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浓度对传质系数的影响及多元物系传质 总被引:4,自引:1,他引:3
在筛板塔中对甲醇-乙醇-水三元物系进行精馏传质过程实验,考虑浓度对传质系数的影响建立了一个数学模型,对各组分在塔中的浓度分布进行模拟计算,计算结果能正确反映各组分在塔中浓度分布的变化规律.实验与计算结果都表明在某些浓度范围内乙醇呈现出比较复杂的变化规律. 相似文献
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《应用化工》2016,(12):2326-2331
精馏过程稳态模拟主要是针对实际精馏操作过程中精馏塔内的温度、压力、汽液相流量及汽液相组成分布进行分析,并通过模拟找到制约生产的瓶颈。稳态精馏过程模拟计算的难点是求解MESH方程组。国内外已经提出了许多稳态精馏过程模拟的计算方法,主要包括三对角矩阵法、牛顿法、内外层法、松弛法以及其他方法。精馏过程的数学模型及其求解方法直接影响到精馏过程模拟结果的准确性。随着计算机的发展,许多精馏过程的稳态计算方法已被编成程序应用于精馏过程模拟。主要介绍了精馏过程的数学模型,国内外稳态精馏过程模拟计算方法的发展历程,归纳了几类主要稳态精馏过程模拟计算方法的应用及优缺点,旨在为稳态精馏过程模拟计算方法的后续研究提供基础。 相似文献
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《应用化工》2022,(12):2326-2331
精馏过程稳态模拟主要是针对实际精馏操作过程中精馏塔内的温度、压力、汽液相流量及汽液相组成分布进行分析,并通过模拟找到制约生产的瓶颈。稳态精馏过程模拟计算的难点是求解MESH方程组。国内外已经提出了许多稳态精馏过程模拟的计算方法,主要包括三对角矩阵法、牛顿法、内外层法、松弛法以及其他方法。精馏过程的数学模型及其求解方法直接影响到精馏过程模拟结果的准确性。随着计算机的发展,许多精馏过程的稳态计算方法已被编成程序应用于精馏过程模拟。主要介绍了精馏过程的数学模型,国内外稳态精馏过程模拟计算方法的发展历程,归纳了几类主要稳态精馏过程模拟计算方法的应用及优缺点,旨在为稳态精馏过程模拟计算方法的后续研究提供基础。 相似文献
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以ChemCAD软件对哌嗪精馏塔进行模拟计算,以确定该精馏塔的理论板数、进料位置、各塔板的温度、压力及流率分布。模拟计算结果精馏塔的理论板数为22块,精馏可使哌嗪的质量分数达到99.38%。间歇精馏实验表明,实验值与模拟值基本吻合。 相似文献
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介绍了大型塔板涉及反应精馏的传质与操作过程,通过对塔板上液体流动分布以及化学反应过程的分析,建立了能够关联液体流速分布和化学反应的塔板液相浓度计算模型。最后将二维定数混合池模型与描述传质的微分方程联立,利用有限元法求解了大型反应精馏塔板上的液相浓度分布。 相似文献
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A new computational mass transfer model is proposed for simulating the distillation process by solving the fluctuating mass flux for the closure of turbulent mass transfer equation in order to obtain the concentration profile and the separation efficiency of distillation column. The feather of the proposed model is to abandon the conventional way of introducing the turbulent mass transfer diffusivity (dispersion coefficient) to the turbulent mass transfer equation. To verify the validity of the proposed model, a commercial scale packed column and a sieve tray column were simulated and compared with published experimental data. The simulated results were satisfactorily confirmed in both concentration distribution and separation efficiency. 相似文献
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I. V. Ivanov V. A. Lotkhov N. N. Kulov 《Theoretical Foundations of Chemical Engineering》2017,51(3):253-261
New data on the concentration profiles in a packed column during extractive distillation of benzene–heptane mixture in the presence of N-methylpyrrolidone as a separating agent have been obtained. A calculation method for the process based on partial mass transfer coefficients in the vapor and liquid has been proposed. The calculated and experimental data have been compared. It has been shown that both continuous and batch extractive distillation are calculated more precisely using the proposed model compared to the equilibrium model. 相似文献
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《Chemical Engineering and Processing: Process Intensification》1987,21(2):107-113
Mass transfer in extractive distillation in plate columns on a laboratory and pilot-plant scale was investigated experimentally by the separation of an azeotropic mixture, acetone—methanol, with water and 1,2-propylene glycol as solvents. The decrease in mass transfer efficiency with increasing solvent concentration was explained by a decrease and partial blocking of the interfacial area caused by the solvent. A mathematical model was established for mass transfer in extractive distillation on valve plates of diameter 0.4 m. This model was applied successfully to an industrial column. 相似文献
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The Intalox metal tower packing was used to simulate an industrial relevant extractive distillation column for purifying azeotropic multicomponent mixture.In order to explain the inconsistencies in the modeling of transfer process in nonideal multicomponent distillation column,a method was developed with equilibrium stage models(EQ)and non-equilibrium model(NEQ)incorporated with Maxwell-Stefan diffusion equations in the framework of AspenONE simulator.Dortmund Modified UNIFAC(UNIFAC-DMD)thermodynamic model was employed to estimate activity coefficients.In addition,to understand the reason for the diffusion against driving force and the different results by EQ and NEQ models,explicit investigations were made on diffusion coefficients, component Murphree efficiency and mass transfer coefficients.The results provide valuable information for basic design and applications associated with extractive distillation. 相似文献
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A computational mass transfer model is proposed for predicting the concentration profile and Murphree efficiency of sieve tray distillation column. The proposed model is based on using modified two equations formulation for closing the differential turbulent mass transfer equation with improvement by considering the vapor injected from the sieve hole to be three dimensional. The predicted concentration distributions by using proposed model were checked by experimental work conducted on a sieve tray simulator of 1.2 meters in diameter for de-sorbing the dissolved oxygen in the feed water by blowing air. The model predictions were confirmed by the ex-perimental measurement. The validation of the proposed model was further tested by comparing the simulated re-sult with the performance of an industrial scale sieve tray distillation column reported by Kunesh et al. for the strip-ping of toluene from its water solution. The predicted outlet concentration of each tray and the Murphree tray effi-ciencies under different operating conditions were in agreement with the published data. The simulated turbulent mass transfer diffusivity on each tray was within the range of the experimental result in the same sieve column re-ported by Cai et al. In addition, the prediction of the influence of sieve tray structure on the tray efficiency by using the proposed model was demonstrated. 相似文献
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S. Hernández 《化学工程与技术》2008,31(4):597-603
Three complex extractive distillation options were studied for the purification of a dilute mixture of ethanol and water. The first option uses an extractive distillation column and the other two options use thermally coupled extractive distillation sequences. The results indicate that the fully thermally coupled extractive option can reduce energy consumption by ca. 30 % compared to the scheme that uses an extractive distillation column. This fully thermally coupled extractive distillation sequence can produce ethanol as distillate with a mass fraction of 0.995, the entrainer as the bottoms product and a mixture of ethanol and water as the sidestream. 相似文献
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苯乙酮与α-苯乙醇属近沸点物系,用普通精馏方法很难将二者进行有效地分离。在对已报道的分离方法进行比较分析的基础上,提出了采用萃取精馏方法来分离苯乙酮和α-苯乙醇。文中首先通过定性判断和基团贡献法定量地估算选择了该二元物系合适的萃取剂为丙三醇。然后采用Aspen Plus化工模拟软件中的RadFrac模块进行了萃取精馏塔的模拟,分别考察了溶剂与原料进料位置、回流比、溶剂比对分离效果的影响。结果表明:对于处理量为1 000 kg/h的待分离物系,操作压力为5 kPa,在塔板数为30的条件下萃取精馏塔在原料进料位置为第19块塔板,溶剂进料位置为第6块塔板,回流比为3∶1(质量比),溶剂流率为800 kg/h的优化条件下,可以使塔顶苯乙酮质量分数达到99.8%,且塔釜几乎不含苯乙酮。模拟结果对进一步的实验研究和工业生产具有一定的指导意义。 相似文献
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一种改进的多元精馏塔动态模型 总被引:3,自引:0,他引:3
综合了精馏塔的物料及能量平衡、塔板水力学方程、塔板效率及再沸器动态特性,给出一种改进的非理想多元物系精馏塔通用动态数学模型.增加了汽液平衡计算,从而弥补了文献[1]所提出的动态模型的缺陷,提高了其精度和通用性.模型仿真算法采用Gear积分方法,稳定性好,对解刚性比很高的精馏塔微分方程组十分有效.通过对某丙烯腈萃取精馏塔的仿真表明,该动态模型能够较好地反映对象的动态形为. 相似文献