Optical properties of composite heterophase objects with liquid crystal material for different display applications

Liquid crystal (LC) director distribution and optical transmission for different types of heterophase systems with different LC boundary conditions is simulated. The first type is a transparent isotropic material with spherical or cylindrical liquid crystalline objects. There are polymer dispersed liquid crystal, LC fiber, lyotropic LC in polarizing films, LC in microgroove and nanogrooves and pores. The second type is an LC layer incorporating an isotropic transparent or non‐transparent object like microparticles and nanoparticles, spacers, protrusions in multi‐domain vertical alignment LC display et al. The system parameters' influence on LC display performances is discussed.     

Plasma‐beam alignment of passive liquid crystals (Invited Paper)

Abstract— A plasma‐beam process, developed for the alignment of liquid crystals (LC) in electro‐optic applications, has been successfully applied to align “non‐standard” LC, such as crystalline materials with LC phases at elevated temperatures and reactive mesogenes. In addition to the high alignment quality of the materials, there is no need for an intermediate layer between the substrate and the LC layer. Furthermore, the construction of our source simplifies the alignment procedure of large‐area rigid substrates and the roll‐to‐roll processing of flexible films. This method opens new horizons for optical retarders and polarizers, as well as anisotropic semiconducting films for organic electronics.     

Review of viewing‐angle compensation of TN‐mode LCDs using WV film

Abstract— Wide‐view (WV) films for TN‐mode LCDs, which optimize the optical parameters of the polymerized discotic material (PDM) layer and cellulose triacetate (CTA) have been developed. The development concept of the WV film and realization of its concept in the past and for the future will be reviewed. In particular, the discotic molecular alignment control enabled the improvement of the contrast ratio at oblique viewing angles of TN‐mode LCDs. In addition, color shifts at oblique angles are important for large‐screen TN‐mode LCD monitors and LCD‐TV sets. To improve the color‐shift problem, new technologies have been developed.     

DIMOS — a software tool for optimizing display systems with LCDS

The Display Modelling System (DIMOS) is a software tool that was developed to evaluate the electro-elastic, electro-optic and colorimetric properties of display systems with liquid-crystal cells. DIMOS enables the user to perform a numerical analysis of the complex interdependencies between the numerous physical parameters of such display systems and the relevant output quantities. These must be known in order to optimize information content (multiplexability) and visibility of display systems with liquid-crystal cells. The structure and organisation of DIMOS is explained with special emphasis on the definition of dichroic dyes, polarizers and birefringence dispersion of LC materials. An overview is given of the numerical procedures used for the evaluation of the field-induced deformation and the optical properties of arbitrary chiral-nematic LC-configurations. The applicability of DIMOS to the optimization of supertwisted LCDs is shown in an example.     

Deformed nanostructure of photo‐induced biaxial cholesteric films and their application in VA‐mode LCDs

Abstract— Novel biaxial retardation films made from photo‐induced deformed cholesteric liquid‐crystal (LC) nanostructures using reactive mesogen mixtures (RMMs) for a viewing‐angle compensation of vertically aligned liquid‐crystal displays (VA‐LCDs) was developed. The deformed cholesteric LC nanostructure has been observed by X‐ray‐diffraction (XRD) measurement. The birefringence of the film was described well by our optical model based on a form birefringence theory. The VA‐LCDs with photo‐induced biaxial cholesteric films have excellent viewing‐angle properties.     

Optical properties of solvent‐cast polarizer films for liquid‐crystal displays: A viscoelastic modeling framework

Abstract— Many of the films used in polarizer assemblies in LCDs (e.g., triacetyl cellulose or TAC) are produced by a solvent‐casting process, which is known to impart optical anisotropy to the film expressed as finite out‐of‐plane birefringence. This feature of the film could have a significant impact on the optical performance of the display and it needs to be accounted for in any compensation scheme for the LC cell. This paper reviews the origin of this optical anisotropy, and it presents a viscoelastic model that links this property to the solvent‐casting process and to some key material parameters. The model results are compared with experimental data generated for polystyrene films cast from toluene, and generally good agreement is demonstrated.     

New measuring method for determining alignment parameters in twisted‐nematic and super‐twisted‐nematic cells

Abstract— A new method for determining the thickness, twist angle, and azimuth of the director for a substrate with twisted‐nematic (TN) and super‐twisted‐nematic (STN) liquid‐crystal (LC) cells has been proposed. The measurement was carried out by using an optical system which consisted of a monochromatic light source, polarizer, rotating analyzer, and software programs. The polarization transfer matrix, or Jones matrix, of a TN or an STN LC cell is formulated by the Fourier coefficient of the signal that is modulated by the rotating analyzer. These three alignment parameters are derived directly from components of the Jones matrix. We made a special effort to design the system to ensure accurate, stable, and quick measurement. Thus, the three parameters were determined simultaneously within a few seconds with good reproducibility; e.g., the standard deviation of the twist angle in the TN cell is 0.02° or less.     

Aggregate‐induced emission in light‐emitting liquid crystal display technology

Nowadays, liquid crystal displays (LCDs) with light‐emission are considered as energy‐efficient devices and are promising alternatives to conventional LCDs. To realize such possibility, strong fluorescent materials with a dichroic properties are required. Aggregate‐induced emission (AIE) is an unusual photophysical phenomenon shown by some luminogenic materials that will be highly emissive in their aggregate state. In this work, we studied the AIE effect of a luminescent liquid crystalline molecule TPE‐PPE in our LC system as a luminophore dopant. The result showed the excellent AIE effect that higher concentration of luminogen in the nematic LC host induced stronger luminescent intensity. Through exposure of a photoisomeriable alignment material sulfonic‐dye‐1, the photopatterning of a light‐emitting LC device was achieved with the use of the TPE‐PPE/nematic LC mixture.     

Liquid‐crystal mixtures having tolane substances for field‐sequential‐color TN‐LCDs

Novel liquid‐crystal (LC) mixtures featuring high optical anisotropy Δn) and small rotational viscosity (γ¹) were developed for field‐sequential‐color TN‐LCD applications. The dynamic behavior of the TN cells in a narrow‐gap range was studied and new tolane LC substances were introduced. The newly developed LC mixtures, having a narrow‐gap cell, enable a TN‐LCD to switch fast enough to be applied to field‐sequential‐color displays not only at a room temperature but also at low temperatures. It was also confirmed that the voltage‐holding ratio (VHR) is sufficiently high in field‐sequential addressing conditions and, therefore, the LC mixtures can be used in active‐matrix LCDs. For practical use, a storage test of the TN cells under light irradiation was performed to evaluate their voltage‐holding property. It was also confirmed that their high VHR can be maintained for over 10,000 hours under practical conditions.     

Effects of carbon‐nanotube doping on the performance of a TN‐LCD

Abstract— The electro‐optical characteristics of a 90° twisted‐nematic liquid‐crystal display (TN‐LCD) were analyzed. The test cell was composed of a minute amount of dopant, multiwalled carbon nanotubes, and a standard nematic mixture, E7, used in TN‐LCDs with direct addressing. Under the experimental conditions, no hystereses in optical transmittance were observed in either the doped cell or a neat counterpart under an applied ac voltage. Experimental results show that doping with nanotubes rectifies the electro‐optical properties of the cells by reducing the driving voltage as well as the rise time. Similar results were found in a TN cell of a TFT‐grade liquid crystal instead of the mixture consisting completely of polar compounds.     

Homeotropic alignment of liquid crystals on ITO surface using LBL assembly

In this work, the very thin layer‐by‐layer (LBL) film that was constructed by dip coating method on indium tin oxide surface can be used in liquid crystal (LC) displays devices. The obtained results indicate that the ultrathin LBL film shows the homeotropic alignment layer, and a uniform vertical alignment of LC molecules was gained very easily. The progress of vertical‐aligned LC cells with a LBL layer was evaluated. The obtained threshold voltage and response time of the LC cell were 2.472 V and 12.5 ms, respectively. So, the competitive performance of the LC cell could allow new sign at a low‐cost budget with rubbing process in LC display technology.     

Measuring and modeling per‐element angular visibility in multi‐view displays

Abstract— Multi‐view displays employ an optical layer which distributes the light of an underlying TFT‐LCD panel in different directions. Certain properties of the layer create specific artifacts, such as ghost images, moiré patterns, and masking. The layer was modeled as an image‐processing channel, and the display parameters related with the model were identified, which are importantfor the design of image‐processing algorithms for artifact mitigation. The identified parameters are interleaving pattern, angular visibility, and frequency throughput of the display. A methodology for deriving these parameters for an arbitrary LCD‐based multi‐view display are presented, which does not require precisely positioned measurement equipment. As a case study, measurement and modeling results for a particular multi‐view display are also presented.     

Parameters on the LC alignment of organosilicon compound films

Abstract— The aligning properties of a set of organosilicon compounds (OSC) were examined. The aligning films of the OSC were obtained. Pretilt angles and the polar and azimuthal anchoring energy of the LC materials on the OSC films were measured by optical and voltage‐capacity methods. The influence of both OSC and LC molecular structure on the results obtained was analyzed and discussed.     

Influence of alkyldiacrylate side‐chains on electro‐optical properties in liquid crystal/composite films

In order to realize a paper‐like display using polymer‐network liquid‐crystal (PNLC) films, an increase in backscattering intensity is required. The morphology of the films, and the molecular interactions between the liquid crystals and polymers forming the polymer network, both play an important role in determining film electro‐optical properties such as the driving voltage and the reflectance. We have analyzed several factors related to the morphology of the films. Aiming at a reduction in the driving voltage, the effects of alkyl side‐chains in diacrylates have been investigated. Based on the results, we successfully produced a prototype paper‐like display.     

High‐transmittance in‐plane‐switching liquid‐crystal displays using a positive‐dielectric‐anisotropy liquid crystal

Abstract— The in‐plane‐switching (IPS) mode exhibits an inherently wide viewing angle and has been widely used for liquid‐crystal‐display (LCD) TVs. However, its transmittance is limited to ～76% compared to that of a twisted‐nematic (TN) cell if a positive‐dielectric‐anisotropy LC is employed. A special electrode configuration that fuses the switching mechanism of the conventional IPS and the fringe‐field switching (FFS) to boost the transmittance to ～90% using a positive LC has been developed. The new mode exhibits an equally wide viewing angle as the IPS and FFS modes.     

Viewing‐angle enhancement in holographic reflective displays by nanoscale holographic patterning

Abstract— This work presents a method to increase the viewing angle of holographic polymer‐dispersed liquid‐crystal (H‐PDLC) reflective displays. One of the drawbacks to H‐PDLC technology is the existence of a narrow viewing angle. We present a way to alleviate this problem by structuring the phase front of the recording beams to increase the viewing cone of the display. Analysis of the diffractive properties of these holograms shows that the macroscopic and the nanoscale morphologies both play a role in the optical properties of the films.     

Method for fabrication of liquid‐crystal cells with narrow gap,fast switching,and flexible plastic substrates

Abstract— A phase‐separation method for the construction of devices with specific internal architecture of LC/polymer composite system is presented. The method results in adjacent uniform polymer and LC films parallel to the substrates. Scanning electron microscopy was employed to investigate the internal structures. The results show that the thicknesses of the LC and the polymer films in cells constructed with fixed‐size spacers directly depends on the LC/polymer in the initial mixture. This can be effectively used for precision cell‐gap control and to fine‐tune the LC optical path length. Cells with a submicrometer gap, prepared with this method and with 35 wt.% of LC in the mixture, exhibited a total response time approaching 1 msec. This method has also been used to fabricate devices with plastic substrates.     

Pixel‐isolated liquid‐crystal mode by using a patterned anisotropic phase separation for flexible LCDs

Abstract— A pixel‐isolated liquid‐crystal (PILC) mode for enhancing the mechanical stability of flexible‐display applications is proposed. Because liquid‐crystal (LC) molecules in this mode are isolated in each pixel by patterned or phase‐separated microstructures, and the two substrates are tightly attached to each other by a solidified polymer layer, the LC alignment is stable against external pressure, and the cell gap of our structure is uniformly preserved against bending deformation of the plastic substrates. The mechanical stability of the PILC structure having plastic substrates was tested for its electro‐optic properties.     

A single‐substrate multicolor cholesteric liquid‐crystal display prepared through ink‐jet printing

Abstract— Ink‐jet printing was used to prepare a single‐substrate multicolor cholesteric liquid‐crystal (Ch‐LC) display incorporating three Ch‐LCs exhibiting different reflective wavelengths. A room‐temperature low‐vacuum chemical‐vapor‐deposition process was developed for coating a thin polymer film onto the Ch‐LC so that the top electrode could be coated onto the Ch‐LC layer. Herein, the successful operation of such a 10.4‐in. QVGA Ch‐LC display at 40 V will be described.     

Transflective twisted‐nematic liquid‐crystal display with double twisted‐nematic cell and twisted liquid‐crystal retarder

Abstract— Two configurations, (i) a double‐cell‐gap twisted nematic (DTN) liquid‐crystal display (LCD) and (ii) a single‐cell‐gap twisted‐nematic (TN) liquid‐crystal display (LCD) using a twisted LC retarder, were optimized for transflective liquid‐crystal displays. For the DTN configuration, both the single‐cell‐gap approach and the double‐cell‐gap approach were considered. The optimized configurations exhibit a high contrast ratio, wide viewing angles, and achromatic (black/white) switching in both the transmissive and reflective modes. They are easy to fabricate and also possess a perfect dark state. Both are suitable for high‐quality transflective TFT‐LCDs.