Relationship between microstructure and fracture behavior of bioabsorbable HA/PLLA composites

Hydroxyapatite particles of four different shapes, that is, micro, nano, spherical and plate, were used to fabricate hydroxyapatite filled poly(l-lactic acid) (HA/PLLA) composites. Effects of HA particle shape on the fracture behavior of HA/PLLA were investigated by mode I fracture testing, fracture surface measurement and scanning electron microscopy. It was found that the micro-HA/PLLA has the highest critical energy release rate, G_IC, with the largest surface roughness, while G_IC of the nano-HA/PLLA was lowest corresponding to the smallest surface roughness. The micro-HA/PLLA composites exhibited interfacial debonding and local ductile deformation of the PLLA matrix, indicating higher fracture energy and therefore, the highest G_IC. On the other hand, the nano-HA/PLLA composites showed brittle fracture surface due to nano-scale interaction between PLLA fibrils and primary HA particles, corresponding to lower fracture energy and hence the lowest G_IC.     

Studies of the effect of metal particles on the fracture toughness of ceramic matrix composites

The purpose of this study was to describe the influence of metal particles on the fracture toughness of ceramic matrix composites. Here, alumina matrix composites with molybdenum particles have been investigated. The results presented show that the change of fracture toughness of a ceramic–metal composite can be controlled by the volume fraction of metallic phase and size of metal particles.

The model proposed in this paper describes the change of crack length and as a consequence, the change of K_IC value. The results of modelling calculations have been compared with experimentally measured K_IC values. This model is useful for simulation of crack length changes in the composites and to design a material with an optimum fracture toughness.     

Influence of in-plane fibre orientation on mode I interlaminar fracture toughness of stitched glass/polyester composites

The influence of in-plane fibre orientation on the mode I interlaminar fracture toughness, G_Ic of unstitched and stitched glass/polyester composites is investigated in this paper. The G_Ic of planar specimens depends on the fibre orientation, θ in the layers adjacent to the fracture plane, in addition to the property of matrix material. The mode I fracture toughness and fracture behavior of unstitched and stitched 0/0, 30/−30, 45/−45, 60/−60, 90/90 and 0/90 interfaces of unidirectional fibre mats (UD) and 30/−30, 45/−45 and 90/90 interfaces of woven roving mats (WRM) are studied. WRM layer orientation is represented by the direction of warp fibres. Stitching is done by untwisted Kevlar fibre roving of Tex 175 g/km at the stitch densities (number of stitches per unit area) of 10.24 and 20.48 stitches/inch². The specimens having same stitch density, but different stitch distributions are prepared, and the influence of stitch distribution on G_Ic is studied. Double cantilever beam (DCB) tests are carried out and the G_Ic is determined using modified beam theory. The G_Ic of both unstitched and stitched specimens increases with increase in orientation angle, θ upto 45° above which it decreases. The G_Ic values of unstitched 45/−45 delamination interface is around 2.4 times that of the unstitched 0/0 interfaces. The influence of fibre orientation on G_Ic is clearly observed in unstitched specimens, whereas in the stitched specimens, stitching plays an important role in improving the G_Ic and suppresses the influence of fibre orientation; degree of suppression increases with increasing stitch density. When the value of θ is above 45°, transverse cracks are observed in the delamination interface surrounded by UD layers; while in the delamination interface surrounded by WRM layers, transverse cracks are not initiated irrespective of the fibre orientation angle.     

Effects of the marine environment on the interfacial fracture toughness of PVC core sandwich composites

An experimental study was undertaken to investigate the facesheet/core interfacial fracture toughness of E-Glass/Vinylester facesheet, closed-cell polyvinyl chloride (PVC) core, sandwich composites. To determine the effects of a marine environment (temperature and sea-water) on conditioned specimens with a crack present, an interfacial crack was induced prior, as well as subsequent to, 5000 h of elevated temperature (80 °C), elevated temperature and moisture (80 °C, 90%+ relative humidity), and sea-water (submersed) conditioning. The interfacial fracture toughness from room temperature double cantilever beam tests for each environmental condition was then compared using the critical strain energy release rate, G_C. The G_C was reduced considerably (greater than 50%) in specimens submerged in sea-water, and significantly (approximately 90%) due to 5000 h of the ‘hot/wet’ and hot/dry exposure. Results showed that elevated temperature exposure contributes greatest to the PVC core degradation, whereas sea-water exposure mostly degrades the facesheet/core interface. Exposure to elevated temperatures, along with inducing cracks between the facesheet and a PVC core degraded by elevated temperature exposure, appear to be the most detrimental to interfacial fracture toughness.     

Characterization of interlaminar fracture behaviour of woven fabric reinforced polymeric composites

An experimental study was conducted to characterize the interlaminar fracture behaviour of 2-D woven fabric reinforced epoxy composites under mode I loading using double cantilever beam tests. A large displacement, small strain non-linear beam model was used to calculate the interlaminar fracture toughness. The fabrics used included fibreglass and Kevlar woven structures with different weave patterns. An attempt was made to enhance the composite interlaminar toughness by adding different types of microfibres into the matrix. Toughening mechanisms of the composites were analysed using scanning electron microscopy. It was found that the weave patterns of fabrics exhibited a strong influence on the interlaminar fracture behaviour, and that the addition of the microfibres to the epoxy matrix could improve the interlaminar fracture toughness significantly.     

Interlaminar and intralaminar durability characterization of wet layup carbon/epoxy used in external strengthening

Carbon fibers in unidirectional fabric form are increasingly being used as a means of strengthening deteriorating and understrength concrete components and systems through application as externally bonded reinforcement. The use of wet layup process under ambient conditions makes these composites susceptible to moisture and environment-related deterioration. In addition since the composite is formed in the field, often in overhead or vertical configurations, by sequential placement of fabric layers, it is critical, for the assessment of materials integrity, to characterize damage mechanisms and durability of interlaminar and intralaminar performance characteristics. It is shown that aqueous exposure, as well as freeze–thaw, results in significant fiber–matrix debonding, and this causes deterioration in short-beam-shear and in-plane shear characteristics. Changes in interlaminar properties are seen to be correlated with moisture uptake. It is also seen that fracture toughness, in the short-term, is enhanced by some of these exposures due to plasticization and flexibilizing of the matrix, which assists in the blunting of crack front progression. However, when accompanied by chemical degradation, such as with immersion in alkali solution, and embrittlement caused by low temperature exposure, G_IC values are seen to deteriorate as well. The data provides a crucial set of material characteristics for consideration side-by-side with fiber dominated characteristics (such as tensile strength and modulus, which are the only ones considered conventionally in rehabilitation design), since the matrix dominated properties will often be the critical links in determining service life.     

Analysis of knitted fabric reinforced composites: Part II. Stiffness and strength

The influence of the knit structure on the stiffness and strength in tensile and in share loading of glass warp knitted fabric epoxy composites is studied. The average strength depends on the fibre content and on the linear density of the yarn. The anisotropy in tensile and shear properties is related to the orientation tensor components a₁₁₁₁ and a₁₁₂₂, respectively. By making use of these relationships, a knit structure can be evaluated with regard to the mechanical properties of its composite with only two measurements: (1) measurement of the achievable fibre content; and (2) measurement of the fibre orientations.     

Monotonic and cyclic short beam shear response of 3D woven composites

Monotonic, multi-step and cyclic short beam shear tests were conducted on 2D and 3D woven composites. The test results were used to determine the effect of z-yarns on the inter-laminar shear strength as well as the multi-loading behavior. The presence of z-yarns was found to affect not only the inter-laminar shear strength of the composite but also the behavior of the composite beyond the elastic limit. Microscopic examination of the damaged specimens revealed large delamination cracks in 2D woven composites while delamination cracks were hindered by z-yarns in 3D composites. This crack arrest phenomena resulted in a reduction in inter-laminar crack lengths and a higher distribution of the micro-cracks throughout the 3D composite. The multi-step and cyclic loading tests are found to be useful in the monitoring of specimen behavior during short beam shear testing. The induced damage was quantified in terms of the loss of strength and stiffness during each loading cycle. It was found that while the 2D composites have higher damage resistance, the 3D composites have a higher damage tolerance.     

Mechanics and mechanisms of delamination in a poly(ether sulphone)—Fibre composite

The interlaminar fracture behaviour of AS4/PES (poly(ether sulphone)) composite has been investigated in Mode I, Mode II and for fixed Mode I to Mode II ratios of 0·84, 1·33 and 2·13. The data obtained from these tests have been analysed using several different analytical approaches. The results obtained show that in Mode I the interlaminar crack growth in double cantilever beam (DCB) specimens is accompanied by fibre bridging behind the crack tip and by splitting at the crack tip, and in Mode II by the formation of a damage zone at the crack tip. These failure mechanisms are shown to increase the value of the interlaminar fracture energy considerably as the crack propagates through the composite, i.e. a rising ‘R-curve’ is measured. It is shown also that the value of the interlaminar fracture energy at crack initiation in Mode I, G_CI (init), increases as the length of the initial precrack is increased. The lowest G_IC (init) value obtained for the poly(ether sulphone) (PES) composite in this study is 0·8 kJm⁻², and this value was ascertained from a specimen with the precrack being grown by about 2 mm ahead of the initial crack (a₀ = 23 mm, a_p = 25 mm). The typical Mode II steady-state propagation energy, G_IIC (s/s-prop), value obtained for the specimens was about 2·0 kJm⁻². The length of the initial precrack had no significant effect on the G_IIC (init) and G_I/IIC (init) values. The Mode II tests gave values of G_IIC (init) = 1·25 kJm⁻² and of G_IIC (s/s-prop) = 1·85 kJm⁻². Finally, the failure loci for the PES composite have been constructed and theoretical expressions to describe these data considered.     

The mechanics and mechanisms of fracture in stress corrosion cracking of aluminium alloys

A fracture mechanics approach to stress corrosion cracking is highlighted. The mechanisms of stress corrosion cracking is presented. Experiments on 2024 and 7075 aluminium alloys are carried out to determine their mechanical properties, microstructure and plane strain fracture toughness (K_IC). Stress corrosion cracking tests, namely, cantilever beam tests as well as wedge opening loading tests using sea water as a corrosive medium, are conducted to establish the critical stress intensity factor for stress corrosion cracking (K_ISCC) for each aluminium alloy. It is found that the K_ISCC is in the range of (1/5) to (1/6) of the plane strain fracture toughness, K_IC, depending on the alloy. The scanning electron microscopy of fracture surfaces reveals a great dependence of the cracking and/or pit severity on the applied stress intensity factor. A brief discussion on the dislocation's role in stress corrosion cracking is given.     

Interlaminar fracture properties of weft-knitted/woven fabric interply hybrid composite materials

An experimental study has been undertaken to characterize the delamination behavior and tensile properties of interply hybrid laminated composites reinforced by interlock weft-knitted and woven glass fiber preform fabrics. The hybrid composites, comprising the alternate layers of interlock and uniweave fabrics, were compared to interlock knitted (only) and uniweave (only) composites with respect to delamination and tensile performances. Mode-I double cantilever beam and mode-II end-notched flexure tests were carried out to assess the interlaminar fracture toughness using aluminum-strip stiffened specimens. The mode-I and mode-II interlaminar fracture toughness values, G _IC and G _IIC, for the hybrid composite were about three and two times higher than that for the uniweave composite, respectively. The tensile strength and modulus of the hybrid composite were 315 MPa and 12.8 GPa in the wale direction, respectively, demonstrating that the strength and modulus were found to be slightly lower than those of the uniweave composite, and significantly improved in comparison with the interlock knitted composites.     

Evaluation and analysis of interlaminar fracture toughness of bead filled matrix hybrid composite materials using orthotropic fracture mechanics

Evaluation of Mode I interlaminar fracture toughness for unidirectional hybrid composites fabricated with a bead filled epoxies was carried out. The two important fracture toughness parameters, G_IC and K_IC values of hybrid composites, were reviewed in accordance with the orthotropic fracture model. The deviation of measured G_IC and K_IC values from predicted values were explained based on the critical review of the basic assumption of orthotropic fracture model and characteristic material properties of hybrid composites. It can be said that, basically, the orthotropic fracture model can be used for evaluation of hybrid composite materials. However, careful analysis for G_IC and K_IC values which were derived from different source and some correction factor for K_IC values are necessary.     

Influence of silane coupling agents on interlaminar fracture in glass fibre fabric reinforced unsaturated polyester laminates

The relationship between the adhesive properties of the interphase of glass fibre/resin and the resultant composite Mode I delamination fracture toughness in glass fibre fabric laminate (GFFL) was studied. The Mode I interlaminar fracture toughness of GFFL was obtained by using a double cantilever beam (DCB) specimen. The delamination resistance of GFFLs which have two silane coupling agents and three concentration finishes is discussed on the basis of interlaminar fracture toughness. The crack propagation behaviour of DCB testing was mainly divided into stable and unstable manners. The fracture toughness and the crack propagation behaviour were dependent on the types and concentration of silane coupling agents.     

The effects of deforming knitted glass fabrics on the basic composite mechanical properties

The effects of deforming knitted fabrics on the tensile and compressive properties of their composites have been investigated for the weft-knit Milano rib fibre architecture. The properties have been studied for both the course and wale directions for composites with fabrics deformed in either of the two directions. It was found that any change in the mechanical properties of the deformed composites with respect to their undeformed counterpart is strongly related to the changes in the knit structure brought about by the induced deformation to the knitted fabric. Deformation in the knitted fabric also affects the tensile fracture mode whereby increased deformation, be it wale- or course-wise, transforms transverse fracture to shear fracture in either loading axis. On the contrary, the compressive fracture mode is insensitive to fabric deformation. Fractographic studies using stereo-optical and scanning electron microscopy have further revealed that tensile failure is caused by fibre breakages occurring at two locations of the knitted loops—one, at the leg components and, two, at fibre crossover points, whilst compression failure is controlled by Euler buckling of the looped fibres of the knitted composite. All these characteristics were revealed to be related to the microstructure of the knitted composite laminates.     

SANDWICH STRUCTURE DELAMINATION OF RESIN TRANSFER MOLDING

One of the apparent advantages of sandwich structures is that after the core is made, the sandwich is produced in one process by resin transfer molding (RTM) and no adhesive is used between the core and skins. The bond between the core and skins is therefore likely to depend upon the core material, the type of matrix and the core surface roughness. This is of great importance, because the stiffness of the sandwich structure is likely to be reduced by even partial delamination of the core and skins. The objective of this study was to ascertain the effects of manufacturing parameters such as injection pressure, mold temperature, core thickness and core surface roughness on skin/core adhesion using the direct tensile adhesion and peel test methods. Polyurethane foam was used as the core material throughout the work. The major objective was to examine different surface treatment methods by which the strength of the skin-core bond could be improved. The influence of the core surface roughness on the adhesive fracture energy and the delamination between core and skin were also measured. The fracture energy release rate equation was used as the basis for comparison and for measurements of the adhesion. For this purpose a double-cantilever beam was used to characterize the delamination. Critical energy release rate (G_IC) and fracture toughness (K_IC) were calculated using several alternative methods based on linear elastic fracture mechanics.     

Effects of biaxial deformation of the knitted glass preform on the in-plane mechanical properties of the composite

The effect of biaxially deforming a weft-knit Milano rib fabric on the overall composite tensile and compressive properties has been studied for a glass/vinyl-ester knitted composite. A range of combinations of wale and course stretch ratios was considered. It was found that the tensile modulus, strength and strain-to-failure were all affected to varying degrees by fabric deformation, whereas the compression properties of these structures, on the whole, appeared to be closer to isotropic and relatively insensitive to fabric deformation. This latter observation is believed to be due to the dominance of the matrix properties. Despite not detecting any gross changes in the knit structure, it is believed that some re-distribution and re-orientation of the fibres did occur during fabric deformation, which in turn altered the relative contents and/or directionality of the fibres in the composites. Consequently, the tensile properties were affected by the stretching of the knitted fabric. Post failure microscopy revealed that tensile fracture typically occurred in the vicinity of the highly stressed crossover points of the knit structure. A feature of the compressive failure was kinking of the highly bent yarns, particularly in resin rich regions having reduced lateral support for yarns.     

Experimental determination of the mode I delamination fracture and fatigue properties of thin 3D woven composites

The mode I delamination fracture toughness and fatigue strength of thin-section three-dimensional (3D) woven composite materials is experimentally determined. The non-crimp 3D orthogonally woven carbon–epoxy composites were thin (2 mm) and consequently their through-thickness z-binder yarns were inclined at a very steep angle (about 70°) from the orthogonal direction. The steep z-binder angle has a marked effect on the delamination toughening and fatigue strengthening mechanisms. Experimental testing revealed that the fracture toughness and fatigue resistance increased progressively with the volume content of z-binders. However, the steep angle caused the z-binder yarns bridging the delamination crack to deform and fail in shear and through-thickness tension, rather than in-plane tension which usually occurs in thick 3D woven composites. Mode I pull-off tests on a single woven z-binder yarn embedded within the composite revealed that the crack bridging traction load, strain energy absorption and failure mechanism were strongly affected by the steep angle.     

Mode I interlaminar fracture toughness properties of advanced textile fibreglass composites

The Mode I interlaminar fracture toughness properties of vinyl ester-based composites reinforced with fibreglass manufactured by the advanced textile technologies of braiding, knitting, stitching and through-the-thickness weaving are assessed in comparison to a variety of traditional composites made from fibreglass such as unidirectional or woven rovings. The interlaminar fracture toughness (G_Ic) of braided and knitted composites are higher than traditional composites by factors of more than two and four, respectively. Toughening in these textile composites was caused by extensive crack branching as the interlaminar crack was forced to follow a tortuous path through the complex fibre architectures. The G_Ic values of the composites reinforced in the through-thickness direction by weaving or stitching were higher than traditional composites by factors of nearly two and three, respectively, with the main toughening mechanism being crack bridging by the through-thickness binder yarns/stitches. A review of Mode I interlaminar fracture data collected from papers shows that advanced textile techniques are capable of manufacturing composites with substantially improved delamination resistance.     

Nesting effect on the mode II fracture toughness of woven laminates

The mode II fracture toughness is evaluated for carbon fibre T700-epoxy reinforced woven laminates using the end notch flexure set-up. The analysed woven composites have a different tow size (3K/12K). Three different nesting/shifting configurations are applied to the plies at the fracture surface. Corrected Beam Theory with effective crack length method (CBTE) and Beam Theory including Bending rotations effects method (BTBE) are evaluated for obtaining mode II fracture toughness. During data post-processing, the importance of the bending angle of rotation and the test configuration is observed to be important. The results show that crack propagation under mode II is more stable if the matrix is evenly distributed on the surface. The nesting does not significantly affect mode II fracture toughness values, although a greater presence of matrix on the delaminated area increases its value.     

Thermoplastic composite from innovative flat knitted 3D multi-layer spacer fabric using hybrid yarn and the study of 2D mechanical properties

Due to their improved mechanical properties, 3D multi-layer spacer fabrics could be used for lightweight applications such as textile-based sandwich preforms. Modern flat knitting machines using high performance yarns are able to knit complex 3D multi-layer spacer fabrics consisting of individual surface and connecting layers. This paper reports on the development of 3D flat knitted spacer fabric for 3D thermoplastic composites using hybrid yarns made of glass (GF) and polypropylene (PP) filaments. Moreover, mechanical properties of reinforcement yarns, 2D knit fabrics and 2D composites manufactured using various integration methods of reinforcement yarns were also studied. The integration of reinforcement yarns as biaxial inlays (warp and weft yarns) is found to be the best solution for knitting, whereas the tuck stitches show optimal results.