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1.
采集了近地面1.5m和40m处气溶胶中的TSP、PM10、SO2和NOx。并对TSP、PM10中的Ag、Al、As、Ba、Be、Bi、Ca、Cd、Co、Cr、Cu、Fe、Pb、Sb等26种微量元素的浓度进行了分析;TSP和PM10的物相结构进行了测试。讨论和研究了气溶胶中不同高度微量元素及晶体物质的垂直分布规律和部分污染物的来源,为河南省和郑州市大气气溶胶的研究奠定了基础。  相似文献   

2.
采用原子吸收分光光度法和化学形态分析流程研究了菥荬籽中13种微量元素的化学形态,初步探讨了其药用功效。实验表明:原料中元素的含量特征为:K>Ca>P>Mg>Fe>Na>Zn>Mn>Cu>As>Cd>Pb>Co;2次煎提效率达87%,表明对其微量元素的提取采用2次煎提方式较为合理。次级形态表明:Fe、Ca、Cu的颗粒吸附态分布>50%;P、As、Na、Fe、Cu、Cd以稳定态形式居多。Cu、Zn、Na的有机态分布约占40%~50%;除P、As以外,其余元素主要以游离阳离子形式存在。从形态分析可见,菥萁籽中Fe含量较丰富,达356μg/g;可溶态中,Zn、Cu的有机态相对较多,且Zn/Cu在原料及水煎液中均为5左右,较为合理。  相似文献   

3.
白马湖水生植物体内重金属调查   总被引:1,自引:0,他引:1  
对白马湖湖区的水生植物进行了Cu、Zn、Pb、Cr和Cd等重金属元素的污染调查与监测分析.结果表明:水生植物对重金属元素的吸收与积累反映了环境中的重金属污染水平,不同水生植物对各种重金属元素的吸收富集状况具有相对一致性,即Zn> Cu> Cr>Pb>Cd.水生植物对各种重金属元素的平均富集系数大小顺序为:Cd> Cu> Zn>Cr>Pb,这与各元素迁移性强弱的顺序也是相一致的,Cd、Cu、Zn等各元素较易为植物所吸收,而Pb的移动性较差.研究表明:可以从中筛选出具有高富集作用的植物,作为修复水体或土壤重金属污染的实验植物,为植物修复作用的研究提供参考.  相似文献   

4.
采用电感耦合等离子体质谱(ICP–MS)法测定了南宁市售茶叶中Cu、Zn、Pb、Cd、As、Cr和Ni七种重金属的含量,运用内梅罗综合污染指数对重金属污染水平进行评价,运用靶标危害系数法对重金属人体健康风险进行评估。结果表明:试验方法精密度和准确度都较高,市售茶叶中重金属Cu、Zn、Pb、Cd、As、Cr和Ni的含量差异较大,其中Pb、Cd、As和Cr的含量均未超过茶叶中重金属标准限值,且均处于安全等级,综合污染指数(P)≤0.7;茶叶中各重金属的单一靶标危害系数(THQ)及综合危害系数的(HI)均远小于1,对人体健康风险小,表明南宁市售茶叶中的重金属不存在明显的健康风险。  相似文献   

5.
ICP-AES测定酵母中有害重金属方法的研究   总被引:1,自引:0,他引:1  
本文建立了高压罐消化-ICP-AES测定酵母中As、Cd、Pb、Cu、Hg的分析方法。As、Cd、Pb、Cu和Hg五种元素方法的相对标准偏差RSD分别为:5.55%、3.83%、4.04%、2.0%和 6.25%,回收率在 95~105%之间,检出限分别为:0.227μg As/g;0.0174μg Cd/g;0.103μg Pb/g;0.098μg Cu/g;0.015μg Hg/g。  相似文献   

6.
通过对淄博市某区域6个月来6个点位大气降尘中重金属监测分析,结果显示淄博市某区域大气降尘受重金属污染比较严重。大气降尘中6中重金属含量范围依次为Cd0.21~0.59mg/kg,Cu115~16gmg/kg,Hi61.8~124mg/kg,Pb555~555mg/kg,Cr117~258mg/kg,Zn685~I820mg/kg。Cd、Cu、Ni、Pb、Cr、Zn等6种主要重金属元素均超出当地土壤中重金属调查含量平均值,而且工业区的污染高于生活区。  相似文献   

7.
为研究厦门市大气颗粒物的污染特征及其对酸雨的影响,于2012年12月至2013年7月在厦门市各区分别采集大气中TSP、PM10、PM2.5颗粒物样品,利用离子色谱法分析了其中的水溶性离子成分含量。结果表明,厦门市大气颗粒物中水溶性离子成分分布特征为:Na+和Ca2+离子主要主要分布在TSP、PM10中,而SO42-离子则主要分布在PM10和PM2.5中。说明Na+和Ca2+离子更容易富集在粗颗粒物粒子上,而SO42-离子主要存在于细颗粒物粒子中。厦门市大气颗粒物中对雨水酸度有重要缓冲作用的Ca2+、Mg2+离子浓度处于较低水平,说明厦门市大气颗粒物对雨水酸度缓冲作用较低,这是厦门地区酸雨发生率较高的原因之一。  相似文献   

8.
用硝酸和高氯酸混合酸消解样品 ,ICP MS法同时测定地衣和鸡蛋粉中Mn、Cu、Zn、Sr、Cd、Fe、Pb、As和Se9种微量元素的含量。在优化实验下 ,测得检出限为 (ng/L) :55Mn2 ,6 3Cu4 ,56 Fe4 ,6 6 Zn9,88Sr1,114 Cd2 ,2 0 8Pb5 ,75As12 ,80 Se6 0。用国家一级标准物质甘兰GBW0 85 0 4验证方法的准确度 ,测定值与标准值吻合较好。并对不确定度的评定程序举例说明  相似文献   

9.
根据《重金属防治"十二五"规划》的要求,本实验对广西某有色矿业周边环境重金属污染进行了监测,对有色金属矿业区周围农田土壤、稻谷和井水进行采样,用火焰原子吸收法和石墨炉原子吸收法测定了采集样品中Cu、Zn、Pb、Cd、Cr含量,对结果进行了初步分析:按照国家标准指标判定,土壤受到了Cu、Zn、Pb、Cd污染;稻谷受到了Pb、Cd污染;矿区生活区水井水受到了Cd的污染。  相似文献   

10.
本文采用微波消解-电感耦合等离子体质谱法(IC P -M S )分析测定苏州古运河野生鲫鱼的肌肉、鳃、眼、肠以及相应河水中Pb、Cd、Cu、Cr、As 、Zn、Ni等重金属含量。该方法的相对标准偏差RSD﹤9%,加标回收率为95.66%~108.32%,检出限在0.0013~0.0049μg/g 之间。测定结果表明:鱼体内重金属分布与水体重金属间相关性不明显,鱼类不同组织器官对重金属积累能力显著不同,Cd、Pb、Cr和Ni主要存在于眼、肠中,鱼肉食用部分中重金属含量符合相关食品安全标准。  相似文献   

11.
An engineering system may consist of several different types of components,belonging to such physical"domains"as mechanical,electrical,fluid,and thermal.It is t...  相似文献   

12.
The strength of composite plate with different hole-shapes is always one of the most important but complicated issues in the application of the composite material. The holes will lead to mutations and discontinuity to the structure. So the hole-edge stress concentration is always a serious phenomenon. And the phenomenon makes the structure strength decrease very quickly to form dangerous weak points. Most partial damage begins from these weak points. According to the complex variable functions theory, the accurate boundary condition of composite plate with different hole-shapes is founded by conformal mapping method to settle the boundary condition problem of complex hole-shapes. Composite plate with commonly hole-shapes in engineering is studied by several complex variable stress fimction. The boundary integral equations are founded based on exact boundary conditions. Then the exact hole-edge stress analytic solution of composite plate with rectangle holes and wing manholes is resolved. Both of offset axis loadings and its influences on the stress concentration coefficient of the hole-edge are discussed. And comparisons of different loads along various offset axis on the hole-edge stress distribution of orthotropic plate with rectangle hole or wing manhole are made. It can be concluded that hole-edge with continuous variable curvatures might help to decrease the stress concentration coefficient; and smaller angle of outer load and fiber can decrease the stress peak value.  相似文献   

13.
Giannuzzi LA  Utlaut M 《Ultramicroscopy》2011,111(11):1564-1573
30 keV Ga+ focused ion beam induced secondary electron (iSE) imaging was used to determine the relative contrast between several materials. The iSE signal compared from C, Si, Al, Ti, Cr, Ni, Cu, Mo, Ag, and W metal layers does not decrease with an increase in target atomic number Z2, and shows a non-monotonic relationship between contrast and Z2. The non-monotonic relationship is attributed to periodic fluctuations of the stopping power and sputter yield inherent to the ion–solid interactions. In addition, material contrast from electron-induced secondary electron (eSE) and backscattered electron (BSE) images using scanning electron microscopy (SEM) also shows non-monotonic contrast as a function of Z2, following the periodic behavior of the stopping power for electron–solid interactions. A comparison of the iSE and eSE results shows similar relative contrast between the metal layers, and not complementary contrast as conventionally understood. These similarities in the contrast behavior can be attributed to similarities in the periodic and non-monotonic function defined by incident particle–solid interaction theory.  相似文献   

14.
The fraction defective of semi-finished products is predicted to optimize the process of relay production lines, by which production quality and productivity ar...  相似文献   

15.
The use of hand gestures can be the most intuitive human-machine interaction medium.The early approaches for hand gesture recognition used device-based methods....  相似文献   

16.
This paper proposes a novel grading method of apples,in an automated grading device that uses convolutional neural networks to extract the size,color,texture,an...  相似文献   

17.
分布动态载荷识别的抗噪处理   总被引:2,自引:2,他引:0  
针对正交多项式频域法在用多种响应对矩形薄板进行载荷识别中抗噪性较差的问题,综合运用平均法、矩阵预处理和奇异值截断法等方法对之进行改善,并引入空间映射的思想,将该方法的应用范围拓展为复杂的模型.利用仿真算例,证实了该方法具有较好的抗噪性.  相似文献   

18.
针对工程实践中环网通讯相关问题的处理缺乏理论基础及国产化安全级DCS平台的开发缺乏成熟经验借鉴问题,对基于MELTAC-N平台核电厂安全级DCS环网的软硬件实现进行了研究。提出了安全级DCS环网双环网冗余设计、光切换开关设计等硬件设计方法,以及以RPR协议为基础,采用全数据收发策略的软件设计方法。在CPR1000安全级DCS平台上对安全级DCS环网的可靠性及实时性进行了评价,并进行了容错能力、响应时间及响应时间稳定性测试验证实验。结果表明,基于MELTAC-N平台安全级DCS环网软硬件设计具有较好的容错能力及响应时间稳定性。  相似文献   

19.
Abrasive wear has long been recognised as one of the most potentially serious tribological problems facing the operators of many types of plant and machinery; several industrial surveys have indicated that wear by abrasion can be responsible for more than 50% of unscheduled machine and plant stoppages. Locating the operating point of a tribological contact in an appropriate operational ‚map’︁ can provide a useful guide to the likely nature and origins of the surface degradation experienced in use, though care must be exercised in choosing the most suitable parameters for the axes of the plot. Laboratory testing of materials and simulations of machine contacts are carried out for a number of purposes; at one level for the very practical aims of ranking candidate materials or surface hardening treatments in order of their wear resistance, or in an attempt to predict wear lives under field conditions. More fundamentally, tests may be aimed at elucidating the essential physical mechanisms of surface damage and loss, with the longer term aim of building an analytical and predictive model of the wear process itself. In many cases, component surface damage is brought about by the ingress of hard, particulate matter into machine bearing or sealing clearances. These may be running dry although, more usually, a lubricant or service fluid is present at the interface. A number of standardised wear test geometries and procedures have been established for both two- and three-body wear situations, and these are briefly described. Although abrasive wear is often modelled as following an ‚Archard’︁ equation (i.e. a linear increase in material loss with both load and time, and an inverse dependence on specimen hardness) both industrial experience and laboratory tests of particularly lubricated contacts show that this is not always the case: increasing the hardness differential in an abrasively contaminated lubricated pair may not always reduce the rate of damage to the harder surface.  相似文献   

20.
A graph as the new engineering method for estimate the safety of bulging deformation of coke tower is proposed. Through stresses analysis of circumferential weld of coke tower and comparing the stresses produced by pressure with heat stress of steady state, residual stress, bending stress produced by both itself weight and wind loads, it showed that the stresses produced by pressure on the angle distortion are the main factor of equivalent stress of the combined stress. After comparing four kinds of stress controlling conditions, the relation to stress with depth of angular distortion, grade of curvature of angular distortion and half of region of angular distortion has been inferred. Graph of deformation allowable value of coke tower for different condition by angular distortion and half of region of angular distortion has been plotted. The five steps for its engineering use have been explained. The lighter the grade of curvature is, the larger of bulge allowance, may be, and the bigger of depth of angular distortion may pose too. For the coke tower with a popular structure of Dg 5 400 mm×28 mm, the result by graph is nearly more than the result of two formulas formed by other research, the error is less than 7.0%. But, the graph can be easily applied to different size of angular distortion.  相似文献   

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