共查询到19条相似文献,搜索用时 93 毫秒
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本发明涉及一种用于金属材料、例如钢材或镀锌钢材的含水磷酸锌化学转化处理液,以及磷酸锌化学转化处理金属材料的方法,更具体讲,本发明涉及一种含水磷酸锌化学转化处理液及用于金属材料的方法,它可均匀地形成包括很细的化学转化晶体的致密磷酸锌化学转化层,它的优点是使化学转化层对油漆或大漆表现出增强的粘合力。 相似文献
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《无机盐工业》2006,38(9):12-12
磷酸锌是一种性能优良的新型无毒防锈颜料,应用于涂料工业,可配制各种防锈漆,可代替红丹作防锈底漆,代替含铅基料作各类涂料、漆类的基料使用,还可用于钢材的磷化处理,以及医学行业等。目前,中国厂家生产磷酸锌一般采用直接法。介绍一种磷酸锌的新生产方法。该方法引入了间接的生产方法,放宽了原料的质量要求,大大降低了磷酸锌的生产成本。方法如下:将低品位氧化锌加入到R溶剂中,溶解、过滤、精制后与磷酸反应,并用烧碱调其pH,制得磷酸锌精浆,分离、洗涤、干燥后得到成品磷酸锌。滤液与氟硅酸反应使R溶剂再生循环使用,并得到副产物氟硅酸钠。该方法将原直接法生产磷酸锌的固-液反应,改为液-液反应,从而缩短了反应时间。 相似文献
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防锈颜料磷酸锌生产工艺改进梁伟光,解志远(河北省石油化工研究所石家庄市050031)防锈颜料磷酸锌用于配制各种底漆和防腐涂料,也可作为牙科的印膜材料。有一磷酸锌生产厂存在工艺不合理、产品质量不合格、收率低等问题。我们受厂家委托,对其生产工艺进行了改进... 相似文献
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底面合一的水性带锈防锈漆 总被引:6,自引:0,他引:6
采用纯丙及苯丙复合乳液为基料,三聚磷酸铝,磷酸锌,氧化锌,滑石粉,硫酸钡等为颜填料制备底面合一的水性带锈防锈漆,介绍乳液及其漆的生产方法及施工方法。 相似文献
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提出了一种将铝离子引入磷酸锌结构的方法。使用正交试验分析及粒径分布分析,优选出最优的反应条件参数,获得收率为 95.3%、中值粒径 d(0.5)为 1.529 μm的磷酸锌铝;使用硅烷偶联剂改性的磷酸锌铝颗粒微细、大小均匀。将改性磷酸锌铝制成水性环氧底漆与水性丙烯酸防锈漆
并进行耐盐雾及贮存性测试,结果表明:改性磷酸锌铝比磷酸锌表现出更好的抑泡性能与防锈性能;探讨了磷酸锌铝的防锈机理,推测磷酸锌铝与金属基材表面形成了电化学抑制 -物理隔绝的综合防腐蚀体系。获得的磷酸锌铝产物在水性防锈涂料中具备较好的使用前景。 相似文献
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C. Kavitha T. S. N. Sankara Narayanan K. Ravichandran Il Song Park Min Ho Lee 《Journal of Coatings Technology and Research》2014,11(3):431-442
The present work aims at the development of an energy-efficient and eco-friendly approach for the deposition of zinc phosphate coatings on steel. The study describes the possibility of preparing zinc–zinc phosphate composite coatings by cathodic electrochemical treatment using dilute phosphoric acid as an electrolyte and zinc as an anode. The methodology enables the preparation of coatings with different proportions of zinc and zinc phosphate by suitably varying the applied current density, pH, and treatment time. Adhesion of the coating on mild steel and adhesion of paint film on the phosphate coating were found to be good. The surface morphology of the coatings exhibited platelet-type features and small white crystals (agglomerated at some places) which represented zinc and zinc phosphate, respectively. An increase in current density (from 20 to 50 mA/cm2) increased the size of the zinc crystals, and coatings prepared at 40 and 50 mA/cm2 resembled that of electrodeposited zinc. Since the proportions of zinc and zinc phosphate could be varied with applied current density, pH, and treatment time, it would be possible to use this methodology to prepare coatings that would offer different degrees of corrosion protection. 相似文献
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The corrosion mechanisms and the inhibiting effect of sodium phosphate at cut edges on galvanized steel was studied by potentiodynamic polarization, EIS and monitoring of local ionic currents made by means of the scanning vibrating electrode technique (SVET). Assessment of zinc and of iron single electrodes was also made for comparison.In the absence of phosphate, corrosion of electrogalvanized steel at the cut edge is cathodically inhibited by the precipitation of zinc corrosion products over the steel surface. Mapping of the ionic currents revealed that the cathodic area becomes laterally shifted away from the anode as zinc corrosion products precipitate along parallel lines that are dictated by the location of the maximum cathodic currents. Sodium phosphate revealed inhibiting properties on the cut edge by precipitation of zinc phosphate, in the form of gel-like zinc phosphate clusters. Estimated inhibiting efficiencies for the cut edge were slightly above 80%. 相似文献
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G. Blustein M. C. Dey�� R. Romagnoli A. R. Di Sarli B. del Amo 《Journal of Coatings Technology and Research》2011,8(2):171-181
The purpose of this investigation was focused on reducing the content of zinc phosphate in anticorrosive paints by means of
the incorporation of low quantities of selected soluble corrosion inhibitors. The article describes the anticorrosive behavior
of alkyd paints containing reduced levels of zinc phosphate, zinc oxide, and some soluble compounds used as additives (e.g.,
sodium polyphosphate, sodium phosphate, and sodium benzoate). Anticorrosive solventborne alkyd paints were formulated with
a zinc phosphate content of 10% by volume (v/v) with respect to the total pigment concentration. In all cases, the PVC/CPVC
(pigment volume concentration/critical pigment volume concentration) ratio was 0.8. Experimental paints, applied on sandblasted
SAE 1010 panels, were evaluated by accelerated tests (salt spray cabinet) and electrochemical measurements (electrochemical
impedance spectroscopy, EIS). The results show that the additions of small amounts of soluble corrosion inhibitors to low
content zinc phosphate paint formulations enhance their performance in a very remarkable way. Perhaps, the most outstanding
feature is that the employment of soluble additives allowed the reduction of the zinc phosphate content with concomitant savings. 相似文献
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The inhibition efficiencies of zinc chromate, barium metaborate, calcium silicate, amino carboxylate, calcium barium phosphosilicate, aluminum triphosphate and a modified zinc phosphate on the corrosion of steel and zinc were determined by polarization experiments on pigment extracts. Zinc phosphate and zinc chromate were the best and were studied further to determine the effect of pH and chloride concentration on their inhibition of steel. Zinc chromate is adversely affected by high concentration of chloride ions, which effect seems to be less pronounced on zinc. A low pH, although increasing the solubility of zinc phosphate, does not increase its efficiency. The pigments were also incorporated into an epoxy-poly(amide) binder, applied to cold-rolled steel and galvanized steel, exposed at a marine exposure station and the degradation monitored by electrochemical impedance spectroscopy. There was a general correlation between the results of pigment extract studies and atmospheric exposure except in the case of phosphate pigments on cold rolled steel. 相似文献