On the interaction of Class C fly ash with Portland cement–calcium sulfoaluminate cement binder

Shrinkage cracking in concrete is a widespread problem, especially in concrete structures with high surface-to-volume ratio such as bridge decks. Expansive cements based on calcium sulfoaluminate phase were developed to mitigate the shrinkage cracking of concrete. The compressive stress induced due to restrained expansion of concrete has been shown to counteract the tensile stress generated during drying shrinkage. This research attempts to address the differential behavior of fly ash type (i.e., Class C vs. Class F) on early-age expansion and hydration characteristics of ordinary Portland cement (OPC)–calcium sulfoaluminate (CSA) cement blend. It was observed earlier that the presence of Class C fly ash (CFA), unlike Class F fly ash, shortened the expansion duration of OPC–CSA cement blend, which was hypothesized to be correlated to early depletion of gypsum. This paper presents a detailed verification of the hypothesis. Addition of external gypsum to OPC–CSA–CFA blend led to simultaneous increase in expansion and disappearance of a shoulder peak in the calorimetric curve. Thermodynamic calculations using a geochemical modeling program (GEMS-PSI) revealed higher saturation levels of ettringite in presence of external gypsum, which led to higher crystallization stress, and thereby increased expansion.     

Fluid transport in high volume fly ash mixtures with and without internal curing

The transport of fluid and ions in concrete mixtures is central to many aspects of concrete deterioration. As a result, transport properties are frequently measured as an indication of the durability that a concrete mixture may be expected to have. This paper is the second in a series investigating the performance of high volume fly ash (HVFA) mixtures with low water-to-cementitious ratios (w/cm) that are internally cured. While the first paper focused on strength and shrinkage, this paper presents the evaluation of the transport properties of these mixtures. Specifically, the paper presents results from: rapid chloride migration (RCM), rapid chloride penetration test (RCPT), apparent chloride diffusion coefficient, surface electrical resistivity, and water absorption. The test matrix consisted of mortar samples with two levels of class C fly ash replacement (40% and 60% by volume) with and without internal curing provided with pre-wetted lightweight fine aggregates (LWA). These mixtures are compared to plain ordinary portland cement (OPC) mortars. The results indicate that HVFA mixtures with and without internal curing provide benefits in terms of reduced transport coefficients compared to the OPC mixtures.     

Creep and drying shrinkage of a blended slag and low calcium fly ash geopolymer Concrete

The main purpose of this research is to study the time dependent behaviour of a geopolymer concrete. The geopolymer binder is composed of 85.2 % of low calcium fly ash and only 14.8 % of ground granulated blast furnace slag. Both drying shrinkage and creep are studied. In addition, different curing conditions at elevated temperature were used. All experimental results were compared to predictions made using the Eurocode 2. The curing regime plays an important role in the magnitude and development of both creep and drying shrinkage of class F fly ash based geopolymer concrete. A minimum of 3 days at 40 °C or 1 day at 80 °C is required to obtain final drying shrinkage strains similar to or less than those adopted by Eurocode 2 for ordinary Portland cement (OPC) concrete. Creep strains were similar or less than those predicted by Eurocode 2 for OPC concrete when the geopolymer concrete was cured for 3 days at 40 °C. After 7 days at 80 °C, creep strains became negligible.     

Optimization of ternary cementitious mortar blends using factorial experimental plans

Producing cements incorporating high-volume replacement of ordinary portland cement (OPC) by recycled industrial by-products is perceived as the most promising venture for the cement and concrete industry to meet its environmental obligations. However, the two-component (binary) cements thus produced are often associated with shortcomings such as the need for extended moist-curing, increased use of chemical admixtures, low early age strength, increased cracking tendency due to drying shrinkage, and de-icing salt scaling problems. There is need for research to investigate whether high-volume replacement multi-component (ternary and quaternary) cements could be optimized with synergistic effects allowing component ingredients to compensate for any mutual shortcomings. This study uses factorial experimental plans to investigate the performance of OPC-silica fume (SF)-class F fly ash (FA) and OPC-SF-ground granulated blast furnace slag (GBFS) ternary cementitious blends. Response surfaces for the superplasticizer requirement to achieve a constant flow, setting time, drying shrinkage up to 112 days, compressive strength at 1, 7, 28 and 56 days, and for the sulfate expansion up to 9-months were obtained for up to 20%, 60%, and 60% replacement levels of OPC by SF, FA and GBFS, respectively. A multiparametric optimization is used to establish response surfaces for a desirability function, which is used to rate ternary cementitious blends. Results indicate that when rheological, mechanical, durability and cost requirements are combined; the use of costly mineral admixtures such as silica fume is not economic in ternary OPC-SF-FA or OPC-SF-GBFS blends beyond levels of about 3 to 5% Moreover, it is shown that the major hurdle for high-volume replacement of OPC with class F fly ash is compromising the early age performance. Results also indicate that a good quality high-fineness GBFS can be used at replacement levels of OPC up to 60% without major disadvantages.     

Use of OPC to improve setting and early strength properties of low calcium fly ash geopolymer concrete cured at room temperature

Most previous works on fly ash based geopolymer concrete focused on concretes subjected to heat curing. Development of geopolymer concrete that can set and harden at normal temperature will widen its application beyond precast concrete. This paper has focused on a study of fly ash based geopolymer concrete suitable for ambient curing condition. A small proportion of ordinary Portland cement (OPC) was added with low calcium fly ash to accelerate the curing of geopolymer concrete instead of using elevated heat. Samples were cured in room environment (about 23 °C and RH 65 ± 10%) until tested. Inclusion of OPC as little as 5% of total binder reduced the setting time to acceptable ranges and caused slight decrease of workability. The early-age compressive strength improved significantly with higher strength at the age of 28 days. Geopolymer microstructure showed considerable portion of calcium-rich aluminosilicate gel resulting from the addition of OPC.     

Influence of curing conditions on properties of high calcium fly ash geopolymer containing Portland cement as additive

This paper investigated the mechanical properties and microstructure of high calcium fly ash geopolymer containing ordinary Portland cement (OPC) as additive with different curing conditions. Fly ash (FA) was replaced with OPC at dosages of 0%, 5%, 10%, and 15% by weight of binders. Setting time and microstructure of geopolymer pastes, and flow, compressive strength, porosity and water absorption of geopolymer mortars were studied. Three curing methods viz., vapour-proof membrane curing, wet curing and temperature curing were used. The results showed that the use of OPC as additive improved the properties of high calcium fly ash geopolymer. The strength increased due to the formation of additional C–S–H and C–A–S–H gel. Curing methods also significantly affected the properties of geopolymers with OPC. Vapour-proof membrane curing and water curing resulted in additional OPC hydration and led to higher compressive strength. The temperature curing resulted in a high early compressive strength development.     

Evaluation of the Techniques to Mitigate Early Shrinkage Cracking through an Image Analysis Methodology

Nowadays, new products are introduced in concrete mixes to reduce the effects of shrinkage, which are the main reason of most of early age cracking phenomena, especially when curing is not performed in accordance to best practices. The lack of a standardized methodology to quantify concrete cracking complicates the determination of the effectiveness of different solutions and comparison between them. This research presents an evaluation through images of the suitability of fibres and shrinkage‐reducing admixtures to control early shrinkage cracking in slab‐type concrete elements. The use of this technique has permitted quantifying the typical cracking parameters objectively and analyse probabilistically the average crack width. Results show a delay and reduction of cracking after adding shrinkage‐reducing admixtures and fibres in concrete, especially 1 kg m^?3 of polymeric microfibres. The incorporation of these components directly into the mix modified the behaviour of concrete, reducing shrinkage cracking from the beginning of moisture losses.     

Shrinkage behavior of structural foam lightweight concrete containing glycol compounds and fly ash

Shrinkage behavior of the structural foam lightweight concrete with density of 1600 kg/m³ was investigated. Owing to high drying shrinkage of the lightweight concrete, glycol compounds were used in the concrete mixture to study their effect on shrinkage behavior. Propylene glycol (PG), triethylene glycol (TEG) and dipropylene glycol tert-butyl ether (DPTE) were selected for testing of drying shrinkage of the lightweight concrete. Partial replacement of cement and sand with fly ash was also used to reduce the shrinkage. Results indicated that PG, TEG and DPTE were effective in reducing the shrinkage of lightweight concrete through reduction of surface tension of water. However, DPTE significantly reduced the surface tension and caused the foam instability and early stiffening of mixture. The partial replacement of cement and sand with fly ash could also reduce the shrinkage of the lightweight concrete. In this case, the compressive strength was also enhanced owing to the additional pozzolanic reaction.     

Influence of clays on the shrinkage and cracking tendency of SCC

The influence of different types of clay on the shrinkage and cracking tendency of fly ash modified self-consolidating concrete (SCCF) for the application of slipform paving were investigated in this study. The mortar phase of each mix was tested for autogenous shrinkage, total free shrinkage under drying and restrained shrinkage cracking. The mechanical properties (flexural strength, compressive strength, and modulus) were studied to supplement the results of the shrinkage and cracking tests. The plain SCCF mix was compared against the clay-modified SCCF mixes, as well as conventional SCC and slipform concrete (SFC) mixes. The results showed that the very early-age autogenous shrinkage of SCCF mortar was increased by the addition of clays due to adsorption effects. The effects of the clays on total shrinkage under long-term drying were found to depend mainly on the pozzolanic reactivity, but these effects were very slight at low dosages of about 1% by mass of binder. The early-age cracking tendency was aggravated by the clays composed of purified magnesium alumino silicate and metakaolin, but little influenced by the clay composed of kaolinite, illite and silica. Overall, the SCC mixture modified with both fly ash and a small amount of clay showed comparable shrinkage and early-age cracking performances as conventional SFC.     

The permeability of fly ash concrete

Oxygen permeability tests were carried out on plain ordinary Portland cement (OPC) and fly ash concretes at three nominal strength grades. Prior to testing the concretes were subjected to a wide range of curing and exposure conditions. The results emphasize the importance of adequate curing to achieve concrete of low permeability, especially when the ambient relative humidity is low. In addition, the results demonstrate the considerable benefit that can be achieved by the use of fly ash in concrete. Even under conditions of poor curing, fly ash concrete is significantly less permeable than equal-grade OPC concrete, the differences being more marked for higher-grade concretes. Attempts were made to correlate strength parameters with permeability but it is concluded that neither the strength at the end of curing nor the 28-day strength provides a reliable indicator of concrete permeability. A reliable correlation was established between the water to total cementitious material ratio [w/(c+f)] and the permeability of concretes subjected to a given curing and exposure regime.     

Shrinkage and restrained shrinkage cracking of self-compacting concrete compared to conventionally vibrated concrete

Self-compacting concrete (SCC) used in Switzerland contains about 80 l/m³ more volume of paste than conventionally vibrated concrete (CVC). Consequently, there are some systematic differences in the properties of the hardened concrete. Normally, shrinkage of SCC is higher than shrinkage of CVC. Therefore, risk of cracking in case of restrained deformations can be increased for SCC. In this study shrinkage of thirteen different SCC mixtures using volume of paste, water content, type of binder, grain size distribution or content of shrinkage reducing admixture (SRA) as variables was compared with shrinkage of three different CVC mixtures with constant volume of paste but variable w/b. Furthermore, the risk of cracking of the different SCC- and CVC-mixtures in restrained conditions was studied under constant and varying curing conditions. The results show that shrinkage is mainly depending on volume of paste. Due to the higher volume of paste, SCC displayed higher shrinkage than CVC. Adding an SRA was the only measure to reduce shrinkage of SCC to values of CVC. Restrained shrinkage cracking is depending on shrinkage rate, mechanical properties and drying velocity. For slow shrinkage stress development, cracking risk of SCC can be lower compared to CVC despite the higher shrinkage rate.     

Effect of supplementary cementitious materials on shrinkage and crack development in concrete

The autogenous and drying shrinkage of Portland cement concrete, and binary and ternary binder concretes, were measured and compared. The binary and ternary binder concretes were formed by replacing part of the cement with fly ash, very fine fly ash and/or silica fume. Restrained shrinkage test was also performed to evaluate the effect of binder type on early age cracking. After the cracking of the restrained ring samples, crack widths were measured and compared with the results of an R-curve based model, which takes post-peak elastic and creep strains into account.The incorporation of fly ash and very fine fly ash decreased the autogenous shrinkage strain but increased the drying shrinkage strain. Since the total shrinkage strains of both the ternary and the binary concrete mixtures were similar, the strength development became an important factor in the cracking. The lower strength of the concrete with ternary binders led to earlier cracking compared to the binary binder concrete. Portland cement concrete cracked the earliest and had the greatest crack width. Measured crack widths were in accordance with the crack widths calculated with the R-curve model.     

自密实混凝土圆环约束收缩试验研究

进行了密封与沿环外侧面干燥两种条件下的自密实混凝土圆环约束收缩试验,分别研究自密实混凝土试件在自生收缩单独作用下,以及在干燥与自生收缩共同作用下钢环应变随混凝土龄期的发展规律及开裂性能,并与普通混凝土进行比较。配合比参数包括粉煤灰掺量、粉煤灰和矿渣复掺掺量、水胶比。揭示了配合比参数在两种不同条件下对钢环应变和开裂龄期的影响规律,并提出以“标准化”的钢环应变曲线作为开裂趋势曲线,以开裂系数为0.95时的龄期为“名义开裂龄期”作为圆环试验中混凝土开裂指标的建议。研究结果还表明,同一配合比参数对干燥约束收缩与自生约束收缩的作用有可能一致,也有可能完全相反,因此有必要对两种收缩分别研究;该文提出的“开裂趋势曲线”和“名义开裂龄期”能综合混凝土开裂中“作用”和“抗力”两个方面的影响,从而对混凝土的开裂性能进行动态、定量、综合的评价。     

A quantitative study on the plastic shrinkage cracking in high strength hybrid fibre reinforced concrete

High strength concrete using silica fume is prone to plastic shrinkage cracking in dry and windy conditions. Addition of fibres is known to restrict the growth of shrinkage cracks. The present study was aimed at controlling plastic shrinkage cracks in high strength silica fume concrete by means of adding fibre reinforcement up to 0.5% by volume of concrete. Individual steel fibres as well as hybrid combinations of steel and non-metallic (polyester, polypropylene and glass) fibres were evaluated for their influence on plastic shrinkage cracking. Results showed that hybrid fibres were most effective in reducing shrinkage cracks. Among the hybrid fibre combinations, the steel and polyester combination was found to reduce plastic shrinkage cracks by more than 99% compared to the plain concrete. Increased fibre availability and low stress levels at early ages were the main factors contributing to the good performance of hybrid fibre mixtures.     

Long-term deformations and cracking risk of concrete with high content of mineral additions

This paper presents results from a study on long-term deformations of concrete with a high content of mineral additions, such as blast-furnace slag and fly ash. Autogenous and drying shrinkage were monitored. The kinetics and magnitude of these deformations are modified by the type and content of mineral additions. This behaviour is mainly due to the slow advancement of their hydration reaction and to the evolution of their microstructure during the first days. Mechanical properties were also affected by mineral additions. All these modifications led to an increase in cracking susceptibility of concrete mixtures with blast-furnace slag. But their optimisation in terms of mechanical performance allowed reducing their cracking risk. An analytical model (Eurocode 2) was also applied for comparison. The prediction of the total shrinkage of the studied concrete mixtures was found to be satisfactory, but the autogenous shrinkage of concrete mixtures with mineral additions was significantly underestimated.     

Efficiency of internal curing by superabsorbent polymers (SAP) in PC-GGBS mortars

This paper evaluates the effect of superabsorbent polymers (SAP) on hydration and microstructure of PC-GGBS mortars. Development of autogenous shrinkage, microstructural characteristics (MIP/SEM) and compressive strength were analysed during the first 90 days. Four levels of Portland cement (PC) replacement by GGBS (0%, 25%, 50% and 75%) and two types of SAP with different water absorption capacities were considered. The results proved the efficiency of internal curing by SAPs in PC-GGBS systems due to significant reduction in autogenous shrinkage, especially for higher contents of GGBS. SAP facilitates GGBS hydration activated by portlandite; its products can be deposited into the nano pores leading to a small relative expansion of the hardened bulk volume. This process is initiated during the second week and it lasts until the sixth week. Despite increased total porosity, compressive strength of SAPs modified mortars is comparable to the reference samples for low GGBS contents in advanced ages.     

Ageing effect on tensile and shrinkage behaviour of new green hybrid fibre-reinforced cementitious composites

Ageing effects on both uniaxial tensile and shrinkage behaviour of new green cementitious composites reinforced with bagasse fibre and steel fibre with ultra-high volume of fly ash are investigated in this paper. The tensile behaviour of the composites is investigated at the age of 28 days, 3 months, 6 months and 10 months after curing in weather conditions. Restrained shrinkage behaviour of the composites after curing for 3 months is tested on ring specimens. SEM tests are also conducted to study the influence of the ageing on the microstructure of the new composites. The test results show that the tensile strength of the composites at all ages increases with the decrease of the content of the fly ash and the bagasse fibre, and that the increasing application of fly ash and bagasse fibre decreases the steel ring strain and restrains the development of crack. It is also found that the tensile strength and the shrinkage of the composites such as crack width ascend greatly with time.     

Effect of fly ash and slag on concrete: Properties and emission analyses

Recycled concrete is a material with the potential to create a sustainable construction industry. However, recycled concrete presents heterogeneous properties, thereby reducing its applications for some structural purposes and enhancing its application in pavements. This paper provides an insight into a solution in the deformation control for recycled concrete by adding supplementary cementitious materials fly ash and blast furnace slag. Results of this study indicated that the 50% fly ash replacement of Portland cement increased the rupture modulus of the recycled concrete. Conversely, a mixture with over 50% cement replacement by either fly ash or slag or a combination of both exhibited detrimental effect on the compressive strength, rupture modulus, and drying shrinkage. The combined analysis of environmental impacts and mechanical properties of recycled concrete demonstrated the possibility of optimizing the selection of recycled concrete because the best scenario in this study was obtained with the concrete mixture M8 (50% of fly ash+ 100% recycled coarse aggregate).     

Effect of polypropylene fibers on shrinkage and cracking of concretes

The effects of admixed polypropylene (PP) fibers on the drying shrinkage of hardened concrete are presented in this paper. Concrete mixtures made with Ordinary Portland cement (OPC) and OPC/Slag blended cements containing various volume fractions of PP fiber were tested. The results show small but consistently higher drying shrinkages in concretes incorporating PP fibers than that without fiber. The effect is more pronounced in slag concretes and in concretes cured for only 1 day. An attempt to explain this phenomenon was made by water loss, nitrogen adsorption, sorptivity and scanning electron microscopy tests on the same concretes. Additional moisture loss and porosity are proposed as possible reasons. The results of early-age restrained shrinkage tests on slag concretes show that PP fiber concrete had higher cracking tendency than the concrete without fiber. This was found to be due to higher shrinkage and elastic modulus of PP fiber concrete.     

Estimation of the risk for early thermal cracking for SCC containing fly ash

Cracking of concrete must be avoided during the hardening phase in order to minimize the risk of durability problems in the future, such as corrosion of the reinforcement, water tightness and damages due to frost. Estimation of the risk of early age cracking requires knowledge of the combined effects from temperature development and mechanical behaviour during the hydration. In the present paper, the influence of fly ash on the young concrete behaviour has been investigated. The concrete is based on a Swedish cement aimed for civil engineering structures, and the fly ash is of class F. A comparison of crack risks between concrete containing fly ash in different amounts with concrete without fly ash is presented. Also a previously tested concrete containing limestone filler is considered. The fly ash was added to replace a part of the aggregate, which gives a higher heat evolution. However, a numerical stress analysis showed that the risk for early age through cracking for a typical civil engineering structure is significantly decreased in the mixes containing fly ash. The denotation typical civil engineering structure is used here for concrete structures such as tunnels, bridges, and ramps of common cross-section dimensions. In the case of fly ash added to concrete by a partial replacement of cement, the crack risk will probably be further decreased. For a self-balancing structure of young concrete there is no restraint from adjacent structures, and the temperature and moisture gradients within the young concrete cause self-stresses governed by equilibrium with zero external forces for any cut. The estimated risk for surface cracking on a self-balancing wall or slab was not improved by an addition of fly ash. It is probably an effect of the increased heat development, which most likely counteracts the positive effect of the increased early age creep for concrete containing fly ash. If the heat evolution decreases when cement is partly replaced with fly ash, the use of fly ash might reduce the risk of surface cracks.