Composite silver electrode for double‐sided‐emitting stacked organic light‐emitting diode

Abstract— A reflective composite silver electrode is proposed and characterized as the middle electrode of a stacked organic light‐emitting diode (OLED) with double‐sided light emission. The proposed electrode is composed of a thermally evaporated stack of LiF (1 nm)/Al (3 nm)/Ag (70 nm) layers. The LiF/Al and the plasma‐treated Ag of the electrode function well as the respective cathode and anode of the bottom‐ and top‐emitting stacked OLEDs, with both being of the non‐inverted type. Power efficiencies of 10.3 and 12.1 lm/W at 100 cd/m² have been measured for bottom‐ and top‐emitting OLEDs, respectively, using dye doping. The stacked OLED having this bipolar middle electrode can be constructed as a two‐terminal‐only device, allowing for simpler driving schemes in double‐side‐emitting passive‐/active‐matrix OLED displays.     

Analyzing and tuning emission characteristics of top‐emitting organic light‐emitting devices

Abstract— Top‐emitting organic light‐emitting devices (OLEDs) have several technical merits for application in active‐matrix OLED displays. Generally, stronger microcavity effects inherent with top‐emitting OLEDs, however, complicate the optimization of device efficiency and other viewing characteristics, such as color and viewing‐angle characteristics. In this paper, using the rigorous classical electromagnetic model based on oscillating electric dipoles embedded in layered structures, the emission characteristics of top‐emitting OLEDs as a function of device structures will be analyzed. From comprehensive analysis, trends in the dependence of ewmission characteristics on device structures were extracted, and, accordingly, a general methodology for optimizing viewing characteristics of top‐emitting OLEDs for display applications will be suggested. The effectiveness of the analysis and the methodology was confirmed by experimental results.     

White‐emitting OLED devices in an RGBW format with microelement white subpixels

Abstract— OLED devices with an RGBW pixel format using an unpatterned white emitter have the potential to provide very good efficiency and color gamut while enabling lower‐cost and large‐format manufacturing. However, the white subpixel often has unacceptably large color shifts with viewing angle. Furthermore, for some architectures such as top‐emitting microcavity devices, it can even be difficult to produce a white subpixel with good on‐axis color. In this paper, we describe the use of a white subpixel made up of a combination of differently tuned microelements and demonstrate how such an approach can overcome these problems. By carefully tuning the color and areas of each of the microelements in the white subpixel, we can trade off between better on‐axis color, less color change with angle, and higher efficiency. Furthermore, it was demonstrated that an RGBW top‐emitter microcavity device with a microelement white subpixel can achieve an increase in both power efficiency and color gamut relative to a conventional RGBW bottom‐emitter non‐microcavity device.     

Microcavity white‐emitting OLED devices

Abstract— Microcavity designs for OLED devices with an unpatterned white emitter have the potential to provide greater brightness and larger color gamut than non‐microcavity designs while still enabling lower‐cost large‐format manufacturing. In this paper, such microcavity and non‐microcavity designs are compared. Color filters must still be employed to provide an adequate color gamut. Top‐emitter structures have somewhat greater on‐axis luminance and color gamut, but increased angular change, than bottom‐emitter designs. In a single‐stack bottom‐emitter active‐matrix TFT device using an RGBW format, the use of microcavities is estimated to reduce the average power usage by 35% and the peak power by 58%, while increasing the NTSC ratio for color gamut area by about 10%. Angular luminance and color change is likely to be acceptable, especially for hand‐held applications. Tandem devices employing multiple emitter stacks increase the lifetime of OLED devices but require larger driving voltages; for such devices, microcavity structures are useful although the percentage reduction obtained in power usage is not quite as large. Generally, tandem devices with microcavities have a slightly stronger cavity effect yielding slightly larger color gamut, but also greater angular color and luminance shift. Therefore, microcavity architectures are less appealing for tandem devices.     

Flexible inverted bottom‐emitting organic light‐emitting devices with a semi‐transparent metal‐assisted electron‐injection layer

Abstract— The development of highly efficient and color‐saturated green‐fluorescent C545T dye‐doped flexible inverted bottom‐emitting organic light‐emitting diode (IBOLED) is reported. This was enabled by the insertion of a silver (Ag) based semi‐transparent metal‐assisted electron‐injection layer between the ITO cathode and n‐doped electron‐transporting layer on a flexible polyethersulphone substrate. This flexible IBOLED with an ITO/Ag bilayer cathode with its synergistic microcavity effect achieved luminous efficiencies of 20.4 cd/A and 12 lm/W and a saturated CIE^x,y of (0.28, 0.68) at 20 mA/cm², which are 1.5 times higher than those of a conventional OLED.     

Highly transparent and conductive CdO thin films as anodes for organic light‐emitting diodes: Film microstructure and morphology effects on performance

Abstract— Highly conductive and transparent CdO thin films have been grown on glass and on single‐crystal MgO(100) by MOCVD at 400°C and were used as transparent anodes for fabricating small‐molecule organic‐light emitting diodes (OLEDs). Device response and applications potential have been investigated and compared with those of control devices based on commercial ITO anodes. It is demonstrated that highly conductive CdO thin films of proper morphology can efficiently inject holes into such devices, rendering them promising anode materials for OLEDs. Importantly, this work also suggests the feasibility of employing other CdO‐based TCOs as anodes for high‐performance OLEDs.     

Optical characteristics of tandem and microcavity tandem organic light‐emitting devices

Abstract— In pursuit of the further enhancement of the luminance and efficiency of organic light‐emitting devices (OLEDs), it is worthy of exploring what benefits could be obtained by combining two luminance‐enhancement techniques, i.e., microcavity and tandem OLEDs. Furthermore, a deeper understanding of the optics in tandem OLEDs will be useful for the design and optimization of tandem OLEDs. In this paper, the optical characteristics of noncavity and microcavity tandem OLEDs are theoretically and experimentally investigated. By the use of rigorous electromagnetic modeling of OLEDs, the radiation characteristics of tandem OLEDs as a function of device structures are analyzed and correspondingly, the guidelines for optimizing the performance of tandem devices are suggested. By making use of the analytical results, it is shown that with well‐designed microcavity conditions and device structures, a five‐fold enhancement in luminance in the normal direction can be achieved with cavity‐tandem devices having only two emitting units. A very high efficiency of 200 cd/A for a rather broad brightness range of 100–4000 nits is demonstrated with a phosphorescent cavity two‐unit device.     

Improved performance of organic light‐emitting devices with ultra‐thin hole‐blocking layers

Abstract— Tris‐(8‐hydroxyqunoline) aluminum (Alq₃)‐based organic light‐emitting devices (OLEDs) using different thickness of 2,9‐Dimethyl‐4,7‐diphenyl‐1,110‐phenanthorline (BCP) as a hole‐blocking layer inserted both in the electron‐ and hole‐transport layers have been fabricated. The devices have a configuration of indium tin oxide (ITO)/m‐MTDATA (80 nm)/BCP (X nm)/NPB (20 nm)/Alq₃ (40 nm)/BCP (X nm)/Alq₃ (60 nm)/Mg: Ag (200 nm), where m‐MTDATA is 4, 4′, 4″‐Tris(N‐3‐methylphenyl‐N‐phenyl‐amino) triphenylamine, which is used to improve hole injection and NPB is N,N′‐Di(naphth‐2‐yl)‐N,N′‐diphenyl‐benzidine. X varies between 0 and 2 nm. For a device with an optimal thickness of 1‐nm BCP, the current and power efficiencies were significantly improved by 47% and 43%, respectively, compared to that of a standard device without a BCP layer. The improved efficiencies are due to a good balance between the electron and hole injection, exciton formation, and confinement within the luminescent region. Based on the optimal device mentioned above, the NPB layer thickness influences the properties of the OLEDs.     

The role of LiF buffer layer in tris‐(8‐hydroxyquinoline) aluminum‐based organic light‐emitting devices with Mg:Ag cathode

Abstract— The device characteristics of organic light‐emitting devices based on tris‐(8‐hydroxyqunoline) aluminum with a thin layer of LiF inserted at the ITO and organic interface or organic and Mg:Ag cathode interface were investigated. A thin layer of LiF can enhance the electron injection when it was inserted only between the organic electron‐transporting layer and the Mg:Ag alloy cathode, but can block hole injection when inserted between the ITO anode and the organic hole‐transport layer. By inserting both a 1.0‐nm LiF layer at side of the ITO anode and a 0.5‐nm LiF layer under the Mg:Ag cathode, the device, at a current injection of 10 mA/cm², exhibited the highest current efficiency of 8.2 cd/A and power efficiency of 1.93 lm/W for all the types of devices investigated in this study. Both the current efficiency and power efficiency of the device were improved by 1.2 times at a current injection of 10 mA/cm², compared to the standard device without any LiF buffer layer. This is due to the increased electron injection and decreased hole injection that off‐sets the imbalance of electron and hole injection and brings it towards the balanced injection of electrons and holes, thus reducing the non‐productive hole current.     

Eliminate angular color shift in top‐emitting OLEDs through cavity design

OLEDs suffer from viewing angle dependent spectral shift due to microcavity effects. To address this issue, we introduce a novel top‐emitting OLED with a dielectric spacer that forms multiple cavity modes. The resulting device shows almost no color shift at different viewing angles.     

Luminous‐efficiency improvement of solar‐cell‐integrated high‐contrast organic light‐emitting diode by applying distributed Bragg reflector

Abstract— Solar‐cell‐integrated organic light‐emitting diodes (OLEDs) were fabricated with both high contrast ratio and energy‐recycling ability. However, the luminous efficiency of the integrated devices is reduced to 50% of that of conventional top‐emitting OLEDs. A novel structure to recover the luminous efficiency from 50% to near 85% by applying a distributed Bragg reflector (DBR) made of 20 layers of GaN/AlN was demonstrated. It saves about 40% of the electric power than that of a device without a DBR. The contrast ratio remains high compared to that of conventional OLEDs. In this paper, simulations were conducted first to prove our models and assumptions. Then, two types of thin‐film solar cells — CdTe and CIGS solar cells — were used. They had different contrast ratios as well as viewing‐angle properties. Finally, the emission spectrum was calculated to be 11 nm FWHM, which is narrower than that for the emission spectrum of a typical microcavity OLED and has the advantage of having saturated colors.     

The effect of transmittance and luminous efficiency with the application of cathode mesh mask in transparent organic light‐emitting devices

With the development of organic light‐emitting devices (OLEDs), the transparent OLED is also restricted by its efficiency and stability. Thus, in order to improve the transmittance and luminous efficiency of transparent OLED, the cathode mesh mask combined with Al:Ag alloy is adopted to prepare the cathode of transparent OLED, which would enhanced the luminance, efficiency, and transmittance of the device. With the same driving voltage, the device has the highest brightness, when the cathode thickness is 85 nm. At the voltage of 13 and 14 V, the luminance, for bottom‐emission and top‐emission, is 9501 cd/m² and 1840 cd/m², respectively. The entire transmittance of the device has achieved about 78% at a 480 nm wavelength.     

Active‐matrix organic light‐emitting diode displays with indium gallium zinc oxide thin‐film transistors and normal,inverted, and transparent organic light‐emitting diodes

Abstract— Active‐matrix organic light‐emitting diode (AMOLED) displays have gained wide attention and are expected to dominate the flat‐panel‐display industry in the near future. However, organic light‐emitting devices have stringent demands on the driving transistors due to their current‐driving characteristics. In recent years, the oxide‐semiconductor‐based thin‐film transistors (oxide TFTs) have also been widely investigated due to their various benefits. In this paper, the development and performance of oxide TFTs will be discussed. Specifically, effects of back‐channel interface conditions on these devices will be investigated. The performance and bias stress stability of the oxide TFTs were improved by inserting a SiO^x protection layer and an N²O plasma treatment on the back‐channel interface. On the other hand, considering the n‐type nature of oxide TFTs, 2.4‐in. AMOLED displays with oxide TFTs and both normal and inverted OLEDs were developed and their reliability was studied. Results of the checkerboard stimuli tests show that the inverted OLEDs indeed have some advantages due to their suitable driving schemes. In addition, a novel 2.4‐in. transparent AMOLED display with a high transparency of 45% and high resolution of 166 ppi was also demonstrated using all the transparent or semi‐transparent materials, based on oxide‐TFT technologies.     

Passive‐matrix polymer light‐emitting displays

Abstract— Organic light‐emitting device research focuses on the use of small‐molecule and polymer materials to make organic electroluminescent displays, with both passive‐ and active‐matrix technologies. This paper will focus on the characteristics of red, green, and blue electroluminescent polymers suitable for fabricating monochrome and full‐color passive‐matrix displays. The stability of polymer OLEDs, and the use of ink‐jet printing for direct high‐resolution patterning of the light‐emitting polymers will also be discussed. It will be shown that the performance of light‐emitting polymers is at the brink of being acceptable for practical applications.     

Electrical characterization and modelling of top‐emitting PIN‐OLEDs

Abstract— Positively doped, intrinsic, negatively doped organic light‐emitting diodes (PIN‐OLEDs) have been shown to exhibit high efficiency and a long lifetime compared to conventional small‐molecule OLEDs (SM‐OLEDs). The improved performance of PIN‐OLEDs makes them attractive for use in display applications. Knowledge of the electrical load exhibited by these devices is used to develop an equivalent electrical‐circuit model. Such models are used by circuit designers to assist with the precise design of active‐matrix‐display driver circuits used in such applications. In this paper, the development of a SPICE model for a top‐emitting PIN‐OLED stack is reported.     

Light‐emitting polymers for full‐color display applications

The latest developments in light‐emitting‐polymer (LEP) technology at CDT continue to show steady progress. Device performance for blue, green, and red systems as well as a high‐performance yellow system in terms of device efficiency and stability will be described. Some of the issues associated with the commercialization of LEP technology including the development of direct‐patterning techniques enabling full‐color passive‐ and active‐matrix display will be discussed.     

Development of 1.5‐in. full‐color double‐sided active‐matrix OLED with novel array design

Abstract— A 1.5‐in. full‐color double‐sided AMOLED with a novel array design was fabricated. Different images on both sides of the panel can be controlled by using only one IC driver. High color gamuts of 67% and 81% on the bottom‐ and top‐emitting sides, respectively, were achieved. In addition, good performance on both sides, such as brightness and white balance, were also achieved.     

Device‐dependent angular luminance enhancement and optical responses of organic light‐emitting devices with a microlens‐array film

Abstract— By taking the organic emitter apodization calculated from electromagnetic theory as input, the angular luminance enhancement of organic light‐emitting devices (OLEDs) with a microlens‐array film (MAF) can be further evaluated by the ray‐tracing approach. First, the OLEDs of different Alq³ thickness are fabricated and their angular luminance measurements are compared to simulation results. Second, mode analyses for different layers are performed to estimate the enhancement potential of the MAF‐attached devices. Finally, by decreasing the Alq³ thickness, increasing the viewing angle, and attaching the MAF, the EL spectral peak shifts of the OLEDs seem irregular, but the spectral blue shifts induced by the optical structures are all explained by the optical responses (EL spectra divided by the intrinsic PL spectrum). In conclusion, the organic emitters with higher off‐axis‐angle luminous intensity cause lower out‐coupling efficiency but gain higher enhancement after the MAF is attached. With the choices of apodizations and microstructures, the tailored or customized angular radiation patterns can be also made possible.     

PIN‐OLEDs for active‐matrix‐display use

Abstract— Novaled's PIN‐OLED® technology allows for highly efficient, temperature stable, and long‐lived OLEDs suited for a variety of display applications. This paper delivers an overview about Novaled's state of the art, including top‐ and bottom‐emitting structures. It is discussed how PIN‐OLEDs give rise to an increased manufacturing yield. The main focus of this paper is the development of white OLEDs for display use. When the RGBW color‐filter approach is used in combination with white OLEDs, the resulting full‐color OLED display is able to deliver high color quality and remain highly power efficient. For such a case, the manufacturing infrastructure of OLEDs for lighting can be used. We use tandem architectures, bottom‐ and top‐emission architectures, and developed specific high‐temperature stable OLED stacks. The importance of matching color coordinates of the white OLED and the targeted display white color point is of outstanding importance. Results have mainly been achieved under the German‐funded project CARO and the European‐funded project AMAZOLED.     

Transflective device with a transparent organic light‐emitting diode and a reflective liquid‐crystal device

Abstract— A high‐transmittance transflective device based on a hybrid structure consisting of a transparent organic light‐emitting diode (OLED) stacked on top of a reflective liquid‐crystal device (RLCD) was conceptually demonstrated. By placing the transparent OLED on top of a vertically aligned LCD operated under normally black mode, a transmittance as high as 75.7% was obtained due to the asymmetric emission characteristics of a transparent OLED. To further improve the performance in the transmissive mode, a polarizer‐free LCD was used, which yielded an ultra‐high transmittance (82.2% overall).