Zinc diffusion in InAsP/InGaAs heterostructures

A systematic study of the sealed ampoule diffusion of zinc into epitaxially grown InP, In_0.53Ga_0.47As, In_0.70Ga_0.30As, In_0.82Ga_0.18As, and through the InAsP/InGaAs interface is presented. Diffusion depths were measured using cleave-and-stain techniques, electrochemical profiling, and secondary ion mass spectroscopy. The diffusion coefficients, , were derived. For InP, D₀=4.82 × 10⁻²cm²/sec and E_a=1.63 eV and for In_0.53Ga_0.47As, D₀=2.02 × 10⁴cm²/sec and E_a=2.63 eV. Diffusion into the heteroepitaxial structures used in the fabrication of planar PIN photodiodes is dominated by the effects of the InP/InGaAs interface.     

Interfaces of InAsP/InP multiple quantum wells grown by metalorganic vapor phase epitaxy

We present results of the growth of InAs_xP_1−x/InP strained heterostructures by low pressure metalorganic vapor phase epitaxy. A large incorporation of arsenic into the InAsP ternary was observed using tertiarylbutylarsine as precursor. High resolution x-ray diffraction, photoluminescence, and optical absorption measurements for InAsP/InP strained multiple quantum wells reveal that the InAsP/InP interface is very sensitive to growth interruption. A systematic study of a growth in terruption sequence designed to improve the InAs/InP interface was carried out. For nonoptimal growth interruption procedures a large density of interface states is created, probably as a consequence of compositional modifications within the interface region. We find that the absorption spectrum may reveal a significant density of interface states. Thus, photoluminescence on its own is insufficient to characterize the interface roughness even for structures showing narrow low-temperature photoluminescence peaks. We also observe an enhancement of the As content for structures grown on InP (001) relative to those simultaneously grown on InP(001) two degrees off toward [100], which suggests that the composition of As in the ternary is limited by its surface diffusion.     

LOW TEMPERATURE OPEN TUBE Zn DIFFUSION IN InP/InGaAs(P)

To fabricate quasi-planar optoelectronic integrated circuits(OEICs),a new open tube Zndiffusion method has been developed.The characteristics of Zn diffusion in InP/InGaAs(P)heterostrueturematerials at comparatively low temperature have been studied,and it has been found for the first time that Zndiffusion rate is proportional to the square of phosphorus content of the InGaAsP materials.     

Self-organization phenomenon of strained InGaAs on InP (311) substrates grown by metalorganic vapor phase epitaxy

We have demonstrated that a self-organization phenomenon occurs in strained InGaAs system on InP (311) substrates grown by metalorganic vapor phase epitaxy. This suggests that a similar formation process of nanocrystals exists not only on the GaAs (311)B substrate but also on the InP (311)B substrate. However, the ordering and the size homogeneity of the self-organized nanocrystals are slightly worse than those of the InGaAs/AlGaAs system on the GaAs (311)B substrate. The tensilely strained condition of a InGaAs/InP system with growth interruption in a PH₃ atmosphere reveals a surface morphology with nanocrystals even on the InP (100) substrate. It was found that strain energy and high growth temperature are important factors for self-organization on III-V compound semiconductors. Preliminary results indicate that the self-organized nanostructures in strained InGaAs/InP systems on InP substrates exhibit room temperature photoluminescent emissions at a wavelength of around 1.3 p.m.     

Metalorganic vapor phase epitaxial growth,characterization and annealing experiments on InP doping superlattices

InP doping superlattices (DSLs) were grown by atmospheric pressure metalorganic vapor phase epitaxy (MOVPE) and their stability was examined by annealing at high temperatures. Diethylzinc (DEZ) and H₂S were used asp- andn-type doping sources, respectively. Photoluminescence (PL) measurements performed on as grown layers show a shift of the main emission peak with increasing excitation power in very good agreement with theoretical models. A comparison of the PL results between these structures and the annealed samples show that even at very high temperatures (up to 850° C) the tunability of the effective bandgap of the annealed superlattices is possible, although less pronounced than for the as grown layers. This is due to diffusion of the dopants, into adjacent layers and partial compensation of each other. Secondary ion mass spectrometry (SIMS) done on the as grown and annealed samples shows that only the Zn atoms diffuse. Diffusion coefficients obtained from the SIMS profiles give values in the range 1 × 10⁻¹⁴ <D < 9 × 10⁻¹⁴ cm²/s, still smaller than other published values estimated on layers, which did not suffer any treatment. This shows the high quality and stability of our layers even at high temperatures.     

InGaAs/InP单光子雪崩光电二极管InP顶层掺杂研究

通过理论计算和对比实验研究了InGaAs/InP单光子雪崩光电二极管中InP顶层掺杂浓度对于器件性能的影响.理论结果显示,InP顶层的掺杂浓度越低越有利于抑制边缘击穿,降低隧穿暗载流子产生速率,提高雪崩击穿几率.实验结果显示,顶层非故意掺杂的器件在223K下获得了20%的单光子探测效率和1kHz的暗计数率,其单光子探测效率比顶层掺杂浓度为5×10~(15)/cm~3的器件高3%~8%,而暗计数率低一个量级.结果表明,降低InP顶层的掺杂浓度有利于提高器件性能.     

InGaAs/InP材料的Zn扩散技术

使用MOCVD反应室进行了InGaAs和InP材料上的Zn扩散工艺条件研究.通过控制扩散温度、扩散源浓度和扩散时间三个主要工艺参数,研究了InGaAs/InP材料的扩散系数和扩散规律,获得了优化的扩散条件.试验表明,该扩散工艺符合原子扩散规律,扩散现象可以用填隙-替位模型解释.样品经过快速退火过程,获得了极高的空穴浓度.InP的空穴浓度达到7.7×1018/cm3,而InGaAs材料达到7×1019/cm3.在优化的扩散条件下,Zn扩散的深度和浓度精确可控,材料的均匀性好,工艺重复性好,能够应用于光电探测器或其他器件.     

Selective area LPE growth and open tube diffusion in InGaAs/InP

Techniques are described in which selective chemical etching, localised LPE growth and localised diffusion in In_0.53Ga_0.47As and InP were carried out. Spun-on silica films were employed as masks in these processes and its performance was found to be comparable with pyrolytic or rf deposited films. Localised LPE growth of In_0.53Ga_0.47As and in-situ etching enabled well-controlled islands of In_0.53Ga_0.47As embedded in InP to be produced. Orientation dependent growth rates were also identified. An open-tube diffusion technique based on an LPE growth system has been successfully used for diffusion of Zn into InP and In_0.53 Ga_0.47As from Sn solutions. A strong variation of diffusion depth in InP with Zn concentration in Sn has been observed at low Zn concentrations but a constant depth is approached for Zn concentrations greater than ∼0.08 atomic fraction.     

Nd:YAG连续激光诱导下InP的Zn掺杂

Nd:YAG连续激光辐照在表面蒸有Zn薄膜的n-InP片上,用激光诱导的方法实现Zn在InP中掺杂。形成PN结。用电化学C-V方法和扫描电子显微镜对辐照后的样品进行分析研究,给出激光辐照功率、辐照时间等工艺参数对结深、浓度分布影响.在n-InP片表面得到受主浓度分布均匀、高掺杂（～1019cm-3）、浅结（～1μm）的P-InP。初步分析其掺杂机理是激光诱导下所形成的合金结过程。     

Performance comparison of state-of-the-art heterojunction bipolar devices (HBT) based on AlGaAs/GaAs, Si/SiGe and InGaAs/InP

This paper presents a comprehensive comparison of three state-of-the-art heterojunction bipolar transistors (HBTs); the AlGaAs/GaAs HBT, the Si/SiGe HBT and the InGaAs/InP HBT. Our aim in this paper is to find the potentials and limitations of these devices and analyze them under common Figure of Merit (FOM) definitions as well as to make a meaningful comparison which is necessary for a technology choice especially in RF-circuit and system level applications such as power amplifier, low noise amplifier circuits and transceiver/receiver systems. Simulation of an HBT device with an HBT model instead of traditional BJT models is also presented for the AlGaAs/GaAs HBT. To the best of our knowledge, this work covers the most extensive FOM analysis for these devices such as I-V behavior, stability, power gain analysis, characteristic frequencies and minimum noise figure. DC and bias point simulations of the devices are performed using Agilent's ADS design tool and a comparison is given for a wide range of FOM specifications. Based on our literature survey and simulation results, we have concluded that GaAs based HBTs are suitable for high-power applications due to their high-breakdown voltages, SiGe based HBTs are promising for low noise applications due to their low noise figures and InP will be the choice if very high-data rates is of primary importance since InP based HBT transistors have superior material properties leading to Terahertz frequency operation.     

Interface strain in organometallic vapor phase epitaxy grown InGaAs/InP superlattices

The spatial distribution of strain in organometallic vapor phase epitaxy grown InGaAs/InP superlattice structures has been studied by varying the thicknesses of the InGaAs well and the InP barrier layers and measuring the strain. High resolution x-ray diffraction rocking curves were used to measure the strain from angular separation between the zeroth-order superlattice peak and the substrate (004) peak. The results are consistent with a compressive strain resulting from arsenic carryover into the InP following InGaAs growth. The strain is not localized at the interfaces but extends into the InP barrier layer. The amount of arsenic carryover increases with the growth time of the InGaAs well.     

Optical properties of Zn-diffused InP layers for the planar-type InGaAs/InP photodetectors

Zn diffusion into InP was carried out ex-situ using a new Zn diffusion technique with zinc phosphorus particles placed around InP materials as zinc source in a semi-closed chamber formed by a modified diffusion furnace.The optical characteristics of the Zn-diffused InP layer for the planar-type InGaAs/InP PIN photodetectors grown by molecular beam epitaxy (MBE) has been investigated by photoluminescence (PL) measurements.The temperature-dependent PL spectrum of Zn-diffused InP samples at different diffusion temperatures showed that band-to-acceptor transition dominates the PL emission,which indicates that Zn was commendably diffused into InP layer as the acceptor.High quality Zn-diffused InP layer with typically smooth surface was obtained at 580 ℃ for 10 min.Furthermore,more interstitial Zn atoms were activated to act as acceptors after a rapid annealing process.Based on the above Zn-diffusion technique,a 50μm planar-type InGaAs/InP PIN photodector device was fabricated and exhibited a low dark current of 7.73 pA under a reverse bias potential of-5 V and a high breakdown voltage of larger than 41 V (I ＜ 10 μA).In addition,a high responsivity of 0.81 A/W at 1.31 μm and 0.97 A/W at 1.55 μm was obtained in the developed PIN photodetector.     

On the role of interface properties in the degradation of metalorganic vapor phase epitaxially grown Fe profiles in InP

Fe doping profiles in InP layers grown by low-pressure metalorganic vapor phase epitaxy (LP-MOVPE) were investigated by secondary ion mass spectroscopy. Different pre-treatments of the InP substrates proved to have substantially different effects on the Fe profiles which strongly indicate the relevance of underlying interfaces to dopant diffusion in subsequent layers, at least in the case of dopants occupying the group-III sublattice. We attribute the degradation of Fe profiles observed for some kinds of treatment to the emission of In interstitials from surfaces covered by oxides or other residues which are incompletely removed during the MOVPE preheat cycle. A favorable substrate preparation method for avoiding Fe profile degradation relies on etching by 5:1:1 H₂SO₄:H₂O₂:H₂O at room temperature followed by 30 min deionized water rinsing.     

Metalorganic vapor phase epitaxial growth and structural characterization of GaAs/InP heterostructures

Highly mismatched GaAs epitaxial layers with thickness ranging from 15 nm to 7 μm have been grown on InP substrates by atomospheric pressure metalorganic vapor phase epitaxy. Layers thinner than 30 nm exhibited 3-D growth mechanism; in the thicker layers, the islands coalesced and then the growth followed the layer by layer mechanism. The elastic strain and the extended defects have been studied by high resolution x-ray diffraction and transmission electron microscopy, respectively. The common observation of planar defects, misfit, and threading dislocations in the layers has been confirmed. The results on the elastic strain release have been discussed on the basis of the equilibrium theory.     

带有复合掺杂层集电区的InP/InGaAs/InP DHBT直流特性分析

设计了一种新结构InP/InGaAs/InP双异质结双极晶体管(DHBT),在集电区与基区之间插入n -InP层,以降低集电结的导带势垒尖峰,克服电流阻挡效应.采用基于热场发射和连续性方程的发射透射模型,计算了n -InP插入层掺杂浓度和厚度对InP/InGaAs/InP DHBT集电结导带有效势垒高度和I-V特性的影响.结果表明,当n -InP插入层掺杂浓度为3×1019cm-3、厚度为3nm时,可以获得较好的器件特性.采用气态源分子束外延(GSMBE)技术成功地生长出InP/InGaAs/InP DHBT结构材料.器件研制结果表明,所设计的DHBT材料结构能有效降低集电结的导带势垒尖峰,显著改善器件的输出特性.     

InP/In_xGa_(1-x)As异质结构中Zn元素的扩散机制

采用闭管扩散方式实现了Zn元素在晶格匹配InP/In_(0.53)Ga_(0.47)As及晶格失配InP/In_(0.82)Ga_(0.18)AS两种异质结构材料中的P型掺杂,利用二次离子质谱(SIMS)以及扫描电容显微技术(SCM)对Zn在两种材料中的扩散机制进行了研究.SIMS测试表明:Zn元素在晶格失配材料中的扩散速度远大于在晶格匹配材料中的扩散速度,而SCM测试表明:两种材料中的实际PN结深度与SIMS测得的Zn扩散深度之间存在一定的差值,这是由于扩散进入材料中的Zn元素并没有被完全激活,而晶格失配材料中Zn的激活效率相对更低,使得晶格失配材料中Zn元素扩散深度与PN结深度的差值更大.SCM法是一种新颖快捷的半导体结深测试法,对于半导体器件工艺研究具有重要的指导意义.     

带有复合掺杂层集电区的InP/InGaAs/InP DHBT直流特性分析

设计了一种新结构InP/InGaAs/InP双异质结双极晶体管(DHBT),在集电区与基区之间插入n+-InP层,以降低集电结的导带势垒尖峰,克服电流阻挡效应.采用基于热场发射和连续性方程的发射透射模型,计算了n+-InP插入层掺杂浓度和厚度对InP/InGaAs/InP DHBT集电结导带有效势垒高度和I-V特性的影响.结果表明,当n+-InP插入层掺杂浓度为3×1019cm-3、厚度为3nm时,可以获得较好的器件特性.采用气态源分子束外延(GSMBE)技术成功地生长出InP/InGaAs/InP DHBT结构材料.器件研制结果表明,所设计的DHBT材料结构能有效降低集电结的导带势垒尖峰,显著改善器件的输出特性.     

Characterization of Mg-doped InP grown by MOCVD using a bis(methylcyclopentadienyl)magnesium dopant source

The use of bis(methylcyclopentadienyl)magnesium (MCp₂Mg) as ap-dopant source for MOCVD-grown InP has been investigated. The Mg incorporation was nonlinear. The relationship between the H₂ flow through the MCp₂Mg bubbler and the Mg concentra-tion in the epilayers suggested that when [Mg] <20 ppb in the reactor it was mostly depleted from the gas mixture, probably by means of reaction with O₂ or H₂O, but at higher concentrations a large fraction of the Mg diffusing to the epilayers was incor-porated. For concentrations >10¹⁹ cm^s-3 the layer morphology deteriorated and stacking faults were observed by TEM, at a density greater than 10⁹ cm^s−2. Significant diffusion of Mg into the substrates during the growth was observed, with diffusion depths up to 0.1 μm at a concentration of 10¹⁹ cm^s−3 in S-doped, and up to 32 μm at 10¹⁷ cm^s-3 in Fe-doped substrates. These concentrations correspond to the S and Fe doping level in those substrates, and the results are explained in terms of the formation of a complex between the S or Fe dopants and the diffusing Mg, which immobilizes the latter species. At [Mg] >10¹⁸ cm^s−3, the net hole concentration, measured by means of electrochemical C-V pro-filing, decreases with increasing [Mg], indicating significant self compensation. Com-pensation at high [Mg] was also suggested by the effect of excitation power density on the peak shift of the donor to acceptor transition observed during photoluminescence measurements at 7 K.     

InP基光电探测器材料的MOCVD锌扩散

锌(Zn)扩散是制作InP基光电探测器(PD)的重要工艺过程.分析了锌扩散的机制,利用金属有机化学气相沉积(MOCVD)设备对InP基PD及雪崩光电探测器(APD)材料进行了锌扩散,由于MOCVD设备具有精确的温度控制系统,所以该扩散工艺具有简单、均匀性好、重复性好的优点.对于扩散后的样品,采用电化学C-V方法和扫描电子显微镜(SEM)等测试分析手段,研究了退火、扩散温度、扩散源体积流量和反应室压力等主要工艺参数对InP材料扩散速率和载流子浓度的影响,并将该锌扩散工艺应用于InP基光电探测器和雪崩光电探测器的器件制作中,得到了优异的器件性能结果.     

The characteristics of Zn-doped InP using spin-on dopant as a diffusion source

Zn diffusion into InP was carried out ex-situ using a spin-on dopant as a diffusion source. The characteristics of Zn-doped InP are analyzed using low-temperature photoluminescence (PL), differential Hall measurement, and secondary ion mass spectrometry (SIMS). Dopant activation of Zn is close to 100% using this method. Band-to-acceptor (B-A) transition peak is dominant in PL, which is a characteristic usually found in in-situ doping. This evidence along with an activation energy of 0.5 eV show that the diffusion is substitutional rather than interstitial.