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Existing State and Partitioning of Rare Earth on Weathered Ores 总被引:5,自引:0,他引:5
The existing state and partitioning of rare earth (RE) on weathered ores in Longnan County(LN), Xingfeng County(XF) and Ninghua County(NH) were characterized systematically by standard geological analytical methods. It is found that RE in the weathered rare earth ores exist as four phases: (a) water soluble, (b) ion-exchangeable, (c) colloidal sediment (oxides), (d) minerals, in which mainly as ion exchangeable phase, accounting for nearly 80% of total RE, with about 20% in the form of colloid sediment phase and mineral phase, but very little as aqueous soluble phase. These rare earth partitioning were mainly chosen mid-heavy RE elements, occupying above 60%, but not equal in the four phases. The mid-heavy RE elements were primarily enriched in the ion exchangeable phase up to 40%, while the containment of cerium dioxide is below 2 %. The cerium deficiency occurs in the ion exchangeable phase in weathered ore. It results from that the Ce^3+ is oxidized into Ce^4+ and changes into CeO2. For LN ore, the containment of Y is high in weathered ore because Y-minerals are abundant in original rock. 相似文献
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《Canadian Metallurgical Quarterly》2013,52(4):377-387
The increasing development of new technologies requiring rare earth elements has resulted in greater demand for rare earth element (REE) extraction and processing. However, REE concentration is a complex process and usually deposit specific. The mineralogy of each deposit can vary widely, but is essentially characterised by the type of REE and host gangue, chemistry and degree of liberation of the minerals that dictate the processing route. This paper presents REE mineral processing routes for the recovery of commercially valuable REE bearing minerals, such as REE fluorocarbonates and monazite, from silicates and carbonate gangue minerals. 相似文献
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方涛 《中国稀土学报(英文版)》1997,(4)
OxygenIsotopeFractionationofCommonREFluorocarbonateFangTao(方涛)(InstituteofGeochemistry,AcademiaSinica,Guiyang550002,China)Re... 相似文献
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主要介绍了稀土资源的重要作用及利用现状,对我国的稀土矿分布及特征进行概述,并提出稀土开采存在的问题及微生物采矿的优势。回顾利用微生物进行稀土矿开采的发展进程,总结其研究进展,介绍微生物采矿作用机理的研究,主要包括微生物浸出、吸附和积累稀土元素机理的相关研究,以及稀土矿采矿微生物的分离方法及种属分布等。以中国白云鄂博矿床和澳大利亚Mount Weld矿床中的矿石为例,说明微生物对矿石中稀土元素的提取作用。简述微生物对废弃物中稀土元素的回收作用,及微生物利用稀土元素技术将面临的挑战,并对其未来进行了展望。 相似文献
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The influence of temperature on the complex process of Bayan Obo rare earth (RE) ore flotation with a collector of naphthyl hydroxamic acid (LF8#) was investigated. Industrial test data shows that the grade and recovery of RE increase with the temperature. However, the proportion of bastnaesite in the bulk concentrate increases as the RE grade improves. Adsorption mechanism of LF8# on the surfaces of bastnaesite and monazite were confirmed via zeta potential, UV/Vis Spectrophotometer (UV/Vis), Fourier transform infrared (FTIR), and X-ray photoelectron spectroscopy analyses (XPS). Although the results indicate that the total amount of the LF8# adsorption on the surface of bastnaesite and monazite decreases with increasing the temperature, the amount of stable adsorbed predominance of characteristic bonds (C(O)N) from LF8# uptake on bastnaesite surfaces increases significantly at high temperatures. This conclusion indicates that the adsorption stability increases with increasing the temperature. For monazite, the amount of characteristic elements C and N in LF8# does not increase as the temperature increases on the mineral surface, but the proportion of characteristic bonds increases, which shows that the adsorption stability of LF8# on the surface of monazite also increases, but it is not as significant as bastnaesite, which may be one of the reasons that the floatability of bastnaesite is better than those of monazite. Pulp dispersion results show that the temperature improve the dispersions of both the gangue and RE minerals. This improved the flotation selectivity so that it favored RE minerals. The calculated bubble size distribution confirms that higher temperatures generate smaller bubbles, thereby increasing the bubble-particle collision probability and the recovery of RE minerals. 相似文献
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赣南离子吸附型稀土矿富含中、重稀土元素,具有极高的经济价值及重要的战略意义.在对大量文献资料进行查阅及分析的基础上,介绍铝在离子吸附型稀土矿中的赋存形态、浸出行为以及对稀土工业生产的影响,系统地阐述离子吸附型稀土矿浸取过程中除铝技术的研究和实践进展,并对现有技术进行分析总结,提出未来离子吸附型稀土矿除铝技术应向环境友好型发展,并实现除铝产物资源化、商品化. 相似文献
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Huang Xiaowei Li Hongwei Xue Xiangxin Zhang Guocheng 《中国稀土学报(英文版)》2006,24(2):154-154
Characteristic and hydrometallurgy processes for Baotou mixed-type rare earth concentrate, bastnasite, and ionic adsorption deposit in China were reviewed. The R & D circumstance and new progresses in extraction and separation of RE element in China were introduced. Moreover, the development trend of RE hydrometallurgy was predicted. The direction and emphasised fields of research and development are also brought forward as: to R & D high efficient green progresses in hydrometallurgy and separation of RE ore, resolve the waste pollution problem of water, slagand gas, reduce the chemical material consumption and improve comprehensive efficiency of resources; to R & D preparation technology for RE compounds with ultra high-purity and special physical property for extending application fields of RE. 相似文献
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为保护资源和生态环境,促进稀土产业绿色可持续发展,基于现代控制理论的能观测性和能控性新视角,采用CRITIC-G1组合赋权与云模型相结合的方法,构建了离子型稀土矿开采工艺评价模型,并对不确定开采条件下的原地浸矿工艺与堆浸工艺进行了评价.研究得出:①基于保护资源和生态环境的目的,离子型稀土矿开采工艺评价指标体系不仅要考虑... 相似文献
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离子吸附型稀土矿是国家战略资源,加强稀土废弃矿资源综合利用、充分回收残留稀土资源是今后稀土研究领域重要研究方向之一.文章在总结离子吸附型稀土矿提取工艺发展演变的基础上,重点分析了离子吸附型稀土废弃矿中残留稀土原因及其赋存状态.研究结果表明,离子吸附型稀土废弃矿中残留稀土的主要因素有浸矿过程的浸矿盲区、毛细现象、风化不完... 相似文献
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通过对赣州稀土产业现状、赣州稀土产业发展优势与存在问题的分析,提出赣州要利用丰富的离子型稀土资源,打造稀土优势产业的建议,建议的主要内容有:优化资源配置,促进精深加工;引进战略投资,延伸产业链条;加快平台建设,健全服务体系;推进资本运作,提高产业发展动力;加大技术创新,促进产业技术进步;完善配套产业,拓宽产业发展空间;建立稀土储备体系,应对价格波动. 相似文献
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为查明建水稀土矿的稀土数值特征,在长岭岗岩体风化壳的黏土层、全风化层、半风化层、弱风化层中采集了82件样品,进行全相稀土氧化物、离子相稀土氧化物质量分数分析,包括全相稀土氧化物的质量分数、离子相稀土氧化物的质量分数、全相与离子相稀土氧化物质量分数的相关系数、全相稀土氧化物在各个风化层位中的变化系数、离子相稀土氧化物在各个风化层位中的变化系数、结晶相稀土氧化物的质量分数。经资料整理,黏土层、全风化层、半风化层、弱风化层中的稀土数值有明显差异。造成稀土数值差异的主要原因为:成矿母岩的风化程度,稀土矿物离解程度,离子相稀土氧化物的迁移富集程度。加强稀土数值的研究,有助于深化风化壳离子吸附型稀土矿的成矿机理认识。 相似文献
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稀土分析检测方法标准述评 总被引:2,自引:0,他引:2
从稀土矿、稀土精矿、稀土金属及其氧化物、稀土深加工产品等方面概述我国稀土分析国家标准体系.其中稀土配分、三氧化二铝、稀土总量、水分、灼减量等参数的检测,是稀土交易和萃取分离工艺过程中重要的技术指标;而钕铁硼、灯用稀土三基色荧光粉、稀土硅铁合金等分析标准,对于稀土磁性材料、稀土发光材料、稀土合金等稀土深加工产品的生产都有重要的指导意义;稀土产品及分析方法的建立,完善了稀土国家标准体系,满足了稀土生产和贸易的需要,促进了稀土行业持续健康发展. 相似文献
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稀土出口价格和稀土储备是稀土研究的两个重要问题.从稀土的应用价值、相对稀缺性、生产的环境代价以及稀土供给的垄断特征,分析我国稀土出口应该有一个比较高的价格;从供求关系、市场结构、储备特征、储备对需求弹性和供给弹性的影响,分析储备对稀土出口价格的影响方向和影响效果;从储备的作用和稀土产业的未来发展目标,提出稀土储备的主要目的和方式.研究结果表明:稀土出口所形成的市场结构使我们丧失了稀土出口的议价能力;稀土国家储备在短期会对稀土出口价格提升产生一定的效果,但长期效果有限;稀土储备的主要目的应该是促进稀土应用产业的发展,并以稀土原矿(稀土资源)储备为主. 相似文献
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Since the discovery of the carbonatitedykes at Bayan Oho of inner Mongolia, Chi..[l], more and more evidence from geologicaland geochemical investigations reveal that theore-hosted dolomite marble of the Bayan OboRE-Nb-Fe giant mineral deposit is similar tocarbonatite in origin['~7]. Although it is notfully clear at present whether there is a realpetrogenetic linkage between the formation ofthe ore deposit and the intrusion of the carbonatite dykes, there is no doubt that the studiesof the … 相似文献
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高岭土精矿具有粒度细、黏度大、渗透性能差、固液分离难、含铝高等特点,南方高岭土常伴有稀土,怎样从精矿中提取合格的稀土,目前国内外还没有一套成熟的工艺技术应用于工业生产上。依据高岭土矿中的稀土赋存特点,通过实验室小试、扩试和工业试验,探索出了一套成熟的工艺技术流程,把浸矿液与高岭土精矿加入到捣浆池中进行搅拌浸取,将矿浆通过板框压滤机压滤,得到的滤饼即是提取稀土后的高岭土精矿,滤液经后续处理即得到稀土产品。同时建成了生产线,已生产稀土10余t,为回收高岭土精矿中的离子型稀土提供了有效工艺。 相似文献