste-to-energy solutions

Olive oil production industry is characterized by relevant amounts of liquid and solid by-products [olive mill wastewater (OMW) and olive husk (OH)], and by economical, technical and organizational constraints that make difficult the adoption of environmentally sustainable waste disposal approaches.In this context, waste treatment technologies aimed at energy recovery represent an interesting alternative. In the paper, a technical and economical analysis of thermal disposal plant solutions with energy recovery has been carried out. The considered plants enable the combined treatment of OMW and OH which, although penalizes the energy recovery, proves to be feasible and profitable in a future legislative scenario when stricter limitation on OMW disposal will force oil producers to bear high disposal costs. Results are compared by using economic performance measures, including revenues from produced energy and avoided disposal costs. A sensitivity and risk analysis is also performed in order to assess the economic profitability of the proposed solutions.     

Application of nuclear energy for environmentally friendly hydrogen generation

It is universally admitted that hydrogen is one of the best energy media and its demand will increase greatly in the near future. However, little hydrogen exists naturally, so that how to generate hydrogen without bringing forth much CO₂${}_2$ will be very important research subject. Hydrogen generation from water using nuclear energy is one of the solutions for this problem. Especially, the high temperature gas cooled reactor (HTGR) has a possibility to generate hydrogen economically compared with other types of nuclear reactors. As for long-lived radioactive waste to be generated by nuclear reactors, it is expected to significantly reduce its burden to the human environment by applying transmutation technologies. This report describes the feature of the hydrogen generation with HTGR and the development of the accelerator-driven subcritical system to reduce radioactive waste ongoing at JAEA.     

Plasma gasification of the medical waste

In terms of infection control in hospitals, especially the Covid-19 pandemic that we are living in, it has revealed the necessity of proper disposal of medical waste. The increasing amount of medical waste with the pandemic is straining the capacity of incineration facilities or storage areas. Converting this waste to energy with gasification technologies instead of incineration is also important for sustainability. This study investigates the gasification characteristics of the medical waste in a novel updraft plasma gasifier with numerical simulations in the presence of the plasma reactions. Three different medical waste samples, chosen according to the carbon content and five different equivalence ratios (ER) ranging from 0.1 to 0.5 are considered in the simulations to compare the effects of different chemical compositions and waste feeding rates on hydrogen (H₂) content and syngas production. The outlet properties of a 10 kW microwave air plasma generator are used to define the plasma inlet in the numerical model and the air flow rate is held constant for all cases. Results showed that the maximum H₂ production can be obtained with ER = 0.1 for all waste samples.     

Enhanced biohydrogen production from date seeds by Clostridium thermocellum ATCC 27405

Biohydrogen production from waste lignocellulosic biomass serves the dual purpose of converting waste into valuable products and alleviates waste disposal issues. In this study, waste date seeds were valorized for biohydrogen production via consolidated bioprocessing by Clostridium thermocellum ATCC 27405. Effect of various surfactants (PEG1000, surfactin, Triton X-100) and sodium carbonate (buffering agent) on biohydrogen production from the acid pre-treated substrate was examined. Among the various surfactants, addition of Triton X-100 resulted in the maximum biohydrogen yield of 103.97 mmol/L at an optimal dosage of 0.75% w/v. Triton X-100 supplementation favoured the production of ethanol and acetate as co-metabolites than butyrate. Addition of Na₂CO₃ to date seed fermentation medium at a concentration of 15 mM enhanced the biohydrogen production by 33.16%. Also, Na₂CO₃ buffering supported the glycolytic pathway and subsequent ethanol production than acetate/butyrate formation. Combined effect of the optimal dosages of Triton X-100 and Na₂CO₃ resulted in high hydrogen productivity up to 72 h (0.443 mmol/g h of H₂) with a total increase in hydrogen yield of 40.6% at the end of 168 h, as compared to fermentation supplemented with Triton X-100 alone. Further analysis revealed that the combined effects of the additives resulted in better substrate degradation, favourable pH window and cell growth promotion which ensured enhanced hydrogen productivity and yield. Thus, the study highlights a novel stimulatory approach for enhanced biohydrogen production from a new substrate.     

The prospects of brewery waste application in biohydrogen production by photofermentation of Rhodobacter sphaeroides

Selection of the source for biohydrogen (H₂) production is essential, since it affects bacterial metabolism. Pure organic substrates give fast H₂ generation with high yields, but they increase the production cost. Using industrial wastes as a source provides inexpensive energy generation with simultaneous waste utilization. H₂ production by photofermentation of Rhodobacter sphaeroides is monitored during cultivation on brewery waste. Maximum specific growth rate is observed for 5–10% waste containing media. H₂ production by cells, grown on waste, is detected at 48–96 h of growth; it is comparable or higher than that of control medium with expensive carbon and nitrogen sources. N,N′-dicyclohexylcarbodiimide-sensitive ATPase activity of R. sphaeroides membrane vesicles from growth on waste containing media is 1.6–1.7-fold higher compared to control, correlating with enhanced H₂ production. Growth medium containing optimal amount of wastes may be a successful alternative to expensive media for high H₂ yield in R. sphaeroides during photofermentation.     

Toward a viable nuclear waste disposal program

The essay deals with the lack of a suitable permanent storage site for the radioactive waste that has been produced by more than 103 open-cycle nuclear reactors in the U.S. The DOE has recently withdrawn the licensing application for the Yucca Mountain Repository leaving the nuclear industry responsible for the safety of more than 800 waste-containing concrete casks currently on the open surface at 34 sites. It also has not undertaken measures to reduce the volume of additional waste produced by both existing and newly planned reactors. The DOE has instead opted to undertake research to develop new cycles that "burn" the radioactive waste. This policy appears subordinated to obvious political pressures. It is short sighted in terms of a practical program to serve the interests of the clean and safe energy requirements of the country. The essay also describes technical initiatives and processes that are recommended for a better solution.     

Feasibility of hydrogen recovery and optimization of gas production from protein-rich food waste by bio-electrochemical system

Microbial electrolysis cell (MEC) can realize effective disposal of organic waste and hydrogen recovery. However, it is not clear whether protein-rich food waste (FW) with complex structural characteristics can be degraded effectively in MEC. And the metabolism process of protein in MEC is still unclear. In this study, feasibility of hydrogen recovery from protein-rich FW by bio-electrochemical system and the anode enrichment strategies were investigated. The results showed that the anaerobic digestated liquid of protein-rich FW is more suitable for hydrogen recovery than raw FW. And the unfavorable protein metabolites to anode electroactive microbe utilization hinder the hydrogen recovery rate from protein by MEC. However, hydrogen production increased by 72.67% when anodic microbes were enriched with protein instead of sodium acetate. The analysis of anode electroactive bacteria and protein metabolites process revealed that protein-enrich strategies could strengthen the co-occurrence of bacteria genus Aeromonas and Blvii28 and thereby shift the protein metabolism towards acidogenic process, which increasing the substrate bio-availability to anode electroactive microbe.     

Evaluation of the environmental impact of waste wood co-utilisation for energy production

The need for a practical, economic and environmentally sound solution for waste wood arises from the requirements for resource conservation and recent regulations. Co-firing with coal is a promising option for the thermal recycling of waste wood. The overall environmental impact caused by the co-utilisation of waste wood with coal was evaluated by using life cycle assessment as established by Society of Environmental Toxicology and Chemistry (SETAC) [A technical framework for life cycle assessment. Washington, DC: SETAC, USA; 1991, Guidelines for life cycle assessments: A code of practice. Brussels: SETAC, Europe; 1993]. This provides opportunities to evaluate direct environmental impact, to identify possible improvements, and to reduce energy resource consumption. In this work, the environmental impact of co-utilising lignite and waste wood in an industrial steam boiler was evaluated. Results obtained showed that co-utilisation is technically feasible and can meet strict environmental standards. A net decrease of CO₂ emissions can be achieved by the thermal use of waste wood, as well as conservation of fossil fuel resources, minimisation of waste disposal and reduction of impacts on health.     

A new pyrolysis technology and equipment for treatment of municipal household garbage and hospital waste

This paper analyzes various methods of disposal of municipal solid waste in China, including refuse incineration, garbage power and landfill technology. Based on the conventional pyrolysis principle, a new apparatus has been developed for waste disposal in China. It is especially useful in China as the waste is not sorted. The experiment shows that the concentration of dioxins meets the emission standard of 0.1 ng-TE/N m³ by controlling the residence time and temperature. The expulsive solid weight is as low as 5–7% of the whole refuse. At the same time, a great deal of fire gas was generated in the treatment process.     

Status and potential of biogas energy from animal wastes in Turkey

Biogas is a potentially important energy source that can be used for the production of heat, electricity and fuel. It can be produced at wastewater treatment plants, landfills, food and other industrial operations throughout the world. There is largely untapped potential in agricultural operations where animal waste is often land applied or otherwise disposal of without conversion to energy. According to the last agricultural census (2009) in Turkey; there are a total of 3,076,650 agricultural enterprises and approximately 70% of these enterprises are running livestock farming. 10,811,165 of total animal is cattle, 26,877,793 of total animal is small ruminant and 234,082,206 is poultry. The amount of wet waste of these animals is about 120,887,280 t. These wastes could be a major problem for enterprises and cannot be utilized properly. The best way to utilize waste is to produce biogas. In this study, biogas amount which will be obtained from animal waste was calculated for all provinces by using the number of livestock animals and also considering various criteria such as the rate of dry matter and availability. Animal origin waste map of Turkey was also produced with these calculated values. The biogas energy potential of Turkey was found to be 2,177,553,000 m³ (2.18 Gm³) by using the animal numbers in the last agricultural census (2009). The total biogas potential is originated from 68% cattle, 5% small ruminant and 27% poultry. Biogas energy equivalence of Turkey is approximately 49 PJ (1170.4 ktoe). When the prepared waste map is examined; provinces that have more than 1 GJ of biogas energy potential are found to be; Bolu, Bal?kesir, ?zmir, Sakarya, Konya, Manisa, Erzurum, Afyon, Kars and Ankara respectively.     

Short communication: Onion skin waste-derived biocarbon as alternative non-noble metal electrocatalyst towards ORR in alkaline media

In this work a first approximation to obtain non-noble metal electrocatalysts from onion skin wastes is reported. Biocarbon were obtained at a range of 600–800 °C of pyrolysis temperature activated by chemical treatment with HNO₃. It was observed that the pyrolysis temperature has a direct effect on the structural and textural properties, besides the morphology of the onion skin waste-derived biocarbon, which shows to have influence on the catalytic activity for the oxygen reduction reaction ORR. AOB700 was the non-noble metal electrocatalyst with the best performance for the ORR evaluated in alkaline electrolyte (0.5 mol L⁻¹ KOH), which had the highest surface area (242 m²g^-1) and a current density of −2.35 mA cm⁻² with an onset potential of 0.82 V/RHE. The chemical surface composition shows that N-pyridinic, N-amine, N-quaternary and N-pyrrolic nitrogen species are present on this electrocatalysts. The use of onion skin waste as raw material in the production of non-noble metal electrocatalysts is a sustainable solution to avoid the disposal of abundant biomass residues as onion skins.