The Effect of WS2 Nanoparticles on Friction Reduction in Various Lubrication Regimes

A study of the tribological behavior of nested inorganic fullerene-like (IF) nanoparticles of WS₂, as a potential additive to base oils is presented. Friction measurement results obtained from three different test rigs over a wide range of normal loads and sliding velocities are shown. Stribeck curves are used to reveal the lubrication regimes where the IF are most effective. It is found that the addition of IF-WS₂ nanoparticles to the base oils results in up to 50% reduction in friction coefficient in the mixed lubrication regime. The mechanism of improved friction and wear behavior with the IF additive is discussed.     

Tribological studies of rhenium doped fullerene-like MoS2 nanoparticles in boundary,mixed and elasto-hydrodynamic lubrication conditions

The tribological properties of rhenium-doped inorganic fullerene-like MoS₂ nanoparticles were studied in poly alpha olefin oil, and compared to inorganic fullerene-like (IF) MS₂ (M=Mo,W) nanoparticles and 2H-MoS₂ platelets. For this purpose a rotational disc tribometer was used. Different regimes in the Stribeck curve, i.e., boundary, mixed and elasto-hydrodynamic lubrication conditions were studied. A precipitous reduction in friction and wear of oil suspensions with nanoparticles were observed for the entire IF samples. However, Re-doped IF exhibited the best results, presumably due to their reduced tribocharging and agglomeration. The various tribological mechanisms of solid state additives are discussed.     

Tribological behaviour of MoS2 and inorganic fullerene-like WS2 nanoparticles under boundary and mixed lubrication regimes

Abstract

For several years different types of nanoparticles have been considered and studied as potential friction modifying lubricant additives. Some nanoparticles can reduce the friction coefficient by 30–70%, depending on the base oil and the experimental conditions. In the present study, an experimental analysis on tribological properties of inorganic fullerene-like metal dichalcogenides was performed in comparison with MoS₂ 2H layered structures. Tribological tests were carried out on a pin on disc tribometer in ambient air. Several contact conditions are analysed in order to realise boundary and mixed lubrication regimes. The experimental study was performed on a mineral base oil, and particle concentration effects were analysed. Antifriction properties were evaluated by measuring the friction coefficient and are presented as generalised Stribeck diagrams. Inorganic fullerene-like WS₂ and MoS₂ nanoparticles present interesting friction reduction properties when tested in boundary and mixed lubrication.     

Load bearing capacity of bronze, iron and iron–nickel powder composites containing fullerene-like WS2 nanoparticles

In the past few years, inorganic fullerene-like (e.g. IF) supramolecules of metal dichalcogenide MX₂ (M=Mo,W, etc.; X=S, Se), materials with structures closely related to (nested) carbon fullerenes and nanotubes have been synthesized. Recent experiments showed that IF possess lubricating properties superior to those of commercially available layered solid lubricant (2H–WS₂ polytype) in a wide range of operating conditions. It was shown before that the impregnation of a small amount of such nanoparticles into porous bronze matrix largely improve the tribological properties of bronze–steel contact pairs. In the present work, the effect of the PV (pressure–velocity) parameter on the transition to seizure for powdered bronze–graphite, iron–graphite and iron–nickel–graphite composites impregnated 2H and IF lubricant has been studied. The tribological tests were performed using a ring–block tester at loads of 150–1200 N and sliding speeds from 0.5 to 1.7 m/s. It was found that impregnation of IF into the pores improves the tribological properties of the powdered composites in comparison to 2H–WS₂ solid lubricant. Furthermore, it was established that the impregnation of oil together with the IF nanoparticles allows to provide very high load bearing capacity of the powdered materials.It is suggested that the transition to seizure occurs when the wear debrises accumulate in the pores on the surface. This process practically blocks the surface pores and limits the supply of the solid lubricant particles to the contact surface. The main advantage of the IF nanoparticles is attributed to: (a) slow release and supply of nanoparticles from the open pores to the surface; (b) sliding/rolling of the IF between the rubbing surfaces; and (c) prevention of the accumulation of the agglomerated wear particles in the pores. The model of third body was used in order to explain the effect of the wear particles, oil and solid lubricant particles on the friction and wear behavior of powdered composites.     

Friction and wear of copper samples in the steady friction state

The effect of sliding velocity and load on the friction and wear of Cu-steel pairs was studied. Elasto-hydrodynamic (EHL), mixed (ML) and boundary lubrication (BL) regions were analyzed using the Stribeck curve. The lubrication number of Schipper, Z, was used in the analysis of the Stribeck curve. Steady friction states were observed in the mixed EHL and BL regions, however two types of the ML region are revealed. The first type is the stable ML range. The second one is the range of unstable friction and wear when a decrease of the lubricant film leads to abrupt change of all controlled parameters. It was found that a transition to the unstable ML region occurs within a narrow range of Z parameter. Wear modes in the lubrication regions were studied. Deformation hardening in the lubricant regimes is discussed.     

Frictional Characteristics of IF-WS2 Nanoparticles in Simulated Engine Conditions

The efficacy of inorganic fullerene-like (IF) tungsten disulfide (WS₂) nanoparticles as engine oil friction modifier additive was investigated using a high-stroke reciprocating piston ring–cylinder bore bench test system. Frictional characteristics of various IF-WS₂ nanoparticle concentrations in mineral oil were experimentally analyzed in simulated engine conditions controlling oil temperature, speed, and normal load. Though the effect of IF-WS₂ nanoparticles on piston ring and cylinder bore friction was minor in low concentrations, after a running period in a mixed lubrication regime with 10% additive, a considerable reduction in friction coefficient was observed when the IF-WS₂ formulated oil was used. This reduction remains to some extent with reference mineral oil after solvent cleaning of the mating components. The results show that a thin tribofilm gradually forms on the piston ring and the cylinder bore surfaces, reducing the friction coefficient in a mixed lubrication regime. However, in order to obtain the friction reduction there seems to be a threshold in the concentration of IF-WS₂ in mineral oil and film development period. The effects of lubrication regime, contact load, speed, and surface roughness on tribofilm formation are also discussed. The presence of WS₂ tribofilm formed on the piston ring and the cylinder bore surfaces was further verified using Raman spectroscopy.     

A new way to feed nanoparticles to friction interfaces

Fullerene-like WS₂ (MoS₂) nanoparticles (IF) have been studied in the past. Their efficacy as additives for lubrication fluids has been demonstrated. It was shown that the IF nanoparticles are usually delaminated in the inlet of the smooth contact. Thin sheets of broken IF nanoparticles can be entrapped between the rubbed surfaces and thus favorably affect the friction and the wear. Friction pairs at real mechanical macrosystems are often subjected to friction-induced vibrations. It was shown that the mechanical excitations can improve the supplying and preservation of fluid lubricant film in the interface. It can be hypothesized that under vibrations in a definite range of frequencies and amplitudes, the probability for small IF aggregates to be entrapped into the interface is increased. The main goal of this work was to study the effect of artificial mechanical excitations on the friction and wear of contact pairs rubbed with nanoparticles. In order to avoid friction-induced excitations, a new ball-on-flat friction device was developed. The frequency and the amplitude of the ball were varied using a motion of miniature micromotor attached to the ball holder. The behavior of IF nanoparticles in friction tests with and without external mechanical excitations was compared with the tribological behavior of the contact pair lubricated with pure paraffin oil. It was found that the external mechanical excitation of the mechanical parts rubbed with nanoparticles allows a penetration of these nanoparticles into interface. This effect leads to a remarkable shortening of the run-in period and improves the tribological properties of contact pairs. From the present results it may be anticipated that the accidental friction-induced vibrations, which are determined by the stiffness and damping force of the device, lead to preferential penetration of the IF nanoparticles into the contact area, affecting thereby the tribological behavior of the interface.     

Tribological Performance of Silver Nanoparticle–Enhanced Polyethylene Glycol Lubricants

This article introduces a new type of nanoparticle additive for tribological purposes. A nanolubricant was synthesized and studied that consists of metallic silver nanoparticles suspended in polyethylene glycol (PEG). Silver nanoparticles were prepared directly in liquid PEG by introducing aqueous silver nitrate and subsequent reduction by PEG. The nanolubricant exhibits excellent stability due to poly(vinyl pyrollidone) used as the coating agent. Thorough tribological analysis was performed on the nanolubricant, including rheology, friction, wear, and Stribeck curve analysis. Results show that the nanoparticle additives are capable of reducing both friction and wear at low concentrations. Stribeck curve analysis also revealed that the particles are effective in reducing friction in both the boundary and mixed lubrication regimes. The possible friction and wear reduction mechanism of silver nanoparticles is also discussed in the current work.     

On the Efficacy of IF–WS<Subscript>2</Subscript> Nanoparticles as Solid Lubricant: The Effect of the Loading Scheme

Fullerene-like WS₂ (MoS₂) nanoparticles (IF) have been studied in the past as solid lubricants. Using the tribological ball-on-flat experiments, it was shown that the size of the aggregates and their distribution determine the penetration and entrapping of the IF nanoparticles at the interface. It is expected that the wedge clearance at the inlet of the contact, i.e., the oblique-angle entrance to the contact zone between the two mating tribological surfaces, as well as the average surface roughness, can limit the supply of the lubricant into the interface in, e.g., the block-on-ring experiment. In the present series of experiments, the Stribeck curve was designed first using a linear loading scheme and pure oil. It was concluded that a wedge clearance (oblique-angle) in the inlet of the contact zone leads to entrapment of the IF nanoparticles and their compaction, which hamper the supply of the fluid lubricant into the interface. A ball-on-flat and flat block-on-ring friction devices with wedge clearance in the inlet of the contact can distort the efficacy of IF. Procedures for improving the supply of the IF nanoparticles to the contact zone and improving thereby their efficacy are considered.     

Formation of Low-Friction Particle/Polymer Composite Tribofilms by Tribopolymerization

Inorganic fullerene-like (IF) solid lubricant particles based on MoS₂ or WS₂ have recently gained attention in various tribological applications, for instance incorporated in coatings, porous materials, greases and dispersed in oils. However, their effect in oil can be limited often due to inadequate penetration into the contact zone. Meanwhile, tribopolymerization of monomer additives in oil have proven to be efficient to reduce wear, but without significantly reducing the friction. This investigation combines these two lubrication techniques in order to form particle/polymer composite tribofilms, aimed to give low friction and wear in high-pressure sliding contacts. A cyclic amine, caprolactam, was used as the monomer together with IF as well as normal 2H WS₂ particles. Zn-DTP was used as a reference antiwear additive and poly-alfa-olefin (PAO) was used as the base oil. Reciprocal ball-on-flat sliding test results found that monomer plus particles reduced the friction by 10–50%, depending on sliding speed and type of particles, compared with particles or monomer alone. And the scattering between different tests was also considerably lower. The wear rate was also substantially reduced to a level similar to that of Zn-DTP. The particle/polymer composite tribofilms were generally much larger than the actual contact area and its thickness varied from below a few nanometres in the contact centre to several micrometers in the outer parts. Consequently, the reduced friction is believed to come from two effects: one being a trapping of particles in the contact zone, which reduces the boundary friction level; and the other a shift in lubrication regime towards EHD-lubrication due to reduced contact pressures accompanied with the formation of the composite tribofilm.     

Correlation Studies of WS 2 Fullerene-Like Nanoparticles Enhanced Tribofilms: A Scanning Electron Microscopy Analysis

The beneficiary effects of tungsten disulphide (WS₂) inorganic fullerene-like nanoparticles (IFLNPs) in the lubrication industry were shown in recent years. However, their successful incorporation into lubricants (oils, greases) is not straightforward. In practice, the lubricant contains several components for different purposes, e.g. reducing the oxidization of the oil (antioxidant), minimizing the wear rate (anti-wear additive), dispersants, etc. These additives can contain chemically active compounds, which under the lubrication process (where locally extreme conditions can develop: high pressure and flash temperatures) can change the chemistry in the contact zone and block the beneficial effects of the inorganic nanoparticles. In this investigation, poly-alpha-olefin (PAO) is being used as base oil in which the WS₂ nanoparticles and different additives are mixed. A ball-on-disc sliding test revealed that certain additives inhibit the nanoparticles to reduce friction (less than 5 % decrease in friction coefficient), while in other cases, the friction reduction was above 50 %. The comparison is being made between PAO + additive and PAO + additive + IFLNPs. Scanning electron microscope and energy dispersive X-ray spectroscopy were used to investigate the elemental composition of the tribofilms formed on the wear marks. Further analysis was made in order to reveal correlations between elemental compositions of the tribofilms and external parameters such as the friction coefficient and wear rate. For instance, a strong correlation between tungsten content of the tribofilm and the friction coefficient was found.     

Understanding the Tribochemical Mechanisms of IF-MoS<Subscript>2</Subscript> Nanoparticles Under Boundary Lubrication

Inorganic fullerene-(IF)-like nanoparticles made of metal dichalcogenides (IF-MoS₂, IF-WS₂) have been known to be effective as anti-wear and friction modifier additives under boundary lubrication. The lubrication mechanism of these nanoparticles has been widely investigated in the past and it is now admitted that their lubrication properties are attributed to a gradual exfoliation of the external sheets of the particles during the friction process leading to their transfer onto the asperities of the reciprocating surfaces. However, the chemical interaction between these molecular sheets and the rubbing surfaces has so far never been investigated in detail. In this study, the tribochemistry of the IF nanoparticles was carefully investigated. A series of friction test experiments on different rubbing surfaces (Steel, Alumina, Diamond-Like Carbon) were performed with IF-MoS₂ nanoparticles. High-resolution transmission electron microscopy, scanning electron microscopy, Auger electron spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the tribostressed areas on rubbing surfaces. A tribofilm composed of hexagonal 2H-MoS₂ nanosheets was only observed on the steel surface. This transfer film was found to be incorporated into an iron oxide layer. A tribochemical reaction between the 2H-MoS₂ nanolayers and the iron/iron oxide has been proposed as an explanation for the adhesion of this tribofilm. The tribochemical mechanism of the IF-MoS₂ nanoparticles is discussed in this article.     

Influence of surface roughness and running-in on the lubrication of steel surfaces with oil containing MoS2 nanotubes in all lubrication regimes

Despite several studies that have confirmed the beneficial effect of MoS₂ and WS₂ nanoparticle-assisted lubrication, an understanding of how the nanoparticles behave in different, even very common contact conditions, such as roughness, is still missing. As a result we have focused on a comparison of the lubrication behaviour of MoS₂ nanotubes mixed with PAO oil using steel surfaces with different roughnesses. Moreover, we have investigated the MoS₂-nanotubes-assisted lubrication of steel/steel contacts in all lubrication regimes and also the effect of the running-in of these contacts. It was realized that the friction with the nanotubes-containing oil was 40–65% lower compared to the base oil, depending on the different contact conditions used. Furthermore, we showed that by using MoS₂ nanotubes in the oil the friction is the same for rough and smooth steel surfaces, meaning that the nanotubes completely govern the lubrication behaviour in self-mated steel contacts in the boundary- and mixed-lubrication regimes, irrespective of the surface roughness or the running-in.     

Ultralow-friction and wear properties of IF-WS<Subscript>2</Subscript> under boundary lubrication

Tested in boundary lubrication, inorganic fullerene-like WS₂ nanoparticles used as additives in oil present interesting friction reducing and anti-wear properties. A dispersion with only 1 wt% of particles leads, from a contact pressure of 0.83 GPa, to a drastic decrease of the friction coefficient below 0.04 and to very low wear. High resolution transmission electron microscopy (HRTEM), Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Raman Spectroscopy and video imaging were used to explain the lubrication mechanisms. A structural modification of fullerene-like nanoparticles into sheets during the friction test was evidenced to be the main effect at the origin of these properties.*To whom correspondence should be addressed. E-mail: lucile.joly-pottuz@ec-lyon.fr     

The Use of D-optimal Design for Modeling and Analyzing the Tribological Characteristics of Journal Bearing Materials Lubricated by Nano-Based Biolubricants

Response surface methodology (RSM) based on a D-optimal design was employed to investigate the tribological characteristics of journal bearing materials such as brass, bronze, and copper lubricated by a biolubricant, chemically modified rapeseed oil (CMRO). The wear and friction performance were observed for the bearing materials tested with TiO₂, WS₂, and CuO nanoadditives dispersed in the CMRO. The tests were performed by selecting sliding speed and load as numerical factors and nano-based biolubricant/bearing materials as the categorical factor to evaluate the tribological characteristics such as the coefficient of friction (COF) and specific wear rate. The results showed that RSM based on a D-optimal design was instrumental in the selection of suitable journal bearing materials for a typical system, especially one lubricated by nano-based biolubricant. At a sliding speed of 2.0 m/s and load of 100 N, the bronze bearing material with CMRO containing CuO nanoparticles had the lowest COF and wear rate. In addition, scanning electron microscopy (SEM) examination of the worn bearing surfaces showed that the bronze bearing material lubricated with CMRO containing CuO nanoadditive is smoother than copper/brass bearing material.     

Friction, wear and structure of Cu samples in the lubricated steady friction state

Friction and wear of copper rubbed with lubrication in wide range of loads and sliding velocities were studied. The results of friction and wear experiments are presented as the Stribeck curve where the boundary lubrication (BL), mixed (ML) and elasto-hydrodynamic lubrication (EHL) regions are considered. The structural state of subsurface layers in different lubricant regions is studied by X-ray photoelectron spectroscopy, optical, transmission and scanning microscopy analysis. Dislocation density of dislocations in EHL and BL lubricant regimes was determined. Nanohardness at thin surface layers rubbed under different lubricant regimes is compared. The dominant friction and wear mechanisms in different lubrications regions are discussed.     

A Novel Surface Texture Shape for Directional Friction Control

An experimental study is presented to evaluate the influence of anisotropically shaped textures on the behaviour of sliding friction and sensitivity to sliding direction. The plate samples were textured with triangular sloped dimples using an ultrafast laser surface texturing technique. Reciprocating cylinder-on-plate tests were conducted with steel sliding pairs using mineral base oil as a lubricant to compare the tribological performance of reference non-textured specimen and dimpled samples. The dimples were designed with varying converging angles in the transverse y–z plane and top-view x–y plane. In this study, no dimple was fully covered in the contact area since the dimples size is much larger than the Hertzian line contact width. Stribeck style dynamic friction curves across boundary, mixed and hydrodynamic lubrication regimes were used to determine the benefit or antagonism of texturing. Observation of the directional friction effect of the anisotropic textures indicated that the converging shapes are beneficial for friction reduction, and the dimpled specimens have a lower friction coefficient particular under prevailing boundary lubrication conditions. It was also found that the real contact length variation rate is a major factor controlling the local friction response. The sloped bottoms of the textures produce effective converging wedge action to generate hydrodynamic pressure and contribute to the overall directional friction effects.     

Friction and wear of fullerene-like WS<Subscript>2</Subscript> under severe contact conditions: friction of ceramic materials

Recently, the behavior of inorganic fullerene-like (IF) WS₂ nanoparticles in the interface of steel-on-steel pair has been analyzed. It was shown that originally when the gap between the contact surfaces is smaller than the size of the IF nanoparticles, there is no effect of the nanoparticles on the friction force. During the test stiff IF nanoparticles can plough the surface of hard steel samples and penetrate into the interface under friction. Molecular sheets of WS₂ from the delaminated IF nanoparticles, which reside in the valleys of the rough surfaces cover the contact spots and thus decrease the number of adhered spots at the transition to seizure. The goal of the present work was to study the behavior of IF nanoparticles in the interface of ceramic surfaces. The friction tests were performed using a ball-on-flat device. A silicon nitride ball was slid against an alumina flat with maximum contact pressure close to 2 GPa. SEM, TEM and AFM techniques have been used in order to assess the behavior of IF nanoparticles in the interface. The behavior of IF nanoparticles in the much harder ceramic interfaces was found to be appreciably different from the steel pair. The pristine IF nanoparticles are damaged in the inlet of the contact during the first few cycles and thin shells of broken nanoparticles gradually cover the middle range of the contact surface. Different modes of deformation and destruction of the IF nanoparticles are exhibited when going from the middle to edge area of the contact. While aggregates of the pristine nanoparticles are formed at the edge of the contact, thin shells of broken IF nanoparticles are observed in the middle area where contact pressure is maximum. Mechanical stability and damage of IF nanoparticles in the ceramic interface are discussed.     

The Influence of Water Addition on High-Temperature Tribological Properties of Interstitial Free Steel Sliding against Different Counterparts

The influence of only water addition on the hot metal forming process has not yet been reported in regard to tribological performance. In the present study, simulation tests were carried out on a pin-on-disc tribometer to evaluate the effects of water lubrication on the wear and friction behaviors of interstitial free (IF) steel sliding against different countersurface materials at 800°C in comparison with those in dry sliding. The opposing materials were selected as GCr15 steel and ceramic-based compounds including ZrO₂, SiC, and Si₃N₄. It has been found that Si-based component–IF steel pairs exhibit the lowest wear losses despite achieving relatively high friction. Water addition adversely impairs the friction and wear characteristics on steel-steel tribopairs, whereas it shows insignificant effects on the pair involving ceramic-based components except ZrO₂. Varying tribological responses can be found among different mated surfaces under water lubrication. X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy were utilized to examine the worn surface. The acting mechanism of water addition for different rubbing pairs was further discussed from the aspects of oxide tribochemistry.     

Lubrication behaviour of iron rhenate in relation to matching pairs at elevated temperatures

Iron rhenate was compounded by a chemical method, which can be reproduced during the wear process of Fe-Re alloys at elevated temperatures. The friction coefficient of iron rhenate was determined using five types of ball material (Si₃N₄, Al₂O₃, glass, 440 C, and Hast C) matching seven types of disc material (Al₂O₃, 761 iron base superalloy, glass, stainless steel, bronze, copper, and Al-Li), using a ball-on-disc device. The results show that the iron rhenate plays a role in lubrication from room temperature to 600°C. The lubrication behaviour is related to the nature of the matching pairs: the hardness of the materials, the compatibility of iron rhenate with the materials of the matching pairs, and the surface roughness of the disc most affect the lubrication behaviour of iron rhenate. The principle of tribologically matching pairs is proposed.